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Additives for Paints and Coatings

Technical support dedicated With our global technical support network, Solvay provides customers with custom-made solutions and develops formulations adapted to their needs and requirements for the paint and coatings industry. Solvay uses its expertise in safety, toxicology, environmental and regulatory affairs to provide guidance on industrial formulation compounds, thus creating additional value for paint and coatings customers.

Global industrial footprintThrough its world-class manufacturing operations in Europe, North America, Asia Pacific and Latin America, Solvay shares best practices within zones and benefits from technology transfer. Strengthened by a worldwideR & D and tech-support network, Solvay develops strong partnerships with customers around the world and creates innovative materials focused on next-generation technologies for the paint and coatings market.

SOLVAY Novecare, Global Expert in Additives for Coatings Applications Solvay, a world leader in the development and production of specialty chemicals, supplies performance additives for a variety of paint and coating applications.

Solvay additives deliver outstanding benefits to coating formulations, such as enhanced surface wetting, improved coating adhesion to substrate, superior dispersion stability and gloss, enhanced color development and stability, and better foam control. Solvay additives are also effective in minimizing production mixing time and improving manufacturing efficiency.

Solvay Novecare offers multiple products

w RHODOLINE® series defoamers

w RHODOLINE® dispersing agents

w RHODOLINE®, IGEPAL® and GEROPON® wetting agents

w RHODOLINE® series freeze/thaw and open time additives

w FENTAMINE® and FENTACARE® specialty amines

w RHODIASOLV® coalescent

Adapted for paint and coating applications:

w Waterborne paints

w Aqueous ink systems

w Water-based adhesives

Solvay Novecare Coating Additives

Note: These products are produced at worldwide locations through the Novecare division of Solvay.

Solvay Novecare works alongside its customers to design products and solutions with reduced impact on health and the environment. As part of corporate social responsibility, Solvay uses procedures that monitor its products throughout their entire life cycles. Solvay supports customers with a broad range of sustainable solutions and services including products optimized around criteria such as biodegradability, eco-toxicity, VOC content, and percentage of renewable materials.

Solvay VOC-free defoamers and APE-free surfactants are examples of its commitment to sustainability and the environment.

Solvay recognizes the difficulties in selecting the optimal surfactant system for wetting, dispersing or designing an emulsion polymer system. Formulators require surfactants that perform and are compatible with the entire formula and do not compromise the quality of the coating. Environmental concerns are also key drivers behind the reformulation of well-established systems, leaving formulators with additional challenges to overcome, such as the conversion to APE-free systems or ensuring compatibility with low to VOC-free formulations.

Solvay Novecare is developing and expanding its line of industry-leading paint additives to enhance the performance of VOC-free and APE-free water-based formulations while providing additional benefits such as improved freeze-thaw, open time, film appearance, defoaming and wetting characteristics. Solvay consistently develops new sustainable additives that allow formulators to address the performance challenges of newer waterborne formulations, while answering the demand for more sustainable and cost-effective products.

Solvay’s Sustainable Portfolio

Solvay offers a versatile toolbox for waterborne paint and coatings formulation.

Solvay Coating Additives / 1

Application Guideline International Inventory Status

PRODUCT NAME DESCRIPTION

APE-

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RHODOLINE® OTE-500

APE-free and VOC-free additive that promotes extended open time

u u u u u u u u u u u u u u

2 / Solvay Coating Additives

RHODOLINE® OTE-500 is a novel APE and solvent free open time additive for low to VOC-free waterborne paints, coatings, inks and adhesives.

RHODOLINE® OTE-500 improves open time for low to VOC-free waterborne paints. It could be utilized in various formulations from low to high gloss paints.

RHODOLINE® OTE-500 significantly improves open time for paints made with the following resin systems:w All-Acrylic copolymerw Styrene-Acrylic copolymer (S/A)w Vinyl Acetate / Acrylic copolymer (V/AC)w Vinyl Acetate / Ethylene Copolymer (EVA)w Water-based Alkyd Paints

RHODOLINE® OTE-500 works in all gloss: high gloss, semi-gloss, satin and flat (matte) systemsKey Featuresw Extends open timew Exhibits excellent dispersion stabilityw Allows formulation of Eco-label compliant coatingsw May reduce/eliminate wetting agents

u Listed

Sustainable Additivesw APE-free and VOC-free additivew Low odor solutionw Enables design of low to VOC-free coating formulationsw Design sustainable coatings with RHODOLINE® OTE-500 [Green Seal (GS-11) or EU Ecolabel compliant paints]

PAINT SAMPLE CONTROL RHODOLINE® OTE-500VOC-free ACRYLIC SG PAINT 2 8

MIN RHODOLINE® OTE-500 CONTROL MIN

0 0

2 2

4 4

6 6

8 8

10 10

12 12

14 14

Visible Xshows limits

OPEN TIME

OPEN TIME

Functional Additives

RHODOLINE® OTE-500: OPEN-TIME ADDITIVE



APE-

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RHODOLINE® OTE-500

APE-free and VOC-free additive that promotes extended open time



OPEN TIME

Low VOC Acrylic Semi-Gloss Paint

PAINT PROPERTIES TESTED CONTROLPAINT

RHODOLINE® OTE-500 + RHODOLINE® 5520

RHODOLINE® OTE-500

Non-Ionic Surfactant R5520 - % 0.39 0.39 0.00RHODOLINE OTE-500 - % 0.00 1.21 1.21 (0.39 + 0.82)Gloss O/N 20°/60°/85 21/56/91 27/61/89 23/57/89Freeze/Thaw - 5 Cycles - ΔKu Fail-1 16 14Open Time – Minutes ASTM D7488 2 8 8Scrub Resistance ASTM D2486 >1000 555 >1000Block Resistance ASTM D4946 Control - -Color Rub-up ΔE – BLK (1.6% by volume) 0.53 0.79 0.65Heat Aged – 2 wks @ 50°C – Δ KU -1 4 0Stain Resistance ASTM D4828 Control = =Surfactant Leaching - O/N Dry 8 9 9Low Temp FF, 5°C – Sealed/Unsealed 10/10 8/10 10/10

Rating System: 10 = Best; 0 = Worst

LOW VOC SEMI-GLOSSPAINT FORMULA

A B CCONTROL

PAINTRHODOLINE® OTE-500 + RHODOLINE® 5520

RHODOLINE®OTE-500

Raw Materials Wt. % Wt. % Wt. %Water 7.75 7.75 7.75RHODOLINE® 286N – dispersant 0.78 0.78 0.78RHODOLINE® 643 - defoamer 0.05 0.05 0.05RHODOLINE® 5520 – wetting agent 0.39 0.39 0.00RHODOLINE® OTE-500 0.00 0.00 0.39Amine 0.19 0.19 0.19Attagel 50 0.48 0.48 0.48Titanium Dioxide 22.29 22.29 22.29Water 8.67 8.67 8.67Acrylic Latex (50%) 46.52 46.52 46.52RHODOLINE® OTE-500 0.00 1.21 0.82RHODOLINE® 643 0.19 0.19 0.19High Shear Builder (ICI) 2.23 1.65 1.94Water 9.21 8.61 8.56Low Shear Builder (Ku) 0.85 0.82 0.97Mildewcide 0.39 0.39 0.39Total 100 100 100

PVC = 22.2%; Weight Solids = 45.4%; Volume Solids = 32.4%

For optimum results use RHODOLINE® OTE-500 as shown in formulation C above by splitting the quantity in the grind to replace the wetting agent and in the letdown. RHODOLINE® OTE-500 increases the open time with minimal impact on dry film properties.


RHODOLINE® FT 100 is a unique APE-free and solvent-free additive utilized to improve freeze-thaw stability primarily for low Tg latex binders as well as waterborne paints formulated with these binders. RHODOLINE® FT 100 also improves gloss, pigment dispersions and stain resistance in these formulations.

Key Features w Delivers freeze-thaw stabilityw Enhances glossw Boosts stain resistancew APE-free and VOC-free

Easy to use for a wide range of polymersw All Acrylicw Vinyl / Acrylicw Styrene / Acrylicw Ethylene vinyl acetate

RHODOLINE® FT-100: FREEZE-THAW STABILITY ADDITIVEFreeze-Thaw Process

Freezing of Latex Polymers (to -18°C)

u Listed



APE-

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RHODOLINE® FT-100

APE-free and VOC-free additive that promotes freeze-thaw stability


Functional Additives

No FT-100 With FT-100


Commercial all acrylic gloss paint (VOC= 50 g/l/ASTM)

Initail Viscosity

(KU)

1Cycle

2Cycle

3Cycle

4Cycle

5Cycle

Usage levels in paint formulations

RHODOLINE® FT 100 102.4 103.8. 104.3 104.0 105.4 105.4 1.0%No additive 121.1 gel paint coagulated —

Ethylene Glycol 103 gel paint coagulated 1.0%Alkyl Phenol Ethoxylate 88 gel paint coagulated 1.0%Linear Alkyl Ethoxylate 96 gel paint coagulated 1.0%

Effects of RHODOLINE® FT-100 on Freeze-Thaw Stability of Low VOC Commercial PAINT

Solvay offers a comprehensive line of wetting and dispersing agents specifically designed for waterborne coatings systems and drives its innovation to deliver new and better performing APE-free and VOC-free solutions. RHODOLINE® and IGEPAL® dispersing and wetting agents provide excellent broad compatibility, improvement of color stability and color acceptance, improved flow and leveling and storage stability in both architectural and industrial paints, inks and adhesive systems. These workhorse additives will reduce the surface tension and improve pigment wetting with minimum foaming. RHODOLINE® 200 and 300 series polymeric dispersants provide exceptional pigment dispersion, improved color acceptance and storage stability.

RHODOLINE® 3000 series provides exceptional pigment wetting and color improvement for carbon black and organic pigments. RHODOLINE® 4000 series is designed for inorganic pigments.

RHODOLINE® WA APE-free wetting agents provide excellent substrate wetting and low foaming for waterborne paints, coatings, adhesives and inks. RHODOLINE® WA line of products are low viscosity with low pour point for ease of handling.

SURFACTANTS

RHODOLINE® WA Series

w Very fast Wetting

w Extremely low foam

w Full compatibility with water based paints

w APE-Free

w VOC-free, flexible for point choice

w Low viscosity easy to handle

Wetting Agents


Rhodoline WA 120 at 1.0% addition Silicone

Rhodoline WA 120 Benchmark

As is



As is



As is Rhodoline WA 120 at 1.0% addition

Silicone


As is RHODOLINE® WA 120 at 1.0% addition

Silicone As is

RHODOLINE® WA 120 Benchmark



Application Guideline International Inventory Status FDA Compliance 21 CFR


HLB

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175.

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176.

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176.

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176.

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176.

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RHODASURF® BC-420 TDA Ethoxylate 8 Yes Yes u u u u u u u u u u u u u u u u u u u

RHODASURF® BC-729 TDA Ethoxylate 13.8 Yes Yes u u u u u u u u u u u u u u u u u u u

RHODOLINE® 5520 Low foam nonionic wetting agent; excellent wetting and color acceptance N/A Yes Low u u u u u u u u u u u u u - - - - -

RHODOLINE® WA 100 Solvent free surfactant with a good balance of wetting and low foaming properties. Yes No u u u u u u u u u u u u - - - - -

RHODOLINE® WA 120 Low foaming surfactant with excellent wetting properties. Great alternative to silicone wetting agents. 10 - 13 Yes No u u u u u u u u u u u u - - - - -

RHODOLINE® WA 200High HLB surfactant with excellent wetting in low to high PVC paint formulations. Excellent alternate for APE, high HLB wetting agents. Improved paint stability.

17 - 19 Yes No u u u u u u u u u u u u u - -

RHODOLINE® 4160Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.

N/A Yes Low u u u u u u u u u u u u - - - - -

RHODOLINE® 4170Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.

N/A Yes Low u u u u u u u u u u u u u NE NE NE NE NE

RHODOLINE® 4188

Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.


IGEPAL® CO series Nonylphenol ethoxylates used as pigment wettersand color stabilizers 4 - 19 N0 No u u u u u u u u u u u u u u u u u u

IGEPAL® CA series Octylphenol ethoxylates used as pigment wetters and color stabilizers 4 - 19 No No u u u u u u u u u u u u u u u u u u

GEROPON® 99 Low Anionic surfactant for improved adhesion over chaulky and weathered surfaces N/A Yes Low u u u u u u u u u u u u u u u u u u u

u Listed - Not listed

Wetting Agents




HLB

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175.

105

176.

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176.

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176.

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176.

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RHODASURF® BC-420 TDA Ethoxylate 8 Yes Yes u u u u u u u u u u u u u u u u u u u

RHODASURF® BC-729 TDA Ethoxylate 13.8 Yes Yes u u u u u u u u u u u u u u u u u u u

RHODOLINE® 5520 Low foam nonionic wetting agent; excellent wetting and color acceptance N/A Yes Low u u u u u u u u u u u u u - - - - -

RHODOLINE® WA 100 Solvent free surfactant with a good balance of wetting and low foaming properties. Yes No u u u u u u u u u u u u - - - - -

RHODOLINE® WA 120 Low foaming surfactant with excellent wetting properties. Great alternative to silicone wetting agents. 10 - 13 Yes No u u u u u u u u u u u u - - - - -

RHODOLINE® WA 200High HLB surfactant with excellent wetting in low to high PVC paint formulations. Excellent alternate for APE, high HLB wetting agents. Improved paint stability.

17 - 19 Yes No u u u u u u u u u u u u u - -

RHODOLINE® 4160Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.

N/A Yes Low u u u u u u u u u u u u - - - - -

RHODOLINE® 4170Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.


RHODOLINE® 4188

Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.


IGEPAL® CO series Nonylphenol ethoxylates used as pigment wettersand color stabilizers 4 - 19 N0 No u u u u u u u u u u u u u u u u u u

IGEPAL® CA series Octylphenol ethoxylates used as pigment wetters and color stabilizers 4 - 19 No No u u u u u u u u u u u u u u u u u u

GEROPON® 99 Low Anionic surfactant for improved adhesion over chaulky and weathered surfaces N/A Yes Low u u u u u u u u u u u u u u u u u u u

Dispersants for Waterborne Systems


Three stepsWettingw Liquid replaces adsorbed gas on the

surface of the pigmentw Immersion, adhesion, spreading,

and capillary penetration

Separationw Breaking up of the aggregates

and agglomeratesw High amount energy needed

Stabilizationw Remaining particle size and its

distribution during storage

Dispersing Process of Pigment Key Performance Features

w Excellent pigment wetting

w Improved flow

w Improved color acceptance

w Improved stability

w Low foaming

w Broad compatibility

Pigment

Wetting

Separation

Stabilization

Liquid


International Inventory Status FDA Compliance 21 CFR


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176.

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176.

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176.

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176.

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RHODOLINE® 3100 Workhorse dispersant for low to medium HLB organic pigments including medium grade carbon black and lampblack pigments. 11 - 13 Yes No u u u u u u u — — — — —

RHODOLINE® 3200 Dispersant for low HLB organic pigment including toluidine red, yellow and other organic pigments. 8 - 11 Yes No u u u u u u u — — — — —

RHODOLINE® 3500 High HLB organic pigment wetting and dispersant agent. Works great with organic pigments as well as industrial grade carbon black pigments. >16 Yes No u u u u u u u u — — — — —

RHODOLINE® 3700 High HLB pigment wetting and dispersant agent. It works great with high surface area pigments such as conductive carbon blacks. >16 Yes No u u u u u u u u — — — — —

RHODOLINE® 4100 Anionic; 100 % active. Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents. Improved corrosion resistance. N/A Yes Low u u u u u u u u — — — — —

RHODOLINE® 4160 Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength. N/A Yes Low u u u u u u u u — — — — —

RHODOLINE® 4170 Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength. N/A Yes Low u u u u u u u u NE NE NE NE NE

RHODOLINE® 4188Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.

N/A Yes Low u u u u u u u u NE NE NE NE NE


u Listed - Not listed NE Not evaluated * Availability based on REACH status


International Inventory Status FDA Compliance 21 CFR


HLB

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(TSC

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175.

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176.

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176.

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176.

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176.

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RHODOLINE® 3100 Workhorse dispersant for low to medium HLB organic pigments including medium grade carbon black and lampblack pigments. 11 - 13 Yes No u u u u u u u — — — — —

RHODOLINE® 3200 Dispersant for low HLB organic pigment including toluidine red, yellow and other organic pigments. 8 - 11 Yes No u u u u u u u — — — — —

RHODOLINE® 3500 High HLB organic pigment wetting and dispersant agent. Works great with organic pigments as well as industrial grade carbon black pigments. >16 Yes No u u u u u u u u — — — — —

RHODOLINE® 3700 High HLB pigment wetting and dispersant agent. It works great with high surface area pigments such as conductive carbon blacks. >16 Yes No u u u u u u u u — — — — —

RHODOLINE® 4100 Anionic; 100 % active. Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents. Improved corrosion resistance. N/A Yes Low u u u u u u u u — — — — —

RHODOLINE® 4160 Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength. N/A Yes Low u u u u u u u u — — — — —

RHODOLINE® 4170 Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength. N/A Yes Low u u u u u u u u NE NE NE NE NE

RHODOLINE® 4188Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.

N/A Yes Low u u u u u u u u NE NE NE NE NE


Application Guideline FDA CLEARANCE FDA Compliance 21 CFR


APE

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VOC-

Free

Hyd

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obic

Salt

pH Perc

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Rec

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175.

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176.

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176.

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RHODOLINE® 111Most versatile hydrophobic dispersant for stabilizing TiO2 and other inorganic pigments

u u u Na 10.0 25 0.1 - 0.3 u u u u u u u u u u u u u

RHODOLINE® 207Neutralized polyacrylated polymer with excellent chlorine and thermal stability

u u Na 7.0 45 1.0 - 5.0 u u u u u u u u u u u u u

RHODOLINE® 226/35

Low-foaming, hydrophobic copolymer for reactive and non-reactive pigments

u u u Na 7.3 35 0.1 - 0.5 u u u u u u u u u u u u u u

RHODOLINE® 230Hydrophobic dispersant, particularly effective with high calcium carbonate pigment loadings

u u Na 7.9 44 0.1 - 0.5 u u u u u u u u u u u u u u —

RHODOLINE® 231

Water-soluble anionic dispersant used in pigment slurries and paper coatings. Suited for stabilizing inorganic pigments like TiO2, CaCO3 and MgOH slurries.

u u Na 7.3 44 0.1 - 0.5 u u u u u u u u u u u u u —

RHODOLINE® 270Low-foaming, hydrophilic polyacrylate for general pigment dispersions

u u Na 7.3 43 0.1 - 0.4 u u u u u u u u u u u u u u u

RHODOLINE® 286NLow foaming, ammonia-neutralized copolymer, best for gloss development. Exterior paints

u u u NH4 7.0 50 0.1 - 0.4 u u u u u NE NE NE NE NE NE u u — — — —

u Listed - Not listed NE Not evaluated * Availability based on REACH status



Application Guideline FDA CLEARANCE FDA Compliance 21 CFR


APE

-Fre

e

VOC-

Free

Hyd

roph

obic

Salt

pH Perc

ent a

ctiv

e (%

)

Rec

omm

ende

do

sage

Lev

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(wt %

)

Flat

to s

emi-g

loss

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Hig

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Elas

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Traffi

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Pain

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Inks

175.

105

175.

300

175.

320

176.

170

176.

180

176.

