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    SANDIA REPORT

    SAND90-0224 •

    UC-126

    Unlimited Release

    Printed December 1991

    DE92 9885

    III

      11/11111111111111 1111

    Strategic Petroleum Reserve SPR

    Additional

      e o ~ o g i ite

    Characterization Studies

      est

    Hackberry Salt Dome, Louisiana

     , Thomas

    R.

    Magorian, James

    T.

    Neal, Stephen Perkins,

    , Qiang

    J.

    Xiao, Kathleen

    O.

    Byrne

      _ ~ : : ~ -

     

    c _::_

    - - ~ ~ ; ~ A

    REPRODUCED BY

    NTIS.],

    u.s.

    Department of Commerce  

    National

    Technicallnronnation

    Service

    I  

    I Springfielcl Virginia 22161

      .

    l

    ~

    SF290QO(B,Bl

    Prepared by

    - Sandia Nat ional Laboratories

    Albuquerque,

    New

    Mexico

    87185

    and Livermore, California

    94550

    fo r the United States Department

    of

    Energy

    under Contract DE-AC04-76DP00789

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    Issued by Sandia Kational Laboratories, operated for the United States

    Department of

    Energy by Sandia Corporation.

    NOTI E

    This report was prepared as an account of work sponsored by an

    agency of the

    enited States

    Government. Neither the United States Govern

    ment nor any agency thereof, nor any of the ir employees, nor any of thei r

    contractors, subcontractors, or their employees, makes any warranty, express

    or implied, or assumes any legal liability or responsibility for the accuracy,

    completeness, or usefulness of any informat ion, apparatus , product , or

    process disclosed, or represents

    that

    it s use would not infringe privately

    owned rights. Reference herein to any specific commercial product, process, or

    service by

    trade

    name, trademark, manufacturer, or otherwise, does

    not

    necessarily constitute or imply its endorsement, recommendation, or favoring

    by the United States Government, any agency thereof or any of their

    contractors or subcontractors.

    The

    views and opinions expressed herein do

    not necessarily state

      r

    reflect those of

    the

    United States Government, any

    agency thereof or any of their contractors.

    Printed

    in the United States of America.

    This

    report has been reproduced

    directly from the best available copy.

    Available to DOE -and DOE contractors from

    Office of Scientific and Technical Informa:tion

    PO

    Box 62

    Oak Ridge,

    TN

    37 31

    Prices available from (615) 576-8401,

    FTS

    626-8401

    Available to the public from

    National Technical Information Service

    US

    Department

    of Commerce

    5285

    Port

    Royal Rd

    Springfield, VA 22161

    NTIS price codes

    Printed copy:

    A05

    Microfiche copy:

    A01

     

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    SAND90-0224

    Unlimited Release

    December 1991

    Strategic Petroleum Reserve  SPR

    Additional

    Geologic

    Site

    Characterization

    Studies

    West Hackberry

    Sal t

    Dome

    Louisiana

    Thomas R Magorian

    Amherst New York

    James T.

    Neal

    Sandia

    National Laboratories

    Albuquerque

    New

    Mexico

    Stephen

    Perkins Qiang

    J Xiao Kathleen

    O

    Byrne

    Acres International

    Corporation

    Amherst New York

    Prepared by Sandia

    National

    Laboratories

    Albuquerque 87185 and Livermore

    CA

    94550

    for the U S. DOE

    under

    Contract DE-AC04-76DP00789

    UC-126

    ABSTRACT

    This report is a revision

    and

    update of

    th e original geologic

    s i te

    characterization

    report

    that

    was published

    in 1980 Many

    of

    the topics

    addressed in

    th e

    earl ier

    report were predictive in nature

    and

    i t

    is now

    possible

    to

    reexamine them some 12

    years la te r using

    the data from 17 new

    caverns

    and more than ten years

    of SPR

    storage

    experience

    Revised maps of the sa l t configuration show

    an

    overhang

    and faults on

    the n orth sid e

    of

    th e

    dome, defining more

    clear ly

    th e

    edge

    relationships

    with

    respect

    to th e SPR

    caverns

    Caprock faults may locally i nf luence the

    p atte rn o f subsidence which is occurring primarily as

    a

    result

    of

    cavern

    creep closure

    The

    greater subsidence

    rate

    occurring at

    West

    Hackberry

    w ill lik ely

    require

    mitiga tive act ion

    within

    a few

    years

    Seismicity

    of

    low intensi ty recurs inf requently at West Hackberry but a

    small

    earthquake in

    1983 caused dish rat t l ing

    in th e

    immediate

    vicini ty

    i i i

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    4.

    i

    q

    ~ ~ ~ - : ~ ~ r : c c ~ -- .c• .,   : ~ ~ ; - ~ : : - - : ~ ; ; ~ - ; - ,

      1

    West Cove

    1

      _ .

    . ::_ -

    . . - l

    l

    :,t

    l

    - .

     

    < .:

    .

    :

    .

    , .

      .

    .

     

    I: ·

    {BlackLakej

    .  

    IC alcasieu Lake ~ ; ~

    z::

      ._, .

      ,  

    F ront is pi ec e: H igh- al ti tu de view of West Hackberry SPR s i te

    shoWing

    th e -20 f t   is land over th e

    dome

    surrounded by

    coastal

    mars hla nd s. G ulf

    of

    Mexico i s 5 mi from

    to p

    of photo, due

    south

    of West Cove.

    .

    .

     C

    0

    a

    e

    CD

    a.

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    TABLE

    OF

    CONTENTS

    Strategic Petroleum Reserve  SPR)

    Additional Geologic

    Site

    Characterization Studies

    West

    Hackberry

    Salt Dome Louisiana

    INTRODUCTION

     N

    PURPOSE .

    1

    New

    or Revised

    I n f o rma t i o n

    1

    GEOLOGIC

    ASPECTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

    Hydrology.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

    Caprock

      . , .

      . . . .

    7

    Salt   ; .

    . .

    .

      . .

    21

    Salt

      on t o u r s

    28

    Struc tural In te rpre ta t ions 33

    SPR

    SYSTEM CONSIDERATIONS.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    . .

    .

     

    33

    Cavern Configurations   33

    Subsidence   42

    Hurricane Storm Surge Levels 48

    Seismici

    ty.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 48

    Environmental Considerations 50

    Summary o f S igni fi cant

    Features Affecting

    SPR 52

    Acknowledgments. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    53

    References   . . . . . . . . . . . . . . 54

    Appendices

    A Yest

    Hackberry Regional Geologic History

    A-1

    B

    Projected

    Loss

    of

    Coastal

    Marshlands B-1·

    C Prediction

    of

    Subsidence Resulting from Creep Closure

    of Solutioned-mined Caverns in Salt Domes C-1

    D Yell Log Data D-1

     

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    LIST OF

    TABLES

    Table

    1

    Stratigraphic Correlation Chart

      10

    Table

    2 West Hackberry

    Cavern

    Geotechnical Parameters 34

    Table

    3

    Oxy

    USA

    Cavern Data.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

    Table 4 Projected Elevations for

    Selected

    West Hackberry

    Stations  

    . . . . . . . . . . . . . . . . . . . . . . . . 47

    LIST OF FIGURES

    Front-

    piece

    Figure 1

    Figure

    2

    Figure

    3

    Figure

    4

    Figure 5

    Figure

    6

    Figure

    7

    Figure 8

    Figure 9

    High

    Altitude

    View

    of

    West Hackberry SPR Site

    i i i iv

    Depth to Anahuac Shale

    3-4

    Depth to Hackberry Shale

    5-6

    West Hackberry Brine

    Disposal

    Well 2-C 8,9

    Depth

    to Top of

    Caprock 11-12

    Base with Site Boundaries, Caverns, and Flood

    Contours   5-16

    North-South Cross Section   17-18

    Depth to

    Top

    of Salt 19-20

    East-West

    Cross Section   25-26

    Conceptual

    Diagram West Hackberry Structural Features. 27

    Figure

    10

    Westernmost

    North-South Cross

    Section

    29-30

    Figure

    11 Easternmost North-South Cross

    Section

     

    . .

    31-32

    Figure 12 Composite of Generalized SPR Cavern Configurations. . . . . 35

    Figure 13

    Air Photo,

    West

    Hackberry SPR Site . ,

    37-38

    Figure 14 Olin Brine Caverns ; October 1989 Sonar Surveys . . . . . . . . . 41

    Figure 15 Oxy

    USA

    Cavern Configurations.. . . 43

    Figure 16 Isoseismal

    Map

    16 Oct 83 Lake Charles

    Earthquake

    . . .

      . .

    49

    Figure

    17 Earthquake

    Acceleration

    Probability Map... 51

    vi

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    INTRODUCTION  N PURPOSE

    The

    in i t i a l

    geologic

    s i te charac te r iza tion repor t

    [Ref.

    1]

    was

    completed

    in

    1980, when

    only the five caverns that were acquired

    from

    th e

    Olin

    Corporation

      s

    6,7,8,9,

    and 11) existed.

    Since that

    time 18

    cavern

    wells were

    dril led

    and

    17 new caverns were leached

    and

    are now some

    90

    f i l led

    with

    crude

    oi l

    toward

    the

    currently

    authorized

    si te

    c apac it y o f

    219 million barrels  MMB). The

    construction

    of

    the

    new

    caverns ha s

    significantly enhanced our confidence

    in understanding

    the

    sa l t

    dome

    features.

