m-c < onitroy mills landfill superfund site, troy, new hampshire tier ii organic data validation...
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SDMS DocID 000234888
Metcalf amp Eddy 701 rdmgtlaquoiKM nmigt Wlkehild MA 01 HBO
036200100006000005 M -a 1-241 ^oo ri ~HI-24S-(gtJ1 H v m-c lt oni
February 24 2005
Christine Clark Regional Sample Control Center US EPA Region I 11 Technology Drive North Chelmsford Massachusetts 01863-2431
Re Work Assignment No 160-RICO-019M Case 0251M SDG D05939 Woods Hole Group Environmental Laboratories Raynham Massachusetts Troy Mills Landfill Superfund Site Troy New Hampshire Tier II Organic Data Validation
Semivolatiles
9Soils D05945 DOS946 D05947 D05948 DOS949 D05950 D05951 D05952 D05953 (Field Duplicate Pairs D05947D05953) 1Aqueous Equipment Blank D05954 1Solid Performance Evaluation Sample D05939
Dear Ms Clark
A Tier II data validation was performed by Metcalf amp Eddy Inc (MampE) on the organic analytical data for nine soil samples (including one field duplicate) one equipment blank and one performance evaluation (PE) sample collected by MampE from the Troy Mills Landfill Superfund Site in Troy New Hampshire on December 14 and 15 2004 The samples were analyzed for semivolatile organic compounds (S VOCs) through the Response Action Contract (RAC) Delivery of Analytical Services (DAS) program using the DAS Specification for the Analysis of Low Concentration TCL Semivolatile Organic Compounds in Solid Samples Including Those with High Moisture Content (D-148) MampE evaluated these data using the Region I EPA-NE Data Validation Functional Guidelines for Evaluating Environmental Analyses December 1996 criteria modified as appropriate for the method
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim ltpd
AN A t ( () M (laquoMlgtm
Ms Christine Clark Page 2 February 24 2005 Case 0251M SDG D05939
The Tier II validation for the SVOC data was based on an evaluation of the following parameters
bull Overall Evaluation of Data and Potential Usability Issues Data Completeness (CSF Audit)
bull Preservation and Technical Holding Times bull GCMS Instrument Performance Checks
bull Initial and Continuing Calibrations bull Blanks
bull Surrogate Spike Recoveries bull Internal Standards
bull Matrix SpikeMatrix Spike Duplicate (MSMSD) bull Field Duplicates
bull Sensitivity Check bull PE Sample ResultsAccuracy Check
NA bull Target Compound Identification bull Sample Quantitation and Reported Quantitation Limits
Tentatively Identified Compounds NA bull Semivolatile Cleanup NA bull System Performance
- All quality control criteria were met for this parameter NA - Not applicable to the analytical method or to a Tier II validation
Note Worksheets are not included for parameters that have met criteria or for criteria that are not applicable to a Tier II data validation
Copies of the field logbook and field sampling notes for this sample delivery group (SDG) may be found as an attachment to Case 0251M SDG D05916 which was previously submitted to the EPA
The following information was used to generate the Data Validation Memorandum attachments
Table I Recommendation Summary Table - summarizes validation recommendations Table II Overall Evaluation of Data - summarizes site DQOs and potential usability issues Table III Tentatively Identified Compound Summary Data Summary Tables - summarizes accepted qualified and rejected data
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 3 February 24 2005 Case 0251M SDG D05939
Overall Evaluation of Data and Potential Usability Issues
The following is a summary of the site DQOs (Data Quality Objectives)
bull To determine the nature and extent of contamination following the completion of two removal actions in order to perform human health and ecological risk assessments and thereby recommend a remedy to eliminate reduce or control risks to human health and the environment
The sample data were qualified as a result of sampling and analytical error Qualifications as a result of sampling error are summarized below
The positive results for benzaldehyde in soil samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in soil sample D05951 were flagged EB due to equipment blank contamination The end data user should consider that an indeterminate amount of sampling error may have affected these sample results The results are usable for project objectives These qualifications have a minor impact on data usability
Qualifications as a result of analytical error are summarized below
bull The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (J and UJ respectively) due to the percent relative standard deviation (RSD) exceedances in the initial calibration All results are usable for project objectives as estimated values and as nondetect results with estimated quantitation limits These qualifications have a minor impact on data usability
bull The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948 D05949 and D05953 for hexachlorocyclopentadiene in samples D05954 D05948 D05949 and D05953 and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to the percent difference (D) exceedances in the continuing calibrations These results are usable for project objectives as estimated values and as nondetect results with estimated quantitation limits These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_socsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 4 February 24 2005 Case 0251M SDG D05939
bull The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration This result is usable for project objective as an estimated value Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration These results are usable for project objectives as estimated values Note that the di-nshybutylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as nondetect (U) at the reported value due to method blank contamination This result is usable for project objectives as a nondetect Note that this result was also qualified as estimated (J) due to calibration nonconformances and high recoveries in the low-level and high-level laboratory fortified blanks (LFBs) Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for bis(2-ethylhexyl)phthalate in equipment blank sample D05954 was qualified as nondetect (U) at the quantitation limit (QL) due to method blank contamination This result is usable for project objectives as a nondetect This qualification has a minor impact on data usability
bull The positive results for di-n-butylphthalate in all soil samples were qualified as nondetect (U) at the reported values due to method blank contamination These results are usable for project objectives as nondetects Note that the di-nshybutylphthalate results in all soil samples were also qualified as estimated (J) due to calibration nonconformances high recoveries in the low-level and high-level LFBs andor ion abundance ratio exceedances Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive results for bis(2-ethylhexyl)phthalate in samples D05950 D05951 and D05952 were qualified as nondetect (U) at the QL due to performance evaluation sample contamination These results are usable for project objectives as nondetects These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DV MemossD05939_svocsim wpd MetcalfA Eddy Inc
Ms Christine Clark Page 5 February 24 2005 Case 0251M SDG D05939
bull The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (4 ugL)] due to low recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as a nondetect with a raised and estimated quantitation limit that may be biased low This qualification has a minor impact on data usability
bull The nondetect results for 4-nitrophenol 46-dinitro-2-methylphenol and pentachlorophenol in equipment blank sample D05954 were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as an estimated value that may be biased high Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The nondetect results for 24-dinitrophenol in all soil samples were qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (800 ugKg) and corrected for all preparation factors] due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with raised and estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 24-dimethylphenol 4-nitrophenol 46-dinitro-2shymethylphenol pentachlorophenol and 33-dichlorobenzidine in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that maybe biased low These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfiMData VahdationDecember 2004DV MemossD05939_svocsm pd Metcalfamp Eddy Inc
Ms Christine Clark Page 6 February 24 2005 Case 0251M SDG D05939
The positive results for di-n-butylphthalate in all soil samples were qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as estimated values that maybe biased high Note that the di-n-butylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to high recovery in the high-level LFB analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) due to the low recovery in the laboratory control sample (LCS) analysis This result is usable for project objectives as a nondetect with an estimated quantitation limit that may be biased low These qualifications have a minor impact on data usability
The nondetect results for benzaldehyde and 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the LCS analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene benzo(a)pyrene and indeno(l23shycd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to the high recoveries in the LCS analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