210

USA

(TSC

A)

CAN

ADA

(DSL

)

EURO

PE *

(E

INEC

S)

AUST

RAL

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(AIC

S)

SOU

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OREA

(K

ECL)

JAPA

N (M

ITI)

RHODOLINE® 111Most versatile hydrophobic dispersant for stabilizing TiO2 and other inorganic pigments

u u u Na 10.0 25 0.1 - 0.3 u u u u u u u u u u u u u

RHODOLINE® 207Neutralized polyacrylated polymer with excellent chlorine and thermal stability

u u Na 7.0 45 1.0 - 5.0 u u u u u u u u u u u u u

RHODOLINE® 226/35

Low-foaming, hydrophobic copolymer for reactive and non-reactive pigments

u u u Na 7.3 35 0.1 - 0.5 u u u u u u u u u u u u u u

RHODOLINE® 230Hydrophobic dispersant, particularly effective with high calcium carbonate pigment loadings

u u Na 7.9 44 0.1 - 0.5 u u u u u u u u u u u u u u —

RHODOLINE® 231

Water-soluble anionic dispersant used in pigment slurries and paper coatings. Suited for stabilizing inorganic pigments like TiO2, CaCO3 and MgOH slurries.

u u Na 7.3 44 0.1 - 0.5 u u u u u u u u u u u u u —

RHODOLINE® 270Low-foaming, hydrophilic polyacrylate for general pigment dispersions

u u Na 7.3 43 0.1 - 0.4 u u u u u u u u u u u u u u u

RHODOLINE® 286NLow foaming, ammonia-neutralized copolymer, best for gloss development. Exterior paints

u u u NH4 7.0 50 0.1 - 0.4 u u u u u NE NE NE NE NE NE u u — — — —


RHODOLINE® DefoamersSolvay’s extensive line of RHODOLINE® defoamers is designed to provide optimal foam control in coatings, inks and adhesive formulations. RHODOLINE® defoamers provide excellent deaeration and prevent foam formation during manufacture and application of paints, coatings, emulsion polymerization, inks and adhesives. RHODOLINE® defoamers minimize foam formation during high-shear applications such as paint roll, brush, spray and high-speed ink or coating applications.

RHODOLINE® defoamer portfolio includes industry workhorse products for flat to high gloss paint systems as well as printing inks and adhesive systems. The newly developed eco-friendly, APE–free and Zero-VOC defoamers, provide quick foam knockdown and the lasting efficiency.

Wide range of use in polymers • All acrylic• Vinyl/Acrylic• Styrene/Acrylic• Vinyl Acetate Ethylene (VAE)


Key Features

w Quick bubble break and lasting efficiency in Flat to SG Paints

w Excellent efficiency in architectural and industrial paints, adhesives and inks

w Does not cause fish-eyes or film defects

w Excellent foam control in latex manufacturing of vinyl, acrylics and VAE resins

w Broad compatibility

0 50

100 150 200 250

300

Fo

am v

olum

e (m

l)

No Defoamer Rhodoline® Competitor

■ Initial Foam■ After 1 Minute■ After 2 Minutes




APE-

Free

VOC-

Free

Silic

one

Free

Flat

to s

emi-

glos

s pa

ints

Hig

h Gl

oss

Elas

tom

eric

s /

Roo

f coa

tings

Traffi

c M

arki

ng

Pain

ts

Inks

Adhe

sive

s

USA

(TSC

A)

CAN

ADA

(DSL

)

EURO

PE

(EIN

ECS)

AUST

RAL

IA

(AIC

S)

SOU

TH K

OREA

(K

ECL)

JAPA

N (M

ITI)

175.

105

176.

170

176.

180

176.

200

176.

210

Oil Based

RHODOLINE® 622 Highly recommended for exterior flat to semi-gloss waterborne coatings u u u u u u u u u u — u u u u

RHODOLINE® 635 In-process defoaming of vinyl latexes for coatings, PSA and paints u u u u u u u u u u u u u u u u

RHODOLINE® 640 Recommended for flat to semi-gloss coatings u u u u u u u u u NE NE NE NE NE

RHODOLINE® 643 Recommended for contractor and consumer latex paints u u u u u u u u u u u u — — u u u

RHODOLINE® 646 In-process defoaming of latexes for coatings, PSA and inks u u u u u u u u u u u u u u u

RHODOLINE® 670 In-process defoaming of latexes for coatings and PSA u u u u u u u u u u u u u u u

RHODOLINE® 679 Recommended for adhesives and inks u u u u u u u u u u u u u u u

RHODOLINE® 681F Recommended for flat to semi-gloss coatings u u u u u u u u u u u u u u u u u

RHODOLINE® 688 Workhorse defoamer for flat to semi-gloss waterborne coatings u u u u u u u u u u NE NE NE NE NE

Glycol Ester

RHODOLINE® 990A molecular defoamer that provides excellent defoaming efficiency with minimum impact on gloss.

u u u u u u u u u u u u u u u u u

RHODOLINE® 999*A molecular defoamer that provides excellent defoaming efficiency in water-based inks and adhesives with minimum impact on gloss

u u u u u u u u u u u L L L L L

u Listed - Not listed NE Not evaluated * REACH compliant

RHODOLINE® Defoamers




APE-

Free

VOC-

Free

Silic

one

Free

Flat

to s

emi-

glos

s pa

ints

Hig

h Gl

oss

Elas

tom

eric

s /

Roo

f coa

tings

Traffi

c M

arki

ng

Pain

ts

Inks

Adhe

sive

s

USA

(TSC

A)

CAN

ADA

(DSL

)

EURO

PE

(EIN

ECS)

AUST

RAL

IA

(AIC

S)

SOU

TH K

OREA

(K

ECL)

JAPA

N (M

ITI)

175.

105

176.

170

176.

180

176.

200

176.

210

Oil Based

RHODOLINE® 622 Highly recommended for exterior flat to semi-gloss waterborne coatings u u u u u u u u u u — u u u u

RHODOLINE® 635 In-process defoaming of vinyl latexes for coatings, PSA and paints u u u u u u u u u u u u u u u u

RHODOLINE® 640 Recommended for flat to semi-gloss coatings u u u u u u u u u NE NE NE NE NE

RHODOLINE® 643 Recommended for contractor and consumer latex paints u u u u u u u u u u u u — — u u u

RHODOLINE® 646 In-process defoaming of latexes for coatings, PSA and inks u u u u u u u u u u u u u u u

RHODOLINE® 670 In-process defoaming of latexes for coatings and PSA u u u u u u u u u u u u u u u

RHODOLINE® 679 Recommended for adhesives and inks u u u u u u u u u u u u u u u

RHODOLINE® 681F Recommended for flat to semi-gloss coatings u u u u u u u u u u u u u u u u u

RHODOLINE® 688 Workhorse defoamer for flat to semi-gloss waterborne coatings u u u u u u u u u u NE NE NE NE NE

Glycol Ester

RHODOLINE® 990A molecular defoamer that provides excellent defoaming efficiency with minimum impact on gloss.

u u u u u u u u u u u u u u u u u

RHODOLINE® 999*A molecular defoamer that provides excellent defoaming efficiency in water-based inks and adhesives with minimum impact on gloss

u u u u u u u u u u u L L L L L


Coalescent

Specialty AminesSOLVAY Novecare offers a broad portfolio of fatty and specialty amines for paints and coatings.

FENTAMINE® and FENTACARE® products are based on specialty amines for use in paints and ink systems. FENTAMINE® and FENTACARE® products offer multi-functional performance properties such as improvement of pigment wetting and dispersions, as polyurethane catalysts, epoxy curing agents and used as neutralizing agents.

Amine Types

w Fatty Alky primary amines

w Fatty Alkyl Tri & Tetra amines

w Alkyl Ethanol/Propanol amines

w Specialty amines

w Ethoxylated amines

w Quaternary amines


DIBRHODIASOLV® DIB is a new generation of low odor coalescent additive that meets tightening VOC regulations in the paint industry. RHODIASOLV® DIB helps in formulating low VOC paints without the drawbacks of plastisizers. RHODIASOLV® DIB coalescent agent is extremely efficient for architectural, industrial coatings and inks. RHODIASOLV® DIB does not cause film softness and provides films with improved hardness and scrub resistance.

Key Features w Enables low VOC formulationsw Low odorw Enhanced efficiencyw Biodegradabilityw Hydrolytically stablew Nonflammablew True coalescing agent

Coalescent

Specialty AminesAmine Types

w Fatty Alky primary amines

w Fatty Alkyl Tri & Tetra amines

w Alkyl Ethanol/Propanol amines

w Specialty amines

w Ethoxylated amines

w Quaternary amines

Recommended Use International Inventory Status

PRODUCT NAME DESCRIPTION CAS #

Epox

y cu

ring

agen

t

PU c

atal

ys

Neu

tral

izer

Disp

ersa

nt/

gr

indi

ng a

id

Ant

ista

tic

USA

(TSC

A)

CAN

ADA

(DSL

)

EURO

PE *

* (E

INEC

S)

AUST

RA

LIA

(AIC

S)

SOU

TH K

OR

EA

(KEC

L)

JAPA

N (M

ITI)

Primary Amines

FENTAMINE® A-CO Coco amine 61788-46-3 u u u u u u NE

FENTAMINE® A-12 Laurylamine 124-22-1 u u u u u u u

FENTAMINE® A-O Oleyamine 112-90-3 u u u u u u u

FENTAMINE® A-HT Hydrogenated tallow amine 61788-45-2 u u u u u u

FENTAMINE® A-T Tallow amines 61790-33-8 u u u u u u

Secondary Amines

FENTAMINE® DA-CO N-Cocoalkyl 1,3-propanediamines 61791-63-7 u u u u u u u u u

FENTAMINE® DA-T N-Tallowalkyl 1,3-propanediamines 61791-55-7 u u u u u u u u u

Tertiary Amines

FENTAMINE® DMA 1295 Dodecyl dimethylamine 112-18-5 u u u u u u u

FENTAMINE® DMA 1695 Hexadecyl dimethylamine 112-69-6 u u u u u u u

FENTAMINE® DMA 1895 Octadecyl dimethylamine 124-28-7 u u u u u u u

FENTAMINE® DMA 0897 Octyl dimethylamine 7378-99-6 u u u u u u u

Specialty Amines

FENTAMINE® DMAPA 3-Dimethylamino 1-Propylamine 109-55-7 u u u u u u u u u

FENTAMINE® DEAPA 3-Diethylamino 1-Propylamine 104-78-9 u u u u u u u

FENTAMINE® MDEA n-methyl diethanol amine 105-59-9 u u u u u u u

Specialty Amine Ethoxylates

FENTACARE® T02 Bis(2-Hydroxyethyl) tallowalkyl amine(2EO) 61791-44-4 u u u u u u u u

FENTACARE® CO5 Cocoamine 5EO 61791-14-8 u u u u u u u u

FENTACARE® CO2 Cocoamine 2EO 61791-14-8 u u u u u u u u

RHODAMEEN® HT-50 Hydrogenated tallow amine ethoxylate

68783-22-2; 7732-18-5

u u u u u u — —

RHODAMEEN® PN-430 Ethoxylated oleyl amine 58253-49-9 u u u u u u u u

RHODAMEEN® VP532 Ethoxylated tallow amine 61791-26-2 u u u u u u u u

Quaternary Amine

FENTACARE® DHT 21 75 Di(hydrogenated Tallow) Dimethyl Ammonium Chloride 61789-80-8 u u u — u u u

Fatty Alkyl Tri and Tetra Amine

FENTAMINE® DPTA- T N1-Tallowalkyl dipropylenetriamines 61791-57-9 u u NE u u u NE

u Listed - Not listed NE Not evaluated ** Availability based on REACH registration


The way we do businessSolvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent upon the responsible way in which we conduct our current activities — a way that reflects our commitment to each of our stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere and the Economic Sphere.

Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self—assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership.

North AmericaSolvay Novecare—504 Carnegie Center Drive, Princeton, NJ 08540—USAPhone: +1-800-973-7873—Fax: +1-609-860-0463—[email protected]

EuropeSolvay Novecare—40, rue de la Haie—Coq-F—93306 Aubervilliers Cedex—FrancePhone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90

Asia PacificSolvay Asia Pacific Pte. Ltd.—438B Alexandra Road—#02—09/12 Alexandra Technopark—Singapore 119968Phone: +65-6291 1921—Fax: +65—6394 3377

Latin America Solvay Novecare—Centro Empresarial—Avenida Maria Coelho Aguiar, 215, Bloco B-1º AndarCep: 05804-902 —São Paulo—SP BrazilPhone: +55 11 3747-7637—Fax: +55 11 3741-8378

www.solvay.com

Material Safety Data Sheets (MSDS) are available by emailing us or contacting your sales representative. Always consult the appropriate MSDS before using any of our products.

Neither Solvay Specialty Polymers nor any of its affiliates makes any warranty, express or implied, including merchantability or fitness for use, or accepts any liability in connection with this product, related information or its use. Some applications of which Solvay’s products may be proposed to be used are regulated or restricted by applicable laws and regulations or by national or international standards and in some cases by Solvay’s recommendation, including applications of food/feed, water treatment, medical, pharmaceuticals, and personal care. Only products designated as part of the Solviva® family of biomaterials may be considered as candidates for use in implantable medical devices. The user alone must finally determine suitability of any information or products for any contemplated use in compliance with applicable law, the manner of use and whether any patents are infringed. The information and the products are for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process. This is not a license under any patent or other proprietary right.

All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners.© 2012 Solvay Specialty Polymers USA, LLC. All rights reserved.

> Responsible Care is the chemical industry’s voluntary continuous improvement initiative to promote safe handling of products. (1987)

> The UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, Working Conditions, Respect for the environment and anti—corruption. (2003)

> The International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005)

> Solvay Novecare has achieved world—wide ISO—9001 Quality Management

System Multi—Site Certification. (2008)

NA

MAR

CH

201

6SO

LVAY

NO

VEC

ARE

— D

iLeo

Gra

phic

Des

ign,

mar

iadi

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com

cast

.net

Surfactants and Specialty Monomers

Contents

FORMULATED EMULSIFIERS ................................................................................... Page 2

SULFATES ............................................................................................................... Page 6

PHOSPHATE ESTERS................................................................................................ Page 8

SULFONATES............................................................................................................ Page 10

NONIONICS (APE FREE) ........................................................................................... Page 12

NONIONICS ............................................................................................................... Page 14

SPECIALTY MONOMERS ........................................................................................... Page 16

DEFOAMERS ............................................................................................................ Page 20

Solvay Novecare Emulsion Polymerization / 1

Solvay Novecare is the leading global supplier of emulsifiers, specialty monomers and specialty additives to the Emulsion Polymerization Industry.

For more than 40 years, we have been committed to providing leading edge solutions to this industry. Our portfolio has evolved into the most compre-hensive range of products addressing formulation challenges and more importantly enabling customers to create tomorrow’s performance require-ments today.

Solvay Novecare supports customers with a broad range of sustainable solutions and services including products optimized around criteria such as biodegradability, eco-toxicity, VOC content, and percentage of renewable materials.

Our APE-free surfactant portfolio covers all chemistries from nonionics (RHODASURF®), to anionics like alkyl sulfonates (RHODACAL®), alkyl ether sulfates (RHODAPEX®), sulfosuccinates (GEROPON®), phosphate esters (RHODAFAC®) and formulated blends (ABEX®).

Solvay Novecare’s dedicated specialty monomer portfolio (SIPOMER®) brings functionality and boosts binder performance to higher levels. Whether seeking to improve substrate wetting, adhesion to different substrates, emulsion stability or simply demand higher film performance, such as high scrub, stain or water resistance, Solvay has the solution.

Working with Solvayw Extensive portfolio of

products

w Surfactants & Specialty monomers dedicated to Emulsion Polymers manufacturing

w Over 40 years as major supplier to the Emulsion Polymer industry

w Global player with local technical teams to support your developments

Solvay Novecare Emulsion Polymerization

Note: These products are produced at worldwide locations through the Novecare division of Solvay.

Contents

FORMULATED EMULSIFIERS ................................................................................... Page 2

SULFATES ............................................................................................................... Page 6

PHOSPHATE ESTERS................................................................................................ Page 8

SULFONATES............................................................................................................ Page 10

NONIONICS (APE FREE) ........................................................................................... Page 12

NONIONICS ............................................................................................................... Page 14

SPECIALTY MONOMERS ........................................................................................... Page 16

DEFOAMERS ............................................................................................................ Page 20

FDA Status International Inventory Status

Product DescriptionAPE/

APE-FreePhysical

FormSolids

Content (%)

Critical Micelle

Concentration (%)

Surface Tension at CMC

(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

181.

30

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

-re

a (K

EC

L)

Jap

an

(MIT

)

Formulated Anionics

ABEX® 18-S Proprietary APE-Free Liquid 35 0.03 48 ● — — ● ● — — — — ● ● ● ● ● ●

ABEX® 23-S Proprietary APE-Free Liquid 60 0.10 40 — — — — — — — — — ● ● ● ● ● ●

ABEX® 26-S Proprietary APE Liquid 33 0.02 55 ● — — ● ● — — — — ● ● ● — ● ●

ABEX® 33-S Proprietary APE Liquid 30 0.12 37 — — — — — — — — — ● ● ● — ● ●

ABEX® JKB Proprietary APE-Free Liquid 30 0.13 40 ● — — ● ● — — RL — ● ● ● ● ● ●

ABEX® VA-50 Proprietary APE Liquid 46 0.17 44 ● — — — ● — — — — ● ● ● ● ● ●

ABEX® 2005 Proprietary APE-Free Liquid 30 — — ● — — ● ● ● — — ● ● ● ● ● ● ●

ABEX® 2020 Proprietary APE-Free Liquid 30 0.01 41 ● — — — ● — — — — ● ● ● ● ● ●

ABEX® 2115-A Proprietary APE-Free Liquid 33 — — ● — — — — — — — — ● ● ● — — —

ABEX® 8018 Proprietary APE-Free Liquid 31 0.05 37 ● — — ● ● — — L — ● ● ● ● ● ●

Formulated Anionics

ABEX® EP-100Ammonium salt of

Sulfated Nonylphenol Ethoxylate; 4 Moles EO

APE Liquid 30 0.03 33 ● ● ● ● ● ● ● ● — ● ● ● ● ● ●



APE Liquid 30 0.01 37 ● — — — ● — — — — ● ● ● ● ● ●



APE Liquid 30 0.05 42 ● — — — ● — — — — ● ● ● ● ● ●

ABEX® EP-120 NASodium Salt of Sulfated Nonylphenol ethoxylate

APE Liquid 35 ND ND — — — — — — — — — ● ● ● ● ● ●

2 /Surfactants and Specialties

Formulated Emulsifiers



APE-FreePhysical

FormSolids

Content (%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

181.

30

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

-re

a (K

EC

L)

Jap

an

(MIT

)

Formulated Anionics

ABEX® 18-S Proprietary APE-Free Liquid 35 0.03 48 ● — — ● ● — — — — ● ● ● ● ● ●

ABEX® 23-S Proprietary APE-Free Liquid 60 0.10 40 — — — — — — — — — ● ● ● ● ● ●

ABEX® 26-S Proprietary APE Liquid 33 0.02 55 ● — — ● ● — — — — ● ● ● — ● ●

ABEX® 33-S Proprietary APE Liquid 30 0.12 37 — — — — — — — — — ● ● ● — ● ●

ABEX® JKB Proprietary APE-Free Liquid 30 0.13 40 ● — — ● ● — — RL — ● ● ● ● ● ●

ABEX® VA-50 Proprietary APE Liquid 46 0.17 44 ● — — — ● — — — — ● ● ● ● ● ●

ABEX® 2005 Proprietary APE-Free Liquid 30 — — ● — — ● ● ● — — ● ● ● ● ● ● ●

ABEX® 2020 Proprietary APE-Free Liquid 30 0.01 41 ● — — — ● — — — — ● ● ● ● ● ●

ABEX® 2115-A Proprietary APE-Free Liquid 33 — — ● — — — — — — — — ● ● ● — — —

ABEX® 8018 Proprietary APE-Free Liquid 31 0.05 37 ● — — ● ● — — L — ● ● ● ● ● ●

Formulated Anionics



APE Liquid 30 0.03 33 ● ● ● ● ● ● ● ● — ● ● ● ● ● ●



APE Liquid 30 0.01 37 ● — — — ● — — — — ● ● ● ● ● ●



APE Liquid 30 0.05 42 ● — — — ● — — — — ● ● ● ● ● ●

ABEX® EP-120 NASodium Salt of Sulfated Nonylphenol ethoxylate

APE Liquid 35 ND ND — — — — — — — — — ● ● ● ● ● ●

Formulated Emulsifiers / 3

FDA Listing Status Codes

● Listed with no specific limits

E Extraction limitation

L Listed with limitations

R Referenced with no limitations

RL Referenced with limitations

International Inventory Status Codes

● Listed — Not Listed



APE-Free HLBPhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

181.