    I n add it io n

    to

    information that has become available during more

    than

    10

    years

    of

    SPR

    operation, new data are

    also

    available from numerous

    commercial wel ls adj acen t

    to the

    s i te

    This report

    is a revision

    and update of th e ear l ier

    si te

    characterization

    r p o r ~ placing

    t he geo logi c

    understanding

    in better

    perspective. Several aspects a re

    given

    special attention in

    the

    report:

    sa l t

    contours

    and structural interpretations

    as

    they relate to

    cavern

    integri ty;

    subsidence

    history

    over

    SPR

    caverns;

    and

    potent ial

    flooding

    during future operations. In

    numerous

    cases, the original

    maps

    are

    re

    interpreted

    in

    l igh t of the

    new

    information,

    and with reference

    to

    current

     1991)

    concepts

    of Gulf Coas t geology.

    New or

    Revised

    Information

    The 18 new

    cavern wells provided detailed information

    on

    th e character

    of th e

    sa l t mass

    and

    also the sa l t

    contours

    on top of

    the

    dome A new

    sa l t map

    is

    presented, along with new interpretations of the structural

    geological

    configuration. These

    have been

    aided by o i l

    company

    interpretations and data, especially

    on

    th e north side adja cent to Black

    Lake.

    Configurations of the 22 caverns are discussed, along with the

    .ten

    year operating

    history

    a t th e s i te

    Few

    i f any , problems exis t although

    Cavern I I I has

    behaved

    in

    an

    atypical manner.

    The

    3-dimensional

    computer

    model shows

    that

    Cavern

    I I I

    is

    approximately

    200

    f t

    further from th e

    edge

    of

    the

    sa l t than previously

    estimated.

    However a

    faul t

    and

    shear zone

    have been found in i t s

    vicini ty.

    Subsidence occurring over the cavern f ield

    has

    been resurveyed

    annually for

    some

    eight years a t

    more

    than

    eighty survey points, and

    suff icient

    data

    exis t

    to

    make definitive

    judgments

    on

    future direction.

    The data show that West Hackberry is

    subsiding

    a t a greater rate than

    the

    other SPR

    s i tes

    and

    that

    th e

    areas

    on

    the

    s i te

    with

    low

    elevation

    will

    eventually requ i re pro tec tion from permanent inundation. The adjacent

    coastal marshlands are

    also

    subsiding and some 35 sq mi/yr of south

    Louisiana is becoming open

    water

    and part of th e Gulf of Mexico Present

    conditions and future

    trends

    suggest

    that

    the

    higher por ti on s o f

    the

    West

    Hackberry

    s i te

    are

    effect ively an island in the

    marsh

     see frontispiece),

    and

    that eventually i t wil l

    be a

    small

    island

    in

    open

    water with direct

    connections to

    th e Gulf.

    1

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    Hurricane

    surge

    heights have been rev ise d to a higher va lu e than

    previous ly indica ted ;

    current 100 yr

    flood stage heights are about

    10 f t

    above

    mean

    sea level  amsl a t the s i te

    The

    eye

    of

    Hurricane

    Audrey

    in

    1957

    passed

    about 12 mi west of

    th e

    s i te and produced high

    water

    marks of

    10 f t above mean sea level

    a t

    that location.

    National

    seismic

    zonation

    maps

    have

    been refined in

    the past ten

    years bu t

    the

    Gulf Coast

    interpretat ion

    is

    l i t t l e changed,

    th e area being

    essentia l ly aseismic.

    Nonetheless; new data and a

    small ear thquake

     1983

    near the

    s i te a re d is cuss ed .

    GEOLOGI SPE TS

    The geologic discussion presented in Appendix A complements

    that given

    in th e ear l ie r

    report [Ref. 1]

    and is

    not intended to dup lic at e

    i t

    The

    geologic information

    base

    is needed to help maintain

    th e integri ty

    of th e

    o il

    storage

    caverns

    and

    in clude s th e

    extent

    and

    cha ra ct er o f

    the

    sa l t

    dome

    in i t s regional set t ing.

    The

    sa l t

    mass containing

    th e o il is in

    turn

    held

    and

    s tabil ized by th e

    regional

    sediments

    into

    which th e

    sa l t

    dome is

    intruded. The low-permeability muds,

    part icularly those a t geopressure

    forming the shale

    sheath,

    form add it io na l p ro te ct ion for any

    o il

    stored in

    the dome

    [Ref.

    2].

    Figures

    1 and 2

    are

    s tructural contour maps showing

    depth to

    Anahuac

    and Hackberry

    shale

    units ,

    respectively.

    Figure

    2

    also

    shows

    the

    locat ion o f c ro ss -s ec tions used

    in subsequent

    figures. Table 1

    explains th e

    abbreviated

    s tr a ti g raph ic un it s

    shown

    on

    th e sections.

    Hydrology

    Fresh

    water

    is

    found

    on

    th e

    is land in

    th e

    upper

    glacial-equivalent

    sands of the

    Chicot

    aquifer. The Wisconsin is freshest and most potable,

    although the I l l inoian

    is

    also

    suitable

    for industrial use. The lower

    Wisconsin or

    Alton

    is referred to

    as

    the 200 f t aquifer.

    The

    water in the caprock may contain quantit ies

    of

    hydrogen sulfide.

    At

    th e

    base

    i t is saturated

    brine

    in equi libr ium with

    th e

    sa l t that i t is

    dissolving.

    Deeper waters in hydrocarbon-bearing

    sands around the

    dome

    vary

    from fully saturated brines

    in the

    more massive Miocene sands

    mineralized

    close

    to

    the sal t to

    anomalously-fresh

    carbonate-saturated

    brines r ich in boron, vanadium and

    other ocean-floor

    concentrates in

    isolated sands in

    contact

    with

    geopressured

    shales.

    The

    DOE

    injection

    well

    f ield

    is

    located

    on

    the opposite south

    side

    of

    th e

    dome from

    th e o il

    storage caverns. Directionally

    dr i l led

    from a

    central

    pad on the

    steep

    southeast

    flank of

    th e dome, a l l th e wells

    were

    completed in

    the

    RL

    zone

    at th e top of

    th e

    lower Miocene  see Table

    1 .

    This

    well-sorted marine bar sand exhibits good permeability

    a t the top

    and dips 30 degrees south-southeast. All of

    the

    wells took brine at

    relatively good rates

    in i t i a l ly

    2

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    -

     

    o

    o

    o

     

    o

     

    Z 1t 8Sl lW III WZ O I  

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  • 8/19/2019 Additional Geologic Site Characterization Studies West Hackberry Salt Dome

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    \

     

    ~ ; : : J ~

     

    I

     

    1MI I  

    1 1

     

    i O

    I :

     

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  • 8/19/2019 Additional Geologic Site Characterization Studies West Hackberry Salt Dome

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      ~

    ' ,[

      .

      .

     

    II

    I 80 ..= ....

    N:...

    ....  

    .

     _

    : . . -

    ••••••••

     l I I

    ••

     

    ••• •••

    •.• I .

    ,

     

    • • •

    I

    .....

     

    ....... .

      _

    • ••

    11.11.

      • • •

    WEST HACKBERRY

    DOE BRINE DISPOSAL WELL

    NO. 2-C

    u

    :E

    >

    0

    >

    :::

    .....

    a

    0 gI =11

    ~

    .  lJ

    0

    .lJCI

    l:lIE

    a

    :5

    0

    CI  :

    >0

    ll

    ::J

    iii

    C1

    . . . . .

     

    25

    Recent

    MUCK

    CLAY

     

    ••

     

    ••

     

    71

    ••

     

    III

    II

    ·: :·: ::: : ::e

    100 Wisconsin SANe •

    : : :.: :.: :.:.: : GRAVEL

    :8::::::6:

    100 ppm

    sooo

    6000

    ppm

    8

      1310 Kansan

    SANe

    GRAVEL

    2

    27: :

    Figure 3

    SHEET

    1

    OF

    2

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    WEST HACKBERRY

    DOE

    BRINE DISPOS L

    WELL

    NO 2 C

    5 30

     

    1

    In .

    I

    n

    ••

     1

    ••••

    noo

    . .

     

    to

    ..0

     E

    9

     

    .

    CL Y

     

    ~

      : : :0: : : : 1660 Nebraskan/Lafayette

      S ND  

    GR VEL

    : :·0

    ·0:·  ;;;

      ~

      1 = = ~ 1

    . . . . . . .

    1860 Pliocene -

    SILT

    with

      :

      thin S ND

    laye,..

    TITr

    IIII

    Trn

    TITr

    IIII

    TITr

    TITr

    TITr

    TITr

    IIII

    IIII

    TITr

    Figure 3 cont.