JNEWAI60 Troy Mills LandfillData ValidationDecember 2004DV MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 7 February 24 2005 Case 0251M SDG D05939
bull The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria These results are usable for project objectives as estimated values Note that the results for di-n-butylphthalate in samples D05950 D05951 D05952 D05945 D05947 D05948 D05949 and D05953 were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
D05950 di-n-butylphthalate D05951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate DOS 95 3 di-n-butylphthalate
Data Completeness (CSF Audit)
The following information was missing or incorrect in the data package This missing or incorrect information was requested from the laboratory on February 7 and 152005 A resubmittal response was received at MampE on February 18 2005 adequately addressing these issues
bull The method detection limit (MDL) study results for two selected ion monitoring (SIM) compounds (pentachlorophenol and di-n-butylphthalate) were missing from the data package
The Form I (TIC) for sample D05946 identified the TIC at 1246 as alphashycaryophyllene while the raw data reported this TIC as l6-octadien-3-ol 37shydimethyl- Clarification was requested
bull The Form I for sample D05949 reported 26-dinitrotoluene and fluoranthene while the quantitation report did not reflect these results The laboratory was asked to verify this discrepancy
bull A relative response factor for 46-dinitro-2-methylphenol was listed on the Form 6 for the initial calibration in association with the 05 ugml standard However this compound was not listed on the quantitation report in the raw data The laboratory was asked to verify this discrepancy
J NEWA16Q Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 2 February 24 2005 Case 0251M SDG D05939
The Tier II validation for the SVOC data was based on an evaluation of the following parameters
bull Overall Evaluation of Data and Potential Usability Issues Data Completeness (CSF Audit)
bull Preservation and Technical Holding Times bull GCMS Instrument Performance Checks
bull Initial and Continuing Calibrations bull Blanks
bull Surrogate Spike Recoveries bull Internal Standards
bull Matrix SpikeMatrix Spike Duplicate (MSMSD) bull Field Duplicates
bull Sensitivity Check bull PE Sample ResultsAccuracy Check
NA bull Target Compound Identification bull Sample Quantitation and Reported Quantitation Limits
Tentatively Identified Compounds NA bull Semivolatile Cleanup NA bull System Performance
- All quality control criteria were met for this parameter NA - Not applicable to the analytical method or to a Tier II validation
Note Worksheets are not included for parameters that have met criteria or for criteria that are not applicable to a Tier II data validation
Copies of the field logbook and field sampling notes for this sample delivery group (SDG) may be found as an attachment to Case 0251M SDG D05916 which was previously submitted to the EPA
The following information was used to generate the Data Validation Memorandum attachments
Table I Recommendation Summary Table - summarizes validation recommendations Table II Overall Evaluation of Data - summarizes site DQOs and potential usability issues Table III Tentatively Identified Compound Summary Data Summary Tables - summarizes accepted qualified and rejected data
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 3 February 24 2005 Case 0251M SDG D05939
Overall Evaluation of Data and Potential Usability Issues
The following is a summary of the site DQOs (Data Quality Objectives)
bull To determine the nature and extent of contamination following the completion of two removal actions in order to perform human health and ecological risk assessments and thereby recommend a remedy to eliminate reduce or control risks to human health and the environment
The sample data were qualified as a result of sampling and analytical error Qualifications as a result of sampling error are summarized below
The positive results for benzaldehyde in soil samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in soil sample D05951 were flagged EB due to equipment blank contamination The end data user should consider that an indeterminate amount of sampling error may have affected these sample results The results are usable for project objectives These qualifications have a minor impact on data usability
Qualifications as a result of analytical error are summarized below
bull The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (J and UJ respectively) due to the percent relative standard deviation (RSD) exceedances in the initial calibration All results are usable for project objectives as estimated values and as nondetect results with estimated quantitation limits These qualifications have a minor impact on data usability
bull The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948 D05949 and D05953 for hexachlorocyclopentadiene in samples D05954 D05948 D05949 and D05953 and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to the percent difference (D) exceedances in the continuing calibrations These results are usable for project objectives as estimated values and as nondetect results with estimated quantitation limits These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_socsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 4 February 24 2005 Case 0251M SDG D05939
bull The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration This result is usable for project objective as an estimated value Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration These results are usable for project objectives as estimated values Note that the di-nshybutylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as nondetect (U) at the reported value due to method blank contamination This result is usable for project objectives as a nondetect Note that this result was also qualified as estimated (J) due to calibration nonconformances and high recoveries in the low-level and high-level laboratory fortified blanks (LFBs) Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for bis(2-ethylhexyl)phthalate in equipment blank sample D05954 was qualified as nondetect (U) at the quantitation limit (QL) due to method blank contamination This result is usable for project objectives as a nondetect This qualification has a minor impact on data usability
bull The positive results for di-n-butylphthalate in all soil samples were qualified as nondetect (U) at the reported values due to method blank contamination These results are usable for project objectives as nondetects Note that the di-nshybutylphthalate results in all soil samples were also qualified as estimated (J) due to calibration nonconformances high recoveries in the low-level and high-level LFBs andor ion abundance ratio exceedances Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive results for bis(2-ethylhexyl)phthalate in samples D05950 D05951 and D05952 were qualified as nondetect (U) at the QL due to performance evaluation sample contamination These results are usable for project objectives as nondetects These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DV MemossD05939_svocsim wpd MetcalfA Eddy Inc
Ms Christine Clark Page 5 February 24 2005 Case 0251M SDG D05939
bull The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (4 ugL)] due to low recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as a nondetect with a raised and estimated quantitation limit that may be biased low This qualification has a minor impact on data usability
bull The nondetect results for 4-nitrophenol 46-dinitro-2-methylphenol and pentachlorophenol in equipment blank sample D05954 were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as an estimated value that may be biased high Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The nondetect results for 24-dinitrophenol in all soil samples were qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (800 ugKg) and corrected for all preparation factors] due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with raised and estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 24-dimethylphenol 4-nitrophenol 46-dinitro-2shymethylphenol pentachlorophenol and 33-dichlorobenzidine in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that maybe biased low These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfiMData VahdationDecember 2004DV MemossD05939_svocsm pd Metcalfamp Eddy Inc
Ms Christine Clark Page 6 February 24 2005 Case 0251M SDG D05939
The positive results for di-n-butylphthalate in all soil samples were qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as estimated values that maybe biased high Note that the di-n-butylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to high recovery in the high-level LFB analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) due to the low recovery in the laboratory control sample (LCS) analysis This result is usable for project objectives as a nondetect with an estimated quantitation limit that may be biased low These qualifications have a minor impact on data usability