30

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

-re

a (K

EC

L)

Jap

an

(MIT

)

Nonionics

ABEX® 2515 Proprietary APE-Free 16.3 Liquid 50 0.03 38 ● — — ● ● — — — ● ● ● ● ● ● ●

ABEX® 2525/40 Proprietary APE-Free 17.4 Liquid 40 0.08 44 ● — — ● ● — — — ● ● ● ● ● ● ●

ABEX® 2535 Proprietary APE-Free 18.0 Liquid 50 0.09 45 ● — — ● ● R R — ● ● ● ● ● ● ●

ABEX® 2545 Proprietary APE-Free 18.3 Liquid 50 0.12 46 ● — — ● ● — — ● ● ● ● ● ● ● ●

Formulated Emulsifiers




APE-Free HLBPhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

181.

30

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

-re

a (K

EC

L)

Jap

an

(MIT

)

Nonionics

ABEX® 2515 Proprietary APE-Free 16.3 Liquid 50 0.03 38 ● — — ● ● — — — ● ● ● ● ● ● ●

ABEX® 2525/40 Proprietary APE-Free 17.4 Liquid 40 0.08 44 ● — — ● ● — — — ● ● ● ● ● ● ●

ABEX® 2535 Proprietary APE-Free 18.0 Liquid 50 0.09 45 ● — — ● ● R R — ● ● ● ● ● ● ●

ABEX® 2545 Proprietary APE-Free 18.3 Liquid 50 0.12 46 ● — — ● ● — — ● ● ● ● ● ● ● ●









Formulated Emulsifiers / 5


Product DescriptionIonic

ChargePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

New

Zel

and

Phi

lipp

ines

ALKYL SULFATES

RHODAPON® UB STD Sodium Lauryl Sulfate Anionic Liquid 30 0.06 29 ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODAPON® L-22EP Ammonium Lauryl Sulfate Anionic Liquid 28 0.06 33 ● — — ● ● — — — ● ● ● ● ● ● ● ●

RHODAPON® LX-28 AEP Sodium Lauryl Sulfate Anionic Liquid 30 0.06 29 ● ● ● ● ● ● ● — ● ● ● ● ● ● ● ●

ETHER SULFATES

RHODAPEX EST-30*Sodium Tridecyl Ether Sulfate;

3 Moles EOAnionic Liquid 30 0.08 33 ● — — — — — — — ● ● ● ● ● ● ● ●

RHODAPEX® LA-40SSodium Salt of Sulfated Linear Alcohol Ethoxylate; 4 Moles EO

Anionic Liquid 31 0.02 32 L — — L L — — L ● ● ● ● ● ● ● ●

RHODAPEX® LA-120SSodium Salt of sulfated linear

Alcohol Ethoxylate, 12 Moles EOAnionic Liquid 30 0.02 34 ● — — L L — — L ● ● — ● — — ● ●


alcohol ethoxylate, 30 Moles EOAnionic Liquid 30 0.03 44 ● — — L L — ● L ● — ● — — ● ● ●

RHODAPEX® AB-20**Ammonium Salt of Sulfated

Alcohol Ethoxylate; 9 Moles EOAnionic Liquid 29 0.03 33 ● — — ● ● — — — ● ● ● ● ● ● ● ●

RHODAPEX® OPS-253Sulfate of Alkyl Phenol Ethoxylate

Sodium SaltAnionic Liquid 36 0.09 36 — — — — — — — — ● ● ● ● ● ● ● ●

RHODAPEX® CO-436Ammonium Salt of Sulfated

Alkylphenol Ethoxylate; 4 Moles EOAnionic Liquid 58 0.03 33 ● ● ● ● ● ● ● L ● ● ● ● ● — ● ●


Sulfates

* North America Only, **Europe- Asia



ChargePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

New

Zel

and

Phi

lipp

ines

ALKYL SULFATES

RHODAPON® UB STD Sodium Lauryl Sulfate Anionic Liquid 30 0.06 29 ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODAPON® L-22EP Ammonium Lauryl Sulfate Anionic Liquid 28 0.06 33 ● — — ● ● — — — ● ● ● ● ● ● ● ●

RHODAPON® LX-28 AEP Sodium Lauryl Sulfate Anionic Liquid 30 0.06 29 ● ● ● ● ● ● ● — ● ● ● ● ● ● ● ●

ETHER SULFATES

RHODAPEX EST-30*Sodium Tridecyl Ether Sulfate;

3 Moles EOAnionic Liquid 30 0.08 33 ● — — — — — — — ● ● ● ● ● ● ● ●

RHODAPEX® LA-40SSodium Salt of Sulfated Linear Alcohol Ethoxylate; 4 Moles EO

Anionic Liquid 31 0.02 32 L — — L L — — L ● ● ● ● ● ● ● ●


Alcohol Ethoxylate, 12 Moles EOAnionic Liquid 30 0.02 34 ● — — L L — — L ● ● — ● — — ● ●


alcohol ethoxylate, 30 Moles EOAnionic Liquid 30 0.03 44 ● — — L L — ● L ● — ● — — ● ● ●

RHODAPEX® AB-20**Ammonium Salt of Sulfated

Alcohol Ethoxylate; 9 Moles EOAnionic Liquid 29 0.03 33 ● — — ● ● — — — ● ● ● ● ● ● ● ●

RHODAPEX® OPS-253Sulfate of Alkyl Phenol Ethoxylate

Sodium SaltAnionic Liquid 36 0.09 36 — — — — — — — — ● ● ● ● ● ● ● ●

RHODAPEX® CO-436Ammonium Salt of Sulfated

Alkylphenol Ethoxylate; 4 Moles EOAnionic Liquid 58 0.03 33 ● ● ● ● ● ● ● L ● ● ● ● ● — ● ●

Sulfates / 7











ChargePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

PHOSPHATE ESTERS

RHODAFAC® RS-410Aliphatic Phosphate Ester;

3 Moles EOAnionic Liquid 100 0.002 — — — — — — — — — ● ● ● ● ● ●


6 Moles EOAnionic Liquid 100 0.002 — ● — — ● ● ● ● ● ● ● ● ● ● ●

RHODAFAC® RS-610A-25Aliphatic Phosphate Ester; 6 Moles

EO; Ammonium Salt SolutionAnionic Liquid 25 0.01 30 ● — — ● ● ● ● ● ● ● ● ● ● ●


10 Moles EOAnionic Liquid 100 0.002 36 ● — — ● ● ● ● ● ● ● ● ● ● ●

RHODAFAC® RS-710 DAliphatic Phosphate Ester;



50 Moles EOAnionic Liquid 80 — — — — — — — — — — ● ● ● ● ● ●

RHODAFAC® RE-410 Aromatic Phosphate Ester; 3 EO Anionic Liquid 100 — — — — — — — — — — ● ● ● ● ● ●

RHODAFAC® RE-610Aromatic Phosphate Ester;

9 Moles EOAnionic Liquid 100 0.01 37 ● — — — — — — ● ● ● ● ● ● ●

RHODAFAC® RK-500 AAliphatic Phosphate Ester;

3.5 Moles EOAnionic Liquid 74 — — — — — — — — — — ● ● ● — — —


Phosphate Esters



ChargePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

PHOSPHATE ESTERS


3 Moles EOAnionic Liquid 100 0.002 — — — — — — — — — ● ● ● ● ● ●


6 Moles EOAnionic Liquid 100 0.002 — ● — — ● ● ● ● ● ● ● ● ● ● ●

RHODAFAC® RS-610A-25Aliphatic Phosphate Ester; 6 Moles

EO; Ammonium Salt SolutionAnionic Liquid 25 0.01 30 ● — — ● ● ● ● ● ● ● ● ● ● ●



RHODAFAC® RS-710 DAliphatic Phosphate Ester;



50 Moles EOAnionic Liquid 80 — — — — — — — — — — ● ● ● ● ● ●

RHODAFAC® RE-410 Aromatic Phosphate Ester; 3 EO Anionic Liquid 100 — — — — — — — — — — ● ● ● ● ● ●

RHODAFAC® RE-610Aromatic Phosphate Ester;

9 Moles EOAnionic Liquid 100 0.01 37 ● — — — — — — ● ● ● ● ● ● ●

RHODAFAC® RK-500 AAliphatic Phosphate Ester;

3.5 Moles EOAnionic Liquid 74 — — — — — — — — — — ● ● ● — — —

Phosphates Esters / 9











ChargePhysical

FormSolids

Content (%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

SULFONATES

RHODACAL® A-246/LSodium Alpha Olefin

SulfonateAnionic Liquid 40 0.07 29 ● ● ● ● ● ● ● L ● ● ● ● ● ●

RHODACAL® 330Isopropyl Amine Dodecyl

Benzene SulfonateAnionic Liquid 90 0.1 32 ● — — — — — ● — ● ● ● — — —

RHODACAL® DS-10Sodium Dodecyl Benzene

SulfonateAnionic Flake 98 0.1 32 L L ● ● ● — — — ● ● ● ● ● ●


SulfonateAnionic Liquid 23 0.1 32 L L ● ● ● — — — ● ● ● ● ● ●

RHODACAL® DSBDisodium Alkyl

Diphenyloxide SulfonateAnionic Liquid 45 0.08 32 ● ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODACAL® LDS-22Sodium Dodecyl (linear)

Benzene SulfonateAnionic Liquid 23 0.1 32 R ● ● ● ● — — — ● ● ● ● ● ●

SULFOSUCCINATES

GEROPON® SS-OIPDisodium Salt of Monoalkyl

Ether SulfosuccinateAnionic Liquid 40 0.1 30 — — — ● R — — L ● ● ● ● ● —

GEROPON® ACR-4Disodium Sort 4Monoalkyl ether Sulfosuccinate

Anionic Liquid 31 0.01 29 ● — — — — — — ● ● ● ● ● ● —

Geropon® 99Aqueous Dioctyl Sodium

sulfosuccinateAnionic Liquid 75 0.35 27 ● ● — ● ● — ● — ● ● ● ● ● ●


Sulfonates



ChargePhysical

FormSolids

Content (%)

Critical Micelle

Concentration (%)


(dynes/CM) 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

SULFONATES

RHODACAL® A-246/LSodium Alpha Olefin

SulfonateAnionic Liquid 40 0.07 29 ● ● ● ● ● ● ● L ● ● ● ● ● ●

RHODACAL® 330Isopropyl Amine Dodecyl

Benzene SulfonateAnionic Liquid 90 0.1 32 ● — — — — — ● — ● ● ● — — —


SulfonateAnionic Flake 98 0.1 32 L L ● ● ● — — — ● ● ● ● ● ●


SulfonateAnionic Liquid 23 0.1 32 L L ● ● ● — — — ● ● ● ● ● ●

RHODACAL® DSBDisodium Alkyl

Diphenyloxide SulfonateAnionic Liquid 45 0.08 32 ● ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODACAL® LDS-22Sodium Dodecyl (linear)

Benzene SulfonateAnionic Liquid 23 0.1 32 R ● ● ● ● — — — ● ● ● ● ● ●

SULFOSUCCINATES

GEROPON® SS-OIPDisodium Salt of Monoalkyl

Ether SulfosuccinateAnionic Liquid 40 0.1 30 — — — ● R — — L ● ● ● ● ● —

GEROPON® ACR-4Disodium Sort 4Monoalkyl ether Sulfosuccinate

Anionic Liquid 31 0.01 29 ● — — — — — — ● ● ● ● ● ● —

Geropon® 99Aqueous Dioctyl Sodium

sulfosuccinateAnionic Liquid 75 0.35 27 ● ● — ● ● — ● — ● ● ● ● ● ●

Sulfonates / 11










Product Description

Moles of Ethylene

OxidePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) HLB 175.

105

176.

170

176.

180

176.

200

176.

210

178.

3400

181.

30

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

ALIPHATIC ALCOHOL ETHOXYLATES

RHODASURF® BC-420 TDA Ethoxylate 3 Liquid 100 — 8 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-610 TDA Ethoxylate 6 Liquid 100 — — 11.4 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-720 TDA Ethoxylate 9-10 Paste 100 — — 13.8 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-729 TDA Ethoxylate 9-10 Liquid 90 — — 13.8 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-840 TDA Ethoxylate 15 Paste 100 — — 15.4 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® TLA 3040 TDA Ethoxylate 30 Liquid 40 0.08 44 17.4 ● ● ● — — — ● ● ● ● ● ● ●

RHODASURF® TLA 4050 TDA Ethoxylate 40 Liquid 50 0.09 45 18 ● ● ● — — — ● ● ● ● ● ● ●


RHODASURF® TR 4070* TDA Ethoxylate 40 Liquid 70 — — — ● ● ● — — — ● ● ● ● ● ● ●

RHODASURF® L-4 LA Ethoxylate 4 Liquid 100 — — 9.7 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® LA-9/85 LA Ethoxylate 9 Liquid 85 — 13.1 ● ● ● ● ● — ● ● ● ● ● ● ●


RHODASURF® ON-870 OA Ethoxylate 20 Solid 100 0.015 37 15.4 ● — ● ● — — — ● ● ● ● ● ●

RHODASURF® ON-877 OA Ethoxylate 20 Liquid 70 ● — ● ● — — — ● ● ● ● ● ●

RHODASURF® 6530 Proprietary — Liquid 65 0.08 41 17 ● ● — — ● — ● ● ● ● ● ● ●

RHODASURF® L-7/90 LA Ethoxylate 7 Liquid 90 — 30 12.5 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® S25 28 TSP Ethoxylate 25 Liquid 28 — 14.5 — — — — — — — ● ● ● ● ● ●

BLOCK CO-POLYMERS

ANTAROX® L-61 EO/PO — Flakes 100 — Insoluble 3.0 ● ● ● ● ● — — ● ● ● ● ● ●

ANTAROX® L-62 EO/PO Liquid 100 — Soluble 7.0 ● — ● ● ● — — ● ● ● ● ● ●

ANTAROX® L-64 EO/PO — Liquid 100 — 43.2 15.0 ● ● ● ● ● — — ● ● ● ● ● ●

*Europe- Asia


Nonionics (APE Free)


Product Description

Moles of Ethylene

OxidePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)


(dynes/CM) HLB 175.

105

176.

170

176.

180

176.

200

176.

210

178.

3400

181.

30

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

ALIPHATIC ALCOHOL ETHOXYLATES

RHODASURF® BC-420 TDA Ethoxylate 3 Liquid 100 — 8 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-610 TDA Ethoxylate 6 Liquid 100 — — 11.4 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-720 TDA Ethoxylate 9-10 Paste 100 — — 13.8 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-729 TDA Ethoxylate 9-10 Liquid 90 — — 13.8 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® BC-840 TDA Ethoxylate 15 Paste 100 — — 15.4 ● ● ● ● ● — ● ● ● ● ● ● ●


RHODASURF® TLA 4050 TDA Ethoxylate 40 Liquid 50 0.09 45 18 ● ● ● — — — ● ● ● ● ● ● ●


RHODASURF® TR 4070* TDA Ethoxylate 40 Liquid 70 — — — ● ● ● — — — ● ● ● ● ● ● ●

RHODASURF® L-4 LA Ethoxylate 4 Liquid 100 — — 9.7 ● ● ● ● ● — ● ● ● ● ● ● ●



RHODASURF® ON-870 OA Ethoxylate 20 Solid 100 0.015 37 15.4 ● — ● ● — — — ● ● ● ● ● ●

RHODASURF® ON-877 OA Ethoxylate 20 Liquid 70 ● — ● ● — — — ● ● ● ● ● ●

RHODASURF® 6530 Proprietary — Liquid 65 0.08 41 17 ● ● — — ● — ● ● ● ● ● ● ●

RHODASURF® L-7/90 LA Ethoxylate 7 Liquid 90 — 30 12.5 ● ● ● ● ● — ● ● ● ● ● ● ●

RHODASURF® S25 28 TSP Ethoxylate 25 Liquid 28 — 14.5 — — — — — — — ● ● ● ● ● ●

BLOCK CO-POLYMERS

ANTAROX® L-61 EO/PO — Flakes 100 — Insoluble 3.0 ● ● ● ● ● — — ● ● ● ● ● ●

ANTAROX® L-62 EO/PO Liquid 100 — Soluble 7.0 ● — ● ● ● — — ● ● ● ● ● ●

ANTAROX® L-64 EO/PO — Liquid 100 — 43.2 15.0 ● ● ● ● ● — — ● ● ● ● ● ●

Nonionics (APE Free) / 13










Product Description

Moles of Ethylene

OxideIonic

ChargePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)

Surface Tension at CMC (dynes/

CM) HLB 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

ALKYLPHENOL ETHOXYLATES

IGEPAL® CA-210 Octylphenol Ethoxylate 1.5 Nonionic Liquid 100 — Insoluble 4.8 ● — — ● — — ● — ● ● ● ● ● ●

IGEPAL® CA-630 Octylphenol Ethoxylate 9 Nonionic Liquid 100 0.005 31 13 ● R R R ● R R ● ● ● ● ● ● ●

IGEPAL® CA-877 Octylphenol Ethoxylate 23 Nonionic Liquid 70 — — 16.6 ● — — — ● — — — ● ● ● ● ● ●

IGEPAL® CA-887 Octylphenol Ethoxylate 30 Nonionic Liquid 70 0.03 38 17.4 ● — — ● ● — — ● ● ● ● ● ● ●

IGEPAL® CA-897 Octylphenol Ethoxylate 40 Nonionic Liquid 70 0.04 44 18 ● ● ● ● ● ● ● ● ● ● ● ● ● ●


IGEPAL® CO-210 Nonylphenol Ethoxylate 1.5 Nonionic Liquid 100 - ● — ● — ● — ● ● ● ● ● ●

IGEPAL®CO-430 Nonylphenol Ethoxylate 4 Nonionic Liquid 100 - ● ● ● ● ● ● ● ● ● ● ● ●

IGEPAL® CO-530 Nonylphenol Ethoxylate 6 Nonionic Liquid 100 0.03 32 10.8 ● R R R ● R ● ● ● ● ● ● ● ●

IGEPAL® CO-630 Nonylphenol Ethoxylate 9 Nonionic Liquid 100 0.005 32 13 ● R R R ● R ● ● ● ● ● ● ● ●

IGEPAL® CO-720 Nonylphenol Ethoxylate 12 Nonionic Liquid 100 0.007 36 14.2 ● — — — ● — ● — ● ● ● ● ● ●


IGEPAL® CO-858 Nonylphenol Ethoxylate 20 Nonionic Liquid 80 0.01 41 16.0 ● — — — ● — — ● ● ● ● ● ● ●

IGEPAL® CO-887 Nonylphenol Ethoxylate 30 Nonionic Liquid 70 0.02 45 17.2 ● R — R ● R R ● ● ● ● ● ● ●

IGEPAL® CO-897 Nonylphenol Ethoxylate 40 Nonionic Liquid 70 0.04 44 17.8 ● R R R ● R R ● ● ● ● ● ● ●

IGEPAL® CO-977 Nonylphenol Ethoxylate 50 Nonionic Paste 70 0.05 44 18.2 ● — — — ● — R ● ● ● ● ● ● ●

IGEPAL® CO-987 Nonylphenol Ethoxylate 70 Nonionic Paste 70 0.05 48 18.6 — — — — ● — — — ● ● ● ● ● ●

IGEPAL® DM-430 Dinonylphenol Ethoxylate 7 Nonionic Liquid 100 — — 9.5 — — — — — — — — ● ● ● ● — ●


Nonionics


Product Description

Moles of Ethylene

OxideIonic

ChargePhysical

Form

Solids Content

(%)

Critical Micelle

Concentration (%)

Surface Tension at CMC (dynes/

CM) HLB 175.

