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Transition metal molecular glasses by design: Mexylaminotriazine-functionalizedsalicylaldehyde imine ligands

Supporting Information

Mahboubeh Jokar,† Michael Cherry,† Jennifer L. Scott*,† and Olivier Lebel*,†

† Department of Chemistry and Chemical Engineering, Royal Military College ofCanada, Kingston, ON, K7K 7B4, Canada

*Corresponding author: jennifer.scott@rmc.ca; olivier.lebel@rmc.ca

Electronic Supplementary Material (ESI) for New Journal of Chemistry.This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019

Figure S1. DSC traces for precursor 1 and ligands 6-10, recorded at a heating rate of 5°C/min.

Figure S2. DSC traces for complexes 8Mn, 8Fe, 8Ni, 8Cu, 8Zn, 9Zn and 10Zn, recorded at aheating rate of 5 °C/min.

S2

Position [°2θ] (Copper (Cu))θ] (Copper (Cu))] (Copper (Cu))

10 2θ] (Copper (Cu))0 30 40 50 60 70 80

Counts

0

500

1000

OL -VI-186-[RTS] Gonio 5-90 5min inorganic_1

Figure S3. Powder X-ray diffraction pattern for complex 8Co.

Figure S4. Thermal Gravimetric Analysis of complex 8Mn.

S3

Figure S5. Thermal Gravimetric Analysis of complex 8Fe.

Figure S6. Thermal Gravimetric Analysis of complex 8Co.

S4

Figure S7. Thermal Gravimetric Analysis of complex 8Ni.

Figure S8. Thermal Gravimetric Analysis of complex 8Cu.

S5

Figure S9. Thermal Gravimetric Analysis of complex 8Zn.

Figure S10. Thermal Gravimetric Analysis of complex 9Zn.

S6

Figure S11. Thermal Gravimetric Analysis of complex 10Zn.

NMR Spectra of New Compounds

S7