advancing chemistry, innovating for sustainability · 2014. 6. 5. · to advancing sustainability...

18th Annual Green Chemistry & Engineering Conference

gcande.org#gcande

American Chemical Society

Advancing Chemistry,Innovating for Sustainability

BETHESDA NORTH MARRIOTT HOTEL & CONFERENCE CENTERNORTH BETHESDA, MARYLAND, USA

JUNE 17 - 19, 2014


The ACS Green Chemistry Institute®What is green chemistry? We are glad you asked! Green chemistry and engineering is an innovation-driven approach to chemistry and chemical processes that seeks to reduce waste, conserve energy, and discover replacements for hazardous substances and nonrenewable raw materials throughout the life cycle of a product. Green chemistry and engineering benefits the economy while protecting human and environmental health.

The ACS Green Chemistry Institute® (ACS GCI) is dedicated to promoting and advancing innovation in sustainable and green chemistry for this century and beyond. We believe that such innovation holds the key to solving many environmental and human health challenges that plague our world today. Therefore, it is our mission to catalyze and enable the implementation of green chemistry and engineering throughout the global chemical enterprise.

ACS GCI welcomes you to the 18th Annual Green Chemistry & Engineering (GC&E) Conference! The conference provides a unique platform for leaders, policy makers, educators, students, and professionals from the scientific community to obtain valuable information on new progress in green research and establish meaningful collaborations and networks. This year’s theme, “Advancing Chemistry, Innovation for Sustainability” examines innovations in the science and application of greener chemistry & engineering needed for a better, brighter future.

The ACS GCI staff thanks each of you for your attendance and for bringing your enthusiasm, passion, and expertise to this conference. It is with your continued support that we can further the development of effective solutions and accomplish our mission.

FOLLOW GC&E POSTS BY JOINING ACS GREEN CHEMISTRY INSTITUTE® ON:

Conference Hashtag: #gcande

facebook.com/ACSGreenChemistryInstitute

linkedin.com/in/acsgci

twitter.com/acsgci [@ACSGCI]

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18th Annual Green Chemistry & Engineering Conference Advancing Chemistry, Innovating for Sustainability 1

Welcome On behalf of the 2014 organizing committee, welcome to the 18th Annual Green Chemistry & Engineering Conference in North Bethesda, Maryland! This year’s conference theme, “Advancing Chemistry, Innovation for Sustainability,” reflects our commitment to educate the science and engineering community on the fundamentals of green innovative solutions and to propel it into action. With three days of dynamic programming comprised of keynote addresses from world-renowned leaders, informative and interactive technical sessions, insightful poster sessions, and several targeted workshops, this year’s conference is guaranteed to energize and challenge attendees to take their passion for green chemistry and engineering to the next level.

An exciting event this year is the Green Business Plan Competition. It will provide a forum for early-stage companies to pitch business plans that incorporate green chemistry and engineering in the initial stages of the entrepreneurial life cycle.

We are also eager to announce the LAUNCH Workshop that will explore why a systems innovation approach is key to accelerating funding for and adoption of green chemistry. We will also discuss why green chemistry is critical to innovating the systems of materials and manufacturing that we rely on.

Back by popular demand is the student workshop where current undergraduate and graduate students will learn and practice how to evaluate the impact of chemicals and syntheses, determine the greenest options, and assess their own research with synthetic, analytical, and process experts!

We are also eager to once again host the American Chemical Society (ACS) Careers Workshop where expert career consultants will provide attendees with invaluable insight on a host of job-search topics guaranteed to excel one’s professional development and how to establish meaningful professional networks.

We’ve worked diligently to bring you an outstanding slate of speakers and poster presenters. We look forward to a remarkable conference that will have lasting impacts for generations to come.

We would like to give a special thank you to our sponsors and exhibitors, whose generous support made this event possible.

The Conference Organizing Committee Co-ChairsDr. Tina Bahadori, National Program Director, Chemical Safety for

Sustainability Research, U.S. Environmental Protection Agency John Frazier, Sr. Director of Chemical Innovation, Nike, Inc. Dr. Jim Hutchison, Lokey-Harrington Chair in Chemistry,

University of Oregon

18th Annual Green Chemistry & Engineering Conference2

Table of ContentsACS Green Chemistry Institute® . . . . . . . . . . . . . . . . . . . . . . . 1

Welcome Letter from the ACS President . . . . . . . . . . . . . . . . . . 3

Welcome Letter from the ACS Executive Director & CEO . . . . . . . . 4

2014 Conference Organizing Committee . . . . . . . . . . . . . . . . . 5

Keynote Speakers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

2014 Highlights & Events . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Welcome Reception . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Poster Session & Student Poster Competition . . . . . . . . . . . . . 7

Special Hybrid Session . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

GC&E Student Workshop . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Business Plan Competition . . . . . . . . . . . . . . . . . . . . . . . . . 9

ACS Careers Workshop . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Conference Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Conference Thematic Tracks . . . . . . . . . . . . . . . . . . . . . . . 10

How to Access Abstracts . . . . . . . . . . . . . . . . . . . . . . . . . 10

Information for Speakers . . . . . . . . . . . . . . . . . . . . . . . . . 10

Information for Press. . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Internet Access . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Conference Badge Policy . . . . . . . . . . . . . . . . . . . . . . . . . 12

Conference Program Books . . . . . . . . . . . . . . . . . . . . . . . 12

Program Schedule-at-a-Glance. . . . . . . . . . . . . . . . . . . . . . . 13

Tuesday Schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

Wednesday Schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

Thursday Schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

Wednesday Poster Session . . . . . . . . . . . . . . . . . . . . . . . . . 23

Congratulations to the Student Award Winners . . . . . . . . . . . . 29

Author Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

Maps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

Dates to Remember . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

Media Partners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44

Exhibitors . . . . . . . . . . . . . . . . . . . . . . . . . . Inside Back Cover

Sponsors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Back Cover

gcande.org


Welcome Letter From the ACS President As President of the American Chemical Society, it is my pleasure to extend a warm welcome to the attendees of the 18th Annual Green Chemistry and Engineering Conference (GC&E) in North Bethesda, MD.

I am pleased that you are joining what is one of the most premier conferences within the scientific community. The theme, “Advancing Chemistry, Innovating for Sustainability,” will unite a diverse network of leaders to explore and celebrate recent green innovations and applications at the cutting edge of chemistry and engineering. This year’s program features dynamic multi-session tracks that I am confident each of you will benefit from.

I am excited to be amongst so many green chemistry and engineering practitioners who share a determination in promoting and creating a more sustainable future. Together, we will continue to make a difference and change the course of chemistry as we know it. Again, welcome. I trust you will find this conference to be relevant and insightful.

Sincerely,

Tom Barton, Ph.D. President, American Chemical Society


Welcome Letter from the ACS Executive Director & CEO As Executive Director and CEO of the American Chemical Society (ACS), I am excited to extend my sincere greetings to all of the 18th Annual Green Chemistry and Engineering Conference (GC&E) attendees!

This is always an exciting time to support the ACS Green Chemistry Institute® (ACS GCI) as it works to inspire green chemistry and engineering enthusiasts. As the Institute annually convenes both domestic and international conference attendees, it continues to prove its dedication to make its mission of implementing green chemistry and engineering throughout the global enterprise a reality. As an attendee, you are actively forging a path towards a more sustainable planet and future for humanity. I am eager to participate in this year’s program and look forward to seeing each of you.

This year’s theme, “Advancing Chemistry, Innovating for Sustainability,” will highlight the importance of developing innovative solutions for current environmental and economic challenges and safer green chemistry and engineering practices. Sustainability has evolved into a prominent driver for innovation.

Thus, it is critical for us to capitalize on increasing the magnitude of our influence by combining our collective expertise as frontline agents of change.

Lastly, this year’s conference is particularly significant because it is my last GC&E Conference as Executive Director and CEO of ACS. In December 2014, I will retire from ACS, but not from my commitment to advancing sustainability awareness and research for greener chemistry approaches. It has been a pleasure to work with the ACS Green Chemistry Institute® staff, and I believe the best is yet to come! Again, welcome to the 18th Annual GC&E Conference. I look forward to a most productive and enjoyable meeting.

Sincerely,

Madeleine JacobsExecutive Director & CEO American Chemical Society

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2014 Conference Organizing CommitteeCOMMITTEE CHAIRS

Tina Bahadori

National Program Director

Chemical Safety for Sustainability Research Program

U.S. Environmental Protection Agency

John Frazier

Senior Director of Chemical Innovation

Sustainable Product Research and Discovery

Nike, Inc.

ORGANIZING COMMITTEE MEMBERS

David Allen University of Texas Eric BeckmanUniversity of Pittsburgh David Constable ACS Green Chemistry Institute® Julie Haack* University of Oregon Elaine Cohen Hubal* U.S. EPA Mary Kirchoff* American Chemical Society

Julie Manley* Guiding Green LLC Libby Sommer* Nike, Inc. Marty Spitzer* World Wildlife Fund Adelina Voutchkova-Kostal*George Washington University Julie Zimmerman*Yale University

Jim Hutchison

Lokey-Harrington Chair in Chemistry

Organic, Organometallic & Materials Chemistry

University of Oregon

*Theme leaders


CONFERENCE ADMINISTRATORS AND VOLUNTEERS

We extend a special “thank you” to our conference administrators.

Somalia Alsobrooks Mike Dickinson

Christiana Briddell Garinè Isassi

Patti Berkes Jennifer MacKellar

Cheryl Carter Savannah Sullivan

David Constable Graham Tiller

Jane Day

Also, a big thank you to ACS employees and contractors who have

worked to help us attain this level of success: Al Hutchins, John Katz,

Lara Kadylak, Nancy Blount, Doug Dollemore, Christine Brennan-

Schmidt, Samuel Toba, Erik Holderman, Tanya Fogg, Michael David,

Shawn Torres, and Adam Dylewski. In addition, we thank our onsite

interns and volunteers who’ve dedicated their time to help the

conference run smoothly. We couldn’t do it without you!

BUSINESS PLAN COMPETITION COMMITTEE

STUDENT POSTER CHAIR

Dan DalyAlabama Innovation and Mentoring of Entrepreneurs Center

Michael LefenfeldSiGNa Chemistry, Inc.

Rui ResendesGreen Centre Canada

Marty MulvihillUniversity of California - Berkeley

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Eric J. Beckman, PhD

George M. Bevier Professor of Engineering

Co-Director, Mascaro Center for Sustainable

Innovation

University of Pittsburgh

Seth Coe-Sullivan, PhD

Founder and CTO

QD Vision

Richard Blackburn, PhD

Senior Lecturer, MSc Advanced Textiles and

Performance Clothing Programme Leader

University of Leeds

Keynote Speakers

2014 Highlights & Events

WELCOME RECEPTION

The welcome reception is open to all conference registrants and

ticketed guests. Join your colleagues for hors d’oeuvres, drinks, and

networking on Tuesday, June 17, 2014, from 5:30 p.m. to 7:30 p.m. in

Ballroom D.