105

175.

300

175.

320

176.

170

176.

180

176.

200

176.

210

178.

3400

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

ALKYLPHENOL ETHOXYLATES

IGEPAL® CA-210 Octylphenol Ethoxylate 1.5 Nonionic Liquid 100 — Insoluble 4.8 ● — — ● — — ● — ● ● ● ● ● ●

IGEPAL® CA-630 Octylphenol Ethoxylate 9 Nonionic Liquid 100 0.005 31 13 ● R R R ● R R ● ● ● ● ● ● ●

IGEPAL® CA-877 Octylphenol Ethoxylate 23 Nonionic Liquid 70 — — 16.6 ● — — — ● — — — ● ● ● ● ● ●

IGEPAL® CA-887 Octylphenol Ethoxylate 30 Nonionic Liquid 70 0.03 38 17.4 ● — — ● ● — — ● ● ● ● ● ● ●



IGEPAL® CO-210 Nonylphenol Ethoxylate 1.5 Nonionic Liquid 100 - ● — ● — ● — ● ● ● ● ● ●

IGEPAL®CO-430 Nonylphenol Ethoxylate 4 Nonionic Liquid 100 - ● ● ● ● ● ● ● ● ● ● ● ●

IGEPAL® CO-530 Nonylphenol Ethoxylate 6 Nonionic Liquid 100 0.03 32 10.8 ● R R R ● R ● ● ● ● ● ● ● ●

IGEPAL® CO-630 Nonylphenol Ethoxylate 9 Nonionic Liquid 100 0.005 32 13 ● R R R ● R ● ● ● ● ● ● ● ●



IGEPAL® CO-858 Nonylphenol Ethoxylate 20 Nonionic Liquid 80 0.01 41 16.0 ● — — — ● — — ● ● ● ● ● ● ●

IGEPAL® CO-887 Nonylphenol Ethoxylate 30 Nonionic Liquid 70 0.02 45 17.2 ● R — R ● R R ● ● ● ● ● ● ●

IGEPAL® CO-897 Nonylphenol Ethoxylate 40 Nonionic Liquid 70 0.04 44 17.8 ● R R R ● R R ● ● ● ● ● ● ●

IGEPAL® CO-977 Nonylphenol Ethoxylate 50 Nonionic Paste 70 0.05 44 18.2 ● — — — ● — R ● ● ● ● ● ● ●

IGEPAL® CO-987 Nonylphenol Ethoxylate 70 Nonionic Paste 70 0.05 48 18.6 — — — — ● — — — ● ● ● ● ● ●

IGEPAL® DM-430 Dinonylphenol Ethoxylate 7 Nonionic Liquid 100 — — 9.5 — — — — — — — — ● ● ● ● — ●

APE Nonionics / 15









International Inventory Status

Trade Name % of Solid Tg (°C) % Water Inhibitor ppmSpecific gravity U

S (T

SC

A)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

Chi

na

(JE

CS

C)

Phi

lipp

ines

(P

ICC

S)

New

Zea

land

(N

ZIo

C)

Performance Features and Application

PAM TechnologyAdhesion and Much More

SIPOMER® PAM-100 100 -18 <1 MEHQ/~5000 1.2 ● — ● ● ● — ● — ●

w Improved adhesion on metal, glass, and other inorganic substrates

w High mono/di alkyl phosphate ratio and low residual acidw Improved latex stability

SIPOMER® PAM-200 100 0 <1 MEHQ/~5000 1.1 ● — ● ● ● — ● — —


w Excellent compatibility with most common organic systemsw High mono/di alkyl phosphate ratio and low residual acidw Improved anti-corrosion propertiesw Polymerizable surfactant

SIPOMER® PAM-300 100 -40 <1 MEHQ/~5000 1.1 ● — ● — — — ● — —



SIPOMER® PAM-4000 100 ND <0.25 MEHQ/~400 1.2 ● ● ● ● ● — ● ● ●w Improved adhesion on metal substratew Improved latex stabilityw Improved gloss

SIPOMER® PAM 5000 100 NA 1.0 max none 1.25 ● — ● — — —Improved scrub resistance when formulated into vinyl binders for high PVC paints

Polymerizable Stabilizers

SIPOMER ® COPS-1 40 NA 60 none 1.17 ● ● ● ● ● ● ● ● ●

Reactive co-stabilizer providing:w Low foaming latexesw Better latex stability at low surfactant dosagew Coatings with improved water and bleach resistance

SIPOMER® COPS-3* 25 NA 75 none — — — — — — ● — —Reactive co-stabilizer providing scrub/washability for high PVC coating formulation

SIPOMER ® AES-100 97 NA <2.0 none 1.0 ● — ● — — — — — —


SIPOMER ® AAE-10 99 NA <0.3 none — ● ● ● ● ● ● ● ● ●

Nonionic reactive co-stabilizer:w Low foaming latexesw Better latex stability at low surfactant dosagew Coatings with improved water and bleach resistance

* Asia - Latin America - MEA

* Remainder consists of acrylic acid (~20%) and higher adducts (~50%) ** Sipomer® BEM contains ~25% methacrylic acid *** Sipomer® SEM-25 contains ~20% methacrylic acid **** Sipomer® WAM II-25 contains ~25% methacrylic acid


Specialty Monomers



S (T

SC

A)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

Chi

na

(JE

CS

C)

Phi

lipp

ines

(P

ICC

S)

New

Zea

land

(N

ZIo

C)


PAM TechnologyAdhesion and Much More

SIPOMER® PAM-100 100 -18 <1 MEHQ/~5000 1.2 ● — ● ● ● — ● — ●


w High mono/di alkyl phosphate ratio and low residual acidw Improved latex stability

SIPOMER® PAM-200 100 0 <1 MEHQ/~5000 1.1 ● — ● ● ● — ● — —



SIPOMER® PAM-300 100 -40 <1 MEHQ/~5000 1.1 ● — ● — — — ● — —



SIPOMER® PAM-4000 100 ND <0.25 MEHQ/~400 1.2 ● ● ● ● ● — ● ● ●w Improved adhesion on metal substratew Improved latex stabilityw Improved gloss

SIPOMER® PAM 5000 100 NA 1.0 max none 1.25 ● — ● — — —Improved scrub resistance when formulated into vinyl binders for high PVC paints


SIPOMER ® COPS-1 40 NA 60 none 1.17 ● ● ● ● ● ● ● ● ●


SIPOMER® COPS-3* 25 NA 75 none — — — — — — ● — —Reactive co-stabilizer providing scrub/washability for high PVC coating formulation

SIPOMER ® AES-100 97 NA <2.0 none 1.0 ● — ● — — — — — —


SIPOMER ® AAE-10 99 NA <0.3 none — ● ● ● ● ● ● ● ● ●

Nonionic reactive co-stabilizer:w Low foaming latexesw Better latex stability at low surfactant dosagew Coatings with improved water and bleach resistance



Specialty Monomers / 17

* Asia - Latin America - MEA

* Remainder consists of acrylic acid (~20%) and higher adducts (~50%) ** Sipomer® BEM contains ~25% methacrylic acid *** Sipomer® SEM-25 contains ~20% methacrylic acid **** Sipomer® WAM II-25 contains ~25% methacrylic acid



S (T

SC

A)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

Chi

na

(JE

CS

C)

Phi

lipp

ines

(P

ICC

S)

New

Zea

land

(N

ZIo

C)


Resin Modifiers

SIPOMER® IBOA 100 94 <0.05 MEHQ/112 0.985 ● ● ● ● ● ● ● ● ●

High Tg hydrophobic monomer providing:w Improved chemical and water resistancew Better gloss and better mar resistancew An excellent radiation curable reactive diluent

SIPOMER® IBOMA 100 110 <0.05 MEHQ/108 0.983 ● ● ● ● ● ● ● ● ●

High Tg hydrophobic monomer providing:w Improved chemical and water resistancew Better gloss and better mar resistancew Lower viscosity in high solid solvent based resin systems

SIPOMER® B-CEA 30* 37 0.5 MEHQ/1000 1.2 ● ● ● ● ● ● ● ● ●

Low Tg acidic monomer:w Effective adhesion promoter for resins used in coatings

and adhesivesw Improved peel strength for adhesives

Rheology

SIPOMER® BEM 50** ND 25 MEHQ/1000 1.06 ● ● ● — ● — ● ● ● Specialty monomer design for low shear HASE polymer

SIPOMER® SEM-25 60*** ND 20 MEHQ/600 1.07 ● ● ● — — — ● — ●Specialty monomer design for mid to high shear HASE polymer

SIPOMER® HPM 100 50 ND 50 MEHQ/1000 1.06 ● ● ● ● ● — ● ● ● Specialty monomer design for mid shear HASE polymer

SIPOMER® HPM 200 50 ND 50 MEHQ/1000 1.06 ● ● ● ● — ● — ● — Specialty monomer design for newtonian HASE polymer

SIPOMER® HPM 400 50 ND 50 MEHQ/1000 1.06 ● ● ● — ● — ● ● ●Specialty monomer design for low to mid shear HASE polymer

Wet Adhesion

SIPOMER® WAM 90 NA 10 none 1.15 ● ● ● — — — — — ● Wet adhesion monomer for latex paints

SIPOMER® WAM II 50*** 87 30 HQ/1800 1.11 ● ● ● ● ● ● ● ● ● Wet adhesion monomer for latex paints

SIPOMER® WAM E W50 50 ND 50 TEMPO 250 and

HQ 750 ppm1.100 ● — — ● — ● ● — ● Wet adhesion monomer for paint applications


Specialty Monomers





S (T

SC

A)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

Chi

na

(JE

CS

C)

Phi

lipp

ines

(P

ICC

S)

New

Zea

land

(N

ZIo

C)


Resin Modifiers


High Tg hydrophobic monomer providing:w Improved chemical and water resistancew Better gloss and better mar resistancew An excellent radiation curable reactive diluent


High Tg hydrophobic monomer providing:w Improved chemical and water resistancew Better gloss and better mar resistancew Lower viscosity in high solid solvent based resin systems

SIPOMER® B-CEA 30* 37 0.5 MEHQ/1000 1.2 ● ● ● ● ● ● ● ● ●

Low Tg acidic monomer:w Effective adhesion promoter for resins used in coatings

and adhesivesw Improved peel strength for adhesives

Rheology


SIPOMER® SEM-25 60*** ND 20 MEHQ/600 1.07 ● ● ● — — — ● — ●Specialty monomer design for mid to high shear HASE polymer

SIPOMER® HPM 100 50 ND 50 MEHQ/1000 1.06 ● ● ● ● ● — ● ● ● Specialty monomer design for mid shear HASE polymer

SIPOMER® HPM 200 50 ND 50 MEHQ/1000 1.06 ● ● ● ● — ● — ● — Specialty monomer design for newtonian HASE polymer

SIPOMER® HPM 400 50 ND 50 MEHQ/1000 1.06 ● ● ● — ● — ● ● ●Specialty monomer design for low to mid shear HASE polymer

Wet Adhesion

SIPOMER® WAM 90 NA 10 none 1.15 ● ● ● — — — — — ● Wet adhesion monomer for latex paints


SIPOMER® WAM E W50 50 ND 50 TEMPO 250 and

HQ 750 ppm1.100 ● — — ● — ● ● — ● Wet adhesion monomer for paint applications

Specialty Monomers / 19

Product uses FDA Status International Inventory Status

Product Description AP

E F

ree

VO

C-F

ree

Co

ntai

ns

Sili

cone

Oil

Acr

ylic

Vin

yl

acry

lics,

VA

E

SB

R

175.

105

176.

170

176.

180

176.

200

176.

210

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

RHODOLINE® DF 540*Zero VOC white oil defoamer for in-process latex processing. BfR compliant

● ● Yes ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 635 Zero VOC oil defoamer for in-process foam control ● ● No ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 646Zero VOC oil defoamer for in-process vinyl and natural latex foam control

● ● Yes ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 670 Zero VOC oil defoamer for in-process vinyl latex processing ● ● No ● ● ● ● ● ● ● ● ● ● — ● ●

RHODOLINE® 990 Oil-free defoamer for latex systems, minimum impact on gloss ● ● No ● ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 999* Oil-free defoamer for latex systems, minimum impact on gloss ● ● No ● ● L L L L L ● ● ● — ● ●


*REACH Compliant

Rhodoline® Defoamers

Product uses FDA Status International Inventory Status

Product Description AP

E F

ree

VO

C-F

ree

Co

ntai

ns

Sili

cone

Oil

Acr

ylic

Vin

yl

acry

lics,

VA

E

SB

R

175.

105

176.

170

176.

180

176.

200

176.

210

US

(TS

CA

)

Can

ada

(DS

L)

Eur

op

e (E

INE

CS

)

Aus

tral

ia

(AIC

S)

So

uth

Ko

rea

(KE

CL)

Jap

an (M

IT)

RHODOLINE® DF 540*Zero VOC white oil defoamer for in-process latex processing. BfR compliant

● ● Yes ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 635 Zero VOC oil defoamer for in-process foam control ● ● No ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 646Zero VOC oil defoamer for in-process vinyl and natural latex foam control

● ● Yes ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 670 Zero VOC oil defoamer for in-process vinyl latex processing ● ● No ● ● ● ● ● ● ● ● ● ● — ● ●

RHODOLINE® 990 Oil-free defoamer for latex systems, minimum impact on gloss ● ● No ● ● ● ● ● ● ● ● ● ● ● ● ● ●

RHODOLINE® 999* Oil-free defoamer for latex systems, minimum impact on gloss ● ● No ● ● L L L L L ● ● ● — ● ●

Rhodoline® Defoamers / 21









The way we do businessSolvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent

upon the responsible way in which we conduct our current activities — a way that reflects our commitment to each of our

stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere

and the Economic Sphere.

Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self—assessments of their

practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable

value for all our stakeholders through innovation and partnership.










www.solvay.com



All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners.© 2012 Solvay Specialty Polymers USA, LLC. All rights reserved. N

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SIPOMER® Specialty MonomersFor enhanced performance

Novecare Coatings is a global leader in surfactant and specialty monomers committed to emulsion and specialty polymers. With over 40 years serving this industry, we have developed one of the most extensive portfolios of specialty monomers (SIPOMER®) dedicated to improve architectural, industrial coatings and adhesives.

Leveraging our portfolio of chemistries and local application expertise, we continue designing structures that will help you solve today’s challenges and define tomorrow’s standards.

Solvay Novecare Coatings

Novecare Coatings / 1

CONTENTS

Process / Adhesion / Surface Properties ...........................................................Page 4w SIPOMER® PAM 100w SIPOMER® PAM 200w SIPOMER® PAM 300w SIPOMER® PAM 4000w SIPOMER® PAM 5000

Polymerizable Stabilizers ....................................................................................Page 16w SIPOMER® COPS-1w SIPOMER® COPS-3w SIPOMER® AES-100w SIPOMER® AAE 10

Wet Adhesion, Alkyd / Wood Adhesion .............................................................Page 20w SIPOMER® WAMw SIPOMER® WAM IIw SIPOMER® WAM E W50

Resin Modifiers .....................................................................................................Page 28w SIPOMER® IBOMA • Hardness w SIPOMER® IBOA • Hardnessw SIPOMER® ß-CEA • Cohesive strength

Rheology ...............................................................................................................Page 29w SIPOMER® BEMw SIPOMER® SEM 25w SIPOMER® HPM series

Note: These products are produced at worldwide locations through through the Novecare division of Solvay.

2 / Specialty Monomers

SIPOMER® “So little delivers so much”

SIPOMER®s are very efficient. In most application, addition of 0.5 to 3% of these monomers deliver significant performance and bring functionality to your polymers.

By leveraging our diverse chemistry platforms, Solvay designs solutions adapted to both monomer systems and formulation performance. Whether your formulation is waterborne, solventborne or you seek support in transitioning towards waterborne, SIPOMER® will deliver in the following properties:

From Technology to Solutions

Process

Surface Properties

Adhesion

MechanicalProperties

• Clean EP Process • Improved mechanical,

thermal & salt stability • Limit foaming

• High Scrub• Gloss• Low water sensitivity• EZ Clean• Scratch resistance

• Wet Adhesion• Metal & Inorganic• Wood• Interaction with

Pigments

• Tg depletion• Tg Increase• Peel Strength

SIPOMER®s / 3


SIPOMER® PAM“Adhesion and Much More”

Performance Benefits w Improves binder

robustness w Adhesion to metal w Adhesion to inorganic

substratew Adhesion to glass w Scrub resistance w Color developmentw Gloss enhancement

Reactive Group

Nature of Extender

Application

SIPOMER® PAM 100 Methacrylate Hydrophilic Industrial

SIPOMER® PAM 200 Methacrylate Hydrophobic Industrial/

Architectural / Adhesive SIPOMER® PAM 300 Acrylate Hydrophobic UV/EB Cure

SIPOMER® PAM 4000 Methacrylate ~ Architectural

SIPOMER® PAM 5000 Allyl Ether Slightly

Hydrophilic Architectural

0.5% PAM200 control

After 2000 scrub cycles

Concrete Concrete

Applications 0.5 to 1 wt% PHM

00

0H

0H

PExtender

Phosphate group

Polymerizablegroup

SIPOMER® PAM / 5

Uses SIPOMER® PAMs are available in a variety of structures compatible with most coatings chemistries, technologies and applications.

Effective in Different Polymer Systems Effective on a Variety of Substrates

w Acrylic

w Styrene/acrylic

w VeoVa/acrylic

w Vinyl VeoVA

w Polyurethane (via acrylic polyols)

w Aluminium (plain and chromated)

w Cold rolled steel

w Zinc phosphated steel

w Iron phosphated steel

w Galvanized steel

w Stainless steel

w Glass

w Concrete


Technologies for different marketsSIPOMER® PAM in various resins by either emulsion or solution polymerization.

SIPOMER® PAM-100

SIPOMER® PAM-200

SIPOMER® PAM-300

SIPOMER® PAM-4000

SIPOMER® PAM-5000

EMULSION POLYMERIZATION

> You want to add the phosphate monomer with no other modification to an existing latex recipe.

SIPOMER® PAM-100 can be

addedto the monomer

feed in acidic form or to a separate

feed inneutralized form.

Due to its surfactantcy properties,SIPOMER®

PAM-200 may generate

problems such as secondarynucleation.

Due to its surfactantcy properties,SIPOMER®

PAM-300 may generate

problems such as secondarynucleation.

SIPOMER® PAM 4000 is perfectly suited to be used in monomer mix

SIPOMER® PAM 5000 is perfectly suited to be used in monomer mix

> You want to minimize or or eliminate the primary surfactant.

*reduce the total amount of

surfactant needed* cannot be

used as a primary surfactant.

Reduce drastically the use

of surfactant or may be used as

the sole surfactant in emulsion

polymerization.

Reduce drastically the use

of surfactant or may be used as

the sole surfactant in emulsion

polymerization.


surfactant needed*cannot be



surfactant needed*cannot be


> You want to stabilize a pre-emulsion without any conventional surfactant.

Not Surface active

SIPOMER® PAM-200 may be

used as a sole emulsifer

to stabilizepre-emulsion.

SIPOMER® PAM-300 may be

used as a sole emulsifer

to stabilizepre-emulsion.

Not Surface active Not Surface active

SOLUTION POLYMERIZATION

> Water solubleSIPOMER®

PAM-100 is morehydrophilic and totally solublein water when neutralized.

