alkanes_straight chain, structural isomers & branch chain

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  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Naming Saturated Aliphatic Hydrocarbons (1 of 26)

    Naming SaturatedliphaticHydrocarbons

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Saturated Term (2 of 26)

    Saturated liphaticHydrocarbons

    ll c rb o n b o n d s re

    s in g le b o nd s

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  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Hydrocarbon Term (4 of 26)

    Saturated liphaticHydrocarbons

    h y d ro g e n n d c rb

    o n

    c o n t in in g c o m

    p o u n d s

    ll c rb o n b o n d s re

    s in g le b o nd s

    c rb o n to m s lin k e d in n o p e n c h in

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: IUPAC (5 of 26)

    The International Union of Pure Applied Chemists (IUPAC) isresponsible for making up the rules for naming organic compounds.

    You will first learn the IUPAC names for the first ten saturatedaliphatic hydrocarbons, called alkanes.

    Next, you will use the IUPAC naming system to name alkenes,alkynes, branched chain hydrocarbons, alcohols, carboxylicacids, and esters.

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: The Carbon Atom (6 of 26)

    The Carbon tom

    4 single bonds2 double bonds

    1 double two single bonds1 triple bond a single bond

    12 C6

    Carbon can form compounds composed of...

    atomic numberatomic mass

    p+e -

    Bohr Diagram

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Methane (7 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    meth ane CH 4(gas)C1H(2x 1+2)

    - 161C 183C Fuel for heating.

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Ethane (8 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    H

    C2H(2x2+2)eth ane C2H6(gas)

    - 89C 172C Component of natural gas, used for heating. Catalyst used in the preparation of other chemicals.

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Propane (9 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    H

    C3H(2x3+2)prop ane C3H8(gas)

    - 42C 188C Fuel used for cooking. Fuel in propane powered vehicles.

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Butane (10 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    H

    C4H(2x 4+2)but ane C4H10(gas)

    - 138C 0.5C Lighter fuel.

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Pentane (11 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    C5H(2x 5+2)pent ane C5H12(liquid)

    36C 130C

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Hexane (12 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    m.p. b.p.

    H

    H

    Common Use(s)

    C6H(2x 6+2)hex ane C6H14(liquid)

    - 95C 68C

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Heptane (13 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    H

    H

    H

    C7H(2x 7+2)hept ane C7H16(liquid)

    - 91C 98C

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Octane (14 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    H

    H

    H

    C8H(2x 8+2)oct ane C8H18(liquid)

    - 57C 126C Major component of gasoline.

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Nonane (15 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    H

    H

    H

    C9H(2x 9+2)non ane C9H20(liquid)

    - 53C 151C

    dragto

    target

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Decane (16 of 26)

    The First Ten Alkanes IUPAC Name Chemical FormulaGeneral Formula

    Structural Formula

    Common Use(s) m.p. b.p.

    H

    H

    H

    H

    C10 H(2x 10 +2)dec ane C10 H22(liquid)

    - 30C 174C Component of gasoline

    dragto

    target

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Graphing m.p. b.p. (17 of 26)

    Construct a graph of melting point and boiling point on the y-axis versus number of carbon atoms on the x-axis.

    Make a statement about the trend(s) that you notice.

    Learning Activity

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Alkane Isomers (18 of 26)

    Alkane Isomers

    Thalidamide A(no morning sickness)

    Make butane Make an isomer of butane

    Structural IsomersAny of two or more chemical compounds having the samemolecular formula but different structural formulas.

    http://www.todayinsci.com/Events/Medical/ThalidamideChildThm.jpg

    Thalidamide B(severe birth defects)

    Structural Isomers Modelling Activity

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Naming (19 of 26)

    Sketching Naming Branched Alkanes

    Name Sketch2 - methyl butane

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Naming (20 of 26)

    Sketching Naming Branched Alkanes

    Name Sketch2,2 - dimethyl - 4 - propyl heptane

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Naming Aliphatic Hydrocarbons_Handout (21 of 26)

    Naming SaturatedAliphatic

    Hydrocarbons

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: IUPAC_Handout (22 of 26)

    The International Union of Pure Applied Chemists (IUPAC) isresponsible for making up the rules for naming organic compounds.

    You will first learn the IUPAC names for the first ten saturatedaliphatic hydrocarbons, called alkanes.

    Next, you will use the IUPAC naming system to name alkenes,alkynes, branched chain hydrocarbons, alcohols, carboxylicacids, and esters.

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: The Carbon Atom_Handout (23 of 26)

    The Carbon Atom

    4 single bonds2 double bonds

    1 double two single bonds1 triple bond a single bond

    12 C6

    Carbon can form compounds composed of...

    atomic numberatomic mass

    p+e -

    Bohr Diagram

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Alkane Isomers_Handout (24 of 26)

    Alkane Isomers

    Thalidamide A(no morning sickness)

    Thalidamide B(severe birth defects)

    Make butane Make an isomer of butane

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Template (25 of 26)

  • 8/11/2019 Alkanes_Straight Chain, Structural Isomers & Branch Chain

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    Title: Nov 30-11:30 AM (26 of 26)