    SHEET

    2

    OF

    2

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    TABLE 1 - VEST

    H CK ERRY

    STRATIGRAPHIC CORRELATION

    CH RT

    Unit

    Recent: Beaumont clay

    Q

    Pleistocene

    U

    Wisconsin

    A

    Alton Peorian:

    Prairie

    Fm

    T Sangamon: Ifontgomery Fm

    E I l l inoian

    R

    Yarmouthian:   n ~ l y Fm

    N Kansan

    A

    Aftonian:

    Williana

    Fm

    R Nebraskan

    Y Lafayette

    Symbol

    a

    s

    i

     p

    ka ks

    ne

    Lithology

    peat muck

     

    mud

    sand

    and

    gravel

    mud

    sand and gravel

    mud

    sand and

    gravel

    mud

    sand

    and gravel

    gravel

    T

    E

    R

    T

    I

    A

    R

    Y

    Pliocene

    Miocene

    Upper

    Bigenerina f loridana

    Textularia

    Bigenerina

    nodosaria

    Textularia

    stapperi

    PL

    MI

     

    L

    2

    s i l t

    mud,

    and

    sa

    mud

      sand

    sand and gravel

    mud

    sand and gravel

    mud

    marine

    sand

    delta ic

    sand

    mud

    delta ic sand

    mud

    Middle

    Bigenerina humblei  H

    Cristel laria

    CI

    Cibicides

    carstensi

    op m CO

    Amphistegina

     

    Lower

    Robulus RL

    Operculinoides OP

    Cibicides

    C

    Ifarginulina ascensionensis M

    Siphonina

    davisi

    - - - U NCO N F O R M I T Y .

    Anahuac

      Discorbis)   R

    Oligocene

    Heterostegina

    H

    Harginulina howei

    MH

    Frio

    F

    Cibicides hazzardi

    -

    CH

    U NCO N   ORM IT Y -

    Hackberry

    facies

    H

    Vicksburg VX

    :10

    unconformity

    shale

    thin

    sands

    sand

    shale  

    m arin e sand

    bituminous l imest

    sand

    and shale

    sand

    shale

    thin sand

    shale

    coral reef

    sand

    shale

    sands

    marine·sands

    geopressured

    sha

    b la ck s ha le

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    LEGEND

      COX: on

    l

     =

    OLIN

    CONST

    OIA

    1= O O E

    OF CAVERN

      W LL

    NO

     .

    -

    X S

    • 20.016

    CENTER OF  L,..-J

    CAVERN L-CAPROQ(

    n

    O O E_ PROPERTY  

    LINE

    CAPRoa<

    CONTOUR

    -5000

    CONTOURS

    IN fEET

    BELOW

     £A N SEA

    LEYUI

    \

     ®

    \

    o

    o

     8

    B LAC K

    L A

    KIE

    IT

     

    6

    _ 5 3000 FEET

    i

     

    fiGURE 4

    WEST

    HACKBERR

    CAPROCK

    p lI U

    \

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    I t

    l ies

    on

    top of

    f la t

    sa l t

    across

    th e

    dome as a resul t of the

    leaching of

    sa l t to a

    f l a t surface by

    groundwater

    as

    the

    dome r ises

    through t he ove rlying sediments.

    The

    relat ively

    insoluble

    anhydrite

    accumulates as

    a cap and,

    in

    the

    presence of

    methane gas

    seeping

    up

    th e

    face of the

    dome

    is part ly

    converted to carbona te .

    The

    continued

    upward

    movement

    of

    the

    sa l t with l each ing to

    a

    f l a t surface creates

    a complexly

    faulted

    and

    fractured

    domal-

    to flat-topped

    cap

    containing extensive

    interconnected voids ranging

    from

    small

    vugs

    to

    caves.

    The

    caprock a t

    West Hackberry

    is

    relat ively

    thin  -400

    f t and l imited

    in aerial extent. I t does not

    overdrape the

    stee p s id es of

    th e

    dome as

    occurring a t th e next dome north, Sulphur

    Mines

    --

    a

    small, round conical

    dome.

    Most

    of

    the

    S caverns

    are loc ated near

    the

    middle

    of

    th e

    dome

    where

    caprock

    condi ti on s a re relat ively uniform. However Cavern I I I

    is

    located

    near the

    steep

    outer edge

    of

    the sal t a t th e feather edge of the caprock

     Figures 5,

    6 . The

    subsurface

    control near

    Cavern

    I I I

    is

    l imited. The

    closest wells dri l led into th e solid sa l t

    face

    are

    in

    Section

    19

    to th e

    west

    and

    Section

    16

    to

    the

    northeast.

    The

    in tervening contro l

    includes

    one well

    that included salt-mineralized

    sands a t a

    depth

    of

    approximately

    3000

    f t indicating that i t is

    close to the sal t

    face, as

    shown

    on the

    cross-section

     Figure 6 . The resul tant

    interpretat ion

    as shown on th e

    sa l t map  Figure 7

    is

    suf fic ien tly s t ra ight , except for the radial

    fault

    bel ieved to be

    related

    to a possible

    shear

    zone, to make the cavern quite

    secure despite th e evidence

    for an

    overhang.

    The

    se ismic su rv ey s, while

    incomplete, support

    this

    interpretation, as does gravity

    data.

    I f

    o i l leakage

    from

    th e storage caverns

    were to

    occur i t

    would

    migrate

    into

    the

    caprock

    and join

    th e

    much

    larger

    volume of o il which

    has

    migrated

    up

    the face

    of

    the sal t

    dome. Although no

    commercial wells

    have

    been

    completed

    in

    th e

    caprock

    at

    th is dome

    due

    to

    i ts

    relat ively

    low

    porosity,

    the thin overlying sands are o il

    productive

    and adequately sealed from the

    surface by more

    than

    200

    f t of

    mud. However

    gas may

    leak

    through these

    muds,The gas accumulation under the brine

    pond

    l iner i s apparently

    biogenic, originating

    possibly from

    unscarified decaying grass

    [Ref. 15],

    but a t other

    domes

    is indicative

    of

    escaping hydrocarbons.

      h l l o ~

    domestic water

    wells

    nearby also

    make

    gas.

    Thus,

    the r isk of

    environmental

    contamination through migra ti on path s a lr eady naturally

    f i l led with hydrocarbons may be

    moot.

    Lost circulat ion:

    The

    hydrology

    of

    caprock i s controlled by th e large

    voids

    crea te d in

    the

    solution process.

    Although the

    water

    is

    s at ur at ed i n

    carbonate

    throughout,

    in sulfate

    half-way down and is

    saturated

    brine at

    the

    base, th e

    flow

    is

    suff icient

    to

    keep

    the

    top

    of

    the

    sa l t

    very

    nearly

    f la t Hydrologic calculations

    of the

    rate of

    sa l t

    solution

     which must

    be

    close to

    that

    of

    intrusion

    inside the

    dome

    were

    made

    a t

    Bayou Choctaw

    and

    found to be

    in

    agreement with the geologic data

    of

    upl i f t on th e

    flanks.

    Thus,

    lost circulat ion is

    to be expected while

    dri l l ing caprock,

    although th e

    problem

    is less in thin caprock here than, for example, a t

    Big

    Hill where

    the

    caprock i s

    one

    of

    th e

    thickest

    known

    in

    the

    Gulf Coast.

    13-14

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  • 8/19/2019 Additional Geologic Site Characterization Studies West Hackberry Salt Dome

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    - ~ . \

    ,

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  • 8/19/2019 Additional Geologic Site Characterization Studies West Hackberry Salt Dome

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    II

    108

    lOS

    101

    03

    115 109

     

    ••

     

    I

    .-

    1m

      _  _

    .

    _.

     

    ---

     

    r

    ...

     

    nl l l l_

    Fl ••

     

    Dr

     

     

    ..

    .-

     1 1141

    .

    .

      ..

    .

    .

    .

    ..

    ..

     

    ·

    .

    ·

     

    ·

    .

    ·

    ·

    .

    . . .

    .

    ·

     

    ·

    ·

    ·

    ·

    I

    ·

    · .

    ,

     ir.

     

    :

     

    ••

     

    I

    ·

    .-

     

     

    ...

     

    ...

    • •

     

    :t .

    .r .

     

     

    .

     

    ·

     

    .

      .

      -

    .,  

    . a

    ..

     

    ....

    1 .

    ....

    PI e

     

    I

     

    =>

     

    1

    \

    SALT

    NOTE:

    REFER

    TO

    TABLE

    I FOR

    STRATIGRAPHIC

    SYMBOlS

    p.17.18

    F IGURE

      SECTIO

    ON FIGU

    WEST H

    SECTIO

    V:H

    = I

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    31

      >

    .p.19 20

    fiGURE

    7

    WEST

    H CK ERR

    SALT

     

    oX OXY

     = OL 1N

    CONST  1

    1=

    o.o .

    Of CAVERN

     

    r

    WELL

    NO

      OX S

    crNT[R

    Of

    l r J

    CAVERN L SALT a n

    0.0 . [ .

    PROPERTY _ ••_ _

    LiNt

    SALT

    CONTOUR

     5

    CONTOURS

    IN

    r[[T

    BELa. Io£AN SO

      [V [U

    LEGEND

    o 1500 3000

    FEET

    SCALE i  

    17

    K

    18

     ®

    .\

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    The most cost-effective method of pene trat ing

    the

    caprock

    has

    clearly been

    demonstrated to

    be

    dri l l ing without returns.

    By using

    water

    instead

    of

    mud to cool the bi t

    hole

    can

    be

    made in

    this

    br i t t l e rock without

    cementing

    every few feet , once casing is se t in the

    hard

    carbonate

    caprock.