The nondetect results for benzaldehyde and 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the LCS analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene benzo(a)pyrene and indeno(l23shycd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to the high recoveries in the LCS analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
JNEWAI60 Troy Mills LandfillData ValidationDecember 2004DV MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 7 February 24 2005 Case 0251M SDG D05939
bull The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria These results are usable for project objectives as estimated values Note that the results for di-n-butylphthalate in samples D05950 D05951 D05952 D05945 D05947 D05948 D05949 and D05953 were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
D05950 di-n-butylphthalate D05951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate DOS 95 3 di-n-butylphthalate
Data Completeness (CSF Audit)
The following information was missing or incorrect in the data package This missing or incorrect information was requested from the laboratory on February 7 and 152005 A resubmittal response was received at MampE on February 18 2005 adequately addressing these issues
bull The method detection limit (MDL) study results for two selected ion monitoring (SIM) compounds (pentachlorophenol and di-n-butylphthalate) were missing from the data package
The Form I (TIC) for sample D05946 identified the TIC at 1246 as alphashycaryophyllene while the raw data reported this TIC as l6-octadien-3-ol 37shydimethyl- Clarification was requested
bull The Form I for sample D05949 reported 26-dinitrotoluene and fluoranthene while the quantitation report did not reflect these results The laboratory was asked to verify this discrepancy
bull A relative response factor for 46-dinitro-2-methylphenol was listed on the Form 6 for the initial calibration in association with the 05 ugml standard However this compound was not listed on the quantitation report in the raw data The laboratory was asked to verify this discrepancy
J NEWA16Q Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 3 February 24 2005 Case 0251M SDG D05939
Overall Evaluation of Data and Potential Usability Issues
The following is a summary of the site DQOs (Data Quality Objectives)
bull To determine the nature and extent of contamination following the completion of two removal actions in order to perform human health and ecological risk assessments and thereby recommend a remedy to eliminate reduce or control risks to human health and the environment
The sample data were qualified as a result of sampling and analytical error Qualifications as a result of sampling error are summarized below
The positive results for benzaldehyde in soil samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in soil sample D05951 were flagged EB due to equipment blank contamination The end data user should consider that an indeterminate amount of sampling error may have affected these sample results The results are usable for project objectives These qualifications have a minor impact on data usability
Qualifications as a result of analytical error are summarized below
bull The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (J and UJ respectively) due to the percent relative standard deviation (RSD) exceedances in the initial calibration All results are usable for project objectives as estimated values and as nondetect results with estimated quantitation limits These qualifications have a minor impact on data usability
bull The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948 D05949 and D05953 for hexachlorocyclopentadiene in samples D05954 D05948 D05949 and D05953 and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to the percent difference (D) exceedances in the continuing calibrations These results are usable for project objectives as estimated values and as nondetect results with estimated quantitation limits These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_socsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 4 February 24 2005 Case 0251M SDG D05939
bull The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration This result is usable for project objective as an estimated value Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration These results are usable for project objectives as estimated values Note that the di-nshybutylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as nondetect (U) at the reported value due to method blank contamination This result is usable for project objectives as a nondetect Note that this result was also qualified as estimated (J) due to calibration nonconformances and high recoveries in the low-level and high-level laboratory fortified blanks (LFBs) Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for bis(2-ethylhexyl)phthalate in equipment blank sample D05954 was qualified as nondetect (U) at the quantitation limit (QL) due to method blank contamination This result is usable for project objectives as a nondetect This qualification has a minor impact on data usability
bull The positive results for di-n-butylphthalate in all soil samples were qualified as nondetect (U) at the reported values due to method blank contamination These results are usable for project objectives as nondetects Note that the di-nshybutylphthalate results in all soil samples were also qualified as estimated (J) due to calibration nonconformances high recoveries in the low-level and high-level LFBs andor ion abundance ratio exceedances Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive results for bis(2-ethylhexyl)phthalate in samples D05950 D05951 and D05952 were qualified as nondetect (U) at the QL due to performance evaluation sample contamination These results are usable for project objectives as nondetects These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DV MemossD05939_svocsim wpd MetcalfA Eddy Inc
Ms Christine Clark Page 5 February 24 2005 Case 0251M SDG D05939
bull The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (4 ugL)] due to low recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as a nondetect with a raised and estimated quantitation limit that may be biased low This qualification has a minor impact on data usability
bull The nondetect results for 4-nitrophenol 46-dinitro-2-methylphenol and pentachlorophenol in equipment blank sample D05954 were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as an estimated value that may be biased high Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The nondetect results for 24-dinitrophenol in all soil samples were qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (800 ugKg) and corrected for all preparation factors] due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with raised and estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 24-dimethylphenol 4-nitrophenol 46-dinitro-2shymethylphenol pentachlorophenol and 33-dichlorobenzidine in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that maybe biased low These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfiMData VahdationDecember 2004DV MemossD05939_svocsm pd Metcalfamp Eddy Inc
Ms Christine Clark Page 6 February 24 2005 Case 0251M SDG D05939
The positive results for di-n-butylphthalate in all soil samples were qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as estimated values that maybe biased high Note that the di-n-butylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to high recovery in the high-level LFB analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) due to the low recovery in the laboratory control sample (LCS) analysis This result is usable for project objectives as a nondetect with an estimated quantitation limit that may be biased low These qualifications have a minor impact on data usability
The nondetect results for benzaldehyde and 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the LCS analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene benzo(a)pyrene and indeno(l23shycd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to the high recoveries in the LCS analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
JNEWAI60 Troy Mills LandfillData ValidationDecember 2004DV MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 7 February 24 2005 Case 0251M SDG D05939
bull The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria These results are usable for project objectives as estimated values Note that the results for di-n-butylphthalate in samples D05950 D05951 D05952 D05945 D05947 D05948 D05949 and D05953 were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
D05950 di-n-butylphthalate D05951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate DOS 95 3 di-n-butylphthalate
Data Completeness (CSF Audit)
The following information was missing or incorrect in the data package This missing or incorrect information was requested from the laboratory on February 7 and 152005 A resubmittal response was received at MampE on February 18 2005 adequately addressing these issues
bull The method detection limit (MDL) study results for two selected ion monitoring (SIM) compounds (pentachlorophenol and di-n-butylphthalate) were missing from the data package
The Form I (TIC) for sample D05946 identified the TIC at 1246 as alphashycaryophyllene while the raw data reported this TIC as l6-octadien-3-ol 37shydimethyl- Clarification was requested