Due to poor solubility in water,using SIPOMER®

PAM-200 maylead to micellar polymerization.

Due to poor solubility in water,using SIPOMER®

PAM 300 maylead to micellar polymerization.

Water Soluble Water Soluble

> Solventborne (Polyacrylate Polyols…)

SIPOMER® PAM-100 can be

used tomake resins but

might havecompatibility

issues with somepolymers.

SIPOMER® PAM-200

is soluble ina broad range of

monomersand solvents.

SIPOMER® PAM-300 is soluble in

a broad range of monomers and solvents and

suitable for UV/EB applications.

UV/EB Cure

UV/EB cure

The acrylic functionality of

SIPOMER® PAM-300 provides

a higher reactivity in

radiation cure application

n Best n Possible n Not suitable


ALUMINUM

IMMERSION HOURS DRY 2 4Control 1B 0B 0B1% PAM 3-4B 0B 0B

4% PAM 5B 0B 0B

COLD-ROLLED STEEL

IMMERSION HOURS DRY 2 4 8 24 48Control 5B 4-5B 2B 0B 0B 0B

1% PAM 5B 2B 2B 1B 0B 0B

4% PAM 5B 5B 5B 5B 4-5B 4-5B

Adhesion is evaluated according to ASTM D3359 test: OB poor adhesion - 5B perfect adhesion.

Example: Car Refinish: More cars coated with fewer problemsDirect-to-metal substrates represent a significant field for innovation yielding process simplification and environmentally friendly solutions such as: w Direct-to-metal priming that consolidates a complex process into one step w Shift from solventborne to waterborne resin systems

Standard primers for car refinishing are based on 2K polyurethanesolventborne resin systems. Either SIPOMER® PAM-100 or SIPOMER® PAM-200, based on the formulation and technology used, will be effective in improving metal adhesion of such systems.

Adhesion Data in 2K Polyurethane Solventborne Systems SIPOMER® PAM-200 can significantly improve the dry and wet adhesion on both aluminum and cold-rolled steel. SIPOMER® PAM is used to make acrylic polyols.

Thanks to their superior MAP/DAP ratio, SIPOMER® PAM-100 and SIPOMER® PAM-200 are easily incorporated into polyurethane systems with minimum impact on viscosity. SIPOMER® PAM 200 can be used in polyurethane waterborne systems where it provides improved adhesion with system and stabilization features.

SIPOMER® PAM / 7

Example: Coil Coating: Improved efficiency and environmentally friendlyCoil coating is a continuous and highly automated process whereas the metal coil is unwound and both the top and bottom sides are cleaned, chemically treated, primed, oven cured, top coated, oven cured again, and rewound for shipment. Thanks to this process, large coils can be coated at high speed before fabrication. Resins incorporating SIPOMER® PAMs will boost primer adhesion and anti-corrosion properties eliminating the need for pre-treatment step(s) translating into less waste, energy & process time.

Top coat

Primer

Pre-treatment

Metal

Top coat

Treating Primer

Metal

Standard Removal of Pre-treatment

100% 89%100%

75%

50%

25%

0

Coil-Coating Cost ($)

Standard System Removal of Pre-treatment

Benefits :w Process savings: one step vs.

two steps

w Eliminate waste treatment and reporting/regulation requirements Linked to the use of heavy metals such as chrome and phosphorous.


Automotive Refinish: Direct-to-Metal (DTM) BenefitsReady-to-apply top coat with DTM primer in 30 minutes instead of 12 hours with standard systems

Clear coat

Top coat

Primer

Pre-treatment

Metal

Clear coat

Top coat

Treating Primer

Metal

lateM ot tceriDmetsyS dradnatS

100% 92%100%

75%

50%

25%

0

Coating Cost ($)

Standard System Direct to Metal


Example: Maintenance Coatings: An environmental solution that works!Organic coatings play an important role in corrosion protection. One of the key challenges to convert solventborne systems to more sustainable, water-based formulation resides in significant loss in adhesion and anticorrosion performances.

Thanks to it’s excellence in metal adhesion, SIPOMER® PAM-200 boosts the performance of acrylic waterborne resins enabling matching performance versus solventborne anticorrosion coatings, allowing low VOC coatings formulations and consumers who are demanding new products that meet or exceed the requirements for lower VOC coatings.

Good Adhesion ResultsSIPOMER® PAM-200 was used to modify a waterborne styrene/acrylic resin. An anticorrosion paint was formulated and tested for adhesion and corrosion-resistance properties. Compared with a control paint formulated without SIPOMER® PAM-200, the results are below:

Good Anti-Corrosion Results

PAINT-BASED ON S/ALATEX WITH 1%

PAINT-BASED ON S/ACONTROL LATEX S/A: Styrene/Acrylic

Adhesion is evaluated

according to ASTM D3359test: 0B poor adhesion –

5B perfect adhesion.Adhesion is evaluated

after 24 hours and after 520 hours of

immersion in water.

CROSSHATCH RESULTSAFTER WATER IMMERSION

CROSSHATCH RESULTSAFTER WATER IMMERSION

24 hrs 520 hrs 24 hrs 520 hrs

> Cold-rolled steel 5B 5B 4B 2B

> Iron phosphate steel 5B 5B 1B 1B

> Zinc phosphate steel 3B 3B 0B 0B

SIPOMER® PAM / 9

Special-Purpose Coatings: Improved performance and efficiencyThis segment includes coatings for various metal substrates mainly applied by Original Equipment Manufacturers. This market ranges from coatings forlarge vehicles, such as trucks, farm tractors and cranes to house appliances. Different technologies compete in this market with the objective of a single, multipurpose coating applied directly to metal. The result is elimination of pre-treatment and fewer steps in the process!

Either SIPOMER® PAM-100 or SIPOMER® PAM-200, based on the formulation and technology used, can boost acrylic resin performances in terms of adhesion and corrosion resistance and offer a viable solution for directto-metal applications.

Good results without pre-treated substrateSIPOMER® PAM-100 was used to modify a waterborne styrene/acrylic resin. The resin was formulated in a clearcoat and tested for adhesion on untreated, coldrolled steel. Wet adhesion was evaluated under differenttest conditions:

ConclusionsSIPOMER® PAM-100 and SIPOMER® PAM-200 specialty monomers enable process simplification and cost savings for the industrial coatings market. Whether your application is automotive refinishing, coil coatings,maintenance or special purpose coatings, the benefits of using the SIPOMER® PAMs include:

w Elimination of costly metal pre-treatment step

w Reduction of layers in the coating system

w Cost saving of labor required for the coating application

w A shift from heavy metals-based conversion coatings to organic

w A shift from solventborne to waterborne systems

Top coat

Primer

Pre-treatment

Metal

Single coat Directto Metal

Metal

lateM ot tceriD taoc elgniSmetsyS dradnatSStandard System Single coat Direct to Metal

100% 84%100%

75%

50%

25%

0

Coating Cost ($)

w Water-spots testw Immersion testw After 24 hours recovery

Anticorrosion is evaluated according to ASTM D3359OB: poor adhesion 5B: perfect adhesion

Control 2% PAM-1004-hour spot test 0B (0%) 4B (95%)4-hour immersion test 0B (0%) 3B (92%)24-hour recovery test 0B (0%) 5B (100%)



BLANK SIPOMER® PAM 4000

Cross-hatched Tape Adhesion Test - Cold Steel

SIPOMER® PAM-4000 – Metal Adhesion PromoterMonomer Ratio (BOTM)

MMA 51.5BA 46.5

MAA 1SIPOMER® PAM-4000 1

Surfactant Charge (BOTM)Rhodapex

RS-610 A250.5 in Kettle

1.0 in Pre-emulsion

Initiator System:Thermal, Ammonium Persulfate

Seed:20% Initiator Solution / 4%

Pre-Emulsion

Particle Size :126 nm

Latex Stability : Freeze/Thaw Stability - 5+ cycles

Heat Stability (60C) - 30+ days

SIPOMER® PAM / 11

High Scrub for high PVC binders in Architectural coatings with SIPOMER® PAM-5000

Matte Paint Application DataScrub Resistance Results (PVC = 82)

Latex Property Results

Improve Scrub Resistance in High PVC Paints

SIPOMER® PAM-5000 – Styrene/Acrylic Starting Point Recipe

Benchmark SIPOMER® PAM 5000

Particle size (nm) 119 126Solids content (%) 50.30% 50.10%Grit / 120mesh (ppm) 92 22Coagulum Clean CleanViscosity @ 20 rpms (mPa) 548 494Viscosity @ 50 rpms (mPa) 386 252

Scrub Resistance Measurement Benchmark 1 % SIPOMER® PAM 5000

ISO test first serial (µ) 36 17DIN scrub resistance (cycles) 1050 4000

Monomer Ratio (BOTM)Styrene 49.5BA 47.5AA 2SIPOMER® PAM-5000 1.0 (in Kettle Charge)

Surfactant Charge (BOTM)

Rhodapex® LA-40S 0.1 in Kettle Charge0.9 in Pre-emulsion

Rhodafac® RS-610A25 1.0 in Pre-emulsion Initiator System: Thermal, Ammonium PersulfateSeed: 20% Initiator Solution / 4% Pre-Emulsion Particle Size: 120 nmLatex Stability: 5 cycles of Freeze/Thaw Stability

Number of cyclesDIN scrub resistance at 85 % PVC

High PVC Vinyl VeoVA paint formulation

IngredientsParts per

weigh

Initial Reactor Charge

Demineralised waterRhodafac® RS 710-E (10%aq. Sol. At pH 7-8)Potassium persulphate

39925

1

Pre-emulsion

Demineralised waterRhodafac® RS 710-E (10%aq. Sol. At pH 7-8) Sodium bicarbonate Vinyl VeoVA*2-Ethylhexyl acrylateSIPOMER® COPS-1 (40% aq. Sol.)Acrylic acidVinyl acetate SIPOMER® PAM 5000 (30% aq. Sol. At pH 5)Silquest A 171

39345

3200709.4

1.573033.2

2.5

Initiator solution

Demineralised waterPotassium persulphate

1201

Other

Line oneDemineralised waterTer-butyl hydroperoxyde (70% aq. Sol.)

201.4

Line two Demineralised water Bruggolite FF6M

201.2

Neutralisation AMP 95 until pH of 8-8.5 8.3

Biocide Parmetol K40 2



Number of cyclesDIN scrub resistance at 85 % PVC

High PVC Vinyl VeoVA paint formulation

IngredientsParts per

weigh

Initial Reactor Charge

Demineralised waterRhodafac® RS 710-E (10%aq. Sol. At pH 7-8)Potassium persulphate

39925

1

Pre-emulsion

Demineralised waterRhodafac® RS 710-E (10%aq. Sol. At pH 7-8) Sodium bicarbonate Vinyl VeoVA*2-Ethylhexyl acrylateSIPOMER® COPS-1 (40% aq. Sol.)Acrylic acidVinyl acetate SIPOMER® PAM 5000 (30% aq. Sol. At pH 5)Silquest A 171

39345

3200709.4

1.573033.2

2.5

Initiator solution

Demineralised waterPotassium persulphate

1201

Other

Line oneDemineralised waterTer-butyl hydroperoxyde (70% aq. Sol.)

201.4

Line two Demineralised water Bruggolite FF6M

201.2

Neutralisation AMP 95 until pH of 8-8.5 8.3

Biocide Parmetol K40 2

General Guidance for use of SIPOMER® PAM Monomers

DO DON’T

> Storage –Feedings tanksDo use stainless steel or plastic

containers to store solutionsof SIPOMER® PAM.

Don’t use iron containers that can be corroded by acidic SIPOMER®

PAM releasing metal ions that could trigger the polymerization.

> High reactivity

Do follow the order of introductionof our starting recipes. Put SIPOMER®

PAM in the kettle when the reaction temperature is met. Do feed separately or

in the monomer mixture/pre-emulsion.

Don’t introduce SIPOMER® PAM in the initial charge before heating.

Don’t mix with the solution of the initiator. This would rapidly

polymerize even without heating.

> Heat stability of polymer

Do neutralize the polymer beforeheating at elevated temperature

( > 140° C).

Copolymers are more stable and canbe handled above 200° C. This is

strongly dependent on the nature ofthe polymer and must be checked

case by case.

Don’t heat acidic homopolymers to temperatures above 140° C.

> Hydrolytic stabilityDo keep between pH = 5 and pH = 9for long time storage or when using

at temperatures above 60° C.

Don’t use diluted SIPOMER® PAM very acidic (pH < 3) or basic (pH >

10) conditions. This would hydrolyze the ester linkage and

the phosphate group.

> Corrosion

Do neutralize with a non volatile baseand add corrosion inhibitor. Keep the

coating at pH > 9 for good anticorrosion properties.

Don’t use SIPOMER® PAM in acidic form when post neutralization is

not possible.

SIPOMER® PAM / 13

SIPOMER® COPS-1 is a 40% aqueous solution of sodium1-allyloxy-2-hydroylpropyl sulfonate:

CH2 = CH - CH2 - O - CH2 - CH(OH) - CH2 - SO3Na

Even at levels as low as 0.5 - 1.0% (based on total monomer), SIPOMER® COPS-1 provides latex stability, such as shelf life, freeze/thaw and mechanical and chemical stability. It also provides block resistance for the final polymer.

With SIPOMER® COPS-1, the levels of conventional can be reduced significantly. Surfactants are key component in providing stability to latex.

However their migration to the interface causes water sensitivity to the dry polymer film.

SIPOMER® COPS-1 reacts with other reacts with other comonomers through the chemical (covalent) bond. The sulfonate group will remain at the surface of the particle providing very good stability to the latex. Since the functionality is anchored to the polymer backbone, it will not migrate after film formation and thus cannot modify interfacial properties. As a result of the reduction of conventional surfactant, the foaming tendency of the latex and the water sensitivity of the polymer film are both reduced.

Stabilizers Key Featuresw Improve mechanical stabilityw Improve thermal stabilityw Improve salt stabilityw Decrease need in surfactantw Reduce foaming & water sensitivity

Applicationsw Use 0.5 Wt% based on total

monomer (BOTM)

w All acrylic, styrene acrylic, vinyl acrylic, vinyl VeoVA

Covalent Bound

Reactive Group Nature of Extender « Head » groupSIPOMER® COPS Allyl ether Hydrophobic Sodium Sulfonate

SIPOMER® AAE10 Allyl ether Hydrophilic Ethoxylate

SIPOMER® AES-100 Allyl ether Hydrophilic Ammonium Sulfate

SIPOMER® Polymerizable Stabilizer


The reactivity ratio data show that the r1 values for SIPOMER® COPS-1 are close to 0, suggesting that homopolymerization of this monomer is unlikely. There is no need for adding an inhibitor to this monomer. As shown on the Mayo representation below, the most favorable reactivity ratios were found for SIPOMER® COPS-1 with vinyl acetate and VeoVA 10. However, SIPOMER®

COPS-1 can also work very effectively in acrylic and styrene/acrylic systems.

Reactivity Ratio Data for SIPOMER® COPS-1 (M1)

Mayo Curves for SIPOMER® COPS-1

SIPOMER® COPS-1Polymerizable Stabilizer

SIPOMER® Polymerizable Stabilizer / 15


SIPOMER® COPS-1Polymerizable StabilizerAddition of SIPOMER® COPS-1

SIPOMER® COPS-1 improves Freeze/Thaw Stability

SIPOMER® COPS-1 improves mechanical stability

Latexes Acrylic control Acrylic with COPS-1 Styrene/acrylic control

Styrene/acrylic with COPS-1

Surfactant % BOTM Rhodacal® DS41

Rhodacal® DS41

Rhodapex® LA40S1.5

Rhodapex® LA40S1.5

SIPOMER® COPS-1% BOTM 0 0.5 0 0.5

Particle size (nm) Solids (%)

17.949.8

18649.9

17551.1

14951.1

Freeze thaw cycles 0 5 0 5

Latexes Acrylic control Acrylic with SIPOMER® COPS-1

Surfactant % BOTM

Rhodacal® DS41

Rhodacal® DS41

SIPOMER® COPS-1% BOTM 0 0.5

Particle size (nm) Solids (%)

17949.8

18649.9

Waring blender5 minutes at 20,000 rpm

Failed Passed

Rhodacal DS4: Sodium dodecylbenzene sulfonate (23%)Rhodapex LA40S: Sodium dodecyl ether sulfate; 4 EO (32%)

Freeze/thaw testProcedure: Latex was placed in -15C conditions for 12 hours and thawed back to RT for 8 hours. Cycles were repeated 5 times.

Mechanical test procedure:Pour 200 mL of latex into a Waring blender. Mix latex at 20,000 rpm under high shear for5 minutes. If the latex does not completely coagulate after 5 minutes of mixing, it “passes.”If it coagulates within 5 minutes of mixing, it fails.


SIPOMER® COPS-1 improves chemical stability

Substitution of surfactant by SIPOMER® COPS-1 in a latex formulation

Latexes AcrylicControl 1

AcrylicControl 2

Acrylic withSIPOMER®

COPS-1

Acrylic with nonionic surfactant

Anionic surfactantRhodapex® LA40S

(%BOTM)1.0 1.5 1.0 1.5

Nonionic surfactant (% BOTM) 0 0 0 1.0

SIPOMER® COPS-1 (% BOTM) 0 0 0.5 0

% CaCl2 added to latex for immediate

coagulation3 6 5 5

Latexes Acrylic control Acrylic with SIPOMER® COPS-1

Surfactant % BOTM

Rhodacal® DS41.0

Rhodacal® DS40.5

SIPOMER® COPS-1 Particle size (nm)

0179

0.5196

Solids (%) Wet coagulum (%

BOTL)

49.80.7

50.60.7

Freeze/Thaw cycles Mechanical stability

1Passed

5Passed

Foaming height (mL) 200 120

Latex Chemical Stability:The ability of latex to resist coagulation in the presence of salts. (Salt used is Calcium chloride)Procedure:Add CaCl2 at different levels to the latex until immediate coagulation is observed.The data above should be read as follows:CaCl2 was added (in term of weight % compared to total latex -% BOTL):«3%» means that the system was stable at 2% of CaCl2«6%» means that the system was stable at 5% of CaCl2Comments:By adding COPS-1, the chemical stability results are improved. To have the same effect in terms of chemical stability, normally non ionic surfactant is used. COPS-1 improves chemical stability without increasing the amount of free surfactant.

Mechanical test procedure:Pour 200 mL of latex into a Waring blender. Mix latex at 20,000 rpm under high shear for5 minutes. If the latex does not completely coagulate after 5 minutes of mixing, it “passes.”If it coagulates within 5 minutes of mixing, it fails.

Features:w Good pigment binding powerw High PVC paints system w Anti-corrosion propertiesw Improved color acceptancew Good stain and block resistancew Improve adhesion to different

inorganic substratew Applicable to most of monomers

systems: SA, FA, VA, VeoVA, etc.