POSTER SESSION & STUDENT POSTER COMPETITION

The GC&E poster session will be held in two parts on Wednesday, June

18, 2014. Even numbers will present from 1:30 p.m. to 2:30 p.m. and

odd numbers from 2:30 p.m. to 3:30 p.m. Stop by and talk to the poster

presenters about their research! Judges will evaluate student posters.

Monetary prizes will be awarded to the top two posters. See page 23 for

a complete poster listing.


SPECIAL HYBRID SESSION

On Thursday, June 19th, at 2:00 p.m. there will be a special hybrid

(live + virtual) session titled, “Endangered Elements: Critical Materials

in the Supply Chain.” Hear from leading experts about the impact

of our chemical demands and how innovators are creating resilient

chemistries in the face of scarcity. Participants from around the world

will be able to watch and ask questions via a live webinar platform.

Invite your friends to watch at acswebinars.org/endangered-elements.

GREEN CHEMISTRY & ENGINEERING STUDENT WORKSHOP

“Greening Your Research”

Monday, June 16, 2014, 8:00 a.m. – 5:30 p.m.


1155 Sixteenth St., NW

Washington, DC 20036

Hach Building, Marvel Halls A-G

Instructors:

Marty Mulvihill, University of California - Berkeley

Marie Bourgeois, University of South Florida

David Constable, ACS Green Chemistry Institute®

Doug Raynie, South Dakota State University

As conventional reagents and key elements become increasingly

scarce and costly, it is crucial that young scientists understand how to

make their research greener. To help meet this need, the ACS Green

Chemistry Institute® is offering a full-day workshop where current

graduate and undergraduate students can learn and practice how

to evaluate the impact of chemicals and syntheses, and practice

determining the greenest options. Throughout the day students will

learn the concepts and tools professional chemists and engineers use

to make their science more sustainable. Via lectures and break-out

sessions, students will learn how to assess the efficiency and safety

of reactions and materials. Most importantly, participating students

have the opportunity to assess their own thesis, undergraduate lab,

or class lab with synthetic and analytical experts. This workshop is

generously supported by funds from the National Science Foundation.

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GREEN CHEMISTRY & ENGINEERING BUSINESS PLAN

COMPETITION

Wednesday, June 18, 2014

Linden Oak

Planning Committee:

Dan Daly, Director of Alabama Innovation and Mentoring of

Entrepreneurs Center

Michael Lefenfeld, President & CTO of SiGNa Chemistry, Inc.

Rui Resendes, Executive Director of Green Centre Canada

The 2014 GC&E Business Plan Competition provides a forum for early

stage, pre-revenue companies to pitch their business plan, and is

open to innovating individuals from across the world. The day will

begin with a session open to all conference attendees where the

semi-finalists will present their business plan to the judges, followed

by an expert panel that will discuss best practices and trends in

GC&E related entrepreneurship. In addition to competing for cash,

the competition is an excellent opportunity for entrants to receive

high-end constructive comments on their business plan, to interact

with experienced mentors, and to make valuable connections.

ACS CAREERS WORKSHOP

ACS Career Pathways, Finding Your Path

Wednesday, June 18, 2014, 6:00 p.m. – 10:00 p.m.

Glen Echo

Pre-registration required.

Instructor:

Jodi Wesemann, American Chemical Society

Organized by ACS GCI in collaboration with the ACS Careers &

Education Departments, conference attendees are invited to join an

expert career consultant from the American Chemical Society who

will provide a host of pertinent information guaranteed to accelerate

one’s professional development. Topics will include initial planning

and résumé preparation, maintaining an effective job search,

reviewing employment trends, enhancing professional skills, and

more. This information session will also be an excellent way for job

seekers to enhance their networking skills.


Conference Overview

CONFERENCE THEMATIC TRACKS

New this year, we have organized our technical programming into

thematic tracks. Tracks can be followed throughout the conference or

you can pick and choose elements of each throughout the day. Tracks

are identified on the pull out schedule, and include:

• Consumer Products • Greener Processes

• Critical Materials • New Chemical Feedstocks

• Design for Safer Chemicals • Organic Chemistry

• Education • Policy & Innovation

HOW TO ACCESS ABSTRACTS

To review speaker abstracts, go to abstracts.acs.org and log in with

your ACS ID. Click on the 18th Annual GC&E Conference under

“Specialty Meeting”, then click on “Online Program”. Continue to click

on gray links to see abstracts.

INFORMATION FOR SPEAKERSORAL PRESENTERSPlease check in at the Speaker Ready Room (Oakley Room) as soon as possible, but at least one hour before your presentation. This will allow for a final quality check and ensure that the formatting, fonts, animations, and other features of your presentation(s) will appear correctly during your session. The Speaker Ready Room computers are configured with the same hardware and software as those in the presentation rooms.

Speaker Ready Room Hours of OperationMonday, June 16th 3:00 p.m. to 5:00 p.m.Tuesday, June 17th 7:00 a.m. to 5:00 p.m.Wednesday, June 18th 7:00 a.m. to 5:00 p.m.Thursday, June 19th 7:30 a.m. to 3:00 p.m. Technical session rooms are equipped with the following standard AV equipment:• LCD projector with VGA • Podium with microphone

connection cable and switcher • Lavaliere microphone• Screen • PC computer• Laser pointer

You may bring your own computer, but we recommend that you use the computer equipment provided in each presentation room.

gcande.org


POSTER PRESENTERS

The poster session will be held Wednesday, June 18th in the White

Oak Room, from 1:30 p.m. to 2:30 p.m. for even numbered posters

and from 2:30 p.m. to 3:30 p.m. for odd numbered posters. Poster

numbers will be placed in the upper corner of each poster board.

This number corresponds with the number assigned to each paper as

listed in the printed program book. Authors must remain with their

poster for the duration of the session to discuss their results and

answer questions from judges and other attendees.

You are responsible for posting your material beginning Tuesday,

June 17th at 12:00 noon, but not later than Wednesday, June 18th at

10:00 a.m. All posters must be removed by 5:00 p.m. on Wednesday.

The ACS Green Chemistry Institute® will not assume responsibility for

any materials left behind after 5:00 p.m. on June 18th.

Each poster board measures 4’ high x 8’ wide, including the frame.

The live area for the poster board is approximately 46” x 94.5”. All

presentations must be confined to the dimensions of the poster board

itself. Computer display equipment, sound and projection equipment,

freestanding or three-dimensional displays, demonstrations,

experiments, or tables for handouts are not permitted.

INTERNET ACCESS

We have arranged with the conference center to provide free Wi-Fi

Internet access. The password is “Green”.

INFORMATION FOR PRESS

Your press pack, available at the Registration Desk, contains

conference press releases.

The conference hashtag is #gcande. Follow @ACSGCI for live-

conference updates on Twitter.

Staff is available to help arrange interviews. Please inquire at the

registration desk.

A Hybrid Session, “Endangered Elements: Critical Materials in the

Supply Chain” will be streamed live on Thursday, June 19, 2013

at 2:00 p.m. EDT and free registration is available at

acswebinars.org/endangered-elements.


CONFERENCE BADGE POLICY

Conference-issued name badges must be worn at all times during

the conference. Our “Badge on Demand” service will allow you to

print your badge upon arrival in the conference registration area.

If you lose your badge, please return to the conference registration

desk to request a replacement badge. The fee for replacing your

badge is $50.00 (payable by credit card only).

CONFERENCE PROGRAM BOOKS

To reduce waste we have printed only enough program books to

provide one copy to each registrant. If you misplace your copy,

please refer to the conference website at gcande.org for the online

conference program. The conference registration desk will be

happy to provide you with a replacement (or additional copy) of the

printed program book while supplies last for a fee of $25.00 (payable

by credit card only). Individual abstracts are not printed, but are

available online at abstracts.acs.org.

06.18.14

To apply for or find out more about

the 2014 challenge visit LAUNCH.org

gcande.org


Program Schedule-at-a-Glance Subject to Change

MONDAY, JUNE 16

8:00 a.m. – 5:30 p.m. Student Workshop

ACS Headquarters, Hach Building, Marvel Halls A-G

3:00 p.m. – 5:00 p.m. Registration Open

Lower Level Registration

TUESDAY, JUNE 17

7:00 a.m. – 5:00 p.m. Registration Open


7:30 a.m. – 8:30 a.m. Networking Breakfast

Grand Foyer

8:00 a.m. – 5:00 p.m. Exhibitions Open

Grand Foyer

8:30 a.m. – 8:35 a.m. Welcome Remarks

Ballroom D

8:35 a.m. – 9:30 a.m. Keynote Address: “Greener Quantum Dot

Synthesis for Energy Efficient, Commercial

Display and Lighting Products”

Presented by Dr. Seth Coe-Sullivan, Founder and

CTO, QD Vision, LLC

Ballroom D

9:30 a.m. – 10:00 a.m. Networking Coffee Break

Grand Foyer

10:00 a.m. – 12:20 p.m. Technical Sessions

(Refer to daily schedule for details)

12:20 p.m. – 1:30 p.m. Lunch (on own)

1:30 p.m. –2:50 p.m. Technical Sessions


2:50 p.m. – 3:20 p.m. Networking Break

Grand Foyer

3:20 p.m. – 4:20 p.m. Technical Sessions


5:30 p.m. – 7:30 p.m. Welcome Reception, Kenneth G. Hancock

Memorial Award Winners Announcement

Ballroom D


WEDNESDAY, JUNE 18

7:00 a.m. – 5:00 p.m. Registration Open


7:30 a.m. – 8:30 a.m. Networking Continental Breakfast

Grand Foyer


Grand Foyer

8:30 a.m. – 8:35 a.m. Welcome Remarks

Ballroom D

8:35 a.m. – 9:35 a.m. Keynote Address: “Sustainability Challenges

of The Apparel & Footwear Industry and

Opportunities for Innovation”

Presented by Dr. Richard Blackburn, Senior

Lecturer, MSc Advanced Textiles and Performance

Clothing Programme Leader, University of Leeds

Ballroom D


Grand Foyer



12:20 p.m. – 1:30 p.m. Networking Luncheon

Ballroom D

1:30 p.m. – 2:30 p.m. Poster Session – Even Numbers Only

White Oak

2:30 p.m. – 3:30 p.m. Poster Session – Odd Numbers Only

White Oak



6:00 p.m. – 10:00 p.m. ACS Careers Workshop (Must be registered.)

