first efficient synthesis of enantiopure homoketopinic acid
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2007
TerpenesU 0200 First Efficient Synthesis of Enantiopure Homoketopinic Acid. — The key step in
this approach is the nucleophilic substitution of the known triflate (I) with cyanide with-out formation of a Grob fragmentation product. — (GARCIA MARTINEZ*, A.; DE LA MOYA CERERO, S.; TESO VILAR, E.; GARCIA FRAILE, A.; DIAZ MORILLO, C.; DE LAS CASAS ENGEL, T.; Lett. Org. Chem. 4 (2007) 2, 123-125; Dep. Quim. Org., Fac. Cienc., UNED, Ciudad Univ., E-28040 Madrid, Spain; Eng.) — K. Schneider
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