Improve Water-Resistance & Corrosion Inhibition50wt% SA latex: 1% of Rhodapex® LA 40S; 0.5% of BOTM COPS-3

COPS-3 in Vinyl VeoVA Systemw 55% Vinyl VeoVA System: VAM/VeoVA-10:70:30w 1% BOTM of COPS-3w 0.3% BOTM of RS610-A25 & 2% BOTM of Rhodasurf® 6530

SIPOMER® COPS-3

Product Specifications

Appearance Transparent liquidActive content 39.0-42.0Color APHA 200 MaxpH (10% aqueous solution) 6.0 - 9.0Ionic type Anionic

Without COPS-3 With COPS-3

• Glass substrate: 100 um film• Soaking into water for 24 hrs

Without COPS-3 With COPS-3

• Substrate: Iron phosphate panel Curing @ room temperature, 60-70% RH

Commercial SA WithoutCOPS-3 COPS-3

Particle size (nm) ~150 262.2 238.7

75 PVC paints

Scrub resistance 550 405 1168

SIPOMER® COPS-3Polymerizable Stabilizer


*Only available in China

Key Benefits w Reduce Gritw Increase stability

(mechanical, FT, chemical )

SIPOMER® AES-100

LatexMMA 52BA 47

MAA 1

SurfactantType Rhodapex® LA40S

Amount in Kettle: 0.10%Amount in Feed: 0.90%

Amount of AES-100 0% 1% 1%

Way of Addition of AES-100 Feed Kettle

Dry Grit 130 ppm 10 ppm 70 ppm

Mechanical Stability 3' 9' 9'

F/T stability 0 > 5 > 5

Calcium Stability 2% 5% 6%

Particle Size: 150 nm

In situ-seeded pre-emulsion

Dry Grit: Filtration on 100 micron net

Mechanical Stability: Waring Blender 22.000 rpm ( time to coagulation )

Calcium Stability: CaCl2*2H2O/Dry latex ratio ( concentration to coagulate a 30 % diluted latex )

SIPOMER® AES 100Copolymerizable Stabilizer


Superior wet-adhesion propertiesSIPOMER® WAM was custom designed to combine the benefits of amine and ureido functionalities in a single monomer. The Table below shows the synergistic effects of this combination.

SIPOMER® WAM is incorporated into all-acrylic and vinyl-acrylic polymer systems through its allylic functionality. It provides wet adhesion in two ways:

w The ureido ring promotes interaction with the substrate via its high polarity and hydrogen bonding.

w The amine functionality provides an additional site for interaction with substrate and pigment.

SIPOMER® WAM modifies the latex binder, enabling it to wet the pigment particles more effectively, due to reduced interfacial tension.

SIPOMER® WAMWet Adhesion Monomers

Effects of Amine and Ureido Functionalities, Alone and In Combination

SIPOMER® WAM into the polymer backbone greatly improves wet-adhesion of both all-acrylic and vinyl-acrylic latex paint systems for both interior and exterior applications.

“The 1% that makes the difference” Reactive Group Binders

SIPOMER® WAM Allyl Ether Both acrylic & vinyl copolymers

SIPOMER® WAM II Methacrylamide Acrylics

SIPOMER® WAM E W50 Methacrylate Ester Acrylics


Lab tests demonstrate exceptional wet adhesionTest after test has proven that all-acrylic and vinyl-acrylic polymers containing SIPOMER® WAM provide latex paints with the best and most cost-effective wet-adhesion properties available. In a Wet Pick Adhesion Test, latex with SIPOMER® WAM showed greater wet adhesion as indicated by the substantially smaller area of peeling. And in a Wet Adhesion Abrasion Test, the latex paint containing SIPOMER® WAM demonstrated outstanding wet-scrub performance.

SIPOMER® WAM-based paints compared to commercial productsAs shown in the Table below, polymers containing SIPOMER® WAM were evaluated against commercial wet adhesion systems. Paints based on SIPOMER® WAM exhibited superior wet-adhesion properties as well as greater shelf stability and improved color stability. When effective use levels were measured, SIPOMER® WAM also proved to be the most cost-effective wet-adhesion promoting system available.

Results of Wet Pick Adhesion Test

Results of Abrasion Test

Gardner Scrub Test Results with SIPOMER® WAM-Based Paints Versus Commercial Standards

Control Control

SIPOMER® WAM / 21

Innovative chemical structureWith SIPOMER® WAM II, emulsion polymerization producers can formulate products with an easy-to-use wet-adhesion monomer which is effectively polymerized in both redox and thermal processes.

MAEEU

SIPOMER® WAM II in Latex Blends

The MAEEU advantage is its ability to easily copolymerize in all-acrylic, vinyl-acrylic and styreneacrylic latex systems.

SIPOMER® WAM II provides enhanced wet-adhesion, wet-scrub resistance and solvent resistance in a wide range of latex systems. SIPOMER® WAM Il’s improved performance is the result of MAEEU (methacrylamidoethyl-ethyleneurea), an advanced ureido-based adhesion promoting monomer.

SIPOMER® WAM IIWet Adhesion Monomer


Similar results with SIPOMER® WAM II in semi-gloss paintWhen all-acrylic latexes containing SIPOMER® WAM II were formulated into a semi-gloss paint at 23% PVC, improved wet-scrub resistance was demonstrated. The paint formulated without SIPOMER® WAM II began lifting from the substrate at 95 cycles. The paint formulated with SIPOMER® WAM II exhibited outstanding scrub resistance, completely covering the substrate after 2000 cycles.

Dramatically improved wet-scrub resistance

Wet-Scrub Resistance Test

SIPOMER® WAM II / 23


SIPOMER® WAM Ester Wet Adhesion MonomersSIPOMER® WAM E Technologiesw Wet adhesion monomers for emulsion polymerization • Based on N-(2-Methacryloyloxyethyl) ethylene urea chemistry • Typical usage levels between 0.5 and 2.0 BOTM

w Primarily recommended for waterborne acrylic and styrene acrylic binder systems

• Improve wet adhesion • Improve scrub resistance

w Also used in polymerizations and co-polymerizations in bulk, suspension and solution with polymers for use in plastics, leather, paper and textile industries

Typical Properties

w Methacrylate polymerizable groupw Ureido ring functionality for wet adhesionw Choice of activity and diluents

SIPOMER® WAM Esterw SIPOMER® WAM E W50

50 % Active in Water

Features:w Excellent wet adhesion

improvement

w Significant scrub resistance improvement

w Readily incorporated into most polymer systems

w Excellent binder conversion rate

ON

O

NH

O

Property SIPOMER® WAM E W50Appearance Yellowish Liquid

Gardner Color 5 max

Solids, % 48 – 52

Viscosity, cPs 50 max

Density at 25 ºC, g/mL 1.00 – 1.20

MMA, % 2.0 max

SIPOMER® WAM Ester / 25

Application Testingw Evaluated SIPOMER® WAM E W 50 & WAM E MMA 50 products

in all-acrylic latex binder system

w Paint application test were conducted in a semi gloss all-acrylic paint system

w Tested for wet adhesion, scrub, gloss, viscosity, stability and all other paint properties


SIPOMER® WAM Ester Wet Adhesion Monomers

Emulsion Polymerization ResultsBinder Property No WAM Added SIPOMER® WAM E W50Seed Particle Size, nm 37 36pH before neutralization 2.2 1.9pH after neutralization 9.2 9.3Solids, % 49.7 49.8Conversion, % 100 100Dried coagulum, % 0.05 0.03Resin Viscosity, cPs 123 125Resin Particle Size, nm 133 126

All-Acrylic Emulsion Polymerization Formula

Materials BOTMMonomersMMA* 52

BA 46

MAA 1

Wet Adhesion Monomer** 1

Surfactant – Rhodacal DS-4 1

Kettle 0.15

Monomer Emulsion 1.25

Initiator System (2 % in water) Thermal

Ammonium Persulfate

Seed2% Monomer

Emulsion

25 % Initiator Solution

Temperature during Monomer Addition 80 ºC

Monomer Addition 3 h

Post-Monomer Addition Temperature 85 ºC

Property TargetResin Solids 50%

Seed Particle Size 40 max

Final Particle Size 130 nm

pH 9.0 – 9.5

Dried Coagulum, % 0.25 max

Resin Viscosity, cPs < 500

SIPOMER® WAM Ester / 27

Paint Test Results

S/G Acrylic Paint Test Formula

Property Blank SIPOMER® WAM E W50Viscosity, ON, KU 95.4 96.3Viscosity, ON, ICI 0.84 1.13Gloss, 20/60/85 º 13.3/50.9/78.7 11.4/47.6/76.4Contrast Ratio 97.3 97.9Scrub Test*# cycles to breakthrough 500 4752Wet Adhesion Test** 100 % 497 %

Materials PARTSGRINDWater 6.0Propylene Glycol 2.0Rhodoline® 111 1.0Rhodoline® 681F 0.2Rhodoline® WA 100 0.2Ti-Pure R-826 27.0LETDOWNLatex 40.0Rhodoline® 681F 0.1Texanol 2.0Acrysol RM-8W 0.5Acrysol 2020 NPR 0.4Water 20.6

Property TargetGloss 45 - 55

PVC 25

KU Viscosity 95 - 97

ICI Viscosity 0.8 – 1.3

* Scrub test results on vinyl scrub panel** Wet adhesion Scrub Test ASTM D6900-10

SIPOMER® IBOARadiation curing resins application w Improves toughness, chemical and abrasion resistancew Reactive Diluentw Radcure polymerizable

SIPOMER® IBOMAClear coat applicationw Improves toughness, chemical and abrasion resistance w Easily incorporated in resins (methacrylate)

SIPOMER® ß-CEA Adhesives applicationw Lowers Tg w Improves adhesion

“Improved peel strength”100% Acrylic Pressure Sensitive Adhesive

0

3

6

9

12

15

0% B - CEA

6.010.0

8.513.0

0.5 % B-CEA

■ After 3 min, adhesion■ After 1 hr. adhesion

Peel

str

engt

h (N

/25m

m)

180° horizontal peel test

SIPOMER® Resin Modifiers


By combining its experience in specialty monomers and emulsion polymerization, Solvay extended the available range of specialty methacrylic esters monomer for HASE thickeners.

SIPOMER® BEM – SIPOMER® SEM – SIPOMER® HPM series Rheology

SIPOMER® BEM SIPOMER® BEM delivers low shear efficiency.

SIPOMER® HPM 400 SIPOMER® HPM 400 delivers low to mid shear efficiency. SIPOMER® HPM 400 allows to easily match cellulosic thickeners profiles.

SIPOMER® HPM-100 SIPOMER® HPM 100 delivers mid shear efficiency.

SIPOMER® SEM 25 SIPOMER® SEM 25 delivers mid to high shear efficiency.

SIPOMER® HPM 200 SIPOMER® HPM 200 delivers high shear efficiency. SIPOMER® HPM 200 allows to easily match Newtonian thickeners profiles.

Solvay SIPOMER® HPMs are 50 Wt% active specialty methacrylic monomers designed to easily access desired rheology profiles. Working with SIPOMER® HPMs provides choice in profile and significant cost saving versus “generic” HASE.

PropertiesSolvay SIPOMER® HPMs were incorporated in standard HASE polymer recipes and benchmarked versus well known “generic” HASE at equal viscosity (95KU) in 30 Wt% solid latex (table 1) as well as at equal use level in flat paints (table 2). While the HPM 200 based thickener presents a very performant solution as Newtonian ICI builder, the HPM 100 based HASE combines KU building and improved ICI viscosity. Whereas cellulosic replacement is targeted, HPM 400 based system offers matching profile with higher efficiency.

Table 1: All paint latex system were adjusted to 95 (±2) KU stormer viscosity

Active HASE Wt% Brookfield (cP) ICI (P)HPM 200 based hase - A 1.87 1400 2.55Benchmark 1 3.17 1350 2.25HPM 100 based hase - B 0.56 6800 0.6Benchmark 2 0.57 4600 0.5HPM 400 based hase - C 0.42 7600 0.25Benchmark 3 0.36 7200 0.22HEC 0.76 7600 0.25

HPM 400 based HASE Benchmark 3 HPM 100

based HASE Benchmark 2 HPM 200 based HASE Benchmark 1

Usage ( Wt% Active) 0.5 0.5 0.5 0.5 1.6 1.6Equilibrium Stormer Viscosity (KU) 78.6 83.5 100.6 94.6 100.3 113.4Equilibrium ICI (P) 0.7 0.6 1 1 2.05 1.5Gloss, 20° / 60° / 85° 1.3/2.4/5.9 1.3/2.3/5.5 1.3/2.4/6.1 1.3/2.5/7.1 1.3/2.6/7.8 1.3/2.5/7.0

Used as KU builders Used as ICI builders

PSEUDOPLASTIC

NEWTONIAN

Table 2: SIPOMER® HPMs based HASE bench marked at equal use level in a flat paint formula

Rheology / 29


Trade name % of Solid Tg (°C) %

WaterInhibitor

ppmSpecific gravity

US (TSCA)

Canada (DSL)

Europe+

(EINECS)Australia

(AICS)

South Korea (KECL)

Japan (MIT)

China (JECSC)

Philippines (PICCS)

New Zealand (NZIoC)


Adhesion and Much More

SIPOMER® PAM-100 100 -18 <1 MEHQ/~5000 1.2 ● — ● ● ● — ● — ●— Improved adhesion on metal, glass, and other inorganic substrates— High mono/di alkyl phosphate ratio and low resididual acid— Improved latex stability

SIPOMER® PAM-200 100 0 <1 MEHQ/~5000 1.1 ● — ● ● ● — ● — —

— Improved adhesion on metal, glass, and other inorganic substrates— Excellent compatibility with most common organic systems— High mono/di alkyl phosphate ratio and low resididual acid— Improved anti-corrosion properties

SIPOMER® PAM-300 100 -40 <1 MEHQ/~5000 1.1 ● — ● — — — ● — —

— Improved adhesion on metal, glass, and other inorganic substrates— Excellent compatibility with most common organic systems— High mono/di alkyl phosphate ratio and low resididual acid— Improved anti-corrosion properties— Polymerizable surfactant

SIPOMER® PAM-4000 100 ND <0.25 MEHQ/~400 1.2 ● ● ● ● ● — ● ● ●— Improved adhesion on metal substrate— Improved latex stability— Improved gloss

SIPOMER® PAM 5000 100 NA 1.0 max none 1.25 ● — ● — — — Improved scrub resistance when formulated into vinyl binders for high PVC paints


SIPOMER® COPS-1 — NA 60 none 1.17 ● ● ● ● ● ● ● ● ●

Reactive co-stabilizer providing:— Low foaming latexes— Better latex stability at low surfactant dosage— Coatings with improved water and bleach resistance

SIPOMER® COPS-3* 25 NA 75 none — — — — — — ● — — Reactive co-stabilizer providing scrub/washability for high PVC coating formulation

SIPOMER® AES-100 97 NA <2.0 none 1.0 ● — ● — — — — — —


SIPOMER® AAE-10 99 NA <0.3 none — ● ● ● ● ● ● ● ● ●

Non ionic reactive co-stabilizer— Low foaming latexes— Better latex stability at low surfactant dosage— Coatings with improved water and bleach resistance

Resin Modifiers


High Tg hydrophobic monomer providing:—Improved chemical and water resistance— Better gloss and better mar resistance— An excellent radiation curable reactive diluent


High Tg hydrophobic monomer providing:— Improved chemical and water resistance— Better gloss and better mar resistance— Lower viscosity in high solid solvent based resin systems

SIPOMER® B-CEA 30* 37 0.5 MEHQ/1000 1.2 ● ● ● ● ● ● ● ● ●Low Tg acidic monomer:— Effective adhesion promoter for resins used in coatings and adhesives— Improved peel strength for adhesives

SIPOMER® Product Performance

* Asia - Latin America - MEA * Remainder consists of acrylic acid (~20%) and higher adducts (~50%) ** SIPOMER® BEM contains ~25% methacrylic acid *** SIPOMER® SEM-25 contains ~20% methacrylic acid **** SIPOMER® WAM II-25 contains ~25% methacrylic acid

+ Availability is based on REACH status ND – not determinedNA – not applicable




WaterInhibitor

ppmSpecific gravity

US (TSCA)

Canada (DSL)

Europe+

(EINECS)Australia

(AICS)

South Korea (KECL)

Japan (MIT)

China (JECSC)

Philippines (PICCS)

New Zealand (NZIoC)


Adhesion and Much More

SIPOMER® PAM-100 100 -18 <1 MEHQ/~5000 1.2 ● — ● ● ● — ● — ●— Improved adhesion on metal, glass, and other inorganic substrates— High mono/di alkyl phosphate ratio and low resididual acid— Improved latex stability

SIPOMER® PAM-200 100 0 <1 MEHQ/~5000 1.1 ● — ● ● ● — ● — —

— Improved adhesion on metal, glass, and other inorganic substrates— Excellent compatibility with most common organic systems— High mono/di alkyl phosphate ratio and low resididual acid— Improved anti-corrosion properties

SIPOMER® PAM-300 100 -40 <1 MEHQ/~5000 1.1 ● — ● — — — ● — —

— Improved adhesion on metal, glass, and other inorganic substrates— Excellent compatibility with most common organic systems— High mono/di alkyl phosphate ratio and low resididual acid— Improved anti-corrosion properties— Polymerizable surfactant

SIPOMER® PAM-4000 100 ND <0.25 MEHQ/~400 1.2 ● ● ● ● ● — ● ● ●— Improved adhesion on metal substrate— Improved latex stability— Improved gloss

SIPOMER® PAM 5000 100 NA 1.0 max none 1.25 ● — ● — — — Improved scrub resistance when formulated into vinyl binders for high PVC paints


SIPOMER® COPS-1 — NA 60 none 1.17 ● ● ● ● ● ● ● ● ●


SIPOMER® COPS-3* 25 NA 75 none — — — — — — ● — — Reactive co-stabilizer providing scrub/washability for high PVC coating formulation

SIPOMER® AES-100 97 NA <2.0 none 1.0 ● — ● — — — — — —


SIPOMER® AAE-10 99 NA <0.3 none — ● ● ● ● ● ● ● ● ●

Non ionic reactive co-stabilizer— Low foaming latexes— Better latex stability at low surfactant dosage— Coatings with improved water and bleach resistance

Resin Modifiers


High Tg hydrophobic monomer providing:—Improved chemical and water resistance— Better gloss and better mar resistance— An excellent radiation curable reactive diluent


High Tg hydrophobic monomer providing:— Improved chemical and water resistance— Better gloss and better mar resistance— Lower viscosity in high solid solvent based resin systems

SIPOMER® B-CEA 30* 37 0.5 MEHQ/1000 1.2 ● ● ● ● ● ● ● ● ●Low Tg acidic monomer:— Effective adhesion promoter for resins used in coatings and adhesives— Improved peel strength for adhesives

International Inventory Status Codes● Listed — Not Listed

SIPOMER® Product Performance / 31

Recommended product formulations



Water Inhibitor ppm Specific gravity

US (TSCA)

Canada (DSL)

Europe+ (EINECS)

Aus-tralia

(AICS)

South Korea (KECL)

Japan (MIT)

China (JECSC)

Philippines (PICCS)

New Zealand (NZIoC)


Rheology


SIPOMER® SEM-25 60*** ND 20 MEHQ/600 1.07 ● ● ● — — — ● — ● Specialty monomer design for mid to high shear HASE polymer

SIPOMER® HPM 100 50 ND 50 MEHQ/1000 1.06 ● ● ● ● ● — Specialty monomer design for mid shear HASE polymer

SIPOMER® HPM 200 50 ND 50 MEHQ/1000 1.06 ● ● ● ● — ● Specialty monomer design for newtonian HASE polymer

SIPOMER® HPM 400 50 ND 50 MEHQ/1000 1.06 ● ● ● — ● — Specialty monomer design for low to mid shear HASE polymer

Wet Adhesion

SIPOMER® WAM 90 10 none 1.15 ● ● ● — — — — — ● Wet adhesion monomer for latex paints


SIPOMER® WAM E W50 50 ND 50 TEMPO 250 and HQ 750 ppm 1.100 ● — — ● — ● ● — ● Wet adhesion monomer for latex paints

SIPOMER® Product Performance continued

* Asia - Latin America - MEA * Remainder consists of acrylic acid (~20%) and higher adducts (~50%) ** SIPOMER® BEM contains ~25% methacrylic acid *** SIPOMER® SEM-25 contains ~20% methacrylic acid **** SIPOMER® WAM II-25 contains ~25% methacrylic acid

+ Availability is based on REACH status


ND – not determined

>SIPOMER® COPS-1

>SIPOMER® PAM-100

>SIPOMER® PAM-200

>SIPOMER® WAM

>SIPOMER® WAM-II

For technical data sheets and other products, visit our website:www.solvay.com



Water Inhibitor ppm Specific gravity

US (TSCA)

Canada (DSL)

Europe+ (EINECS)

Aus-tralia

(AICS)

South Korea (KECL)

Japan (MIT)

China (JECSC)

Philippines (PICCS)

New Zealand (NZIoC)


Rheology


SIPOMER® SEM-25 60*** ND 20 MEHQ/600 1.07 ● ● ● — — — ● — ● Specialty monomer design for mid to high shear HASE polymer

SIPOMER® HPM 100 50 ND 50 MEHQ/1000 1.06 ● ● ● ● ● — Specialty monomer design for mid shear HASE polymer

SIPOMER® HPM 200 50 ND 50 MEHQ/1000 1.06 ● ● ● ● — ● Specialty monomer design for newtonian HASE polymer

SIPOMER® HPM 400 50 ND 50 MEHQ/1000 1.06 ● ● ● — ● — Specialty monomer design for low to mid shear HASE polymer

Wet Adhesion

SIPOMER® WAM 90 10 none 1.15 ● ● ● — — — — — ● Wet adhesion monomer for latex paints


SIPOMER® WAM E W50 50 ND 50 TEMPO 250 and HQ 750 ppm 1.100 ● — — ● — ● ● — ● Wet adhesion monomer for latex paints

International Inventory Status Codes● Listed — Not Listed

SIPOMER® Product Performance / 33


Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self—assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership.










www.solvay.com



All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners.© 2012 Solvay Specialty Polymers USA, LLC. All rights reserved. N

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Color Solutions

Committed to your Coatings Success

Applicationsw Flat to high gloss architectural paintsw Pigment slurriesw Grind or letdownw Excellent co-dispersantw Stabilizing agentsw Wetting agents

Key featuresw Improved wetting of pigments w Improved color acceptance/developmentw Better general dispersion stabilityw Improved resistance to color floatingw Enhanced glossw Excellent wettingw Improved adhesionw Better corrosion inhibition w Improved water resistancew No impact on other paint properties

Control Rhodoline® 4188

Semi-Gloss Acrylic Paint Formulation

www.solvay.comNorth America

Phone: + 1-800-973-7873 Europe, Middle East, AfricaPhone: +33 01 53 56 50 00

Asia PacificPhone: +65 62 91 19 21

Latin AmericaPhone: +55 11 3747-7637 www.solvay.com

w

Rhodoline® 4188 Specialty Additive for Improved Color Stability

Rhodoline® 3000/4000 Series

Dispersants for Pigment

Concentrates

Color Solutions

INNOVATIVE SOLUTIONS FOR AN INCREASINGLY DEMANDING MARKETSolvay, a world leader in the development and production of specialty chemicals, supplies performance additives for a variety of paint and coatings pplications.