Glen Echo

6:00 p.m. – 9:30 p.m. 4th Annual ACS GCI Roundtable Poster Reception

Ballroom D

(Advanced registration required)

(Open to poster presenters and sponsors only

until 7:00 p.m.)

gcande.org


THURSDAY, JUNE 19

7:30 a.m. –3:00 p.m. Registration Open



Grand Foyer

7:30 a.m. – 8:30 a.m. Networking Breakfast

Grand Foyer

8:30 a.m. – 8:45 a.m. Welcome Remarks, Winners announced for

the Student Poster Competition and Applied

Separations Grant

Ballroom D

8:45 a.m. – 9:45 a.m. Keynote Address: “Innovation and the Green

Chemistry Enterprise”

Presented by Dr. Eric Beckman, George M. Bevier

Professor of Engineering, University of Pittsburgh;

Co-Director, Mascaro Center for Sustainable

Innovation

Ballroom D


Grand Foyer



12:35 p.m. – 1:35 p.m. Lunch (on your own)




Fostering collaborations across the value chain in industry for

chemical manufacturing, formulated consumer products,

hydraulic fracturing, and pharma.

Advance registration required.

are proud sponsors of the


®

4th Annual ACS GCI Roundtable Poster Reception

Wednesday, June 18, 20147:00 p.m.-9:30 p.m.

Ballroom D

7:00 a.m. – 5:00 p.m. Registration Open — Lower Level Registration

7:30 a.m. – 8:30 a.m. Networking Breakfast — Grand Foyer

8:00 a.m. – 5:00 p.m. Exhibition Open — Grand Foyer

8:30 a.m. – 9:30 a.m. Keynote Address: Greener quantum dot synthesis for energy efficient commercial display and lighting products. Presented by Dr. Seth Coe-Sullivan, Founder and CTO, QD Vision — Ballroom D

9:30 a.m. – 10:00 a.m. Networking Coffee Break — Grand Foyer

THEMATIC TRACKS EDUCATION GREENER PROCESSES DESIGN FOR CHEMICAL SAFETY GREENER PROCESSES NEW CHEMICAL FEEDSTOCKS

TECHNICAL SESSIONS

GREEN CHEMISTRY BEYOND THE BACHELORS DEGREE (….AND PHD) - PART I

EXPLORING GREENER APPROACHES TO HYDRAULIC FRACTURING DESIGNING SAFER CHEMICALS STUDIES IN GREEN CHEMISTRY BUILDING NEW CHEMICAL PLATFORMS

FROM BIOLOGICAL SYSTEMS

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B

J. Haack, Organizer, Session ChairJ. Manley, Organizer

D. Durham, D. Long, Session ChairsA. Voutchkova -Kostal, Organizer

A. Richard, Session ChairS. DeVito, Session Chair R. Wool, Organizer , Session Chair

10:00 a.m. – 10:20 a.m.

2. Lose the jargon, but don’t dumb it down: Lessons from a science communication fellowship. L. N. Vandenberg

7. Public controversy over hydraulic fracturing: The role of safer alternatives for fracturing fluids. R. Liroff

12. Bridging SAR and QSAR approaches for flagging or avoiding compounds with undesired toxicity profiles. A. Tropsha, D. Fourches, R. Politi, Y. Low, E. Muratov

19. Roots of green chemistry (1983-84) at the US Environmental Protection Agency: Investigation of substitutes for epichlorohydrin. G. E. Parris

26. Bio-renewable alternatives to petroleum-based polyesters using continuous flow. R. T. Mathers, D. Dakshinamoorthy, S. P. Lewis

10:20 a.m. – 10:40 a.m.

8. An environmentally-focused crosslinked gel system for hydraulic fracturing using chemicals sourced from the food industry. J. Holtsclaw, J. Weaver

13. Designing out toxicity by exploiting ‘Tox21’ computational approaches. G. Patlewicz, C. Kuseva, I. Popova, A. Mehmed, S. Kotov, T. Zhechev, T. Pavlov, S. Temelkov, P. Petkov, S. Dimitrov, O. Mekenyan

20. Defining the role of pollutant release and transfer (PRTR) information in global sustainability. S. C. DeVito

27. Who says monomers can’t grow on trees? The utilization of lignin bio-oil as a styrene alternative. K. H. Reno, M. G. Karavolias, D. P. Wool, D. H. Epps, III

10:40 a.m. – 11:00 a.m.

3. Beyond the PhD: Start-ups as early employee or founder. E. J. Beckman

14. Prediction of bioavailability from spectroscopic data: Quantitative spectra-property models for octanol/water partition coefficient, skin permeability and bioconcentration factors. N. An, Y. Tang, A. Voutchkova-Kostal

21. Merging automated green alternative assessments with quantitative REACH risk exposure algorithms. G. Thompson

28. Creating highly functional polyurethane dispersions with recycled raw material streams. R. Tabor, S. Mukerjee

11:00 a.m. – 11:20 a.m.

4. Sustainability is the key driver of innovation. D. R. Cooper-Hayes

9. Green solvents and microemulsions for stimulation A. Sehgal, R. Pabalan, & C. Aymes

15. Functionalized lignin-based environmentally-benign nanoparticles as replacement for antimicrobial silver nanoparticles. A. P. Richter, J. S. Brown, V. N. Paunov, S. D. Stoyanov, A. Wang, S. Gangwal, K. Houck, E. A. Cohen Hubal, O. D. Velev

22. Wealth from waste through green chemistry: GCNC contribution towards few real world cases in India. R. Sharma

29. Cellulose nanocrystals (CNCs) as supporters, reducers and chiral inducers. M. Kaushik, A. Moores

11:20 a.m. – 11:40 a.m.

5. Continuing education through the alternatives assessment community of practice. C. Baier-Anderson

16. Comparative external validation of common aquatic toxicity prediction tools: Informing selection and development of tools for alternatives assessment. F. Melnikov, A. Voutchkova-Kostal, J. Kostal, J. L. Tunkel, J. Zimmerman, P. T. Anastas

23. Bio-derived solvents in enzymatic catalysis. G. Paggiola, J. H. Clark, A. J. Hunt, C. R. McElroy, J. Sherwood

30. Chemical modification of sophorolipids for the synthesis of novel biomaterials. M. H. Schofield, M. L. Dahle, G. M. Sapienza

11:40 a.m. – 12:00 p.m.

10. Alternative to traditional biocidal chemicals in the oil and gas industry. D. Maley, B. O’Neil

17. Integrating informatics, SAR, QSAR, and decision theory to tease out undesired properties of molecules in chemical design. C. Yang, J. F. Rathman, C. H. Schwab, B. Bienfait

24. Advanced Silanes: Exploring sustainable and greener options for coatings applications. M. Singh, A. Maddox, H. Kiester, J. Matisons, J. Zazyczny, B. Arkles

31. High speed reactive extrusion processing for renewable polymer blends. M. S. Sobkowicz, J. Gug, X. Chen

12:00 p.m. – 12:20 p.m.

6. Driving innovations in green chemistry and educating on sustainability through life cycle assessment tools. B. W. Uhlman

11. Improved health, safety and environmental performance of a new field proven stimulation fluid in oilfield application. C. D. Wolf, B. Daigle, E. Bisinger, J. LePage, W. Braun

18. Mining the ToxCast chemical-data landscape for green chemical design: A SAR-Chem-Informed approach. A. M. Richard, P. Volarath, K. Mansouri, R. Judson

25. MoDRN: Rational design and development of the next generation chemicals. K. E. Mellor, E. Beach, F. Melnikov, L. Q. Shen, J. B. Zimmerman, J. Corrales, L. Kristofco, M. Mullins, G. Saari, E. Williams, J. Kostal, C. Schaupp, M. Mills, T. Kavanagh, N. Simcox, A. Voutchkova-Kostal, E. Gallagher, B. Brooks, P. Anastas

32. Shear-enhanced membrane processes for efficient biomass concentration in the design of biorefineries. C. Slater, M. J. Savelski, P. Kostetskyy, M. Johnson

SCHEDULE / Tuesday, June 17, 2014Seth Coe-Sullivan, PhDFounder and CTOQD Vision

gcande.org

Advancing Chemistry, Innovating for Sustainability 17

SCHEDULE / Tuesday, June 17, 2014

gcande.org



THEMATIC TRACKS EDUCATION ORGANIC CHEMISTRY DESIGN FOR CHEMICAL SAFETY GREENER PROCESSES NEW CHEMICAL FEEDSTOCKS

TECHNICAL SESSIONS

GREEN CHEMISTRY BEYOND THE BACHELORS DEGREE (….AND PHD) - PART II

SAFER AND MORE EFFICIENT APPROACHES TO HIGHLY REACTIVE CHEMISTRY KNOWLEDGE AND TOOLS TO EVALUATE ALTERNATIVES SUSTAINABLE PRACTICES IN BIOPHARMACEUTICALS ABUNDANT INNOVATION: PATHWAYS TO FEEDSTOCKS

FROM CO2 AND NATURAL GAS

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B

J. Haack, Organizer, Session ChairA. Marteel Parrish, Session Chair

J. Manley, OrganizerJ. Tucker, Session Chair

A. Voutchkova -Kostal, OrganizerE. Cohen Hubal, Session Chair

J. Manley, OrganizerK. Budzinski, Session Chair

J. Jackson, Organizer, Session Chair

1:30 p.m. – 1:50 p.m.

33. Connecting students with real-world applications of chemistry through project-based courses, outreach, and a focus on science communication. M. J. Mulvihill, M. Schwarzman, M. Douskey

40. A method for aromatic nitration which demonstrates remarkable thermal stability. L. Desai, G. Beutner, D. Fanfair, P. Lobben, M. Eastgate

44. Cheminformatic approaches for toxicity prediction. G. Daston

51. Greener biopharmaceuticals production: Evaluating ancillary substances using spatially explicit environmental risk assessment methods. J. Straub, R. Shearer, J. Klemmer, M. Studer

86. From waste to wealth using green chemistry. J. Clark

1:50 p.m. – 2:10 p.m.

34. Network of Early-Career Sustainable Scientists and Engineers (NESSE): An initiative from the ACS Summer School on Green Chemistry and Sustainable Energy 2013. C. Coss, J. Dodson, O. Zaskoka, M. Mastronardi, L. Hoch

45. Rapid in silico methods to characterize and predict ADME properties for chemical toxicity and exposure prioritization. D. T. Chang, C. M. Grulke, Y. Yin, R. Tornero-Velez, M. A. Pasquinelli, M. Goldsmith

57. (1:55 p.m.) Greenhouse gas and energy life cycle assessment of pine chemicals derived from crude tall oil: Benefits of material versus biofuel use. S. Cashman, K. Moran

2:10 p.m. – 2:30 p.m.

35. Project GreenLab: A regional student-faculty collaboration in green chemistry curriculum development, research and outreach education. E. J. Brush

41. A green ozonolysis/oxidation process to produce multi kilograms of drug substance. B. M. Cochran

46. Showcase of ChemView: EPA’s online database to access information under the Toxic Substances Control Act. D. Parsons, E. Lavoie, M. Doa, M. Leopard, S. Canavan, Y. Gonzalez, T. Klosterman, P. Lewis

52. EMD Millipore’s biopharmaceutical product recycling program. J. Ignacio

59. (2:15 p.m.) The acid-base chemistry of CO2 capture with liquid amines. S. Calabro, L.S. Baugh, P. Kortunov, M. Siskin.