bull The Form I for sample D05949 reported 26-dinitrotoluene and fluoranthene while the quantitation report did not reflect these results The laboratory was asked to verify this discrepancy
bull A relative response factor for 46-dinitro-2-methylphenol was listed on the Form 6 for the initial calibration in association with the 05 ugml standard However this compound was not listed on the quantitation report in the raw data The laboratory was asked to verify this discrepancy
J NEWA16Q Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 4 February 24 2005 Case 0251M SDG D05939
bull The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration This result is usable for project objective as an estimated value Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration These results are usable for project objectives as estimated values Note that the di-nshybutylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as nondetect (U) at the reported value due to method blank contamination This result is usable for project objectives as a nondetect Note that this result was also qualified as estimated (J) due to calibration nonconformances and high recoveries in the low-level and high-level laboratory fortified blanks (LFBs) Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive result for bis(2-ethylhexyl)phthalate in equipment blank sample D05954 was qualified as nondetect (U) at the quantitation limit (QL) due to method blank contamination This result is usable for project objectives as a nondetect This qualification has a minor impact on data usability
bull The positive results for di-n-butylphthalate in all soil samples were qualified as nondetect (U) at the reported values due to method blank contamination These results are usable for project objectives as nondetects Note that the di-nshybutylphthalate results in all soil samples were also qualified as estimated (J) due to calibration nonconformances high recoveries in the low-level and high-level LFBs andor ion abundance ratio exceedances Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The positive results for bis(2-ethylhexyl)phthalate in samples D05950 D05951 and D05952 were qualified as nondetect (U) at the QL due to performance evaluation sample contamination These results are usable for project objectives as nondetects These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DV MemossD05939_svocsim wpd MetcalfA Eddy Inc
Ms Christine Clark Page 5 February 24 2005 Case 0251M SDG D05939
bull The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (4 ugL)] due to low recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as a nondetect with a raised and estimated quantitation limit that may be biased low This qualification has a minor impact on data usability
bull The nondetect results for 4-nitrophenol 46-dinitro-2-methylphenol and pentachlorophenol in equipment blank sample D05954 were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as an estimated value that may be biased high Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The nondetect results for 24-dinitrophenol in all soil samples were qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (800 ugKg) and corrected for all preparation factors] due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with raised and estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 24-dimethylphenol 4-nitrophenol 46-dinitro-2shymethylphenol pentachlorophenol and 33-dichlorobenzidine in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that maybe biased low These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfiMData VahdationDecember 2004DV MemossD05939_svocsm pd Metcalfamp Eddy Inc
Ms Christine Clark Page 6 February 24 2005 Case 0251M SDG D05939
The positive results for di-n-butylphthalate in all soil samples were qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as estimated values that maybe biased high Note that the di-n-butylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to high recovery in the high-level LFB analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) due to the low recovery in the laboratory control sample (LCS) analysis This result is usable for project objectives as a nondetect with an estimated quantitation limit that may be biased low These qualifications have a minor impact on data usability
The nondetect results for benzaldehyde and 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the LCS analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene benzo(a)pyrene and indeno(l23shycd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to the high recoveries in the LCS analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
JNEWAI60 Troy Mills LandfillData ValidationDecember 2004DV MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 7 February 24 2005 Case 0251M SDG D05939
bull The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria These results are usable for project objectives as estimated values Note that the results for di-n-butylphthalate in samples D05950 D05951 D05952 D05945 D05947 D05948 D05949 and D05953 were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
D05950 di-n-butylphthalate D05951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate DOS 95 3 di-n-butylphthalate
Data Completeness (CSF Audit)
The following information was missing or incorrect in the data package This missing or incorrect information was requested from the laboratory on February 7 and 152005 A resubmittal response was received at MampE on February 18 2005 adequately addressing these issues
bull The method detection limit (MDL) study results for two selected ion monitoring (SIM) compounds (pentachlorophenol and di-n-butylphthalate) were missing from the data package
The Form I (TIC) for sample D05946 identified the TIC at 1246 as alphashycaryophyllene while the raw data reported this TIC as l6-octadien-3-ol 37shydimethyl- Clarification was requested
bull The Form I for sample D05949 reported 26-dinitrotoluene and fluoranthene while the quantitation report did not reflect these results The laboratory was asked to verify this discrepancy
bull A relative response factor for 46-dinitro-2-methylphenol was listed on the Form 6 for the initial calibration in association with the 05 ugml standard However this compound was not listed on the quantitation report in the raw data The laboratory was asked to verify this discrepancy
J NEWA16Q Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 5 February 24 2005 Case 0251M SDG D05939
bull The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (4 ugL)] due to low recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as a nondetect with a raised and estimated quantitation limit that may be biased low This qualification has a minor impact on data usability
bull The nondetect results for 4-nitrophenol 46-dinitro-2-methylphenol and pentachlorophenol in equipment blank sample D05954 were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The positive result for di-n-butylphthalate in equipment blank sample D05954 was qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses This result is usable for project objectives as an estimated value that may be biased high Note that this result was also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for this result is estimated nondetect (UJ) These qualifications have a minor impact on data usability
bull The nondetect results for 24-dinitrophenol in all soil samples were qualified as estimated (UJ) at the raised quantitation limit [equivalent to the concentration of the high-level LFB (800 ugKg) and corrected for all preparation factors] due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with raised and estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 24-dimethylphenol 4-nitrophenol 46-dinitro-2shymethylphenol pentachlorophenol and 33-dichlorobenzidine in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
bull The nondetect results for 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as nondetects with estimated quantitation limits that maybe biased low These qualifications have a minor impact on data usability
J NEWA160 Troy Mills LandfiMData VahdationDecember 2004DV MemossD05939_svocsm pd Metcalfamp Eddy Inc
Ms Christine Clark Page 6 February 24 2005 Case 0251M SDG D05939
The positive results for di-n-butylphthalate in all soil samples were qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as estimated values that maybe biased high Note that the di-n-butylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to high recovery in the high-level LFB analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) due to the low recovery in the laboratory control sample (LCS) analysis This result is usable for project objectives as a nondetect with an estimated quantitation limit that may be biased low These qualifications have a minor impact on data usability
The nondetect results for benzaldehyde and 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the LCS analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene benzo(a)pyrene and indeno(l23shycd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to the high recoveries in the LCS analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
JNEWAI60 Troy Mills LandfillData ValidationDecember 2004DV MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 7 February 24 2005 Case 0251M SDG D05939
