advanced layered technology approach (alta) for nox reduction 2014/marc... · 2011. 6. 14. ·...
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Advanced Layered Technology Approach (ALTA) for NOx Reduction
746 East Winchester, Suite 120, Murray, Utah 84107
M. Hot Topic Hour
Coal-fired Power Plant NOx Reduction Innovations
November 6, 2014
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NOx Emissions Don’t SCRs Solve This Problem?
• Cost
– Power producer goal is not “lowest NOx”; goal is
emissions compliance at lowest cost
– High capital cost for small units
• Catalyst blinding for some coals
Advanced in-furnace controls
can be more economically
attractive in some cases
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2400-3100oF
NOx
N2
Chemical
Injection
NHi NCO
Staged
Combustion
Zone
Fuel Rich Zone
Burnout ZoneOFA
Fuel
2400-3100oF
NOx
N2
Chemical
Injection
NHi NCO
Staged
Combustion
Zone
Fuel Rich Zone
Burnout ZoneOFA
Fuel
Rich Reagent Injection (RRI)
• Staging creates hot, fuel rich
lower furnace
• NH3/urea accelerate the rate of
NOx reduction under reducing
conditions
• Insignificant NH3 slip
• Developed by REI and EPRI
• Fuel Tech, CCA, and FERCo are
licensed implementers
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Advanced Layered Technology
Approach (ALTA)
OverfireAir - Rapid mixing with relatively
unstratified combustion products
Rich Reagent Injection -Urea accelerates
rate of NOx reduction
Homogenizing Burners
-Limited stratification
-Lower furnace SR near optimum
SNCR -Enhanced by reduced
stratification
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ALTA in Cyclones
• Inherent Advantages for Cyclones – Partial combustion in cyclone barrels
results in a fuel-rich, relatively well mixed, lower furnace
– Relatively small furnaces accommodate effective reagent and overfire air mixing
• ALTA installed in 16 cyclone boilers in the US – Single and opposed wall-fired boilers
– 50 MW – 500 MW units
– CFD based design is critical
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Reaction Engineering International
ALTA Performance 488 MW Opposed Wall Cyclone
445 MWg
RRI Flow Rate
NOx (OFA+RRI)
0.16 lb/MBtu
NOx
0.23 lb/MBtu
NOx (ALTA)
0.12 lb/MBtu
SNCR Flow Rate
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ALTA Economics 50 MW Target Wall Cyclone
• ALTA is an economically attractive option for NOx control
– ALTA installed capital cost = $32.5/kW
– ~85% lower capital costs vs. SCR
– ALTA operating costs at Summer 2008 urea prices ($1.76/gal)
• ~ $900 - $1200/ton NOx removed (0.7 lb/MBtu baseline)
• ~55% NOx Reduction
• Full load control strategy
– Fixed OFA damper positions
– Reagent flows: 60 gph for 55% reduction target (NSR~1.7)
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ALTA in PC Units
• DOE funded program to evaluate ALTA approach in pulverized coal units
• Major components
– Deep staging
– Optimized burner design for deep staging
– RRI in fuel-rich zone
• Pilot-scale tests
– U of Utah
– 5 MMBtu/hr furnace
• CFD of pilot-scale tests and full-scale unit
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Pilot-scale Testing
• PC with conventional low
NOx burner design
• NOx as low as 38 ppm,
(0.04 lb/MMBtu) under
extended residence time
• 79% reduction from RRI at
SRb of 0.85
• Reagent enhancement of
NOx reduction kinetics
irrelevant at SRb < 0.75
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Rapid Homogenization Burner Pilot Scale
RRI OFA
Conventional LNB
“Homogenizing” Burner
Better mixing / reduced stratification
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Impacts of Rapid Homogenization Burner Pilot Scale
60
70
80
90
100
110
120
130
0.63 0.68 0.73 0.78
Burner Stoichiometric Ratio (Staging)
NO
[p
pm
v]
0.06
0.07
0.08
0.09
0.10
0.11
0.12
0.13
NO
[lb
/MB
tu]
MRRIB NSR = 0
MRRIB NSR = 2
LNB NSR = 0
LNB NSR = 2
dNOx = 30%
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Full-scale Conceptual
Implementation
• 180 MW Front-wall-fired boiler using
Eastern Bituminous coal
• Previous CFD-based modeling and
site testing of RRI indicated < 10%
NOx reduction
• Simulations with homogenizing
burners to:
– Optimize burner stoichiometry
– Guide reagent injection strategy
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Impacts of “RRI” Burner 180 MW Boiler
Ba
Baseline_SR=0.90 RRIB_SR=0.70 RRIB_SR=0.80 RRIB_SR=0.90
The “RRI” burner homogenizes the lower furnace flue gas
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Predicted Full Scale NOx Emissions 180 MW Boiler
0
0.1
0.2
0.3
0.4
0.5
0.9 0.8 0.7
Baseline
Baseline-With RRI
RRIB
RRIB-With RRI
Burner SR
NO
x (l
b/M
MB
tu)
36% Reduction
The “RRI” burner significantly improves RRI performance and leads to
an overall NOx reduction of 36%
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Summary • ALTA in cyclone units
– Implemented in cyclone boilers as a cost effective alternative to SCR
– Commercially installed and operated in 16 cyclone boilers to-date
• ALTA in PC units
– Pilot-scale testing and CFD modeling of a 180 MW coal boiler show
that RRI can produce significantly lower NOx emissions than
conventional LNB approaches
– RRI performance in PC units relies on LNB technology optimized for
deep staging
• ALTA leverages use of common reagent equipment in RRI
and SNCR processes
• RRI, a key ALTA component, is an EPRI owned technology