    Hydrogen

    Sulfide: ~ t Hackberry

    may

    have

    signif icant

    concentrations

    of hydrogen sulfide. This

    toxic

    gas, commonly known in oi l f ie ld

    terminology as sour gas; is formed in the re ac ti on o f hydrocarbons with

    anhydrite to form carbonate caprock and sulphur.

    Although

    sulphur

    exploration was not commercially

    success fu l, t he re

    are abundant shows of

    sulphur

    a t

    the

    top

    of

    the

    anhydrite cap,

    part icularly

    in th e usual

    location

    near

    th e

    rim of

    th e dome West

    Hackberry

    has

    been

    prospected

    and

    i s

    close to

    many domes that have produced commercial

    sulphur,

    including

    High Island,

    Fannett

    and Spindletop [Ref. 4].

    As

    a result hydrogen

    sulfide is

    detectable

    in most sal t-dome caprocks

    [Ref.

    5].

    The

    presence

    of hydrogen

    sulfide complicates

    dri l l ing

    through

    th e

    hard

    caprock because

    everything

    in

    th e

    hole, including

    th e

    dr i l l

    str ing, t urn s b la ck and corrodes. Any pipe harder than API  American

    Petroleum Ins t i tu te) Class E is

    subject

    to brl t t le fai lure under

    normal

    fatigue loads,

    part icularly when corrosive saturated

    brine must also be

    used  to

    dr i l l

    into sal t . Nickel

    and

    manganese, used to harden the

    steel are more subject to sulfide corrosion

    and

    c rack ing than even

    iron.

    Faults: Caprock

    is characterist ical ly fau lted in

    most of

    the cores

    that are recovered,

    so much so

    as to

    be

    a

    permeable jumble of

    broken

    blocks

    with

    secondary

    calcite

    cementation. Some of these faults

    extend to

    th e

    surface, and

    may

    control

    subsidence as

    well as

    localize small,

    natural

    shallow

    o il

    accumulations.

    The

    faults

    are

    further

    suggested by th e shape

    of

    the tr iangular subsidence trough [Ref.

    18], and by

    the producing

    wells

    on

    higher

    blocks

    across

    the

    top

    of

    th e

    dome

    The active shallow faults origina ti ng in th e caprock or sa l t

    shear

    zones have

    only displaced th e

    Recent

    sediments a few

    feet .

    They do not

    pose

    any

    apparent r isk to th e storage caverns by themselves, but

    subsidence

    along them

    could

    conceivably damage surface faci l i t ies or well

    casing, as has occurred at

    other

    domes used

    for

    storage o f  LPG) products,

    e. go ,

    Stratton

    Ridge,   [Ref.

      ]

    Salt

    The general shape of

    the

    combined

    East

    and West Hackberry domes a

    flat-topped and

    sl ight ly- t i l ted el l ipsoidal

    cylinder,

    is

    similar to that

    of

    most

    elongated

    sa l t

    domes

    In

    the

    case

    of

    Hackberry,

    th e

    t i l t

    is

    northward.

    The

    west

    end

    is relat ively

    blunt and

    the

    east end,

    a t

    th e

    saddle to

    East Hackberry, sharply

    poin ted F ig .

    7).

    This disagrees

    signif icant ly

    with

    the ear l ie r interpretations [Ref. I ]

    which

    included a

    deep

    valley

    on the no rth side and an

    elongate

    conical dome As a result ,

    several

    signif icant

    revisions

    in the

    external geometry of

    the

    sal t stock

    were required in revising the dome contours.

     

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    Commercial

    exploratory dr i l l ing

    was

    very

    l imited in

    the

    area f rom 1986

    to

    1991

    because of the decline in o il prices so l i t t l e

    new data

    has been

    available although

    a few

    old

    wells

    have been twinned to keep

    up

    production.

    The

    steep

    southeast face

    along

    with

    the sharp

    east end

    suggests

    that a transform

    or

    wrench fault

    separates the

    domes.

    Study

    Method:

    Sediment

    structure

    around

    th e

    dome

    is

    used

    in

    this

    study to he lp de fin e

    the

    sa l t face. Methods of

    determining th e

    sa l t

    face

    include

    dip and convergence or thinning

    of the

    beds

    uplif ted

    by

    the sa l t

    intrusion.

    Asymptotic Dip: . From f la t beds

    in the

    bottom

    of th e

    rim

    syncline the

    dips

    of

    the sediments

    around

    the

    sa l t

    increase

    65

    degrees in

    many places

    against the near-vertical face. This

    asymptote

    allows the horizontal

    posit ion of the sa l t face

    to

    be calculated

    from

    the observed

    change

    in

    dip.

    Convergence: In

    addition to

    structure as discussed below

    s tr a tig raph ic vari a tion

    is

    used

    in

    this

    study

    to

    help

    define

    the

    edge

    of

    the sa l t That i s th e intersection

    point

    a t which

    projected beds meet

    is

    a good

    estimate of th e sa l t face. There is extreme

    convergence

    in th e

    Oligocene with i t s thick shales but very l i t t l e convergence

    in

    th e

    overlying Miocene Sands. The resul tant thinning is

    part icularly

    apparent

    in th e oil-productive

    Frio

    sands.

    Rate

    Of

    Uplift :

    The

    overal l average intrusive r ise of the dome

    as

    a

    whole

    can be calculated

    from

    the upl i f t

    of dated marker

    beds

    that are

    asymptotic to

    th e face

    of th e sa l t

    The

    deepest penetrated

    Hackberry

    shale

    sheath

     HB , some 40

    million years old

     my ,

    has been uplif ted

    some

    7000

    f t the top of the Oligocene  DR,

    30

    my

    6000

    f t

    middle Miocene

     AB,

    15

    my

    3000

    f t

    Miocene

     10 my

    2000

    f t Pliocene  2

    my

    500

    f t and

    Peorian

     p

    0.5

    my

    100

    f t

    These

    value s a re

    a ll

    very

    close to

    a

    rate

    of

    0.1

    mm/yr,

    which is the

    same

    as that observed a t

    Bayou Choctaw

    and Big

    Hill .

    This

    rate

    is exceeded only

    by

    th e Five Island Chain including

    Weeks

    Island which has an apparent

    upl i f t

    rate

    as

    high as

    4 mm/yr.

    Spines:

    The

    spine theo ry

    of

    sa l t intrusion

    and i t s

    validation

    in

    mines

    is reviewed in the

    Weeks Island

    SPR Geological

    Characterization

    Report

    [Ref.

    7].

    The

    well log data and

    their

    correlation a t

    Weeks shows

    two

    spines separa ted by

    a

    shear zone in the south half of the dome used by

    SPR. The

    spines

    are

    interpreted as anticl inal

    features or.domes

    in the

    anhydrite correlation data

    a t

    Big Hill

    [Ref. 8].

    In

    east-west domes

    l ike

    West

    Hackberry th e sa l t

    flow

    l ikely occurs in

    widely-separated spines .

    However,

    there is·

    insufficient

    control within

    the

    sa l t

    to define

    the se spine s by their shear

    zones

    i

    e areas of

    more

    anhydrite which

    separate them. The

    holes that were dr i l led to

    leach

    th e

    new DOE caverns were

    only

    part ia l ly logged and a few cores cut. Only one

    hole per cavern was dr i l led  except 117

    which has

    two and logged through

    the

    sa l t so tha t i t was not possible to use th e methodology developed a t

    Big Hill

    for mapping anhydrite bands and

    th ereby th e in ternal structure of

    the

    sa l t

    intrusion. Consequently

    any

    additional cavern development should

    22

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    requi re exploratory dri l l ing

    and

    logging

    to

    delineate such features within

    the sa l t

    mass, even

    though

    speci fi c e ff ec ts on cavern construction

    may

    be

    speculative.

    Core samples show that

    the sa l t is relat ively

    dark

    with considerable

    disseminated anhydrite, even in the middle

    of

    apparent spines. The sa l t

    crystals

    are

    t ightly

    interlocked,

    as

    a result

    of

    the

    compaction

    due

    to

    the

    weight of th e caprock. This dark sa l t beli ev ed t o be

    l es s r ec ry s ta ll iz ed

    since

    upl i f t i s typical

    of slower-moving domes

    Shear

    Zones: All sa l t domes

    that

    have

    been

    studied have their shear

    zones

    centered

    on

    and

    paral le l to the

    underlying sa l t ridges. The

    shear

    zones are a lways between th e spines. They are observed

    as

    a

    high

    concentration

    of near-vert ical anhydrite

    and

    o th er i nc lu si on

    bands,

    usually

    ref lected as

    a

    sharp

    trough

    or

    low on the surface of the sal t

    Sediment trapped between the spines

    in an

    overhang could

    be

    incorporated

    into

    the sa l t dome

    by

    continued

    int ru sion , c reat ing

    potent ial

    prryblems i f

    cavern leaching is attempted

    acro ss s hear z o s ~

    The

    postulated

    nor theast -southwest shear zone correlates very closely

    with the faul t running

    into

    th e overhang  Figures

    8,

    9 . A secondary shear

    zone

    normal to

    this appears to cross i t

    over the

    center of th e

    dome

    somewhat l ike Weeks Island. This

    complication

    may be related to the

    apparent

    steep

    dips

    in

    Miocene sediments near

    the nor thwest corner

    where a

    radial

    faul t

    t ies

    in with the

    apparent

    shear. This shear zone also

    represents th e axis of th e sa l t ridge upon which th e dome s i t s

    The par t ia l near-vert ical overhang on th e north side adjacent to the

    s i te is a

    much-less

    complete seal, requiring la te ra l

    sealing

    along

    th e

    shear zone which has acted as a fault beyond the edge of the sa l t stock.