2:30 p.m. – 2:50 p.m.36. Impact of active student participation on driving the

green chemistry conversation. L. B. Hoch47. Functional use: An underappreciated foundational

concept in advancing safer chemistry. J. A. Tickner, J. N. Schifano

2:50 p.m. – 3:20 p.m. Networking Break — Grand Foyer 42. From batch to flow processing: Benzimidazole ring formation via catalytic heterogeneous hydrogenation. J. Chen, K. Przyuski, R. Roemmele, R. P. Bakale

Networking Break — Grand Foyer (3:00 p.m.) Networking Break — Grand Foyer

3:20 p.m. – 3:40 p.m.

37. Mentoring graduate students in research and teaching by utilizing research as a template. M. N. Jackson Jr, C. C. Knutson, M. Beekman, M. E. Carnes, D. W. Johnson, D. A. Kezler

48. Incorporating SAR and high-throughput screening data into alternatives assessment: Challenges and opportunities. C. Baier-Anderson, E. T. Lavoie

53. Ultra low temperature freezer evaluations: NIH main campus. L. Gumapas

58. (3:30 p.m.) Nitrogen heterocycles as a hydrogen alternative in polymer electrolyte membrane fuel cells. L. K. Rubin, E. Deunf, K. T. Clark, S. Gottis, D. Faulkner, C. D. Vulpe, J. B. Kerr, J. Arnold 43. Making bonds safely in water @ RT. B. H. Lipshutz

3:40 p.m. – 4:00 p.m.38. Green chemistry high school professional

development: For teachers, by teachers. A. S. Cannon, K. Anderson

49. Developing systematic review approaches for mechanistic data and the relevance to chemical alternatives assessment. J. A. McPartland, J. A. Lam

54. Bioinspired technologies for sustainability: From fully compostable bioplastics to human organs-on-chips. D. E. Ingber

55. (3:50 p.m.) New materials for solar fuels from CO2. A. Bocarsly

4:00 p.m. – 4:20 p.m.39. Learn to see green with GREEN. D. E. Hogan, C. Coss,

R. Eismin50. Using Chemical Hazard Assessment for Informed

Substitution: Applications of GreenScreen for Safer Chemicals. L. Heine

4:20 p.m. – 4:40 p.m.

4:40 p.m. – 5:00 p.m.

56. (4:40 p.m.) Biodiesel production via transesterification using carbon dioxide-methanol mixtures in the presence of a heterogeneous catalyst. L. Soh, C. Chen, E. Beckman, J. Zimmerman

5:30 p.m. – 7:30 p.m. Welcome Reception – Kenneth G. Hancock Award Winners Announcement — Ballroom D

SCHEDULE / Wednesday, June 18, 2014

gcande.org




8:00 a.m. – 5:00 p.m. Exhibition Open — Grand Foyer

8:30 a.m. – 9:35 a.m. Keynote Address: Sustainability challenges of the apparel & footwear industry and opportunities for innovation. Presented by Dr. Richard Blackburn, Professor, University of Leeds; Head, Sustainable Materials Research Group — Ballroom D


THEMATIC TRACKS ORGANIC CHEMISTRY NEW CHEMICAL FEEDSTOCKS EDUCATION DESIGN FOR CHEMICAL SAFETY CONSUMER PRODUCTS

TECHNICAL SESSIONS

COMMERCIALIZING RESEARCH ADVANCES - PART I

FROM WASTE TO WEALTH: CHEMICALS FROM DISCARDED FOOD AND TRASH

GREEN CHEMISTRY EDUCATION: CHARTING THE COURSE AHEAD

WORKSHOP - MAKING TOOLS FOR SAFER CHEMICAL DESIGN WORK FOR YOU

INNOVATIVE AND SUSTAINABLE SOLUTIONS IN APPAREL AND FOOTWEAR - PART I BUSINESS PLAN COMPETITION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B Linden Oak

J. Manley, OrganizerD. Leahy, Session Chair

J. Clark, Organizer, Session ChairJ. Haack, Organizer

E. Brush, Session ChairJ. Kostal, Organizer, Session Chair J. Frazier, Organizer, Session Chair

D. Daly, M. Lefenfeld, R. Resendes, Organizers, Session Chairs

10:00 a.m. – 10:20 a.m.

62. The academic side of industrial collaborations aimed at advancing catalytic C–H borylations. R. E. Maleczka, Jr, M. R. Smith III

66. 5-(Chloromethyl)furfural (CMF) is the new HMF: Functionally equivalent but more practical in terms of its production from biomass. M. Mascal, E. B. Nikitin, S. Dutta, I. Gandarias, F. Chang

73. Integrating LCA into an introductory engineering course on material and energy balances. M. J. Savelski, C. Slater, G. Brereton, M. Oakley, S. Schanck

19. Making tools for safer chemical design work for you. L. Heine, K. Houck, J. Wang. This workshop will arm toxicologists and chemists with practical approaches for the rational design of safer industrial chemicals. Participants will learn the basics of computational theory and how computations can be paired with experimental findings to design chemicals with minimal biological activity. Specifically, tutorials will demonstrate how property-based design guidelines can be applied to maximize probability that chemicals will not exert acute or chronic toxicity to aquatic species and mammals. In learning about model development, the presenters will also outline sources of experimental data, which can be used to train computational models, as well as future strategies for secure data-sharing. Finally, participants will learn how data from models can be used for chemical hazard assessment, and drive development of decision-making frameworks that translate scientific progress to action items for the user or the regulator.

80. Applications of scCO2 as a “green” solvent in the textile industry. A. Lutz, R. Schlake, R. May, M. Anand, P. Hobbs

Semi-Finalists will be presenting their business plans:

SioTeX. L. Taylor & A. KotwalCirca Group. S. CaddeduCell-Free Bioinnovation. Z. ZhuU.S. Bioplastics. S. MillerHydroCoat. T. Shultz10:20 a.m. – 10:40 a.m.

63. C-H Borylation: Gateway to molecular diversity. S. W. Krska, T. Cernak, R. Dermenjian, K. Dykstra, B. Ghaffari, Y. Liu, P. Maligres, K. Moore, C. Parish, D. Perera, D. Plattner, S. Preshlock, M. Reibarkh, F. Shen, E. Streckfuss, S. Tyagarajan, P. Vachal, R. Maleczka, M. Smith

67. Biomass valorisation, sustainable materials and the methanol economy. R. J. White

74. Adapting a one-semester Green and Sustainable Chemistry course to the demands of the 21st century. A. Marteel-Parrish

81. Extend your cotton knits lifetime with biopolishing, develop consumer loyalty and achieve significant sustainability benefits. G. A. Screws

10:40 a.m. – 11:00 a.m.

68. A high-power and high-energy-density biobattery running on renewable sugars. Z. Zhu, Y. Zhang, J. Rollin

75. EPA-sponsored model program in sustainability: The Institute for Green and Sustainable Science summer program. C. S. Lecher

82. Pure solutions chemical line for industrial laundries. L. Boyd

11:00 a.m. – 11:20 a.m.

69. Alginic acid derived mesoporous carbonaceous materials as super-adsorbents for the removal of bulky dyes from waste waters. H. J. Abdoul, V. L. Budarin, M. De bruyn, J. H. Clark

76. Student-driven and teacher-supported, design-thinking approach toward the integration of STEAM activities into, and augmentation of, an existing high school curriculum. R. L. Broadrup, K. Umunna, M. Pereira, S. Lee

83. Waterborne polyurethane: A strong lever towards improved performance and sustainability in apparel and footwear materials. N. Smith

11:20 a.m. – 11:40 a.m.

64. Selective C-H activation borylation ortho to fluorine on fluoroaromatic systems. J. Oppenheimer, M. R. Smith, III, R. E. Maleczka, Jr, H. Li, D. Shabashov, C. Jayasundara

70. Valorization of rice bran and other agro-industry wastes by extraction of oil and esterification over solid catalysts. N. Ravasio, F. Zaccheria, M. Mariani, R. Psaro

77. The Green Chemistry Commitment: Resources for implementing green chemistry student learning objectives. A. S. Cannon

84. Biobased composites for applications in footware and apparel. R. Wool, S. Gong, X. Su, H. Cao

11:40 a.m. – 12:00 p.m.

71. Bioprocess development for the production of ethyl lactate from dairy waste. M. Koutinas, M. Menelaou, E. N. Nicolaou

78. A green chemistry experiment for undergraduates: Eugenol titration. P. Chen, H. Barcena

85. Where did my ZnO go? T. Wilson III

12:00 p.m. – 12:20 p.m.65. The NSF SusChEM Initiative. T. Li 79. Detection of ethidium bromide residues in

a teaching laboratory. H. Barcena, A. Gorbenko, P. Chen

12:20 p.m. – 1:30 p.m. Networking Lunch and Dedicated Exhibitor Time - Announcement of the Business Plan Competition Winners — Ballrom D and Grand Foyer

R ichard Blackburn, PhDProfessor, University of Leeds; Head, Sustainable Materials Research Group University of Leeds

SCHEDULE / Wednesday, June 18, 2014

gcande.org


1:30 p.m. – 2:30 p.m. Poster Session – Even Numbers Only — White Oak

2:30 p.m. – 3:30 p.m. Poster Session – Odd Numbers Only — White Oak

THEMATIC TRACKS ORGANIC CHEMISTRY CRITICAL MATERIALS EDUCATION NEW CHEMICAL FEEDSTOCKS CONSUMER PRODUCTS

TECHNICAL SESSIONS

COMMERCIALIZING RESEARCH ADVANCES - PART II

FROM WASTE TO WEALTH: CHEMICALS FROM E-WASTE

ADVANCING SUSTAINABILITY THROUGH THE ACS SUMMER SCHOOL ON GREEN CHEMISTRY

AND SUSTAINABLE ENERGY

GREENING THE SUPPLY CHAIN USING BIOBASED CHEMICALS - PART I

INNOVATIVE AND SUSTAINABLE SOLUTIONS IN APPAREL AND FOOTWEAR - PART II BUSINESS PLAN COMPETITION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Brookside B Linden Oak

J. Manley, OrganizerD. Leahy, Session Chair

A. Matharu, Organizer, Session ChairM. Kirchhoff, Organizer

J. F. Stanzione, Session Chair

J. Manley, OrganizerP. Williams , B. Comanita, Session Chairs

A. Phillips, Session ModeratorJ. Frazier, Organizer, Session Chair

D. Daly, E. Beckman, R. Resendes, Organizers, Session Chairs

3:30 p.m. – 3:50 p.m.