bull The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria These results are usable for project objectives as estimated values Note that the results for di-n-butylphthalate in samples D05950 D05951 D05952 D05945 D05947 D05948 D05949 and D05953 were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
D05950 di-n-butylphthalate D05951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate DOS 95 3 di-n-butylphthalate
Data Completeness (CSF Audit)
The following information was missing or incorrect in the data package This missing or incorrect information was requested from the laboratory on February 7 and 152005 A resubmittal response was received at MampE on February 18 2005 adequately addressing these issues
bull The method detection limit (MDL) study results for two selected ion monitoring (SIM) compounds (pentachlorophenol and di-n-butylphthalate) were missing from the data package
The Form I (TIC) for sample D05946 identified the TIC at 1246 as alphashycaryophyllene while the raw data reported this TIC as l6-octadien-3-ol 37shydimethyl- Clarification was requested
bull The Form I for sample D05949 reported 26-dinitrotoluene and fluoranthene while the quantitation report did not reflect these results The laboratory was asked to verify this discrepancy
bull A relative response factor for 46-dinitro-2-methylphenol was listed on the Form 6 for the initial calibration in association with the 05 ugml standard However this compound was not listed on the quantitation report in the raw data The laboratory was asked to verify this discrepancy
J NEWA16Q Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 6 February 24 2005 Case 0251M SDG D05939
The positive results for di-n-butylphthalate in all soil samples were qualified as estimated (J) due to high recoveries in the low-level and high-level LFB analyses These results are usable for project objectives as estimated values that maybe biased high Note that the di-n-butylphthalate results in all soil samples were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to high recovery in the high-level LFB analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
The nondetect result for caprolactam in equipment blank sample D05954 was qualified as estimated (UJ) due to the low recovery in the laboratory control sample (LCS) analysis This result is usable for project objectives as a nondetect with an estimated quantitation limit that may be biased low These qualifications have a minor impact on data usability
The nondetect results for benzaldehyde and 4-chloroaniline in all soil samples were qualified as estimated (UJ) due to low recoveries in the LCS analyses These results are usable for project objectives as nondetects with estimated quantitation limits that may be biased low These qualifications have a minor impact on data usability
The positive results for benzo(b)fluoranthene benzo(a)pyrene and indeno(l23shycd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 were qualified as estimated (J) due to the high recoveries in the LCS analyses These results are usable for project objectives as estimated values that may be biased high These qualifications have a minor impact on data usability
JNEWAI60 Troy Mills LandfillData ValidationDecember 2004DV MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 7 February 24 2005 Case 0251M SDG D05939
bull The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria These results are usable for project objectives as estimated values Note that the results for di-n-butylphthalate in samples D05950 D05951 D05952 D05945 D05947 D05948 D05949 and D05953 were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
D05950 di-n-butylphthalate D05951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate DOS 95 3 di-n-butylphthalate
Data Completeness (CSF Audit)
The following information was missing or incorrect in the data package This missing or incorrect information was requested from the laboratory on February 7 and 152005 A resubmittal response was received at MampE on February 18 2005 adequately addressing these issues
bull The method detection limit (MDL) study results for two selected ion monitoring (SIM) compounds (pentachlorophenol and di-n-butylphthalate) were missing from the data package
The Form I (TIC) for sample D05946 identified the TIC at 1246 as alphashycaryophyllene while the raw data reported this TIC as l6-octadien-3-ol 37shydimethyl- Clarification was requested
bull The Form I for sample D05949 reported 26-dinitrotoluene and fluoranthene while the quantitation report did not reflect these results The laboratory was asked to verify this discrepancy
bull A relative response factor for 46-dinitro-2-methylphenol was listed on the Form 6 for the initial calibration in association with the 05 ugml standard However this compound was not listed on the quantitation report in the raw data The laboratory was asked to verify this discrepancy
J NEWA16Q Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 7 February 24 2005 Case 0251M SDG D05939
bull The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria These results are usable for project objectives as estimated values Note that the results for di-n-butylphthalate in samples D05950 D05951 D05952 D05945 D05947 D05948 D05949 and D05953 were also qualified as nondetect (U) due to method blank contamination Therefore the overall qualification for these results is estimated nondetect (UJ) These qualifications have a minor impact on data usability
D05950 di-n-butylphthalate D05951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate DOS 95 3 di-n-butylphthalate
Data Completeness (CSF Audit)
The following information was missing or incorrect in the data package This missing or incorrect information was requested from the laboratory on February 7 and 152005 A resubmittal response was received at MampE on February 18 2005 adequately addressing these issues
bull The method detection limit (MDL) study results for two selected ion monitoring (SIM) compounds (pentachlorophenol and di-n-butylphthalate) were missing from the data package
The Form I (TIC) for sample D05946 identified the TIC at 1246 as alphashycaryophyllene while the raw data reported this TIC as l6-octadien-3-ol 37shydimethyl- Clarification was requested
bull The Form I for sample D05949 reported 26-dinitrotoluene and fluoranthene while the quantitation report did not reflect these results The laboratory was asked to verify this discrepancy
bull A relative response factor for 46-dinitro-2-methylphenol was listed on the Form 6 for the initial calibration in association with the 05 ugml standard However this compound was not listed on the quantitation report in the raw data The laboratory was asked to verify this discrepancy
J NEWA16Q Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 8 February 24 2005 Case 0251M SDG D05939
Initial and Continuing Calibrations
Full Scan
The following table summarizes the initial calibration (1C) and continuing calibration (CC) results that failed to meet the relative response factor (RRF) criterion of ^005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C CC CC CC 12505 12705 13105 2105
Compound RSD D D D
benzaldehyde 792 155 156 153
hexachlorobutadiene - - - 453
hexachlorocyc lopentadiene 488 448 - 360
24-dimtrophenol 337 - 25 8 -
4-nitrophenol - - - 467
hexachlorobenzene - - - 286
46-dimtro-2-methylphenol 450 - - -
atrazme 434 - - -
pentachlorophenol 384 - - -
33-dichlorobenzidme - 726 463 628
2-fluorophenol (surrogate) - - - 285
Associated samples All samples D05954 D05950 D05951 D05948RE D05952 D05945 D05949 D05946 D05947 D05953RE D05948 D05953 D05949DL
D05945DL D05946DL D05947DL D05948DL D05953DL
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
JNEWA160 Troy Mills LandftllData VahdationDecember 2004DV MemossD05939_socsim pd Metcalf amp Eddy Inc
Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 9 February 24 2005 Case 0251M SDGD05939
The positive and nondetect results for benzaldehyde hexachlorocyclopentadiene 24-dinitrophenol 46-dinitro-2-methylphenol atrazine and pentachlorophenol in all samples were qualified as estimated (UJ) due to initial calibration RSD exceedances
The positive and nondetect results for benzaldehyde and 33-dichlorobenzidine in all samples for hexachlorobutadiene 4-nitrophenol and hexachlorobenzene in samples D05948RE D05949 and D05953RE for hexachlorocyclopentadiene in samples D05954 D05948RE D05949 and D05953RE and for 24-dinitrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 were qualified as estimated (J and UJ respectively) due to continuing calibration D exceedances
No validation actions were necessary for the calibration nonconformances associated with the dilution sample analyses or for the original analyses of samples D05948 and D05953 since the compounds listed in the table above were not reported from these analyses
No validation actions were necessary for the surrogate compound calibration nonconformance
SIM
The following table summarizes the 1C and CC results that failed to meet the RRF criterion of gt005 andor RSD lt 30 in the 1C andor D lt 25 in the CC for all compounds
Calibration Date 1C 12105 1C 2205 CC 2305
Compound RSD RSD D
pentachlorophenol 621 402 -
di-n-butyl phthalate 331 - 297
bis(2-ethylhexyl)phthalate 347 306