    I t is

    unlikely,

    however, that a l l

    th e

    o i l and gas trapped against this

    sa l t

    dome

    have

    been

    found.

    Well Control

    Significant dri l l ing has

    been

    done

    close

    to

    th e sa l t face

    around the

    dome

    since the

    original geologic

    characterization.

     moco

    has dr i l led two

    additional wells downdip in the product ive

    sa l ien t a t th e

    southwest

    corner

    of the

    dome which

    do not

    change

    the

    interpretat ion

    of

    th e sa l t

    face. All

    of

    the available well data are included in th e appended Well Tables

     Appendix

    D . A long

    overhang may l imit the depth

    and extent of

    caverns

    in a broad arc

    across

    the north s id e of the  OE property. This overhang

    is very nearly ver t ica l l ike the

    north

    side of Weeks

    Island and

    the West

    side of

    Bayou Choctaw and

    unlike

    the 60

    degree

    overhang on the south side

    of

    Big

    Hill .

    Seismic Data

    The

    original

    seismic data from 1983 was obtained under contract by

    Woodward

    Clyde Consu lt an ts , Inc.

    However th e

    l ines

    were

    not extended

    out

    into Black Lake

    far

    enough

    to

    get good

    ref lect ions

    from th e steep

    sa l t

      3 4

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    -

     

    -

     

    --

    .

     

    SALT

    -

    -  

    -

     

    -

    -

      :

     :

    :

    -  

    --

     :

    :

    ·

    .

     

    :::

     

    .

    .

     

    .. :,

    .

     

    I

     

    ,

    CAPROCIC

    1

    I

    , I

    D

     

    D 7

    8

    U

    V

    U

    114

    107

    1011

    .-

     

    --

    m

     :

    NOTE: R EFER TO

    TABLE I FOR

    SmA TI

    GRAPH

    IC S n8OlS

    FIGURE

     SECTIO

    ON

    FIGU

    p.

    25 26

    l T H

    SECTIO

    V,H =

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    22

    27

    LEGEND

    SAL

    T

    CONTOUR   5

    D O Eo PROPERTY _ ••

    LINE

    PROBABLE

    SP IHE CENTER

    21

    20

    H

     

    ..

     o. s o. J

    l _

     

    I

    PROBABLE

    SPINE

    CENTER

      2 500

    1

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    face

    and i t s flanking sediments. The only data

    is

    from the top of the

    cap

    and

    sa l t

    Amoco data is available, possibly

    indicating

    an

    overhang. The

    cr i t i ca l

    l ine ,

    closest to

    Cavern 111, was to have been

    reprocessed

    in

    early

    1991

    to help resolve the

    overhang uncer ta in ty , but

    with

    lower

    o il

    prices

    apparently

    has been delayed

    indefini tely.

    Amoco g ravi ty d ata was

    examined to

    improve

    the

    interpretation of

    shallow

    faults , sal t spines, and possibly

    subsidence.

    The

    data

    support

    th e overal l i n te rpret a ti ons reported

    on

    here.

    Sal t

    Contours

    The sa l t contours

     Figure

    7 were f i t ted to the digitized database

    using

    more

    than

    50

    cross-sections, smoothed both horizontally and

    ver t ica l ly between

    the

    faults found

    in well

    cuts   in th e

    oil-bearing

    and

    overlying sediments near the sa l t The most

    important

    changes in th e

    shape

    of

    the

    dome

    from

    previous

    maps

    are

    th e overhang and

    faults

    on the

    north side, next to the SPR storage s i te

    Most

    of

    the

    shape of the

    rest of

    the

    dome

    connecting to

    East

    Hackberry in a neck

    protected

    by shale, is smoother than previously mapped

    since

    we have shown that

    the shallow

    solution topography

    on th e top

    of

    the

    dome

    is

    unrelated

    to

    th e s t ~

    flanks which

    have never been systematically

    contoured via

    computer

    graphics with

    a

    digi ta l database.

    An

    east-west and th ree north-south cross-sections  Figures 6, 8, 10,

    and

    11 ;

    located

    on Fig.

    2

    have

    been prepared from the

    digi t ized

    database

    for this report . The two westernmost north-south

    sections

    show clearly

    the

    overhang

    jus t

    north of

    the

    SPR

    s i te

    The

    westernmost section  Figure

    10 shows

    th e northwest corner of th e

    dome

    where the

    complex

    near-ver t ical

    Frio sands have been dragged up to

    a lmos t cover

    th e shou lder of th e

    dome. The

    o i l has leaked

    up

    into th e

    basal Miocene sand, and

    probably

    from here into

    the

    sands above the

    caprock.

    A

    similar

    complex area is found

    in the

    same posit ion a t Weeks

    Island where the n e r ~ v e r t i l sands are basal Miocene age.

    The middle north-south section

     Figure

    6 through

    th e

    SPR

    caverns

    shows the normal 60 degree dips

    extending

    nearly

    a

    mile

    out from the sa l t

    overhang,

    providing

    most of

    th e o il production.

    The

    easternmost

    section

     Figure

    11

    shows a

    wide

    band

    of

    geopressured

    Hackberry

    sha le t runcat ed by the unconformity a t the top of the Oligocene

    which

    protects

    the sa l t face,

    suggesting

    a

    large

    area

    of

    undeveloped

    storage potentia l .

    The eas t-west sec tion

     Figure 8 runs

    th e length of

    the

    dome crossing

    the

    SPR

    s to rage a re a

    and

    showing

    one

    of th e faults believed poss ib ly

     

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    NORTH

    SOUTH

    1_1

    ....

      6 :

    41

     

    41

     

    81 11ft  

    1

    . .

    .

    .

    .

    .

    .

    .

    .

      .

    .

     

    . .

    ·

    .

    1 0

     IGOD

     

    1-  llIOII

     

    2lIOII

    PRO K

      l IOII

     «lOG

    O

    0

      «lOG

    ........  

    ........

    -l OOO

     

     

     

     

    SALT

      7000

    J

     1

    \

     .

     

    1 7000

     

    /

     

    -lIOOO

     laaa I  

    ICIXII

    nn

    nn

    NOTE: REFER TO TABLE I FOR

    STRATIGRAPHIC SYMBOLS

    p 29 3O

    FIGURE 10

     SECTION LO

    ON

    FIGURE 2

    WEST H CK

    SECTION C

    V:H

    =

     

    I

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    SALT

     

     

    -

     

    -

     

    I

    -

    -

     

    ...

     

    .. 

    ....

    - -

    ...

    -

    ,

    ..

     

    -

    .IF

     V

     r

     I

    .

    .

    .

    .

    . .

    . .

    .

    ·

    .

    .

    .

    .

    .

    .

    .

    .

    .

    I

    ,

     I

    ·

    .

     

    11

     

    .....

    CAPROCK

     

    NOTE: REfER

    TO

    TABLE I

    fOR

    STRATIGRAPHIC

    SYMBOLS

    fiGURE  

    SECTION

    L

    O

    fiGURE

    p.31·31

    WEST H C

    SECTION

    V:H =   :

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    activated by cavern

    creep

    and bounding the tr iangle of greatest surface

    subsidence. This faul t is th e sur face expression

    of

    a probable shear zone

    separating active spines. I t shows on

    both

    sa l t and caprock maps.   e have

    no

    evidence

    that any

    of

    these faults intersect the caverns,or the well

    casings.

    Structural Interpretation

    Dome-Related Fault iD : The

    shear

    zone observed

    in the

    new

    wells

    continues

    outside

    the

    sa l t

    as the single

    radial

    faul t on the dome  Figures

    1, 2)

    that is

    o il

    productive, having been substantiated at th e northwest

    corner

    of

    the

    dome and

    discussed

    earl ier under the section on shear zones.

    The West and

    East

    Hackberry Salt Domes, along

    with

    the Big Lake

    structure to th e east,

    form an east-west

    ridge in the

    middle of

    the

    Hackberry embayment, the most

    prominent

    Frio

    feature

    of the Gulf Coast.

    I t

    is

    a large

    depression

    that was f il led in Oligocene middle Frio

    time

    with deep-water shale.

    Big

    Hill , a preViously

    characterized

    SPR dome,

    l ies on

    the

    west edge of

    th e

    embayment [Ref. 8].

    The rim syncline surrounding

    the

    sa l t

    r idge represents

    the

    equilibrium

    in the intrusive

    sa l t

    between the sands being deposited from the northwest

    and

    the

    Hackberry Embayment.

    SPR SYSTEM

    CONSIDER TIONS

    The

    effects

    of regional and local geology may

    affect th e

    SPR

    operations in a variety

    of

    ways. These aspects

    are

    discussed in the

    fol lowing pages.

    Cavern

    Configuration

    The

    five caverns

    which were purchased from

    the Olin Corp.,

     

    6, 7,

    8,

    9, and

    l l ex i s t ed

    at the time of th e 1980

    si te

    characterization. The

    geometry of

    these caverns is

    unchanged, but refinements in some of

    the

    technical

    data

    have been made; these

    changes are

    indicated in

    Table

    2,

    along

    with the

    data from

    the

    17 new caverns,  

    101-117.