157. Bicyclic nitroxyl (co)catalyzed aerobic alcohol and amine oxidation. J. E. Steves, K. Miles, J. Kim, M. Lauber, J. Hawkins, S. S. Stahl

161. Rare metals recovery and recycling in the context of an integrated critical materials strategy. A. H. King

Introductory Remarks. 172. Composites from plant oil-based resin. A. Campanella

176. Chemicals management and green chemistry. S. Echols, J. Frazier

Panel Discussion: Innovating with Science, Technology, & Entrepreneurship

Panelists:D. DalyE. BeckmanR. Resendes Grand Prize Winner

165. (3:35 p.m.) Teaching green chemistry to undergraduate students and advances in green synthesis of nanomaterials. A. H. Moores, M. J. Rak

3:50 p.m. – 4:10 p.m.

166. (3:55 p.m.) Covalent tethering of earth-abundant metal corrole catalysts with applications to oxygen reduction in a PEM fuel cell. H. L. Buckley, D. T. Gryko, J. Arnold

177 Beyond the RSL: Taking an attributes-based approach to preferred chemicals. J. Rinkevich162. (4:00 p.m.) Development of a

thermodynamic database for rare metal recovery and recycling. I. Jung, M. Van Ende, Y. Kim, T. Kim

4:10 p.m. – 4:30 p.m.

158. Flow oxidations and reductions with heterogeneous catalysts. J. M. Hawkins

167. (4:15 p.m.) Lignin-based plastics and a hands-on biodiesel project for first-year engineering students. J. F. Stanzione, III, S. Farrell, R. P. Wool

173. Growing with Ingeo lactide derivatives. M. Natal

178. Hazard and risk assessment for process chemicals in textile factories: Practical considerations of process and utility. S. B. Moore

4:30 p.m. – 4:50 p.m.

163. (4:30 p.m.) Green technologies for Elemental Recovery and Sustainability. A. J. Hunt, H. L. Parker, A. Muñoz García, V. L. Budarin, L. Rylott, N. Bruce, J. H. Clark

168. (4:35 p.m.) 1,1-Dimethyl-2,3,4,5-tetraphenylsilole as a molecular rotor probe to investigate the microviscosity of imidazolium ionic liquids. R. E. Scalise, P. A. Caradonna, H. J. Tracy, J. L. Mullin, A. E. Keirstead

179. Is ‘blue’ the new green? P. Johnson

4:50 p.m. – 5:10 p.m.

159. Transforming organic synthesis from chemistry in organic media to chemistry in water: Suzuki-Miyaura cross-couplings. B. H. Lipshutz

169. (4:55 p.m.) Metal oxide nanostructures for CO2 photoreduction. L. B. Hoch, T. E. Wood, P. G. O’Brien, L. M. Reyes, K. Liao, G. A. Ozin

174. A pine-based solution for increasing recycled asphalt pavement content in new road construction. P. Williams, R. Severance

180. Archroma One Way sustainability tool. P. Cowell

164. (5:00 p.m.) Critical elements in electronic applications. N. T. Nassar

5:10 p.m. – 5:30 p.m.

170. (5:15 p.m.) Transforming from a student seminar series into an interdisciplinary campus center with help from the green chemistry community and the ACS Summer School. M. J. Mulvihill

181. Green chemistry challenge. L. Adams

5:30 p.m. – 5:50 p.m.

160. The development of new enzymatic platforms for accessing chiral amines. G. Hughes

Panel Discussion on e-waste and rare metals. 171. (5:35 p.m.) Effects of PFOS and other perfluorinated compounds on the permeability of a black lipid membrane model system. C. Martinez, S. Ferguson, D. Scoville, P. Novak, N. Mohapp

175. Use of soy and bio-based materials in industrial applications. L. Kim-Habermehl

182. EcoChem: Where the new value chains meet. N. Hawker

(5:55 p.m.) Concluding Remarks.

6:00 p.m. – 10:00 p.m. ACS Careers Workshop (Advanced registration required) - Glen Echo

7:00 p.m. – 9:30 p.m. 4th Annual ACS GCI Roundtable Poster Reception (Advanced registration required) - Ballroom D

SCHEDULE / Thursday, June 19, 2014

gcande.org




7:30 a.m. – 3:00 p.m. Exhibitions Open — Grand Foyer

8:30 a.m. – 8:45 a.m. Welcome Remarks and Announcement of Student Poster Awards.

8:45 a.m. – 9:45 a.m. Keynote Address: “Innovation and the Green Chemistry Enterprise” Presented by Dr. Eric Beckman, George M. Bevier Professor of Engineering, University of Pittsburgh; Co-Director, Mascaro Center for Sustainable Innovation — Ballroom D


THEMATIC TRACKS ORGANIC CHEMISTRY NEW CHEMICAL FEEDSTOCKS CRITICAL MATERIALS CONSUMER PRODUCTS POLICY AND INNOVATION

TECHNICAL SESSIONS CATALYSIS IN GREEN CHEMISTRY

GREENING THE SUPPLY CHAIN USING BIOBASED CHEMICALS

PART II

USING EARTH ABUNDANT ELEMENTS TO REPLACE CRITICAL MATERIALS

GREENING THE SUPPLY CHAIN: DEFINING GREENER AND MORE SUSTAINABLE CONSUMER PRODUCTS

PART ITRENDS IN GREEN CHEMISTRY INNOVATION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Ballroom A

J. Manley, OrganizerN. Strotman, Session Chair

J. Manley, OrganizerP. Williams , B. Comanita, Session Chairs

A. Phillips, Session Moderator

L. Sommer, OrganizerJ. Hutchison, Session Chair

J. Manley, OrganizerP. Sliva, Session Chair

M. Spitzer, K. Weber, K. Clansky, K. Roberts, J. Jackson, Organizers M. Spitzer, Session Chair

10:15 a.m. – 10:35 a.m.

184. Evolution of dirhodium(II) catalyzed oxidations by tert-butyl hydroperoxide for practical applications. M. P. Doyle, M. O. Ratnikov

189. Transforming waste gases to low carbon fuels and chemicals. M. Koepke

193. Investing in the future of materials innovation. C. Wadia

199. Johnson & Johnson’s Earthward process: Moving toward a healthy future. M. Chung, R. Predale

Introductory Remarks.

203. (10:20 a.m.) Economic benefits of green chemistry process innovations. R. P. Wool

10:35 a.m. – 10:55 a.m. 204. (10:40 a.m.) Lessons from the PureBond experience. T. Vogelsinger

10:55 a.m. – 11:15 a.m.

185. Asymmetric alkene hydrogenation with cobalt catalysts: Moving away from precious metals. M. R. Friedfeld, M. Shevlin, J. M. Hoyt, S. W. Krska, M. T. Tudge, P. J. Chirik

190. Solvent elimination from large scale processing of plant materials for purification of low abundance enzymes. R. Mehigh

194. Critical material alternatives energy applications: R&D at DOE. E. Rohlfing

200. Green products, green commerce, and life cycle assessment. M. H. Wolf

205. (11:00 a.m.) NGO trends driving innovation in green chemistry. E. Simon

11:15 a.m. – 11:35 a.m.

186. Effect of CO2 pressure and water on the Suzuki coupling of basic nitrogen containing substrates. C. Senter, A. Rumple, W. Medin-Ramos, D. Houle, L. Cheng, J. Fisk, B. Holden, P. Pollet, C. A. Eckert, C. L. Liotta

198. Fe(0) Nanoparticles as sustainable catalysts for the hydrogenation reaction and catalysts supports for the Huisgen condensation. A. H. Moores, R. Hudson, S. Ishikawa, M. Masnadi Khiabani, A. Castonguay, M. Bateman

Discussion

11:35 a.m. – 11:55 a.m.

187. Base metal catalysts for the synthesis of organoboron compounds. J. V. Obligacion

191. Green chemistry in the agrochemical industry: Chiral bio-based building blocks as starting material for crop protection compounds. M. P. Fleer, B. J. Verkuijl

195. Reductive disassembly of lignin and lignocellulose using earth-abundant catalysts. P. C. Ford, K. Barta, A. V. Iretskii, S. L. Scott

201. Execution, performance, and benefits of sustainable cleaning programs. N. B. Green, II

206. (11:30 a.m.) Turing greem chemistry into commercial reality: The Coca-Cola Company’s Global PlanBottle® Program. M. Schultheis

207. (11:45 a.m.) Constrained resources, sustainability, performance: Key drivers for innovation. J. Frazier

11:55 a.m. – 12:15 p.m.

188. Aggressive use of green technologies in the development of a benign manufacturing process for the potent PARP inhibitor, niraparib. K. M. Belyk, C. K. Chung, P. Bulger, B. Kosjek, N. Rivera, M. Scott, G. R. Humphrey, J. Limanto, D. C. Bachert, K. M. Emerson

196. Earth-abundant materials in energy sustainability: Encapsulation of iron pyrite (FeS2) nanoparticles in an elastic carbon matrix for Li-ion battery cathodes. T. S. Yoder, M. Tussing, J. E. Cloud, Y. Yang

(12:00 p.m.) Breakout discussion.

12:15 p.m. – 12:35 p.m.

231. Delivering performance and sustainability with polymers of itaconic acid into a market of changing trends, labels and laws. Y. Durant

197. Heterogeneous 1st row metal C-H oxidation catalyst derived from dicobalt octacarbonyl and 1,2-bis(diphenylphosphino)ethane. S. L. Collom, R. H. Crabtree, P. T. Anastas

202. The challenges involved in formulating green products for the I&I market. M. Gottardi


Eric J. Beckman, PhDGeorge M. Bevier Professor of EngineeringCo-Director, Mascaro Center for Sustainable InnovationUniversity of Pittsburgh

SCHEDULE / Thursday, June 19, 2014


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22

THEMATIC TRACKS ORGANIC CHEMISTRY GREENER PROCESSES CRITICAL MATERIALS CONSUMER PRODUCTS POLICY AND INNOVATION

TECHNICAL SESSIONS

GREENER CHEMISTRY THROUGH KINETICS AND MECHANISTIC UNDERSTANDING

TOOLS AND METRICS FOR INDUSTRIAL IMPLEMENTATION OF GREEN CHEMISTRY

ENDANGERED ELEMENTS: CRITICAL MATERIALS IN THE SUPPLY CHAIN

GREENING THE SUPPLY CHAIN: DEFINING GREENER AND MORE SUSTAINABLE CONSUMER PRODUCTS

PART II

REGULATORY LANDSCAPE AND IMPLICATIONS FOR INNOVATION

Ballroom B Ballroom C White Flint Amphitheater Brookside A Ballroom A

J. Manley, OrganizerL. Desai, Session Chair

J. Manley, OrganizerR. Giraud, Session Chair

D. Constable, Organizer, Session ChairJ. Manley, OrganizerP. Sliva, Session Chair

M. Spitzer, K. Weber, K. Clansky, K. Roberts, J. Jackson, OrganizersL. Bergeson, Session Chair

1:35 p.m. – 1:55 p.m.