Associated samples D05954 all soil samples all soil samples
- - QC acceptance criteria were not exceeded for this compound
Actions RSD gt 30 Estimate (J and UJ respectively) positive and nondetect results D gt 25 Estimate (J and UJ respectively) positive and nondetect results
The positive di-n-butylphthalate result in equipment blank sample D05954 was qualified as estimated (J) due to the RSD exceedance in the initial calibration
The positive di-n-butylphthalate results in all soil samples were qualified as estimated (J) due to the D exceedance in the continuing calibration
J NE WA160 Troy Mills LandfillData Validation December 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 10 February 24 2005 Case 0251M SDG D05939
The pentachlorophenol and bis(2-ethylhexyl)phthalate results in all samples were reported from the full scan analyses therefore no data validation actions were required as a result of the calibration nonconformances
Blanks
Full Scan
Target compounds were detected as contaminants m the performance evaluation sample (PES) as well as the equipment and laboratory method blanks The highest concentration detected was used to qualify associated sample results The following table summarizes the blank actions as they apply to the samples
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
Affected SamplesActions
benzaldehyde D05954 (EB)
15 ugL NA 100 ugKg Qualify as EB in samples D05950 D05951D05952 D05945 D05946 and D05949
acetophenone D05954 (EB)
0 35 ugL NA 100 ugKg Qualify as EB in sample D05951
4-chloro-3shymethylphenol
D05954 (EB)
5 6 ugL NA 100 ugKg 4-Chloro-3shymethylphenol was not detected in all associated samples No actions were required
di-n-butylphthalate D05954 (EB)
049 ugL NA 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
di-n-butylphthalate method 42 ugKg 420 ugKg 100 ugKg Di-n-butylphthalate results were reported from the SIM analyses No actions were required
bis(2shyethylhexyl)phthalate
method 0 68 ugL 6 8 ugL 1 0 ugL Qualify as nondetect (U) at the QL m equipment blank sample D05954
J NEWA160 Troy Mills LandfillData VahdatwnDecember 20Q4DVMemossD05939_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 11 February 24 2005 Case 0251M SDGD05939
Compound Blank
Maximum Concentration
(units)
Blank Action
Level (units)
Quantitation Limit (units)
bis(2shyethylhexyl)phthalate
PES 490 ugKg 4900 ugKg 100 ugKg
NA - Not applicable SIM - selected ion monitoring EB - equipment blank PES - performance evaluation sample
Sample results were qualified as follows
Affected SamplesActions
Qualify as nondetect (U) at the QL in samples 005950005951 and D05952
bull If sample result was gtQL and ltblank action level (BAL) the result was qualified as a nondetect (U) at the reported concentration
bull If the sample result was sQL and iBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required bull Positive results for compounds detected in the equipment blank are flagged with EB
SIM
Target compounds were detected in the laboratory method blanks The following table summarizes the blank actions as they apply to the samples
Compound
di-n-buty Iphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Blank Maximum Action Quantitation
Concentration Level Limit Blank (umts^ (units) (units)
method 120ngL 1200 ngL 100 ngL
method 760 ngL 7600 ngL 1600 ngL
method 49 ugKg 490^1^ 10 ugKg
Affected SamplesActions
Qualify as nondetect (U) at the reported value in sample D05954
Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions vere required
Qualify as nondetect (U) at the reported value in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939_nocsirn vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 12 February 24 2005 Case 0251M SDGD05939
Blank Maximum Action Quantitation
Concentration Level Limit Affected Compound Blank (units) (units) (units) Samples Actions
bis(2-ethylhexyl)phthalate method 31 ugKg 3 10 ugKg 160 MgKg Bis(2shyethylhexyl)phthalate results were reported from the full scan analyses No actions were required
Sample results were qualified as follows bull If sample result was gtQL and ltBAL the result was qualified as a nondetect (U) at the reported
concentration bull If the sample result was sQL and ltBAL the results was qualified as a nondetect (U) at the QL bull If the sample result was gtBAL qualification of the data was not required bull If the sample result was nondetect qualification of the data was not required
Internal Standards
Full scan
The following table summarizes the internal standards (IS) that did not meet the acceptable area criteria
Sample ID Internal Standard IS Area Acceptable Range Action
D05948 perylene-d|2 394921 407622-1630486 Results not reported from this analysis
D05948RE chrysene-d2 1720979 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
D05953 perylene-d2 311034 407622-1630486 Results not reported from this analysis
D05953RE chrysene-dl2 1565496 350682-1402728 Sample results associated with this IS were either not detected or were reported from the dilution analysis No data validation actions required
SIM
Internal standards were within the acceptance criteria in all sample analyses
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DV MemossD05939_svocsim npd Metcalfamp Eddy Inc
Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 13 February 24 2005 Case 0251M SDG D05939
Sensitivity Check
Full Scan
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F05 (low-level)
SW122104F04 (high-level)
Compound
caprolactam
24-dimtrophenol
4-mtrophenol
46-dmitro-2-methylphenol
pentachlorophenol
caprolactam
Recovery Action
0 Raise the quantitation limit to the concentration of the high-level LFB (4 ngL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
0 Since the QL for this compound is 4 |igL the high level LFB (spiked at 4 ugL) was used to evaluate this compound for sensitivity
38 Qualify as estimated (UJ) the nondetect 4shynitrophenol result in sample D05954
38 Qualify as estimated (UJ) the nondetect 46shydimtro-2-methylphenol result in sample D05954
36 Qualify as estimated (UJ) the nondetect pentachlorophenol result in sample D05954
27 Raise the quantitation limit to the concentration of the high-level LFB (4 ugL) and qualify as estimated (UJ) the nondetect caprolactam result in sample D05954
QL - quantitation limit LFB - laboratory fortified blank
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound
SS012805FL01 24-dimethylphenol (low-level)
4-chloroanihne
Action Recovery
26 Qualify as estimated (UJ) the nondetect 24shydimethylphenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shychloroamlme results in all soil samples
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossD05939j5vocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark February 24 2005
LFB
SS012805FL01 (low-level)
SS012805FH01 (high-level)
SIM
Compound
24-dimtrophenol
4-mtrophenol
4 6-dimtro-2-methylphenol
pentachlorophenol
33-dichlorobenzidme
4-chloroanilme
24-dimtrophenol
Page 14 Case 0251M SDG D05939
Action Recovery
0 Raise the quantitation limit to the concentration of the high-level LFB [800 ngKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 4shynitrophenol results in all soil samples
13 Qualify as estimated (UJ) the nondetect 46shydmitro-2-methylphenol results in all soil samples
32 Qualify as estimated (UJ) the nondetect pentachlorophenol results in all soil samples
35 Qualify as estimated (UJ) the nondetect 33shydichlorobenzidme results in all soil samples
39 Qualify as estimated (UJ) the nondetect 4shychloroamhne results in all soil samples
21 Raise the quantitation limit to the concentration of the high-level LFB [800 ugKg (corrected for all preparation factors)] and qualify as estimated (UJ) the nondetect 24-dimtrophenol results in all soil samples
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LFB
SW122104F03 (low-level)
SW122104F04 (high-level)
Compound
pentachlorophenol
di-n-butylphthalate
bis(2-ethylhexyl)phthalate
di-n-butylphthalate
Recovery
0
327
622
131
Action
Pentachlorophenol was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
Qualify as estimated (J) the positive di-nshybutylphthalate result in sample D05954
J NEWA160 Tro Mills LandfillData VahdationDecember 2004DVMemossD05939_socsim npd Metcalf amp Eddy Inc
Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 15 February 24 2005 Case0251M SDGD05939
LFB Compound Action Recovery
SW122104F04 bis(2-ethylhexyl)phthalate 161 Bis(2-ethylhexyl)phthalate was reported from the (high-level) full scan analysis therefore no actions were
required
The following table summarizes the LFB recoveries outside the 40-120 criteria in association with all soil samples in this data set and the validation actions taken
LFB Compound Action Recovery
SS012805FL02 di-n-butylphthalate 237 Qualify as estimated (J) the positive di-nshy(low-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 376 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 149 Since the QL for this compound is 160 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
indeno( 1 23-cd)pyrene 121 Since the QL for this compound is 1 60 ugKg the high level LFB (spiked at 50 ugKg) was used to evaluate this compound for sensitivity
SS012805FH02 di-n-butylphthalate 150 Qualify as estimated (J) the positive di-nshy(high-level) butylphthalate results in all soil samples