    Caverns   101-

    116 are single-well

    caverns,

    whereas   117   a two-well cavern, similar

    to

    the Phase

    III

    caverns

    at Big

    Hill .

    Table 2 was compiled by Boeing

    Petroleum Services

    and Usts

    the

    most

    relevant parameters

    associated

    with cavern integrity. All depths

    are

    given

    in

    feet below the bradeDbead

    flange

    (which

    varies

    from 4 to 19 f t

    emsl),

    but

    cavern-induced subsidence

     

    gradually lowering th e

    mean

    sea

    level

    values.

    A

    brief

    description

    of

    the

    data

    follows:

    ·Cavern number

    i s

    shown on Figures 5

     base

    map), and 13

     a ir photo)

    -Date constructed indicates

    time of

    leaching,

    but does not

    include

    workovers, etc performed subsequently.

     

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      WEST HACKBERRY CAVERN GEOTECHNICAL PARAMETERS

    DataCurrent to 6105191

    Cavern

    Date

    Constructed

    Cavern

    Volume,

    MMB

    Top

    Caprock

    Top

    Salt

    Casing

    Seat

    Top

    Cavern

    BottomCavern,

    Dale

    Cavern

    Height

     H

    Diameter

     D

    HID

    Nearest

    Cavern

    Pillar

    Thlckness P PID

    Rool

    Thickness

     B

    Distance

    toDome

    BID Edge E

    EID

    Distance

    To Property

    Line

    BH

    Eleva

    198

    6

    1946 8.8

     1598

      1949 2582 3249 3390 01191

    141

    662

    0.21

    9 331 0.50

    1300 1.96 480 0.73

    350

    5.2

    7

    1946

    13.1

     1551

      1992 2393 2552 3494 01191

    942 315

    2.99

    6 609 1.93

    560 1.78 1650 5.24

    189 4.3

    8 1946 10.3

     1515

     2035

      2337 2450

     3449 12190 999

    272 3.67

    9

    149 0.55

    415 1.53 1700 6.25

    239

    13

    9 1947

    9.8

      1550

      2100 2525 .,.3213

      -3555,02191

    342 454

    0.75

    8

    149 0.33

    1113

    2.45

    1200

    2.64

    744

    11.

    11

    1962 8.6

      1529 2085 2790 -2951

      3756

    2 9

    804

    276

    2.92 108 567 2.05

    866 3.13 2500 9.06

    349

    10.

    101

    05181-1 2 83

    11.2

     1609 2050

     2434

     2555

     4440

    03191

    1885

    206

    9.15 103 397 1.93

    505 2.45 2600 12.62

    735 18.

    102

    02182-11184

    11.1  1621

      2063

      2440

     2628

     4498 03191

    1870 206

    9.08 103

    448 2.17

    565

    2.74

    2210 10.73

    122

    15

    103 05181-01184

    10.4  1558

      2038 2432

      2667

      4423 01191

    1756 205

    8.57 101 397

    1.94

    629

    3.07 1900 9.27 746 16.

    104

    05181-02184

    11.5 1561

      2076

      2450 2625

      4546 2 9 1921 206 9.33 102 450

    2.18

    549

    2.67

    3000

    14.56

    101

    17

    105

    01181-01184 11. 5

      1647

     2058 2458 2640

      4609

    2 9 1969

    204

    9.65

    104

    492

    2.41

    582

    2.85

    3000

    14.71

    641

    17

    106

    01184-08187

    11.3

     1660

     2065 2402 2556   4346 2 9 1790 212

    8.44

    104 492 2.32 491 2.32 1560

    7.36 154 16.

    107

    07181-07184

    11.5

     1608

     2058 2473 2585

     4556 12190

    1971

    204

    9.66

    103 470 2.30 527 2.58 1510

    7.40 149 14.

    108

    02182-12184 11.5  1664

     2053 2420 2596

    -4440,01191 1844

    212 8.70 112 513 2.42

    543 2.56

    1700

    8.02

    144 7.5

    109

    03184-11185 12. 0   1606

     2057

      2469

     2563  4644 12190

    2061 204.

    10.10

    9

    386 1.89 526 2.58 1000

    4.90

    820

    9.3

    110

    02182-03185 11. 2  1683

     2072 2430 2567

     4568

    03191

    2001 200

    10,01

    111 520 2.60

    495

    2.48

    400 2.00 206

    6.7

    111

    01182-04188 10.6   1980

     2180 2534 2622

    -4596,01191 1974 196

    10.07 110 520

    2.65

    442 2.26

    500

    1.53 100

    6.9

    112

    09183-01187

    11.4

      1650

     2050 2437 2562

      4532 2 9

    1970

    203

    9.70 108 513 2.53 512

    2.52 1800 8.87 157

    7.9

    113

    07182-06185 12. 2

     1920

      2113

      2772

     2827

      4692 12190

    1865

    216

    8.63

    114 518

    2.40 714 3.31 500

    2.31

    106

    6.2

    114

    09182-09185

    11.3

      1668

      2073 2380 2520

      4549 2 9 2029 200

    10.15 113 518 2.59 447 2.24

    1000 5.00

    213

    6.1

    115

    02184-06187

    11.8  1713

     2073 2450 2540

      4634 2 9

    2094

    201

    10.42 107 478 2.38 467 2.32

    900

    4.48

    636

    7.7

    118

    07182-09185

    11.5

     1773

     2088 2520 2840

     4718 12190

    2078

    199

    10.44

    114 542 2.72 552 2.77

    1100 5.53

    180 6.9

    117

    06185-09188 12.7   1594

      2051

      2412 2560

      4609 06190

    2049

    211

    9.71 108

    421

    2.00

    509

    2.41

    2100 9.95

    241 13.

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    FIGURE 12 GENERALIZED CAVERN CONFIGURATIONS WEST HACKBERRY SPR SITE

     0»

    I

    6  z

    NI

    9 11

    101

    ~

    103

    104

    105

      ~

    ..

    sw

     

    500

    a

    11III

    N.llL

    S

     

    2500

    3000

    I

    I

     

    =I 3000

     

    I

    8.6 9.8

    X 3500

    3346

    FT

     

    .-

     

    =I

    3500

    ti

    01/91),

    3450

    FT

    3420

    FT

     01/91)

     12190

    3540

    FT

    W

     02191

    0

    I LEGEND

    I

    3724 FT

     02191

    4000

    8.6 • Csvsm volums million bsrrels

     

    =I 4000

     3363 • OlllbrtneInlerfsC8deplhsnd dsle

    0

    200 400 600 800 1000 1200

    4500

    I

    CAVERN WIDTH

    I

    4181 FT  03191). 4368;; ;;3/91

    4356

    FT

     01191

    4500

    4518

    FT

     02191

    4700

    4700

    \:.I,

    CIt

    2300 E

    1

    2300

    106 107 108 109 110 111 112 113

    11

    4

    115 116 117

    2500

     

    .

    2500

    4500

    3500

    4000

    3000

    4036 FT  02191

    4224FT

     12190

    3761 FT 12190 4339 FT  02191

    4179

    FT

     02191

    4424

    FT

     12190 3928

    FT

     03/91)

    FT

     01191

    3821

    FT

     01/91)

    4528

    FT  12190

    3950 FT 02191

    4554 FT  12190 1 4900

    4900 [

    4500

    3000

    t-

    I i l l 2. 111 51

    .11 5 .

    112.0. 1i1O:9.

    110.6

    X 3500

    t-

    Il

    W

    0

    4000

    TA01l1601 ZJ

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    •   ...  _

      _.

    _

    ••

    _ _ ~ , •• •

    __

    ._ , .

    __

    ._

    ••• __

     

    __ ..

    __

    ••

    _ __  . __ __

    •• •

     

    . _ ••

    • ••

    _

    _ • _ ......  

    _ ,

     Cavern

    volume

    , in millions

    of barrels,

    i s usually

    about

    10 larger

    than the volume

    of

    stored material, allowing for brine in th e cavern

    bottom.

    ·Top

    of

    caprock

    and

    sal t

    respectively, are

    the

    uppermost

    surfaces of

    those

    units .

    ·Casing

    seat · and ·cavern

    top

    (or bottom)

    is

      e l f ~ e x p l a n a t o r y

    ·Cavern

    Height  H)

    i s  the distance

    from

    cavern top to bottom.

    ·Diameter  D) is the cons truc ted diameter, Which is an idealized

    (average) cylinder diameter that

    would

    correspond to the f inal

    cavern

    volume

    with

    the

    given height.

     H/O is

    the rat io of the cavern heigh t to the constructed diameter,

    providing

    a measure

    of

    th e

    cavern

    shape.

    ·Pi l lar thickness (P)· is t he thi ckness of

    the

    pi l lar

    of

    sal t between

    a cavern

    and

    i ts nearest neighbor.

     P/O is the

    rat io

    of the

    pi l lar

    thickness and the const ructed

    diameter,

    providing

    a relative measure of mechanical integrity.

     Roof thickness  B) i s

    th e distance between th e top of the

    cavern and

    the

    top of sal t .

     B/O is the rat io

    of

    the roof thickness to the const ructed

    diameter,

    providing a

    measure

    of mechanical integrity.