213. Understanding the pharmaceutically relevant maillard reaction. M. E. Kopach, S. W. Baertschi, M. E. Kobierski, M. Hawk, A. Dion, M. L. Williamson, C. H. Hyzer, P. J. Jansen

217. Coatings with improved eco-footprint through the use of polymer pigment composites. J. Bohling, D. Fasano

227. Transparency in cleaning product formulation: What do we know about ingredients and available hazard data? P. C. DeLeo, E. S. Williams, M. Ciarlo, C. Horne, B. Greggs

Introductory Remarks.

208. (1:40 p.m.) Setting up a new trend in EPA PMNs: Using the P2 page to your company’s advantage. L. Bergeson

1:55 p.m. – 2:15 p.m.218. Innovating with intent: Science and sustainability

at Eastman. D. Kossor (2:00 p.m.) Introductory Remarks.

224. (2:05 p.m.) R. Eggert 209. (2:00 p.m.) State chemical management initiatives’ undercurrent of green chemistry. E. Tipaldo

2:15 p.m. – 2:35 p.m.214. Mechanistic studies on the synthesis of sulfilimines

with Chloramine. T. G. Beutner, J. Nye, A. Ortiz, B. Remy, C. Sfouggatakis

219. Eco-footprint : A new tool for the Made in CHIMEXTM considered approach. S. Duprat de Paule

225. (2:25 p.m.) P. Chirik 228. Green chemistry alternatives: An industry perspective. J. T. Gannon 210. (2:20 p.m.) REACH: From Europe to Asia. S. Hong

2:35 p.m. – 2:55 p.m. 220. Program for assisting the replacement of industrial solvents (PARIS III). P. F. Harten

226. (2:45 p.m.) A. Matharu (2:40 p.m.) Q&A and Discussion.

2:55 p.m. – 3:15 p.m.

215. A few of my favorite rings: Catalysis inspired by macrocycles. V. M. Dong

221. Sustainability assessment and feedback model for development of pyrolysis processes to produce biofuels from waste pinewood chips: Framework and results. A. D. Patel, M. Zabeti, K. Seshan, M. Patel

(3:05 p.m.) Panel Discussion. 229. A review of the FTC’s guides for the use of environmental marketing claims (the ‘Green Guides’). L. Koss, L. Kim

211. (3:00 p.m.) Regulatory Approvals: The gatekeepers to commercialization. A. L. Shafer

3:15 p.m. – 3:35 p.m.

222. TRI’s pollution prevention search tool: New metrics for assessing progress in green chemistry and sustainability. D. Teitelbaum

212. (3:20 p.m.) Moving California towards flame retardant-free furniture and baby products. M. Green, C. Cox, J. Levin

(3:40 p.m.) Discussion and Brainstorm.

3:35 p.m. – 3:55 p.m. 216. Ru-catalyzed 1,4-dynamic kinetic resolution involving vinylogous enolates. N. A. Strotman, J. Deerberg, O. Soltani, D. Treitler

223. Tracking green chemistry advances using EPA’s Toxics Release Inventory. C. Keenan

230. Valuing natural capital in your supply chain. L. Bernick

3:55 p.m. – 4:15 p.m.

gcande.org


Wednesday Poster Session

1:20 p.m. – 2:30 p.m. Poster Session (even numbers)

2:30 p.m. – 3:30 p.m. Poster Session (odd numbers)

White Oak

Student Poster Chair: Marty Mulvihill

CONSUMER PRODUCTS

87. Sustainable packaging: A life cycle analysis of beverage

packaging materials. E. Dave, M. Moscherosch

CRITICAL MATERIALS

88. Increased efficiency of gold conversion via a re-seeding

approach. S. A. Canonico-May, J. W. Stone

89. Recovery of critical materials from wastestreams using

biosurfactants. D. E. Hogan, J. E. Pemberton, R. M. Maier

90. Acceptorless dehydrogenation of alcohols: Catalytic

synthesis of imines using base metal recyclable catalysts

under mild conditions. J. Bain, A. Voutchkova-Kostal

91. Development of homogeneous iron-based catalysts for

the hydrogenation of carbonyl groups. E. A. Meucci,

J. B. Elder, S. L. Willis, L. Boisvert

DESIGN FOR CHEMICAL SAFETY

92. The Chemistry Scoring Index (CSI): A comparison to other

hazard ranking tools. K. Reid, T. Verslycke, T. Bowers,

A. Lewis, D. Tuck, J. Sanders

93. Quantum mechanical In Silico tools for prediction of skin

sensitization and aquatic toxicity. J. Kostal, A. Voutchkova,

P. Anastas, J. Zimmerman

94. Framework for the toxicological assessment of industrial

compounds during the chemical design process.

D. Faulkner, C. Genualdi, C. Hill, L. Rubin, D. Johnson,

C. D. Vulpe


EDUCATION

95. Charting a green path ahead: Texas Woman’s University’s

journey to sustainability. D. Caltrider, E. Springer,

R. D. Sheardy

96. Epoxidized soybean oil: A green chemistry undergraduate

experiment. Y. Zhang, H. Barcena

GENERAL

97. Microwave assisted acid and alkaline pretreatment for

sugarcane bagasse. Z. Zhu

99. Thermochemical properties of greenhouse gases:

Perhalocarbons and hydrohalocarbons. K. R. Jorgensen

100. Planetary boundaries as criteria to guide life cycle

assessments: A case study comparison of a battery electric

vehicle and a vehicle powered by a gasoline internal

combustion engine. W. Ayling

101. What are we talking about? How sustainable and green

chemistry are communicated. C. Briddell

102. Effect of a natural cactus based-mucilage dispersant on

the surface tension and droplet size of dispersed crude

oil. F. Guo, D. Stebbins, T. Peng, R. Falahat, S. Thomas,

R. Toomey, N. Alcantar

103. Integration of nanotechnology and bioremediation: A

strategy for the environmental sustainability of soils in

the south of PR. A. G. Colon Santiago, G. Maldonado,

B. J. Collazo, J. I. Ramirez Domenech, E. J. Ferrer Torres,

E. Medina

104. Naturally removing ammonia for preserving bait and

fresh caught fish. W. Zhao, D. Stebbins, S. Sandra Pettit,

S. Ergas, N. Alcantar

106. A green approach to the digestion of environmental,

mineral, and ore samples for elemental analysis.

I. D. Brindle, Y. Wang, R. Kanipayor

gcande.org


107. Photocatalysis and radiation induced degradation of

ciprofloxacin in water. H. M. Khan, M. Sayed, M. Ismail

108. Multi-stakeholder recommendations for sustainable

chemical alternatives assessment. R. Francis, D. Muir,

P. Spencer, J. Young Tanir

109. Energy efficient process for the decomposition of

polyfluorinated compounds using palladium doped

nanoscale zerovalent iron and common oxidants.

W. A. Lawal, H. Choi

110. Corrosivity of choline chloride-based deep eutectic

solvents. A. J. Robison, T. Letcher, D. Raynie

GREENER PROCESSES

111. Development of a tripartite solvent blend for sustainable

chromatography. F. M. Chardon, S. G. Koenig, N. Blaquiere,

G. Castanedo

112. Alternative solvents and technologies for precision

cleaning operations. H. Grandelli, P. Maloney, R. DeVor,

P. Hintze

113. Creating carbon dioxide free cement, the Solar Thermal

Electrochemical Process (STEP) for converting calcium

carbonate to calcium oxide with no carbon dioxide

emissions. J. Lau, O. El-Ghazawi, F. Meng, F. Li, J. Stuart,

S. Licht

114. From batch to continuous-flow processes: The Meerwein-

Ponndorf-Verley reduction and the homo-Nazarov

cyclization reactions. W. Woodham, R. Shenje, J. Aponte-

Guzman, Y. Huang, P. Pollet, S. France, C. Eckert, C. Liotta

115. Ionic liquid-immoibilized palladium catalysts on tunable

hydrotalcite clays: Catalytic activity and support

interactions. M. Finn, A. Moran, A. Voutchkova-Kostal

116. Magnetically recoverable Cu-Fe catalysts for the synthesis

of biocompatible molecules via “click” chemistry:


Application to the synthesis of a rhodamine-labeled

hormone. M. Bateman, A. Castonguay, M. Masnadi Khiabani,

D. Maysinger, C. Li, A. Moores

117. Scaleup of subcritical water extraction of polyphenolic

compounds from fruit waste material. R. Schlake,

A. Kaziunas, J. King

118. Polyaldehyde route to production of metal nanoparticles.

H. Gowda, M. Daniel-Onuta, Y. Kostov

119. Dynamic mixing of polyurethane materials in a closed

system. S. L. Steelman, M. Jackson

120. Epoxidation of propylene with aqueous hydrogen

peroxide on HTS catalyst. M. Lin, H. Li, W. Wei, J. Long

121. Green oxidation of glycerol to value added chemicals over

supported phosphotungstate. A. U. Patel

122. A green one-pot biosynthesis of reduced graphene oxide

(RGO)/bacterial cellulose (BC) nanocomposites.

A. Nandgaonkar, Q. Wang, W. Krause, L. Lucia

123. Towards active recyclable supported homogeneous

catalysts: Tuning immobilized palladium pincer

complexes by support interactions. A. Azua-Barrios,

A. Voutchkova-Kostal

124. Utilization of green nanotechnology for the synthesis of

pharmaceutically exigent heterocycles. A. Dandia

NEW CHEMICAL FEEDSTOCKS

125. Novel natural solid-acid catalysts from carrageenan for

the upgrading of glycerol. J. R. Dodson, C. J. Mota

126. GTL white paper. E. Chen

129. Magnetic porous poly(vinylsulfonic-co-divinylbenzene)

for Rambutan seed oil transesterification. D. H. Nguyen, D.

H. Dao Thi, H. M. Nguyen Thi, T. P. Nguyen

gcande.org


130. Incorporating green chemistry concepts into the design

and synthesis of nanostructured block copolymers.

A. L. Holmberg, T. H. Epps, III

131. Ecoefficient coloration. M. Ho, S. F. Li

132. Atom economic conversion of acetone-butanol-ethanol

(ABE) fermentation products. C. Leung, D. Robinson,

M. Folan

133. Recovery of bio-products from microorganisms using

submerged hydrodynamic cavitating jets (DynaJets).

G. Loraine, G. Chahine

134. Green catalyst for green chemistry: Preparation of a

recyclable sulfonic acid functioned carbon catalyst

derived from glycerol and starch for the synthesis of

biodiesel. R. E. Borg, M. Hausman

135. Succinic acid based polyester polyols as promising

building blocks for polyurethane dispersions. I. Hevus,

K. J. Croes, K. M. Kingsley, W. D. Coggio, T. J. Mullen, D. C. Webster

136. Photochemical transformations of lignin models. X. Ji,

W. G. Forsythe, M. Garrett, G. Sheldrake

138. Investigating the CO2-surface interactions of silica

nanomaterials for CO2 capture. L. M. Reyes, V. Hoepfner,

G. A. Ozin

139. Properties of epoxy resins hardened by woody lignins

obtained by steam explosion. H. Kagawa, Y. Okabe, C.