bis(2-ethylhexyl)phthalate 185 All bis(2-ethylhexyl)phthalate results were reported from full scan analysis therefore no actions were required
benzo(b)fluoranthene 132 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D0595 1 D05952 D05945 D05946 and D05949
QL - quantitation limit
PE Sample ResultsAccuracy Check
PE Sample Results
Full Scan
A single-blind solid PE sample D05939 (PES number SS0491) was analyzed with this data set Eight compounds were scored as Within Limits 2-Chlorophenol acenaphthylene acenaphthene dibenzofuran fluorene anthracene fluoranthene benzo(a)anthracene and chrysene were scored as
J NEWA160 Troy Mills LandfillData VahdatwnDecember 2004DVMemossD05939_svocsim vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 16 February 24 2005 Case 0251M SDGD05939
Action High These compounds were not detected in any of the associated soil samples therefore no data validation actions were required Six compounds (naphthalene hexachlorobenzene phenanthrene pyrene and dibenz(ah)anthracene and benzo(ghi)perylene) were scored as Warning High two compounds (4-hydroxy-4-methyl-2-pentanone and 4-methyl-3-penten-2-one) were scored Non-spiked TIC and one compound (din-n-butylphthalate) was scored Less than CRQL No data validation action is required on the basis of the Warning High Non-spiked TIC and less than CRQL scores Bis(2-ethylhexyl)phthalate was scored as Contaminant This compound was also detected in the associated laboratory method blanks and consequently evaluated in the blank section of this memorandum (please see Blanks above)
Laboratory Control Sample (LCS) Results
Full Scan
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
LCS Compound Recovery Action
SW122104L06 caprolactam 35 Qualify as estimated (UJ) the nondetectresult in sample D05954
caprolactam
atrazine 135 Atrazine was not detected in the associaNo actions were required
ted sample
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Recovery Action
SS012805L01 benzaldehyde 46 Qualify as estimated (J) the positive and (UJ) the nondetect benzaldehyde results in all soil samples
4-chloroanihne 35 Qualify as estimated (UJ) the nondetect 4shychloroaruhne results in all soil samples
SIM
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with equipment blank sample D05954 and the validation actions taken
J NEWA160 Troy Mills LandfillData VahdationDecember 2004DVMemossDQ5939_svocstm vpd Metcalfamp Eddy Inc
Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 17 February 24 2005 Case 0251M SDGD05939
LCS Compound Action Recovery
SW122104L05 pentachlorophenol 194 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 123 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(a)pyrene 122 Benzo(a)pyrene was not detected in the associated sample No actions were required
mdeno( 1 2 3 -cd)pyrene 130 Indeno(l23-cd)pyrene was reported from the full scan analysis therefore no actions were required
dibenz(ah)anthracene 136 Dibenz(ah)anthracene was not detected in the associated sample No actions were required
The following table summarizes the LCS recoveries outside the 50-120 criteria in association with all soil samples in this data set and the validation actions taken
LCS Compound Action Recovery
SS012805L02 pentachlorophenol 126 Pentachlorophenol was reported from the full scan analysis therefore no actions were required
bis(2-ethylhexyl)phthalate 142 Bis(2-ethylhexyl)phthalate was reported from the full scan analysis therefore no actions were required
benzo(b)fluoranthene 128 Qualify as estimated (J) the positive benzo(b)fluoranthene result in samples D05951 D05952 D05945 D05946 and D05949
benzo(a)pyrene 121 Qualify as estimated (J) the positive benzo(a)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
mdeno( 1 23-cd)pyrene 129 Qualify as estimated (J) the positive indeno(l23shycd)pyrene result in samples D05951 D05952 D05945 D05946 and D05949
dibenz(ah)anthracene 133 Dibenz(ah)anthracene was not detected in the associated samples No actions were required
J NE WA160 Troy Mills LandfillData Validation December 2004 D V MemossD0593 9_svocsim pd Metcalfamp Eddy Inc
Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 18 February 24 2005 Case 0251M SDG D05939
Compound Ouantitation and Reported Ouantitation Limits
Full Scan and SIM
Because of their high moisture content samples D05945 D05946 D05949 D05951 and D05952 were freeze-dried prior to extraction
The following table summarizes the SIM and full scan reporting when data existed for both full scan and SIM analyses Professional judgment was used to select specific analyses in order to report the lowest quantitation limit achievable and to report results with values within the calibration range
Compound Results reported from Full Scan Results reported from SIM
pentachlorophenol all samples none
di-n-butyl phthalate none all samples
benzo(a)anthracene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
bis(2-ethylhexyl)phthalate all samples none
benzo(b)fluoranthene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
benzo(a)pyrene none all samples
indeno(l23-cd)pyrene D05947 D05948 D05950 D05945 D05946 D05949 D05953 D05954 D05951D05952
dibenz(ah)anthracene none all samples
Full Scan
The bis(2-ethylhexyl)phthalate results in the following samples were reported from the dilution analysis listed in parentheses since these results exceeded the calibration range in the undiluted analysis D05945 (5x) D05946 (20x) D05947 (20x) D05948 (20x) D05949 (5x) and D05953 (20x)
JNE WA160 Troy Mills LandfillData ValidationDecember 2004D V MemossD05939_svocsim wpd Metcalfamp Eddy Inc
Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 19 February 24 2005 Case 0251M SDGD05939
SIM
The following compounds in the samples listed below were qualified as estimated (J) due to uncertainty in the quantitation as a result of the exceeded ion abundance ratio criteria
D05950 di-n-butylphthalate DOS951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate indeno(l23-cd)pyrene D05946 indeno(l23-cd)pyrene DOS 947 di-n-butylphthalate DOS 948 di-n-butylphthalate DOS 949 di-n-butylphthalate D05953 di-n-butylphthalate
Tentatively Identified Compounds (TICs)
One TIC 4-hydroxy-4-methyl-2-pentanone was detected in all samples and is considered an aldol condensation product Consequently this TIC was not included on Table III Tentatively Identified Compound Summary for the affected samples
The following compound in the sample listed was reported twice in the affected sample For this sample this result was renamed to a more general identification since a compound cannot elute at multiple retention times The renamed TIC is described in the table below
Compound name as reported by the Compound name as renamed during data Affected sample laboratory validation
oleic acid unknown D05951
JNEWA160 Troy Mills LandflllData ValidationDecember 2004DV MemossD05939_svocsimwpd MetcalfA Eddy Inc
Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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Ms Christine Clark Page 20 February 24 2005 Case 0251M SDG D05939
Please contact Ms Constance Lapite at (781) 224-6628 or at Constance lapite(am-ecom if you have any questions regarding this Tier II validation
Paula L DiMattei Data Validator
Deborah A Trwini ^mjrjat
Robert Shoemaker Project Chemist
bullgt pound^ampgtlt^ Constance D Lapite MampE RAC Lead Chemist
cc ^James Chow EPA Remedial Project Manager (DV memo and data summary tables) Karen Wedlock-Hunt MampE Project Manager (entire package) Robert Shoemaker Project Chemist (entire package) Troy Mills Landfill Project File WA No 160-RICO-019M (entire package)
Attachments ORDA Table I Recommendation Summary Table Table II Overall Evaluation of Data Table III Tentatively Identified Compound Summary Data Summary Tables Data Validation Worksheets PE Score Report Copy of non-CLP Analytical Method (MampE DAS Specification D-148) Copies of Telephone LogCommunications Forms Supporting Data for Reduced Payment Recommendations (not applicable) Copies of Field Sampling Notes (previously submitted) Copies of EPA-Approved Amendments not QAPjP or SAP (not applicable) CSF Completeness Evidence File Audit (DC-2 Form) DQO Summary Form
J NEWA160 Troy Mills LandfillData ValidatwnDecember 2004DVMemossD05939_svocsim pd Metcatfamp Eddy Inc
REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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REGION I EPA-NE ORGANIC REGIONAL DATA ASSESSMENT (ORDA)
CASE raquozjggtH _ SITE NAME TV
LAB NAME uoAlaquo Vlaquo- amp+ OF SAMPLESMATRIX
SDG Posirt_ VALIDATION CONTRACTOR
SOW CONTRACT p-rttll-- VALIDATORS NAME
EPA-NE DV TIER LEVEL JC_ DATE DP RECD BY EPA-NE
TPOPO ACTION _ FYI ^ DV COMPLETION DATE
ANALYTICAL DATA QUALITY SUMMARY tffpft^m t~
bullVGA SV-SM PestPCB 1 Preservation and Contractual Holding Times 2 GCMS GCECD Instrument Performance Check raquo 3 Initial Calibration laquo 4 Continuing Calibration o 5 Blanks ~ o 6 Surrogate Compounds raquo 7 Internal Standards o 8 Matrix SpikeMatrix Spike Duplicate ggt 9 Sensitivity Check 0 10 PE Samples-Accuracy Check 0 11 Target Compound Identification jpy 12 Compound Quantitation and Reported QLs o 13 Tentatively Identified Compounds o 14 Semivolatile CleanupPesticidePCB Cleanup ulaquor 15 Data Completeness 0 16 Overall Evaluation of Data laquo
o = Data had no problems or were qualified due to minor contractual problems m = Data were qualified due to major contractual problems z = Data were rejected as unusable due major contractual problems
