alkynes
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Alkynes presentationTRANSCRIPT
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Alkynes
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Group Members
Novella I.C (20)
Nurul Izzatil A. (21)
R. Dandy Y. (22)
Raka S.W.S (23)
Reyan P.B. (24)
Rizqi Cahyo .Y (25)
Rosita Devi (26)
Sabrina Amelia J. (27)
Zaynita A . A (28)
X-1
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Alkynes
Alkynes are aliphatic hydrocarbons (straight chain), unsaturated hydrocarbon with a triple bond between two carbon atoms.
Alkynes are traditionally known as acetylenes, although the name acetylene also refers specifically to C2H2, known formally as ethyne using IUPAC nomenclature.
Like other hydrocarbons, alkynes are generally hydrophobic but tend to be more reactive. It is widely thought to be the greatest of all the functional groups.
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Common Formula of Alkynes
CnH2n-2
n : Number of C
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Function of Common Formula of Alkynes
• Determine the molecular formula alkynes compounds.
• The molecular structure of these compounds can be described by the molecular formula.
Example :Number of Carbons: 3Index Numbers of Hydrogen : 2(3)-2 = 6-2 = 4Molecular Formula: C3H4
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Number of Carbons: 5Index Numbers of Hydrogens: 2(5)-2 = 10-2 = 8Molecular Formula: C5H8
Number of Carbons: 7Index Numbers of Hydrogen: 2(7)-2 = 14-2 = 12Molecular Formula: C7H12
Number of Carbons: 9Index Numbers of Hydrogen: 2(9)-2 = 18-2 = 16Molecular Formula: C9H16
http://chemistry.about.com/od/lecturenoteslabs/tp/Simple-Alkyne-Chains.htm
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Nomenclature of
Alkynes
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Straight Chain
1. Check the type of bond, if it has a triplicate bond, meaning the compound is an alkyne compound.
2. Count the number of its C atom.3. Write the prefix based on the number
of its C atom and ending with the suffix-una.4. If the number of C atoms alkyne compounds of
more than 3, give the number of each atom in such a way that the smallest number is located on the C atom attached to a triple bond. Then, naming compounds is initiated by the first C atom numbers are bound to triplicate bonds, followed by a dash (-) and the name of the main chain.
http://smartchemistry.wordpress.com/2012/02/14/tata-nama-senyawa-alkuna/
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Example
2 - Pentyne
Butyne
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Branched Chain1. Check the type of bond, if it has a triplicate
bond, meaning the compound is an alkyne compound.2. Determine the main chain and branch chain. The
main chain is determined from the longest chain of C atoms containing a triplicate bond.
3. Give the number of each atom in such a way that the smallest number is located on the C atom attached to a triplicate bond.
4. The main chain are named by the rules straight chain alkyne compound naming.
5. Branched chain named after the number of C atoms and the structure of the alkyl group.
6. Order in a compound name with a sequence of writing the name of the compound alkanes and alkenes.
http://smartchemistry.wordpress.com/2012/02/14/tata-nama-senyawa-alkuna/
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Example
3-methyle-1-butyne (true) 2-methyle-3-butyne (false)
2,2-dimethyle-3-heptyne
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Although the determination is wrong because the one of the main chain has the
longest chain, but doesn't through the triplicate.
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http://www.chem-is-try.org/materi_kimia/kimia_organik_dasar/hidro-karbon/alkuna/
Determining of the main chain is true(Name: 3,5-dimethyle-3-prophyle-1-hexyne
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Triplicate bond More than One
1. Check the type of bond, if it has a triple bond, meaning the compound is an alkyne compound.
2. Count the number of its C atom.3. Count the number of triplicate bond.4. If the number of all triplicate bonds = 2, compound
names end with the suffix-diuna. If the number of all triplicate bonds = 3, compound names end with the suffix-triuna.
5. Give the number of each atom in such a way that the smallest number is located in two or three C atoms bound to the first triplicate bond. Then, naming compounds C atom numbers preceded by the first and second / third that bound to the triplicate bond, followed by a dash (-) and the name of the main chain.
6. If there is a branched-chain, branched chain names similar to the naming of alkyne compounds.
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1,3-Pentadiyne
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Physical and Chemical
Properties of Alkyne
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Physical Properties of Alkyne
• Alkyne is non-polar, have intermolecular forces are weak and have a molecular masssimilar to alkanes and alkenes.
• The higher interest alkyne, the greater the boiling point.
• At room temperature, the first three tribes are gaseous, the next rates are liquid, while the greater rates are in solid shape
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Some physical properties of the alkyneNama alkuna
Molecularformula
Mr
Melting point(oC)
Boiling point(0 C)
Density(g/Cm3 )
On phase250 C
Etyne C2H2 26 -81 -85-
Gas
Propyne C3H4 40 -103 -23 - Gas
But-1-yne C4H6 54 -126 8 - Gas
Pen-1-yne C5H8 68 -90 40 0,690 Cair
Hex-1-yne C6H10 82 -132 71 0,716 Cair
Hept-1-yne C7H12 96 -81 100 0,733 Cair
Okt-1-yne C8H14 110 -79 126 0,740 Cair
Non-1-yne C9H16 124 -50 151 0,766 Cair
Dec-1-yne C10H18 138 -44 174 0,765 Cair
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Chemical Properties of Alkyne
• With the same amount of C, the alkyne is more reactive than alkanes
• The existence of a triple bond which is owned alkyne allow the addition reactions, polymerization, substitution and combustion
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A. Addition reaction of alkynes
In contrast to alkenes, alkynes have triple bonds so the adition reaction can take place in two stages
Example
Alkyne adition with the halogen
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• Alkyne adition to the halide acid
Markovnikov law applicable, H atoms of hydrogen halides into atoms Cdouble bind more H atoms.
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B. Polymerization reaction of alkynes
In the etyne addition polymerization reaction (C2H2), two molecules etyne combine to form one molecule vinyl etyne (C4H4)
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C. Substitution reaction of alkynes
Substitution on the alkyne reaction involves the release of H atoms bound to the C C bond at the end of the chain of alkyne
2CH CH + 2Na 2CH C-Na + H2 CH C-CH3 + NaI
Etyne natrium asetilide propyne
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D. Combustion reaction of alkynes
Combustion alkyne with a limited amount of O2, CO or C will result in
2C2H2(g) + 5O2(g) 4CO2(g) + 2H2O(g)
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Alkyne Isomers
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Alkyne Isomers
Type of the alkyne isomers i structure isomers, namely framework/chain isomers and position isomers. Isomers of alkyne is started from alkyne butyne.
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Examples of C5H8 isomers :
• Chain isomers
Pen-1-yne 3-methyl but-1-yne
• Position isomers
Pen-1-yne Pen-2-yne
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• Alkyne also get isomers with cycloalkene that called functional group isomers
• C4H6 Functional group isomers
CH CH2 CH
CH CH2 CH CH CH3
Cyclobutene 3-methyl cyclopropene
CH C CH2 CH3
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Thank You