Sasaki, Y. Nakamura

140. Preparation of carbon-silica composite from bio-oil.

T. Jiang, A. J. Hunt, V. L. Budarin, P. S. Shuttleworth, D. J.

Macquarrie

141. Bio-based epoxy resins from lignin model compounds:

Renewable BPA substitutes. E. D. Hernandez, T. H. Epps, III,

R. P. Wool, J. F. Stanzione, III


142. An even greener biofuels option: Use of recycled

hydrolyzate to grow microalgae. C. R. Talbot, H. Drake, J. L.

Garcia-Moscoso, S. Kumar

143. Poly lactic acid production from renewable resources for

application in biomedical devices. M. S. Lopes, A. L. Jardini,

R. M. Filho

144. Life cycle assessment of lignin-derived chemicals from

catalytic reaction of candlenut nutshells with methanol.

M. Montazeri, E. Beach, M. J. Eckelman

ORGANIC CHEMISTRY

146. Progress in the development of a parabolic solar reflector

for use in organic synthesis reactions. B. M. Agee,

G. Mullins, D. J. Swartling

148. Utility of environmentally benign solid materials in

organic transformations. P. Puthiaraj,

M. Shunmughanathan, K. Pitchumani

150. Green, catalyst free synthesis using benzotriazole

methodology. S. S. Panda, A. R. Katritzky

151. Synthesis of five putrescine analogs using a series of

alcohol solvents. J. M. Miller, N. A. Kowaleuski, F. C. Mayville

152. Synthesis of five spermidine analogs using a series of

alcohol solvents. N. S. Carvis, D. J. Mcgouldrick,

F. C. Mayville

POLICY AND INNOVATION

155. Greenhouse gas mitigation benefits of expanding U.S.

biofuel incentives to promote biomass use in chemical

feedstocks. I. D. Posen, W. M. Griffin, H. S. Matthews,

I. L. Azevedo

156. Data collection to drive green chemistry: Washington

state’s chemical policy efforts. J. A. Grice, S. van Bergen

gcande.org


Congratulations to the Student Award Winners

KENNETH G. HANCOCK MEMORIAL AWARD

This annual award recognizes outstanding student contributions to

furthering the goals of green chemistry through research or education.

The Hancock Award is sponsored by the ACS Division of Environmental

Chemistry (ENVR) and by the National Institute of Standards and

Technology (NIST). It is administered by ACS Green Chemistry

Institute®. The 2014 awardees attending this conference are:

Graduate Student Awardee: Heather Buckley, University of

California, Berkeley

Undergraduate Awardee: Florence Chardon, University of

California, Berkeley

JOSEPH BREEN MEMORIAL FELLOWSHIP

This annual award sponsors a young international green chemistry

scholar to participate in a green chemistry technical meeting,

conference, or training program. The Breen Fellowship is sponsored

by the ACS International Endowment Fund and administered by

ACS Green Chemistry Institute®. The 2014 awardee attending this

conference is:

Jennifer Dodson, Federal University of Rio de Janeiro, Brazil

CIBA TRAVEL AWARD IN GREEN CHEMISTRY

This annual award sponsors participation of students (high school,

undergraduate, and graduate) in an American Chemical Society

technical meeting, conference, or training program that has a

significant green chemistry or sustainability component. The award

is sponsored by the Ciba Green Chemistry Student Endowment and

administered by ACS Green Chemistry Institute®. The 2014 awardees

that either attended the 246th ACS National Meeting and Exposition

in Dallas, TX or will be attending the 247th ACS National Meeting and

Exposition in San Francisco, CA are:

Matthew DeNardo, Carnegie Mellon University

Angela Holmberg, University of Delaware

Avinav Nandgaonkar, North Carolina State University

Jing Zhang, North Dakota State University


ACS GCI PHARMACEUTICAL ROUNDTABLE SPONSORED

STUDENTS

The ACS GCI Pharmaceutical Roundtable is sponsoring the following

students to attend the conference:

Max Friedfeld, Princeton University

Jennifer Obligacion, Princeton University

Corbett Senter, Georgia Institute of Technology

Janelle Steves, University of Wisconsin-Madison

AmgenAstraZenecaBoehringer IngelheimBristol-Myers SquibbCodexisCubist PharmaceuticalsDr. Reddy’sDSM Pharmaceutical ProductsEli Lilly and Company

F. Hoffmann-La RocheGlaxoSmithKlineJohnson & JohnsonMerck & Co., Inc.Novartis Pharma AGPfizer Inc.SanofiACS Green Chemistry Institute®

ACS GCI Pharmaceutical Roundtable

ACS Green Chemistry Institute®www.acs.org/[email protected] ext 6102

ACS GCI Pharmaceutical Roundtable Members

• Informing & influencing the research agenda

• Educating current & future chemists & engineers

• Developing tools for GC&E implementation

• Collaborating globally

Announcing a new research grant to be awarded in 2014!RFP now available at acs.org/gcipharmaroundtable

gcande.org


Abdoul, H. J. . . . . . . . . . . . . . . 69

Adams, L.. . . . . . . . . . . . . . . 181

Agee, B. M. . . . . . . . . . . . . . . 146

Alcantar, N. . . . . . . . . . . 102, 104

An, N. . . . . . . . . . . . . . . . . . . 14

Anand, M. . . . . . . . . . . . . . . . 80

Anastas, P.T. . . . . . . . 16, 25, 93, 197

Anderson, K.. . . . . . . . . . . . . . 38

Aponte-Guzman, J. . . . . . . . . 114

Arkles, B. . . . . . . . . . . . . . . . . 24

Arnold, J. . . . . . . . . . . . . . 58, 166

Aymes, C.. . . . . . . . . . . . . . . . . 9

Azevedo, I. L. . . . . . . . . . . . . 155

Azua-Barrios, A.. . . . . . . . . . . 123

Bachert, D. C. . . . . . . . . . . . . 188

Baertschi, S. W. . . . . . . . . . . . 213

Baier-Anderson, C. . . . . . . . . . 5, 48

Bain, J. . . . . . . . . . . . . . . . . . 90

Bakale, R. P. . . . . . . . . . . . . . . 42

Barcena, H.. . . . . . . . . . . 78, 79, 96

Barta, K.. . . . . . . . . . . . . . . . 195

Bateman, M. . . . . . . . . . . 116, 198

Baugh, L. S. . . . . . . . . . . . . . . .90

Beach, E. . . . . . . . . . . . . . 25, 144

Beckman, E.J. . . . . . . . . . 3, 56, 183

Beekman, M. . . . . . . . . . . . . . 37

Belyk, K. M. . . . . . . . . . . . . . 188

Bergeson, L. . . . . . . . . . . . . . 208

Bernick, L. . . . . . . . . . . . . . . 230

Beutner, G. . . . . . . . . . . . . 40, 214

Bienfait, B. . . . . . . . . . . . . . . . 17

Bisinger, E. . . . . . . . . . . . . . . . 11

Blackburn, R. . . . . . . . . . . . . . 61

Blaquiere, N.. . . . . . . . . . . . . 111

Bocarsly, A. . . . . . . . . . . . . . . 55

Bohling, J. . . . . . . . . . . . . . . 217

Boisvert, L. . . . . . . . . . . . . . . . 91

Borg, R. E. . . . . . . . . . . . . . . 134

Bowers, T. . . . . . . . . . . . . . . . 92

Boyd, L. . . . . . . . . . . . . . . . . . 82

Braun, W. . . . . . . . . . . . . . . . . 11

Brereton, G. . . . . . . . . . . . . . . 73

Briddell, C. . . . . . . . . . . . . . . 101

Brindle, I. D. . . . . . . . . . . . . . 106

Broadrup, R. L. . . . . . . . . . . . . 76

Brooks, B.. . . . . . . . . . . . . . . . 25

Brown, J. S.. . . . . . . . . . . . . . . 15

Bruce, N. . . . . . . . . . . . . . . . 163

Brush, E. J. . . . . . . . . . . . . . . . 35

Buckley, H. L. . . . . . . . . . . . . 166

Budarin, V. L.. . . . . . . . 69, 140, 163

Bulger, P. . . . . . . . . . . . . . . . 188

Calabro, D. C. . . . . . . . . . . . . . .59

Caltrider, D. . . . . . . . . . . . . . . 95

Campanella, A. . . . . . . . . . . . 172

Canavan, S. . . . . . . . . . . . . . . 46

Cannon, A. S. . . . . . . . . . . . 38, 77

Canonico-May, S. A. . . . . . . . . . 88

Cao, H. . . . . . . . . . . . . . . . . . 84

Caradonna, P. A. . . . . . . . . . . 168

Carnes, M. E. . . . . . . . . . . . . . . 37

Carvis, N. S. . . . . . . . . . . . . . 152

Cashman, S. . . . . . . . . . . . . . . 57

Castanedo, G. . . . . . . . . . . . . 111

Castonguay, A. . . . . . . . . 116, 198

Cernak, T.. . . . . . . . . . . . . . . . 63

Chahine, G. . . . . . . . . . . . . . 133

Chang, D. T. . . . . . . . . . . . . . . 45

Chang, F. . . . . . . . . . . . . . . . . 66

Chardon, F. M.. . . . . . . . . . . . 111

Chen, C. . . . . . . . . . . . . . . . . 56

Chen, E.. . . . . . . . . . . . . . . . 126

Chen, J. . . . . . . . . . . . . . . . . . 42

Chen, P. . . . . . . . . . . . . . . . 78, 79

Chen, X. . . . . . . . . . . . . . . . . 31

Cheng, L. . . . . . . . . . . . . . . . 186

Chirik, P. . . . . . . . . . . . . 185, 225

Choi, H. . . . . . . . . . . . . . . . . 109

Chung, C. K. . . . . . . . . . . . . . 188

Chung, M. . . . . . . . . . . . . . . 199

Ciarlo, M. . . . . . . . . . . . . . . . 227

Clark, J. H. . . . . . . . . 23, 69, 86, 163

Clark, K. T. . . . . . . . . . . . . . . . 58

Cloud, J. E. . . . . . . . . . . . . . . 196

Cochran, B. M.. . . . . . . . . . . . . 41

Coe-Sullivan, S. . . . . . . . . . . . . . 1

Coggio, W. D. . . . . . . . . . . . . 135

Cohen Hubal, E. A. . . . . . . . . . . 15

Author Index

To access abstracts, see page 10 of this program book.