ACTION ITEMS (z items)
AREAS OF CONCERN (m items)
COMMENTS
This form assesses the analytical data quality in terms of contractual compliance only It does not assess sampling errors andor non-contractual analytical issues that affect data quality
Check ACTION only if contractual defects resulted in reduced paymentdata rejection recommendations
Validator t ltiJSagt3gtlt -3 Date
INSTRUCTIONS ON REVERSE SIDE
1296
Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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anic
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S s S g S S S S S S S S S S n S S S S S 2 - 2 S n g O __ W
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Table I Recommendation Summary
Soil Semivolatile Organic Analysis Troy Mills Landfill Superfund Site
Case0251M SDGD05939
Sample ID Matrix
D05945 SO
D05946 SO
D05947 SO (FD)
D05948 SO
D05949 SO
D05950 SO
D05951 SO
D05952 SO
D05953 SO (FD)
D05954 EB
EB shy Equipment Blank FD shy Field Duplicate SOshy Soil
Qualifier
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 11 13 14 15
2 Jl 3 4 7 8 9 10 13 15
A 2 jl 3 4 7 8 9 10 13 15
A 1 2 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 jl 3 4 7 8 9 10 13 15
A 2 3 jl 3 4 7 8 9 10 11 13 14 15
A 1 2 3 Jl 3 4 7 8 9 10 11 13 14 15
A 2 jl 3 4 7 8 9 10 13 15
^2 4 jl 2 3 5 6 7 12
A - Accept the data but qualify the positive results for benzaldehyde in samples D05945 D05946 D05949 D05950 D05951 and D05952 and for acetophenone in sample D05951 as (EB) due to equipment blank contamination
A2 - Accept the data but qualify the positive result for di-n-butylphthalate as nondetect (U) at the reported value due to laboratory method blank contamination
A5 - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to PE sample contamination
A - Accept the data but qualify the positive result for bis(2-ethylhexyl)phthalate as nondetect (U) at the QL due to laboratory method blank contamination
J - Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde hexachlorocyclopentadiene 24shydmitrophenol 46-dmitro-2-methylphenol atrazine and pentachlorophenol due to initial calibration RSD exceedances
J2 Estimate (J) the positive result for di-n-butyl phthalate due to the initial calibration RSD exceedance
J3 Estimate (J) the positive and (UJ) the nondetect results for benzaldehyde and 33-dichlorobenzidme in all samples for hexachlorobutadiene 4-mtrophenol and hexachlorobenzene m samples D05948 D05949 and D05953 for hexachlorocyclopentadiene m samples D05954 D05948 D05949 and D05953 and for 24shydimtrophenol in samples D05950 D05951 D05952 D05945 D05946 and D05947 due to the continuing calibration D exceedances
J4 - Estimate (J) the positive results for di-n-butylphthalate in all soil samples due to continuing calibration exceedance
J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
Drg
anic
s
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amp u 3 t o ~ c i ~ o p r o c c sect c l ~ J = 1 poundlaquo Q
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J5 - Estimate (UJ) the nondetect caprolactam result and raise the quantitation limit to 4 ugL (equivalent to the concentration of the high-level LFB) due to low low-level and high-level LFB recoveries This result may be biased low
J6 - Estimate (UJ) the nondetect results for 4-mtrophenol 46-dmitro-2-methylphenol and pentachlorophenol due to low low-level LFB recoveries These results may be biased low
J7 - Estimate (J) the positive result for di-n-butylphthalate due to high low-level and high-level LFB recoveries This result may be biased high
J8 - Estimate (UJ) the nondetect 24-dmitrophenol result and raise the quantitation limit to 800 ugKg (equivalent to the concentration of the high-level LFB and corrected for all preparation factors) due to low low-level and high-level LFB recoveries This result may be biased low
J9 - Estimate (UJ) the nondetect results for 24-dimethylphenol 4-mtrophenol 46-dimrro-2-methylphenol pentachlorophenol and 33-dichlorobenzidme due to low low-level LFB recoveries These results may be biased low
J10 - Estimate (UJ) the nondetect result 4-chIoroamlme due to low low-level and high-le el LFB recoveries This result may be biased low
J1 - Estimate (J) the positive result for benzo(b)fluoranthene due to high high-level LFB reco ery This result may be biased high
J12 - Estimate (UJ) the nondetect caprolactam result due to low LCS recovery This result may be biased low
J3 - Estimate (UJ) the nondetect benzaldehyde and 4-chloroamline results due to low LCS recoveries The results may be biased low
J14 - Estimate (J) the positive results for benzo(b)fluoranthene benzo(a)pyrene and mdeno(l23-cd)pyrene in samples D05951 D05952 D05945 D05946 and D05949 due to high LCS recoveries The results may be biased high
J15 - Estimate (J) the positive results for the following compounds in the samples listed below due to uncertainty in the quantitation as a result of the exceeded ion abundance ration criteria
DOS 950 di-n-butylphthalate DOS 951 di-n-butylphthalate benzo(a)pyrene D05952 di-n-butylphthalate benzo(a)pyrene D05945 di-n-butylphthalate mdeno(l23-cd)pyrene D05946 mdeno(l23-cd)pyrene D05947 di-n-butylphthalate D05948 di-n-butylphthalate D05949 di-n-butylphthalate D05953 di-n-butylphthalate
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D05953
|
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Requ
ired
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antit
atu
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gram
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ter
rt
The
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ata
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C 1i
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ortin
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II 0 0 o o O U~l o o o o o 0 o o o o o o o o o o o o o 0 O o o 0 0 o o o 0 0 A (N r^ CO C
Imdash I _^ W ^- QN P- mdash t5 = o fe oshypound UJ
O 9 11 g-g| JJ o o o o o o o o o o o o o o 0 o o o o 0 o o o o o o 0 0 o o o o o o o o 0 0
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degdeg D o 0 0t3 ~ ~ 5w uf
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ired
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The
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Hex
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nant
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Ant
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Requ
ired
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The
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feb _0
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03 J fflQ 00 mdashraquo 00 D so ffl cx w j~ 111 a 3|
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degdeg D o 0 0t3 ~ ~ 5w uf
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mdash o mdash C S ( T l 1^3 bullo
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S
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Hex
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nant
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But
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then
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Ben
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Eluor
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ntit
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H a CO
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Requ
ired
QL
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ampl
e qu
antit
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- m
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gram
s i pe
r li
ter
rt
The
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ata
an
feb _0
S 1_) c
a
C 1i
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11 iT ogt cd CJ
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ortin
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The
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5 e
p
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lt pound 0 U
03 J fflQ 00 mdashraquo 00 D so ffl cx w j~ 111 a 3|
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r but
not
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ecte
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lim
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5
0 0 U O
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ntit
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H a CO
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ulaquobull5 ltu gE c S3 C3
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Requ
ired
QL
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ampl
e qu
antit
atu
- m
icro
gram
s i pe
r li
ter
rt
The
- d
ata
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feb _0
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a
C 1i
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11 iT ogt cd CJ
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ortin
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b|
5 e
p
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3
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lt pound 0 U
03 J fflQ 00 mdashraquo 00 D so ffl cx w j~ 111 a 3|
oi ^1 bullsect3O pound
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