     Distance

    to

    dome

    edge

    (E)

    is

    the est imated

    distance

    between

    the

    cavern and the

    outside

    edge of dome sal t .

    ·E/O is the

    rat io

    of

    the distance

    to

    th e

    edge of dome to

    th e

    constructed diameter , providing

    a measure of

    mechanical integrity.

    ·Distance to

    property

    l ine is the closest

    distance between

    the

    cavern

    edge

    and the SPR property l ine.

     BHF Elevation

    is

    the

    bradenhead

    flange

    elevation

    in

    1988,

    rounded

    to

    0.1 f t .

    The values shown in Table 2

    ref lec t

     the very

    conservative design

    approach used throughout the SPR system, espec ia ll y for

    Caverns

    W 101

    117. The

    preexisting

    caverns (W 6-11) do not follow those same

    guidelines, of course,

    but

    there have

    been no s tabi l i ty

    or safety issues

    with them.

    Cavern

    Shapes

    Figure 12 s w ~ current cavern shapes by best estimates.

    Caverns

     

    6-11 are

    quite

    well

    mapped, having

    been sonar

    surveyed when

    fi l led only

     6

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    V e r t i c a l ai r phot o

    cavern locations.

      a1 s ur f ace features

    showing

    p r n ~ 1 12 000.

    10   y 90 sca e

    37-38

      ~

    eproduced f rom

    best

    available copy

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    with

    b rin e . However

    data

    used

    to compile cavern

    shapes

    for W 101-117

    were derived

    from

    s on ar r ec or ds

    obtained

    d ur in g c av er n

    development,

    an d

    from o il f i l l an d in te rfa c e

    records

    obtained

    during

    leach an d

    f i l l

    operations. Because sonar

    recordings

    could

    not

    be obtained through oi l

    the o il f i l l vs

    volume

    data r e s u l t in axisymmetric cavern

    shapes

    on the

    drawings,whereas

    in

    fact

    they

    are N on et he le ss , t he

    data

    an d sonar

    r ec o rd s o bt ai ne d

    d ur in g c av er n

    development

    show

    v er y s ym me tr ic al c av er n

    shapes

    fo r the

    new

    caverns  W

    101-117),

    suggesting there is

    a

    general

    absence

    o f s ig n if ic a nt

    mineralogical or s t ru c tu r al e f fe c ts

    t h a t

    have

    re s ulte d in

    p r e f e r e n t i a l l y

    oriented

    caverns. Cavern

    W 111

    is

    a

    notable

    exception, with pronounced

    assymetry

    in

    the

    to p 2 f t .

    Cavern

     

    6.is

    somewhat

    s au ce r- sh ap ed , w i th

    a

    diameter

    o f nearly 12

    f t an d a height of about 14

    f t .

    The

    aspect

    r a t i o o f 0.21   using

    the

    constructed diameter) is the lowest in the SPR system an d there has been

    c on ce rn o ve r possible

    collapse o f

    th e cavern roof.

    However

    the

    twelve

    plus

    year h is to ry o f SPR

    operations

    combined

    with the former 32-year

    hi st ory

    o f O l i n s brine

    feedstock

    e x tra c tio n at tests to i t s

    long-term

    s tabi l i ty . The September 1978 blowout and f ire

    a t

    t h i s cavern was

    unrelated to the

    low

    aspect rat.io [Ref. 9].

    Cavern

     

    9

    ha s

    two lobes separated by a 6 0 f t neck at

    about

    337

    f t

    depth.

    The

    sa l t ledges

    here

    are

    a

    pot ent i al source for sa l t fal ls which

    could

    damage hanging

    s t r i n g s

    but

    t h i s

    has

    not occurred.

    Caverns

     

    101-117 are for the most p a r t

    unremarkable,

    an d

    s i g n i f i c a n t

    deviations from

    design

    shapes

    have

    not

    occurred. Caverns W

    101, 102, and 1 3 have s l i g h t l y

    wider

    tops

    than

    an

    id e a l

    tapered cylinder,

    a nd Ca ve rn

    W 111

    has

    a

    small ledge, o r s ho ul de rs , near

    the

    top.

    The

    s ma ll d ia me te r

    above

    t he s ho ul de rs

    was

    d e lib e ra te ly

    caused

    by

    f i l l ing

    with

    o il d ur in g the las t

    l ea ch in g s ta ge

    to prevent

    fu rth e r growth.

    T he se m in or

    departures

    have

    no

    bearing

    on

    cavern

    operation

    an d

    present

    no

    sa fe ty

    or

    i n t e g r i t y concerns.

    Cavern

      113 was constructed

    with

    the las t

    cemented

    casing s e t 27 f t deeper than the other Phase II wells. This re su lte d

    in

    a

    s l i g h t l y deeper cavern top

    and

    th e cavern height

    was reduced somewhat

    so t hat the

    nominal

    to p an d

    bottom

    are

    at 28 and 47

    f t

    re sp e c tiv e ly

    [Ref. 10].

    Cavern

    112

    ori gi nal l y

    was

    to have

    been

    constructed j us t west o f Cavern

    113 b ut e xp lo ra ti on

    revealed

    a re -e n tra n t

    an d f a u l t st ruct ure in the sa l t

    face

    along

    the

    north side of the dome resul t i ng in i n s u f f i c i e n t distance

    to the edge of

    sa l t

    an d requiring t hat th e cavern be re -lo c a te d

    south

    of

    Cavern

    11

      F igure 13 ).

    Additional

    Cavern

    Space

    In

    the event

    i t would become

    n ec es sa ry t o abandon

    one

    or

    more o f

    the

    exi st i ng

    caverns,

    or

    to t ransfer o il

    for some

    reason,

    there

    is

    probably

    room for another cavern jus t

    outside the DOE property

    n o rth e a st

    of Cavern

      11 an d s ou th ea st o f abandoned

    Olin

    Caverns 3- 4

      coal esced) .

    To v e rify

    t h a t s u f f i c i e n t pi l lar

    space

    e x i s t s

    at this

    location,

    the

    former Olin

    caverns

    would

    need to be ope ned an d sonar

    surveyed.

    Space fo r

    two other

    caverns also

    e x i s t s

    immediately

    south

    of

    Cavern W

    106,

    an d

    southwest of

     

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    Caverns

    WH 108 and

    117,

    but neither

    of

    these l ocat ions a re

    presently

    on

     O property.

    Similarly, off

    of  O property,

    j us t

    west

    of

    Caverns 104, 102,

    and 107

    (Fig. 13), there are p ossib le locations where storage caverns

    could

    be

    constructed,

    with

    cavern

    roofs

    at

    -2500

    f t

    or

    deeper.

    These

    depths

    have

    . already

    led to

    greater creep/subsidence rates a t West Hackberry. and th is

    fact

    combined with the already low elevation would have to be reconciled.

    With th e exist ing cavern volume

    to ta l

    exceeding 275

    million

    b arre ls in

    36 exist ing and five abandoned

    caverns,

    the

    dome is approaching the

    reasonable upper

    l imit f or s to ra ge . All

    of the

    above

    considerations

    would

    require

    study

    prior to

    serious thought of expansion.

    New

    Olin Caverns 12., 13. 14

    The Olin Chemicals Group completed th re e b ri ne wells in 1977 to

    provide feedstock for i ts ch1or-a1kal i operat ions a t Lake Charles.

    SPR

    Cavern

    116

    is

    th e

    closest

    adjacent

    cavern

    to

    th is

    group,

    750

    f t

    northeast

    of Olin  12 (Figs. 5. 13). Figure 14 shows

    the

    pi l la r thickness between

    the two

    caverns

    to be more

    than

    500 f t  

    All

    three

    Olin well s were

    ident ical

    in

    design, but

    minor

    var ia ti on s i n

    tubing and cavern depths occur. The three wells produce brine which

    consumes sa l t a t a rate of

    about

    one million barrels  volume) annually.

    Total cavern volume was

    12.72

    MM

    (from

    sonar) in

    O c t o b ~ r

    1989 and 1991

    year-end estimates are 15.5

    MM

    1989 sona r r ecords show th e caverns

    as elongated

    cylinders

    approximating

    baseball

    b ~ ~ ~ · .in shape,

    with

    th e large dimension a t the

    bottom. The

    highly

    s Y m m e ~ i c a shapes are somewhat questionable because

    the sonar survey was performed through two

    hanging

    str ings. At that time

    the to ta l volume was 12.7

    million barrels ,

    with maximum diameters

    of 188,

    178,

    and

    173 f t

    for Caverns

    12 ,

    13, and

    14 , respectively.

    All three wells

    had

    operated

    in

    the

    bottom

    injection

    - top

    recovery

    mode, which produces

    th e observed-shape

    caverns.

    A December 1989 Olin

    l e t te r to

    th e

    Louisiana

    Office of

    Conservation,

    Injection and.Mining Division, indicated that i ts

    1989 sonar logging showed the

    inter-cavern

    distance between two caverns

    was 205 f t So

    as

    to not exceed

    the

    200 f t separation s pe cif ie d in

    Statewide

    Order  29-M, Olin requested a change in

    i t s

    leach extraction

    procedure for two of i t s wells, with the

    apparent

    intent of al ter ing the

    shapes

    to more regular cylindrical forms.