Collazo, B. J. . . . . . . . . . . . . . 103

Collom, S. L. . . . . . . . . . . . . . 197

Colon Santiago, A. G. . . . . . . . 103

Cooper-Hayes, D. R. . . . . . . . . . . 4

Corrales, J. . . . . . . . . . . . . . . . 25

Coss, C. . . . . . . . . . . . . . . . 34, 39

Cowell, P. . . . . . . . . . . . . . . . 180

Cox, C. . . . . . . . . . . . . . . . . 212

Crabtree, R. H.. . . . . . . . . . . . 197

Croes, K. J. . . . . . . . . . . . . . . 135

Dahle, M. L. . . . . . . . . . . . . . . 30

Daigle, B. . . . . . . . . . . . . . . . . 11

Dakshinamoorthy, D. . . . . . . . . 26

Dandia, A. . . . . . . . . . . . . . . 124

Daniel-Onuta, M. . . . . . . . . . . 118

Dao Thi, D. H. . . . . . . . . . . . . 129

Daston, G. . . . . . . . . . . . . . . . 44

Dave, E. . . . . . . . . . . . . . . . . . 87

De bruyn, M. . . . . . . . . . . . . . 69

Deerberg, J. . . . . . . . . . . . . . 216

DeLeo, P. C. . . . . . . . . . . . . . 227

Dermenjian, R. . . . . . . . . . . . . 63

Desai, L. . . . . . . . . . . . . . . . . 40

Deunf, E. . . . . . . . . . . . . . . . . 58

DeVito, S. C. . . . . . . . . . . . . . . 20

DeVor, R. . . . . . . . . . . . . . . . 112

Dimitrov, S. . . . . . . . . . . . . . . 13

Dion, A. . . . . . . . . . . . . . . . . 213

Doa, M. . . . . . . . . . . . . . . . . . 46

Dodson, J. . . . . . . . . . . . . 34, 125

Dong, V. M.. . . . . . . . . . . . . . 215

Douskey, M. . . . . . . . . . . . . . . 33

Doyle, M. P. . . . . . . . . . . . . . 184

Drake, H. . . . . . . . . . . . . . . . 142

Duprat de Paule, S.. . . . . . . . . 219

Durant, Y.. . . . . . . . . . . . . . . . 231

Dutta, S. . . . . . . . . . . . . . . . . 66

Dykstra, K. . . . . . . . . . . . . . . . 63

Eastgate, M. . . . . . . . . . . . . . . 40

Echols, S. . . . . . . . . . . . . . . . 176

Eckelman, M. J. . . . . . . . . . . . 144

Eckert, C. . . . . . . . . . . . . 114, 186

Eggert, R.. . . . . . . . . . . . . . . 224

Eismin, R. . . . . . . . . . . . . . . . . 39

El-Ghazawi, O.. . . . . . . . . . . . 113

Elder, J. B.. . . . . . . . . . . . . . . . 91

Emerson, K. M. . . . . . . . . . . . 188

Epps, III, T. H.. . . . . . . . 27, 130, 141

Ergas, S.. . . . . . . . . . . . . . . . 104

Falahat, R. . . . . . . . . . . . . . . 102

Fanfair, D. . . . . . . . . . . . . . . . 40

Farrell, S. . . . . . . . . . . . . . . . 167

Fasano, D. . . . . . . . . . . . . . . 217

Faulkner, D. . . . . . . . . . . . . 58, 94

Ferguson, S. . . . . . . . . . . . . . 171

Ferrer Torres, E. J. . . . . . . . . . . 103

Filho, R. M. . . . . . . . . . . . . . . 143

Finn, M. . . . . . . . . . . . . . . . . 115

Fisk, J. . . . . . . . . . . . . . . . . . 186

Fleer, M. P. . . . . . . . . . . . . . . 191

Folan, M. . . . . . . . . . . . . . . . 132

Ford, P. C. . . . . . . . . . . . . . . . 195

Forsythe, W. G. . . . . . . . . . . . 136

Fourches, D. . . . . . . . . . . . . . . 12

France, S. . . . . . . . . . . . . . . . 114

Francis, R. . . . . . . . . . . . . . . 108

Frazier, J. . . . . . . . . . . . . 176, 207

Friedfeld, M. R. . . . . . . . . . . . 185

Gallagher, E. . . . . . . . . . . . . . . 25

Gandarias, I. . . . . . . . . . . . . . . 66

Gangwal, S. . . . . . . . . . . . . . . 15

Gannon, J. T. . . . . . . . . . . . . . 228

Garcia-Moscoso, J. L. . . . . . . . 142

Garrett, M. . . . . . . . . . . . . . . 136

Genualdi, C. . . . . . . . . . . . . . . 94

Ghaffari, B. . . . . . . . . . . . . . . . 63

Goldsmith, M. . . . . . . . . . . . . . 45

Gong, S. . . . . . . . . . . . . . . . . 84

Gonzalez, Y. . . . . . . . . . . . . . . 46

Gorbenko, A. . . . . . . . . . . . . . 79

Gottardi, M. . . . . . . . . . . . . . 202

Gottis, S. . . . . . . . . . . . . . . . . 58

Gowda, H. . . . . . . . . . . . . . . 118

Grandelli, H. . . . . . . . . . . . . . 112

Green, M.. . . . . . . . . . . . . . . . 212

Green, II, N. B. . . . . . . . . . . . . 201

Greggs, B. . . . . . . . . . . . . . . 227

Grice, J. A. . . . . . . . . . . . . . . 156

Griffin, W. M.. . . . . . . . . . . . . 155

Grulke, C. M. . . . . . . . . . . . . . . 45


gcande.org


Gryko, D. T. . . . . . . . . . . . . . . 166

Gug, J.. . . . . . . . . . . . . . . . . . 31

Gumapas, L. . . . . . . . . . . . . . . 53

Guo, F.. . . . . . . . . . . . . . . . . 102

Harten, P. F. . . . . . . . . . . . . . 220

Hausman, M. . . . . . . . . . . . . 134

Hawk, M. . . . . . . . . . . . . . . . 213

Hawker, N. . . . . . . . . . . . . . . . 182

Hawkins, J. M. . . . . . . . . . 157, 158

Heine, L. . . . . . . . . . . . . . . . . 50

Hernandez, E. D. . . . . . . . . . . 141

Hevus, I. . . . . . . . . . . . . . . . 135

Hill, C. . . . . . . . . . . . . . . . . . . 94

Hintze, P. . . . . . . . . . . . . . . . 112

Ho, M. . . . . . . . . . . . . . . . . . 131

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Williams, E. S. . . . . . . . . . . 25, 227

Williams, P. . . . . . . . . . . . . . . 174

Williamson, M. L. . . . . . . . . . . 213

Willis, S. L. . . . . . . . . . . . . . . . 91

Wilson III, T. . . . . . . . . . . . . . . 85

Wolf, C. D. . . . . . . . . . . . . . . . 11

Wolf, M. H. . . . . . . . . . . . . . . 200

Wood, T. E. . . . . . . . . . . . . . . 169

Woodham, W. . . . . . . . . . . . . 114

Wool, D. P. . . . . . . . . . . . . . . . 27

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Yang, Y. . . . . . . . . . . . . . . . . 196

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Yoder, T. S. . . . . . . . . . . . . . . 196

Young Tanir, J. . . . . . . . . . . . . 108

Zabeti, M. . . . . . . . . . . . . . . 221

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Zhu, Z. . . . . . . . . . . . . . . . . . 97

Zimmerman, J. B.. . . . 16, 25, 56, 93



MapsNORTH BETHESDA MARRIOTT HOTEL & CONFERENCE CENTER

5701 Marinelli Road

North Bethesda, MD 20852

T: (301) 822-9200

Closest METRO rail station stop: White Flint (Red Line)

NORTH BETHESDA MARRIOTT HOTEL & CONFERENCE CENTER

– MAIN LEVEL

gcande.org


NORTH BETHESDA MARRIOTT HOTEL & CONFERENCE CENTER –

LOWER LEVEL


Washington, D.C. Metro MapFor more info on the METRO system, visit www.wmata.com.

gcande.org


A Sustainable Conference

Our conference is truly GREEN!

Some of the efforts by ACS GCI to green the conference include:

• The conference registration process is primarily online, thus,

reducing the need for printed registration forms.

• We print this program book with soy ink and on paper certified

by the Forest Stewardship Council. Also, starting with the 2010

meeting, we drastically reduced the size (and footprint) of the

conference program book.

• We print onsite registration materials (forms, receipts) on recycled

paper stock.

• We do not print conference abstracts in the printed conference

book. This measure was taken to save paper and ink. Please refer to

the conference website (gcande.org/program) for information on

abstracts.

• We do not serve bottled water to conference attendees.

• We encourage exhibitors to bring only what they need to the

conference and ask that attendees take only what they need. Any

printed materials left behind when the conference has ended are

recycled.

• We ask all conference attendees to recycle badge holders and other

printed materials. There will be several recycling receptacles on the

premises for this purpose.

• We calculate and offset the carbon emissions of all conference

participants by donating to the Carbon Fund. [Logo]

• In addition, the Bethesda North Marriott Hotel & Conference center:

- Recycles office paper, plastic and glass

- Only uses post-consumer paper

- Has installed water-saving shower heads and toilets and faucets

- Has installed energy efficient lighting

- Offers an energy saving linen programs

- Partners with Clean the World to recover soap and bottled

amenities to be recycled and distributed to people in need

PRINTER TO PLACE FSC LOGO AND INFORMATION HERE


Dates to Remember

ACS Summer School on Green Chemistry and Sustainable

Energy

July 22 – July 29, 2014

Nominations Due for the ACS-CEI Award for Incorporation of

Sustainability in Chemistry Education

September, 1, 2014

ACS National Meeting & Exposition in San Francisco, CA

August 10-14, 2014

Nominations Due for 2014 Ciba Travel Award in Green

Chemistry (for 2015 travel)

October 17, 2014

Nominations Due for the 2014 ACS Award for Affordable

Green Chemistry

November 1, 2014

Applications Due for the 2014 Joseph Breen Memorial

Fellowship

February 2, 2015

Applications Due for the 2014 Kenneth G. Hancock

Memorial Award

February 2, 2015

ACS National Meeting & Exposition in Denver, CO

March 22-26, 2015

ACS Student Chapter Green Chemistry Awards Ceremony

March 22, 2015

19th Annual Green Chemistry & Engineering Conference in

N. Bethesda, MD

July 14-16, 2015


19th Annual Green Chemistry & Engineering

ConferenceJuly 14-16, 2015N. Bethesda, MD

MARK YOUR CALENDAR

Get involved today! Email [email protected]



Media PartnersWe thank our media partners for their help in promoting this

year’s conference.

gcande.org

Advancing Chemistry, Innovating for Sustainability

Exhibitors

M o DRNMolecular DesignResearch Network

M o DRNMolecular DesignResearch Network

A U.S. EPA Program

GOLD

SILVER

BRONZE

TECHNICAL SESSIONS

CAREERS WORKSHOP

GENERAL

ROUNDTABLE POSTER RECEPTION

Thank you to our sponsors

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