To meet market demands, Solvay’s global technical support network provides customers with custom-made solutions, and develops formulations adapted to theirneeds and requirements for the paint and coatings industry.

These are surface-active solutions and functional monomers for the production of polymers in emulsion, meeting performance and sustainability requirements, such as zero VOC, biodegradability and low ecotoxicity. Solvay coatings also provides paint additives solutions, providing benefits in formulation and application.

Solvay shares its best practices throughout its world-class manufacturing operations in North America, Latin America, Europe and the Asia Pacific region and benefits from technology transfer to create innovative materials focused on next-generation technologies for the paint and coatings market.

The Solvay Group is committed in sustainably recreating the chemical industry, focusing on innovation and operational excellence

DISPERSANT MECHANISM

Wetting: Liquid that replaces air on the surface of the pigment particle by reducing the interfacial tension

Dispersant: Product that maintains fine solid particles in a suspended state and inhibits aggregation or sedimentation in a liquid medium

Stabilization: Prevents re-agglomeration by electrostatic and/or steric repulsion

Electrostatic Stabilisation

Steric Stabilisation

PIGMENT STABILIZATIONChallenges:

• Maintain storage stability of pigment concentrates over longer time periods

• Compatibility of these pigment concentrates with different coating systems after enduring longer storage time

• Color acceptance/development in tinted systems

Performance:

• Anchoring of dispersant over the pigment’s surface

- Improved compatibility

- Improved color acceptance

- Preventing flocculation and sedimentation

Pigment Properties: Inorganic vs. Organic

Property Inorganic Organic

Solubility Generally insoluble Slightly soluble

Tint strength Low High

Hiding power High, opaque Low, more transparent

Ease of dispersion Fairly easy to disperse Difficult

Specific gravity High Low

Heat resistance High Low

Weathering Excellent Poor

Brightness (Intensity) Low High

The Rhodoline® 3000 and Rhodoline® 4000 lines are high efficiency dispersants for water-based pigments concentrates, without VOCs and alkylphenols.

RHODOLINE® 3000 SERIES

ATTRIBUTES High performance with less dispersant

Exceptional color strength development

Exceptional color acceptance upon tinting

Improved stability

APE and VOC free

Product Active % HLB Recommendation Dosage

Rhodoline® 3100 85 11 - 13Workhorse dispersant for low to medium HLB organic pigments including medium grade carbon black and lampblack pigments.

5 - 30% of the pigment weight.

Rhodoline® 3200 90 8 - 11 Dispersant for low HLB organic pigment including toluidine red, yellow and other organic pigments.

Rhodoline® 3500 70 > 16High HLB organic pigment wetting and dispersant agent. Works great with organic pigments as well as industrial grade carbon black pigments.

Rhodoline® 3700 97 -High HLB pigment wetting and dispersant agent. Works great with high surface area pigments such as conductive carbon blacks.

Colour Index Rhodoline®% of additive on the

pigment total

PR 112 3100 8 - 15%

PY 74 3100 11 - 15%

PBK 7 3500 15 - 30%

PB 15:0 3500 15 - 20%

PB 15:1 3500 20 - 30%

PG 7 3500 15 - 25%

PO 5 3500 8 - 15%

RHODOLINE® 4000 SERIES

Product Ion Nature Active % Recommendation Dosage

Rhodoline® 4100 Anionic 100Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents.

0.1 - 0.5% (active) as paint wetting agent; 1 - 2% (active) as pigment wetting; 5 - 20% (active) based on total pigment weight as dispersant for concentrates.

Rhodoline® 4160Anionic

(ammonium salt)25

Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents.


(potassium salt)25



(ammonium salt)87



Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self-assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership.


> The UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, working conditions, respect for the environment and anti-corruption. (2003)


> Solvay Novecare has achieved world wide ISO-9001 Quality Management System

Multi-Site Certification. (2008)

North AmericaSolvay Novecare – 504 Carnegie Center – Princeton, NJ 08540 – USAPhone: +1-800-973-7873 – Fax: +1-609-860-0463 – [email protected]

EuropeSolvay Novecare – 40, rue de la Haie-Coq – F-93306 Aubervilliers Cedex – FrancePhone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 – [email protected]

Asia PacificSolvay Novecare – 1, Biopolis Drive – #05-01/06 AMNIOS – Singapore 138 622Phone: +65 - 6291 1921 – Fax: +65 - 6394 3376 – [email protected]

Latin AmericaSolvay Novecare – Centro Empresarial – Avenida Maria Coelho Aguiar, 215, Bloco B-1º AndarCep: 05804-902 – São Paulo-SP BrazilPhone: +55 11 3747-7637 – Fax: +55 11 3741-8378 – [email protected]

www.solvay.com

While the information herein is believed to be reliable, we do not guarantee its accuracy. Customers (direct and indirect) are urged to make their own tests withproducts described herein. Various patents owned by Solvay or others may be pertinent to their use and to compositions containing them. Nothing containedherein is intended as a recommendation to use our products so as to infringe any patent. We assume no liability for any intellectual property rights violation bycustomers (direct or indirect). Customers (direct and indirect) should make their own patent investigation related to the freedom to operate for any specific intendeduse. If a relevant patent is identified, customers (direct and indirect) should secure a license from the patent owner. Customers (direct and indirect) should evaluatethe products to determine notably their strength, performance and safety. All applicable laws and regulations should be consulted. All the names mentioned areregistered trademarks of Solvay, its subsidiaries or affiliates.

AEROSOL® Surfactants Specialty Additives

AEROSOL Surfactants Chemical Name Type & Form

(approx. conc.)

Solubility (as is)

Biodegradability

Flash Point °F/°C

(Pensky Martens

Closed Cup)

Water @ 25°C g

(as is) /100ml

Organic Solvent

Diester Sulfosuccinates

TR-70Sodium bistridecyl

sulfosuccinateAnionic 70% solution in

ethanol and water0.1 Very Soluble

Not readily Biodegradable2

77 / 25

TR-70 HGSodium bistridecyl

sulfosuccinateAnionic 70% solution in

hexylene glycol and water0.1 Very Soluble


>212 / >100

TR-60 ISodium bistridecyl

sulfosuccinateAnionic 60% solution in isopropanol and water

0.1 Very SolubleNot readily

Biodegradable291 / 33

OT-75Sodium dioctyl sulfosuccinate

Anionic 75% solution in ethanol and water

2.0 Very SolubleReadily


OT-75 E OPVSodium dioctyl sulfosuccinate




GPGSodium dioctyl sulfosuccinate




OT-70 PGSodium dioctyl sulfosuccinate

Anionic 70% solution in propylene glycol and water


Biodegradable1>212 / >100

OT-70 PG OPVSodium dioctyl sulfosuccinate



Biodegradable1>212 / >100

OT-75 PGSodium dioctyl sulfosuccinate



Biodegradable#>212 / >100

OT-100Sodium dioctyl sulfosuccinate

Anionic 100% waxy solid 1.5 Very SolubleReadily

Biodegradable1Not Applicable

OT-BSodium dioctyl sulfosuccinate

Anionic 85% powder in 15% sodium benzoate

1.0 Partially SolubleReadily

Biodegradable1Not Applicable

OT-A (ND)Sodium dioctyl sulfosuccinate

Anionic 70% solution in Solvesso 150****

— Very SolubleReadily


OT-SSodium dioctyl sulfosuccinate

Anionic 70% solution in light petroleum distillate



OT-SE ULASodium dioctyl sulfosuccinate

Anionic 70% solution in light petroleum distillate


Biodegradable#169 / 76

OT-85 AEProprietary

sulfosuccinate blendAnionic 85% solution

in water2.0 Very Soluble

Readily Biodegradable1

>212 / >100

AEROSOL® Surfactants

* AEROSOL 22N is the European version of this product ** KRUSS -K12 *** Calcium Tolerance at 0.05% for AEROSOL TR products

and 0.25% for AEROSOL WA-300

**** Aromatic Solvent from ExxonMethods for assessment of biodegradation: 1: 301A DOC (dis-solved organic carbon) die-away test2: 301B Modified Sturm test

3: 301D Closed Bottle test 4: 301E Modified OECD screening5: 302B: Zahn Wellens Inherent #: Based on evaluation of components

Surface Tension in

Water (min. mN/m)**

Ca Tolerance

ppm CaCO3 at 0.5%

CMC %/wt** Features & Benefits

27 <60*** 0.001Extremely hydrophobic surfactant with excellent solubility in organic media, as well as very low critical micelle concentration and equilibrium surface tension. High oil solubility and limited water solubility. Imparts some surface water resistance in coatings and films.

27 <60*** 0.001High flash point analogue of AEROSOL TR-70 in hexylene glycol and water. Same features and benefits as AEROSOL TR-70.

27 <60*** 0.001 General purpose grade of AEROSOL TR-70, commonly used in ePVC polymerizations.

26 540 0.12

Excellent wetting, rewetting and levelling agent. Also good emulsifying and dispersing properties. Has very low dynamic surface tension, and migrates to interfaces very rapidly. Used to reduce surface tension and to increase absorbency and penetration. AEROSOL OT also has some antistatic and softening properties.

26 540 0.12 Low DEHM (Diethylhexyl maleate) content specifically for over print varnish (OPV) applications.

26 540 0.12 General purpose grade of AEROSOL OT.

26 540 0.12High flash point analogue of AEROSOL OT-75 in propylene glycol and water. Same features and benefits as AEROSOL OT-75.

26 540 0.12 Low DEHM (Diethylhexyl maleate) content specifically for OPV applications.

26 540 0.12 Higher solids version of AEROSOL OT-70 PG.

26 540 0.12Solid version of AEROSOL OT. For use when no water can be tolerated. Same features and benefits as AEROSOL OT-75.

26 540 0.12 Powder version of AEROSOL OT that is easier to handle than the AEROSOL OT-100.

28 540 0.12Solution of AEROSOL OT in an aromatic solvent. Same features and benefits as AEROSOL OT-75. Suitable for organic, oil based systems that can not tolerate water. Used in Agrochemical formulations.

26 540 0.12Solution of AEROSOL OT in high purity petroleum distillate. Superior detergent for oily stains. Used in organic, oil based systems. Higher flash point grade used in oil spill dispersants.

26 540 0.12Solution of AEROSOL OT in high purity petroleum distillate. Superior detergent for oily stains. Used in organic, oil based systems. Higher flash point grade used in oil spill dispersants. Food grade product approved for paper chemicals.

29 >2250 0.02Low VOC and high solids version of AEROSOL OT. Same features and benefits as AEROSOL OT-75. Allows a lower coalescing agent requirement in formulations.

N.B. Not all products may be offered for sale in all regions. Please check with your local Sales Manager. N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe.



(approx. conc.)

Solubility (as is)

Biodegradability

Flash Point °F/°C

(Pensky Martens

Closed Cup)

Water @ 25°C g

(as is) /100mlOrganic Solvent

Diester Sulfosuccinates (continued)

OT-NVProprietary

sulfosuccinate blendAnionic 85% solution

in water2.5 Very Soluble

Readily Biodegradable#

>212 / >100

LF-4Proprietary

sulfosuccinate blendAnionic 80% solution in isopropanol and water

10 SolubleNot readily

Biodegradable3

110 / 43

WA-300Proprietary

sulfosuccinate blendAnionic 75% solution in

propylene glycol and water2.5 Soluble


>212 / >100

MA-80Sodium dihexyl sulfosuccinate



Biodegradable4

97 / 36

MA-80 ISodium dihexyl sulfosuccinate

Anionic 80% solution in isopropanol and water


Biodegradable4

101 / 38

A-196 40Sodium dicyclohexyl

sulfosuccinateAnionic 40% solution

in water25 Soluble warm


>212 / >100

A-196 97Sodium dicyclohexyl

sulfosuccinateAnionic 97%

flaky solid10 Soluble warm


Not Applicable

AY-65Sodium diamyl sulfosuccinate


62 InsolubleReadily

Biodegradable#

77 / 25

AY-100Sodium diamyl sulfosuccinate

Anionic 100% waxy solid

40 SolubleReadily

Biodegradable#

Not Applicable

IB-45Sodium diisobutyl

sulfosuccinateAnionic 45% solution

in waterInfinite Insoluble


>212 / >100

Alkylamine-Guanidine Ethoxylate

C-61Alkylamine-guanidine

polyoxyethanol

Cationic 70% viscous solution in isopropanol, ethylene

glycol and water

Forms Dispersions

Soluble in the presence of alcohol


85 / 29

Methods for assessment of biodegradation:1: 301A DOC (dissolved

organic carbon) die-away test

2: 301B Modified Sturm test 3: 301D Closed Bottle test 4: 301E Modified OECD

screening

5: 302B: Zahn Wellens Inherent#: Based on evaluation of

components

* AEROSOL 22N is the European version of this product** KRUSS -K12*** Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300**** Aromatic Solvent from Exxon


Surface Tension in

Water (min. mN/m)**

Ca Tolerance

ppm CaCO3 at 0.5%


29 >1000 0.02Low VOC and high solids version of AEROSOL OT. Same features and benefits as AEROSOL OT-75.

24 >2250 0.02Wetting, dispersing, levelling, and emulsifying agent specially designed for applications requiring good dynamic wetting with low and unstable foam generation.

24 500*** 0.02Excellent wetting agent designed for use in the production of pressure sensitive adhesives (PSA). Product is functional at low concentrations and has a high flash point.

28 700 1.5Good dynamic wetting properties with unstable foam generation. Emulsifying, dispersing and solubilizing agent. High electrolyte stability.

28 700 1.5Good dynamic wetting properties with unstable foam generation. Emulsifying, dispersing and solubilizing agent. High electrolyte stability.

38 >2250 3.0Imparts high surface tension, high filler loading capacity, good mechanical stability and reduced water sensitivity. Excellent low foaming surfactant. Produces dispersions with excellent electrolyticstability. Liquid at approximately 40°C.

38 >2250 3.0 Flaky solid form of AEROSOL A-196 40 with same features and benefits.

30 >1125 1.8Wetting and dispersing agent for hydrophilic systems. Imparts good electrolytic and mechanical stability. It has a high tolerance for electrolytes.

30 >1125 1.8Solid version of AEROSOL AY-65 used in water free systems. Same features and benefits as AEROSOL AY-65.

30 >2250 3.5Very hydrophilic surfactant which is an extremely efficient wetting agent in high concentrations of electrolytes. Imparts good electrolytic and mechanical stability and reasonably high surface tension.

40 >2250 0.05Combines cationic and non-ionic features. Good wetting, dispersing and flushing agent.Allows anionic systems to be compatible with cationic systems. Excellent acid and alkali stability.



(approx. conc.)

Solubility (as is)

Biodegradability

Flash Point °F/°C

(Pensky Martens

Closed Cup)

Water @ 25°C g

(as is) /100ml

Organic Solvent

Mono-ester Sulfosuccinates

EF-800Proprietary sulfosuccinate

compositionAnionic 50% solution


Inherently Biodegradable5

>212 / >100

EF-810Proprietary sulfosuccinate



Inherently Biodegradable5

>212 / >100

A-102Disodium ethoxylated alcohol half ester of Sulfosuccinic acid

Anionic 31% solution in water

InfiniteSparingly

soluble in polar solvents


>212 / >100

A-103Disodium ethoxylated

nonyl phenol half ester of Sulfosuccinic acid


InfinitePartially soluble in polar solvents


>212 / >100

501Proprietary sulfosuccinate




>212 / >100

Sulfosuccinamates

18PDisodium N-octadecyl

sulfosuccinamateAnionic 30% semi-paste

in water18 at 40°C Insoluble


195 / 91

22 / 22N*Tetra sodium N-(1,2

dicarboxy ethyl)- N-octadecyl sulfosuccinamate

Anionic 35% solution in water with ethanol/ methanol residuals

Infinite InsolubleNot readily

Biodegradable#

129 / 54156 / 70

22 SpecialTetra sodium N-(1,2 dicarboxy

ethyl)- N-octadec(en)yl sulfosuccinamate



Biodegradable#

129 / 54

Nonyl Phenol Ether Sulfates

NPES-458Ammonium salt of sulfated

nonylphenoxy poly (ethyleneoxy) ethanol


InfinitePartially soluble

Not readily Biodegradable 83 / 28

NPES-930 P

Ammonium salt of sulfated nonylphenoxy poly

(ethyleneoxy) ethanol



Biodegradable#

>212 / >100

Alkyl Naphthalene Sulfonate

OSSodium diisopropyl

naphthalene sulfonateAnionic 75% powder in

odium sulfate>20

Partially soluble

Not readily Biodegradable#

Not Applicable

Methods for assessment of biodegradation:1: 301A DOC (dissolved

organic carbon) die-away test

2: 301B Modified Sturm test 3: 301D Closed Bottle test 4: 301E Modified OECD

screening

5: 302B: Zahn Wellens Inherent#: Based on evaluation of

components

* AEROSOL 22N is the European version of this product** KRUSS -K12*** Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300**** Aromatic Solvent from Exxon


Surface Tension in

Water (min. mN/m)**

Ca Tolerance

ppm CaCO3 at 0.5%


31 >2250 0.03Versatile, APE free, primary or sole emulsifier enabling easy design of new latexes while meeting regulatory requirements. Can reduce the number of raw material required, simplifying formulations. Also highly effective, functioning at low concentrations. High tolerance for water-sensitive monomers.

31 >2250 0.03

Versatile, APE free primary or sole emulsifier. Highly effective, functions at low concentrations, making it extremely cost effective. The product imparts outstanding pre-emulsion stability, giving robust reaction kinetics, high conversions and minimizes final latex grit and coagulum in emulsion polymerization reactions. High tolerance for water-sensitive monomers.

29 >2250 0.1

Excellent APE free primary emulsifier for acrylic, styrene acrylic, vinyl acrylic and EVA latexes. Imparts both steric and charge stabilization giving systems with very good electrolytic and mechanical stability. Excellent acid stability and low surface and interfacial tension values make it a useful stabilizer/dispersant in a variety of aqueous systems. Good tolerance for cationic surfactants and polyvalent cations. Non-dermatitic.

34 >2250 0.01

Excellent primary emulsifier for acrylic, styrene acrylic and vinyl acrylic latexes especially high gloss systems. Imparts both steric and charge stabilization giving systems with very good electrolytic and mechanical stability. Outstanding compatibility with divalent and trivalent cations as well as quaternary ammonium surfactants. Non-dermatitic.

28 >2250 0.03 Emulsifier for generation of small particle size acrylic latexes. Also dispersing and wetting agent.

40 102 0.06Emulsifying, dispersing, and foaming agent exhibiting good stability in acid and alkali solutions. Also has excellent lubricating properties.

36 200 0.04Surfactant combining high hydrophilic and hydrophobic moieties with excellent acid and alkali compatibility. Emulsifier, dispersant and hydrotrope solubilizer. Non-dermatitic.

36 200 0.04 Same as for AEROSOL 22 but can have some additional grafting properties.

30 >2250 0.02 High foaming surfactant, also used as an emulsifier.

31 >2250 0.02 Emulsifier which is effective at low usage levels.

35 >2250 1.0Stable wetting and dispersing agent in relatively high concentrations of acid or alkali. Highly effective in the manufacture of wettable powders.

Commercial Uses

AEROSOL Surfactants Emulsion Polymer Applications Other Applications


TR-70

TR-70 HG

Used as an emulsifier in acrylic, styrene acrylic and vinyl systems. In vinyl systems it modifies surface active properties which can make the finished film water resistant. It has an excellent synergy with primary emulsifiers to generate and stabilize fine latex dispersions as well as improving pre-emulsion stability in all acrylic and styrene acrylic systems.

Highly hydrophobic wetting agent. Dispersing agent for resins, pigments, polymers and dyes in organic systems. Particularly effective in flushing pigments from aqueous press cakes to solvent media. Used for the preparation of printing inks, rust inhibitors and anti-misting coatings. Dispersing dyes and pigments into plastics.

TR-60 I

A version of AEROSOL TR designed specifically for VCM polymerization. Due to its hydrophobic nature it stabilizes the VCM droplet very well. Offering the opportunity to generate bimodal and high solid latexes by allowing secondary nucleation. Polymer can be easily recovered.

–

OT-75

Used in a wide variety of emulsion and suspension polymerizations as a primary or co-emulsifier. It can produce latexes with low levels of coagulum, very low particle size and narrow distribution. As a post additive it lowers surface ten-sion, improving flow and levelling characteristics.

Wetting and levelling agent for a wide range of industries: inks and OPVs, paint, adhesives, textile, paper, petroleum, rubber, metal, agricultural, mining, detergent compounding. Additionally used as dewatering aid and mould-release agent.

OT-75 E OPV

–Specifically for OPV applications, ultra low levels of diethyl hexyl maleate (DEHM).

GPG –Used by a variety of industries as a wetting agent, e.g. in fire fighting foams, dust control, lubricants and coolants, degreasing, dry cleaning, cleaning solutions for glass etc.

OT-70 PG A high flash point version of AEROSOL OTSame uses as for AEROSOL OT-75 but when a higher flash point is required. Compatible in paint formulations. Used in oil spill dispersants.

OT-70 PG OPV

–Specifically for OPV applications, ultra low levels of diethyl hexyl maleate (DEHM).

OT-75 PG A high flash point version of AEROSOL OTSame uses as for AEROSOL OT-75 but when a higher flash point is required. Compatible in paint formulations. Used in oil spill dispersants.

OT-100 –

Used in solvent and non-aqueous systems. Mould release for poly methyl methacrylate (PMMA). Used in inks, photographic products, dyes, textile, leather, scintillation fluid, agrochemical applications and fibre production. Wetting agent and antistat for polyethylene manufacture. Dispersing aid for dyes and pigments in plastics such as polyethylene and polypropylene.

OT-B –Used in agrochemicals for wettable powders and water dispersible granules.

N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe


Diester Sulfosuccinates (continued)

OT-A (ND) –Used in agrochemical formulations, where it wets out active ingredients aiding their spread on to and penetration of the plant structure.

OT-S

OT-SE

–

Very compatible and effective as a wetting/solubilizing/ dispersing agent in a wide variety of organic/hydrocarbon/ oil-based systems. Designed for instant solubility in all organic systems, such as rust inhibitors, degreasers, lubricants, dry cleaning solvents, pre-wash spot removers. Also used as a wetting and dispersing agent in plastics, lacquers and varnishes. Used in oil spill dispersants. Wetting and antistat agent for polyethylene manufacture.

OT-85 AE

OT-NV

Primary or co-emulsifier for a wide variety of latex types for effective small particle generation at low usage levels.

Used in low VOC systems as a wetting agent, emulsifier and dispersant. Low surface tension and rapid dynamic wetting for a range of applications including printing inks, OPVs, paint, coatings, textiles and all types of cleaning formulations.

LF-4

Co-emulsifier to enhance wetting properties of a dispersion with limited foam generation. Produces low surface tension latexes for adhesives, paints, floor polishes, printing inks, etc. Reduces or eliminates the need for post-addition of wetting agents to latexes.

Post addition wetting agent for OPVs, printing inks, paints, textile, paper, adhesives and coating applications. Gives excellent wetting and low foam. Also gives improved adhesion, gloss and color resolution.

WA-300Co-emulsifier providing enhanced stability and wetting properties of latex. Also reduces the need for non-ionic co-surfactants.

Post addition wetting and levelling agent for PSA applications.

MA-80

MA-80 I

Effective in all monomer systems. Yields complete conversion, coagulum-free latexes with good mechanical stability. Imparts good adhesion on porous substrates. Polymer can be easily recovered. Also reduces the need for non-ionic co-surfactants.

Wetting agent for OPVs, PSAs, paints, inks, textiles, battery separators, strong electrolyte solutions, electroplating, leaching operations, etc.

A-196 40

A-196 97

Emulsifier for modified styrene-butadiene and styrene-acrylic latexes. Unsurpassed for manufacturing styrene butadiene latexes. Imparts excellent water resistance and adhesion. Produces high surface tension latexes with good mechanical stability and high filler loading capacity. Imparts good adhesion of deposited film to its substrate.

Excellent low foaming surfactant. Produces dispersions with excellent electrolytic stability.

AY-65

AY-100

Surfactant for emulsion polymerization systems, especially where polymer recovery is desirable.

Extremely effective wetting agent in concentrated salt solutions. Used in electroplating as a wetting and dispersing agent. Additive for agricultural chemical applications. Effective dispersant for hydrophilic resins and pigments. Very effective wetting agent for leather coatings.

IB-45Used in emulsion polymerization and stabilization of styrene, styrene butadiene and other styrene based systems. Imparts high surface tension and good mechanical stability to latexes.

Extremely stable in concentrated electrolyte solutions for leaching, wetting, electroplating and dispersion applications. Highly hydrophilic surfactant.

Commercial Uses


Alkylamine-Guanidine Ethoxylate

C-61 –

Cationic dispersing and fixing agent for pigments, dyes and fillers. Emulsifying agent used alone or with AEROSOL OT. Used in the manufacturing of glass fiber matting. Softening agent for textiles. Used in acid or alkali cleaning formulations.

Mono-ester Sulfosuccinates

EF-800

APE free primary or sole emulsifier for acrylic, vinyl acrylic, styrene acrylic and styrene butadiene latex systems. High tolerance for water-sensitive monomers facilitates easy development of high performance systems. Yields high solids/low viscosity latexes, enabling solids > 60% in final latexes. Yields excellent mechanical, electrolytic and freeze/thaw stability, low coagulum and grit, hence increasing operational efficiencies. Produces latex films with high optical clarity and excellent heat stability.

APE free surfactant for variety of industries providing excellent emulsification, low surface tension and good stability.

EF-810

APE free primary or sole emulsifier for acrylic, vinyl acrylic, styrene acrylic and styrene butadiene latex systems. High tolerance for water-sensitive monomers facilitates easy development of high performance systems. Yields high solids/low viscosity latexes, enabling solids >60% in final latexes. Excellent pre-emulsion stability giving increased manufacturing flexibility. Also produces latexes with excellent mechanical, electrolytic and freeze/thaw stability, low coagulum and grit hence increasing operational efficiencies. Produces latex films with high optical clarity and excellent heat stability.

APE free surfactant for variety of industries providing excellent emulsification, low surface tension and good stability.

A-102

APE free primary emulsifier for acrylic, vinyl acrylic, styrene acrylic and EVA latexes. Can be used with N-methylolacrylamide without modifying performance requirements. Generates small to intermediate particle size emulsions, effective as a post stabilizer. Provides good adhesion in combination with AEROSOL MA-80 and 22. Gives low-coagulum levels, clear film formation and resistance to yellowing on heating. Films also have good water resistance.

Surfactant or foaming agent for personal care and cleaning applications, suitable for use in shampoos, bath and shower gels as well as germicidal cleaners. Additionally used in foaming cement, wallboard and adhesives. Also a good solubilizer and dispersant for medium HLB resin systems and other aqueous systems.

A-103

Used in emulsion polymerization as either the sole or primary emulsifier for the preparation of high gloss vinyl acetate and acrylic latexes. Produces small particle size emulsions with good film clarity as well as mechanical stability. Can be used with AEROSOL’s 22, MA-80 and A-102 to modify particle size. Gives good water resistance of the latex film and is resistant to yellowing on heating. Effective as a post-additive stabilizer.

Surfactant or foaming agent for personal care and cleaning applications, suitable for use in shampoos, bath and shower gels as well as germicidal cleaners. Additionally used in foaming cement, wallboard and adhesives. Also a good solubilizer and dispersant for medium HLB resin systems.

501

Used in emulsion polymerization of acrylic systems especially at low surfactant concentrations. High tolerance for water soluble monomers. Yields high solids/low viscosity latexes with freeze/thaw stability, mechanical stability and high optical clarity.

Provides low surface tension and good stability in printing ink, textile and paper applications. Used in the production of fire fighting foams.

N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe


Sulfosuccinamates

18P

Imparts excellent rheological properties to pigmented latexes. Used in emulsion and suspension polymerizations. Foaming agent for latexes especially in carpet backing and textile applications.

Used as a foaming agent in foamed insulation, carpet backing, cement, wallboard and resins. Excellent stability in acid and alkali solutions, therefore also used in cleaning formulations and lubricants.

22/22N

Imparts small particle size for all latexes except vinyl acetate. In combination with AEROSOL’s MA-80 or A-102 produces highly stable high solids latexes. Excellent as a post-additive for mechanical stabilization, especially in paint applications giving high water resistance. Imparts excellent rheological properties in pigmented latexes.

Excellent pigment dispersant. Used in agrochemical formulations, industrial, household and metal cleaners. Excellent solubilizing agent for soaps and other surfactants in soluble salt solutions. Excellent lime soap dispersant.

22 SpecialSame as for AEROSOL 22 but can have some additional grafting properties.

–

Nonyl Phenol Ether Sulfates

NPES-458Emulsion polymerization of vinyl acetate, acrylic and styrene acrylic systems giving very small particle size emulsions.

Used in textile scouring agents and detergents. Also used in iodine based germicidal cleaners.

NPES-930 P

Produces very fine particle size vinyl acetate, acrylic and styrene acrylic latexes with low levels of coagulum and good mechanical stability. Latexes also have good freeze/thaw stability. Superior emulsifier for Zn cross-linking latexes for floor finishes. Extremely low surfactant levels needed that result in superior water resistance and high optical clarity.

Used in detergents and rosin dispersions.

Alkyl Naphthalene Sulfonate

OSSurfactant for emulsion polymerization and additive for latexes.

Dispersant for pigments and dyes in paints and plastics. Used in agrochemical wettable and dispersible powders. Used in metal cleaning, bottle washing, paint strippers, brick and tile cleaning, pickling, acid etching agents and hard surface cleaners due to its excellent acid and alkali stability.

Cytec Solvay Group5 Garret Mountain PlazaWoodland Park, NJ [email protected]: +1.973.357.3100Fax: +1.973.357.3100

Disclaimer: Cytec Industries Inc. in its own name and on behalf of its affiliated companies (collectively, “Cytec”) decline any liability with respect to the use made by anyone of the information contained herein. The information contained herein represents Cytec’s best knowledge thereon without constituting any express or implied guarantee or warranty of any kind (including, but not limited to, regarding the accuracy, the completeness or relevance of the data set out herein). Nothing contained herein shall be construed as conferring any license or right under any patent or other intellectual property rights of Cytec or of any third party. The information relating to the products is given for information purposes only. No guarantee or warranty is provided that the product and/or information is adapted for any specific use, performance or result and that product and/or information do not infringe any Cytec and/or third party intellectual property rights. The user should perform its own tests to determine the suitability for a particular purpose. The final choice of use of a product and/or information as well as the investigation of any possible violation of intellectual property rights of Cytec and/or third parties remains the sole responsibility of the user.

All trademarks are the property of their respective owners. © 2015 Cytec Industries Inc. The ® indicates a Registered Trademark in the United States and the ™ indi-cates a trademark in the United States. The mark may also be registered, subject of an application for registration, or a trademark in other countries.

www.cytec.com

AEROSOL® Surfactant Selection Guide

Specialty Additives


TR-70

TR-70 H

G

TR-60 I

OT-75 (E

)

OT-70/75 P

G

GP

G

OT-100

OT-B

OT-A

(ND

)

OT-S

(E)

OT-85 A

E

OT-N

V

LF-4

WA

-300Polymer

Emulsion Polymerization

Acrylics E E E E E E E E E E E E E E E E E E E

Styrene & Styrene / Acrylics E E E E E E E E E E E E E E E E E E E E E

Styrene / Butadiene E E E E E E E E E E E E E E E E

Styrene / Acrylonitrile E E E E E E E E E E

Vinyl Acetate & Vinyl Acetate / Acrylics E E E E E E E E E E E E E E E E E

Vinyl Chloride & Vinylidene Chlorides E E E E E E E E E E E

(micro)Suspension Polymerization E E E D D E E D D D D

Latex Post Stabilization E E E E E E E E E

Foaming Rubber or Plastic F F

Pigment & Color Dispersing D D D D D D D D D D D D D D D D D D D

Polymer Processing Aids W W W W W W W W

Coatings & Inks

Pigments Dispersing & Wetting D D D D D D D D D D D D D D D

Color / Tint Development W W W W W W W W W W X X X

Paint & Coating Formulation X X X X D X X X X X D D D

Printing Ink Formulation X X X X D X X X W D D D D

OPV W W W W W W W W

Adhesives

PSA W W W W W W W W W

Sealant W W W W W X

General Adhesives W W W W W W W W W W W W

Construction / Building Materials W W W W Z F Z Z Z D X

Textile / Non Woven D D W W W W W W W W W E E E X D

Agrochemical X X X X X W W X X X X X X X X X W X E X E D X W

Oil Industry

Oil Spill Dispersants S S S S S

Drilling / Production / Stimulation S S S S S S S F

Remedial Cleaning S S S S S

Mining, Paper & Pulp

Dust Control W W W

Dewatering Aids W W W W W W W W D

Electronics & Electrical W W W W W W W W

Cleaning

Automotive X X X X X X X X D D

Dry Cleaning S D S D D S S D

Germicidal W W W W D W D W D S

Glass & Bottle W W W W X X D

Metal - Etching, Plating W W X X W W W D X X D X


D - Dispersing E - Emulsification F - Foaming S - Detergency (Wetting, Dispersing, Emulsification)

Applications

The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe.

WA

-300

MA

-80 (I)

A-196 40

A-196 97

AY

-65

AY

-100

IB-45

EF-810

EF-800

A-102

A-103

501

18P

22 / 22N

22 Special

NP

ES

458

NP

ES

930 P

OS

C-61Polymer

Emulsion Polymerization

Acrylics E E E E E E E E E E E E E E E E E E E

Styrene & Styrene / Acrylics E E E E E E E E E E E E E E E E E E E E E

Styrene / Butadiene E E E E E E E E E E E E E E E E

Styrene / Acrylonitrile E E E E E E E E E E

Vinyl Acetate & Vinyl Acetate / Acrylics E E E E E E E E E E E E E E E E E

Vinyl Chloride & Vinylidene Chlorides E E E E E E E E E E E

(micro)Suspension Polymerization E E E D D E E D D D D

Latex Post Stabilization E E E E E E E E E

Foaming Rubber or Plastic F F

Pigment & Color Dispersing D D D D D D D D D D D D D D D D D D D

Polymer Processing Aids W W W W W W W W

Coatings & Inks

Pigments Dispersing & Wetting D D D D D D D D D D D D D D D

Color / Tint Development W W W W W W W W W W X X X

Paint & Coating Formulation X X X X D X X X X X D D D

Printing Ink Formulation X X X X D X X X W D D D D

OPV W W W W W W W W

Adhesives

PSA W W W W W W W W W

Sealant W W W W W X

General Adhesives W W W W W W W W W W W W

Construction / Building Materials W W W W Z F Z Z Z D X

Textile / Non Woven D D W W W W W W W W W E E E X D

Agrochemical X X X X X W W X X X X X X X X X W X E X E D X W

Oil Industry

Oil Spill Dispersants S S S S S

Drilling / Production / Stimulation S S S S S S S F

Remedial Cleaning S S S S S

Mining, Paper & Pulp

Dust Control W W W

Dewatering Aids W W W W W W W W D

Electronics & Electrical W W W W W W W W

Cleaning

Automotive X X X X X X X X D D

Dry Cleaning S D S D D S S D

Germicidal W W W W D W D W D S

Glass & Bottle W W W W X X D

Metal - Etching, Plating W W X X W W W D X X D X

Diester Sulfosuccinates Mono-ester Sulfosuccinates Sulfo Succinamates Nonyl Phenol Ether Sulfates Others

S - Detergency (Wetting, Dispersing, Emulsification)

W - Wetting X - Wetting & Emulsification or Dispersing

Z - Wetting & Foaming

Disclaimer: Cytec Industries Inc. in its own name and on behalf of its affiliated companies (collectively, “Cytec”) decline any liability with respect to the use made by anyone of the information contained herein. The information contained herein represents Cytec’s best knowledge thereon without constituting any express or implied guarantee or warranty of any kind (including, but not limited to, regarding the accuracy, the completeness or relevance of the data set out herein). Nothing contained herein shall be construed as conferring any license or right under any patent or other intellectual property rights of Cytec or of any third party. The information relating to the products is given for information purposes only. No guarantee or warranty is provided that the product and/or information is adapted for any specific use, performance or result and that product and/or information do not infringe any Cytec and/or third party intellectual property rights. The user should perform its own tests to determine the suitability for a particular purpose. The final choice of use of a product and/or information as well as the investigation of any possible violation of intellectual property rights of Cytec and/or third parties remains the sole responsibility of the user.

All trademarks are the property of their respective owners. © 2015 Cytec Industries Inc. The ® indicates a Registered Trademark in the United States and the ™ indi-cates a trademark in the United States. The mark may also be registered, subject of an application for registration, or a trademark in other countries.

www.cytec.com

Cytec Solvay Group5 Garret Mountain PlazaWoodland Park, NJ [email protected]: +1.973.357.3100Fax: +1.973.357.3100

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