    Because

    the

    wells

    are

    spaced

    390

    f t

    apart,

    and

    because the

    maximum

    diameters

    are already

    being

    approached

    in two of

    th e

    three caverns there

    is a l imit to

    how

    much more extraction ,of brine

    is

    ,possible, perhaps as

    much as twice the current

    to ta l

    or

    roughly twelve

    years.

    a t current rates.

    Olin management

    personnel

    indicated

    they

    had no

    immediate plans

    for

    expansion to o.ther·

    locations.

    40

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    · 5

    Figure 14

    O in Brine Caverns;

    October 1989

    Sonar Surveys

    Cavern locations are

    shown on Fig. 7

    SPR

    Cavern 116 shown

    In two dimensions on

    this cross section

    5 08 =Volume, In

    Million Barrels

      -2860

    -3036

    5 08

    3 59

    4 05

    1 4275

    1 4560

    -4660

    I

    4500

    ·4

    t ·3

    LL

    C

     

    J

    -

     

    C 3500

     5000

    o

      200

     ... ...

    so

    150 250

    FEEi

    41

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     x USA

    Caverns 1-11

    Oxy

    USA

    I nc . ope ra te s

    11 storage caverns

    containing

    a

    variety

    of LPG

    products   Figs. 5, 15 ; Table 3 . Total storage volume in

    m i d ~

    was

    sl ightly

    more than 16 million barrels ,

    with individual

    caverns ranging

    from

    0.86 to

    2.77 MMB.

    Useable

    storage volume is approximately 14 MMB.

    Cavern

    12

    has been

    permitted, and once constructed will

    produce

    brine

    for

    several years prior to product

    storage; i ts location

    is

    north of

    and

    centered between caverns 1

    and

    3.

    TABLE 3

    OXY

    USA

    CAVERN DATA:

    WEST IlACKBERRY

    LA

    Cavern

    Volume,

    Product

    Casing

    Tota l

    Diameter ,

    Diameter .

    Las t

    MMB

    Seat

    Depth

    Maximum

    Constructed

    Sonar

    ox-

    1

    1 . 61

    Raw

    -2252

    -2855

    249

    138

    17 May 91

    ox-

    2

    0.98

    Citco

    nC-4

    -:2254

    -2891

    244

    105

    19 Fe b

    90

    Ox-

    3 0.86

    Ci tco

    nC-4

    -2287

    -2873

    261

    102

    14

    Dec

    88

    ox-

    4  

    Ci tco

    iC-4/BB

    -2343

    -3030

    258

    108

    27

    Mar

    90

    ox-

    5

    2.77

    Propane

    -2366

    -3361

    248

    148

    31 Mar

    89

    Ox-

    6 1 .

    66

    Ethane

    -2352

    -3101

    181

    126

    16

    Apr 88

    ox-

    7

    0.89

    Propylene

    -2328

    -3175

    115

    87

    08 Mar

    90

    ox-

    8

    1 . 53

    fg B utane

    -2347

    -3106

    176

    120

    30

    Aug

    89

    ox-

    9

    2.00

    Butane

    -2345

    -3091

    273

    139

    09

    Apr

    90

    Ox-l0

    1.

    35

    fg Butane

    -2561

    -3583

    144

    97

    03

    Aug

    90

    Ox-l l .

    1. 40

    Propane -2566

    -3383

    145 110 15 Apr

    88

    Cavern shapes as revealed on

    sonar

    .records are a l l very symmetrical

     Fig.

    15 , at test ing to th e uniformity and purity of sal t and the general

    lack

    o f non -hal it e const it uent s

    that

    lead. to assymetry.

    Oxy

    Cavern

    5

    is

    closest to

    SPR

    Cavern   112; the

    web

    thickness between them

    is

    700

    f t a t

    th e

    closest

    approach a t -3150 f t . Using constructed

    diameter

    values

     average cylinders , the average pi l lar thickness increases to 780

    f t .

    Subsidence over. the

    Oxy cavern f ield

    has

    been

    monitored by way of

    repet i t ive leveling on some six

    occasions

    in

    the las t

    seven years. The

    data,

    while

    not

    subjected

    to

    de ta i led sc ru t iny ,

    show

    very l i t t l e i f

    any,

    lowering

    .of surface elevations. In view

    of

    th e

    subst an t ia ll y l es s

    storage

    volume 6.6 of

    the

    SPR

    to tal spread

    out over 140 acres, combined

    with

    substantial ly

    more sha llow cave rns average depth - 3132 f t a negligible

    amount of subsidence is not unreasonable to expec t. The effect of cavern

    depth on subsidence

    is explained further

    in Appendix

    C

    42

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    Ox-1

    Ox 2

    Ox-3

    Ox 4 Ox 5

    Ox-6

    Ox 7 Ox 8

    Ox-g

    Ox 1 Ox

    -2000 .

    =-----=r/--

    Caprock

    -2200

    I

     

    E   Nis E  

    NIS E IW

    NIS

    E IW NIS EIW

    NIS

    -2400

    -2600

    -

    I

     

    \

     

    \

     

    \

     

    \

     

    \

     

    \

     0 89

    Q

    Q

    -2800

    l

    LL

    w

    I

     

    [

     

    1

    -

      111 \

    / \ J 1 1

    I

    1

    I 1.53

    :

     s:

    -

    o

    -3000

    Q

    I

    /

     

    U l

     

    1 1

    11.40

    C

    . I

    Legend

    -3200

    I

    =

    Cavern Volume,

    I

    I

    r

    /1.35

    Million Barrels

    -3400

    l

    I

    0

    100

    200

    300

     

    . -. 1

      150

    250

    FEET

    -3600 l

    I

    Cavern Locations are

    .shown on Fig. 7

    -3800

    Figure 15 Oxy USA Cavern Dep ths and Configurations;

    Composite

    section not a

    cross

    section.

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     Subsidence

    Subsidence p o t e n t i a l was d i s c u s s e d .i n the 1980

    s i te

    c h a r a c t e r i z a t i o n

    r e p o r t an d

    acknowledged to be

    a

    concern.

    The

    p r i n c i p a l

    causes

    o f

    subsidence were

    i dent i f i ed as f l ui d

    withdrawal o f

    water, gas,

    an d oi l ,

    cavern c o l l a p s e , an d cavern creep closure.

    Ten

    years o f

    experience an d numerous

    observations

    can.now put these

    an d o t h e r subsidence sources into accurate perspective, an d provide

    numerical bounds on

    each.

    The

    p r i n c i p a l

    sources and.

    average values,

     in

    order

    o f importance,

    are:

    Subsidence

    Category

     UY :

    a) cavern creep

    closure

    -0.20

    b)

    f l ui d withdrawal,

    Black Lake)

    -0.08

     ?

    c)

    regi onal

    subsidence

    0.010

    d)

    sea

    level

    r i s e 0.0075

    e) other

    subsidence/collapse

    minor

    f) cavern collapse none

    a t

    W

    H

    Understanding these

    sources makes

    i t

    possible tO,estimate future

    elevation

    trends, an d to enable

    remedial measures

    to be planned, where

    appropriate. Examinatior th e values

    shows t h a t

    s u bs id en c e i nd uc ed by

    c av er n c re ep cl osure OVE the overall n um eric al b ud ge t, a lm os t to

    the p o i n t

    o f negating th, sources.

    However, each

    is

    discussed

    b r i e f l y ,

    in

    reverse

    o rdE . impor t ance ,

    to

    show

    how i t af f ect s

    th e

    SPR

    si te :

    Cavern

    collapse

      f)

    h as o cc ur re d over numerous s o lu t io n -m i ne d c av er ns

    in Texas and Louisiana,

    generally

    r esul t i ng from uncontrolled

    brining

    an d

    e ro sio n i nt o the overlying caprock

    and/or

    overburden

    [

    Refs. I I ,

    12].

    Hindsight

    in

    each case u su al ly r ev ea ls t h e c ir cu m st an ce s t hat le d to

    f a i l u r e .

    .

    Even though

    today s solution

    m1n1ng

    t ec hn ol og y c an

    avoid the

    problems

    t h a t previously

    plagued

    the

    industry,

    West

    Hackberry ha s

    some

    older

    caverns adjacent

    to

    the

    SPR

    property

    about

    which l i t t l e is known,

    an d

    some

    p o t e n t i a l fo r

    ins tabi l i ty

    may e x i s t . Abandoned Olin Caverns

    I ,

    2, 3, 4,

    an d

    5

    have

    not

    been sonar-logged

    an d

    the

    i nt er nal

    dimensions

    are

    u n c e r t a i n .

    1989 volume

    estimates [Ref.

     1 3]

    based

    on

    O li n p r od u ct io n

    s ta t i s t i cs

    showed t he fo ll ow in g

    values:

    Olin

      1 & 2 -

    147.7

    dia x

    600

    h t;

    1.83 MM vol.   each)

    Olin  

    3   4 -

    179.8

    dia x

    600

    h t;

    2.71 MM vol.   each)

    Olin  

    5 -

    80.2 dia

    x

    600 h t; 0.54 MM vol.

    44

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    These dimensions are the cylindrical forms

    of known

    cavern heights

     constructed d iamet er s , u si ng the

    assumed

    maximum volumes based on

    conservative

    estimates

    of

    production

    obtained

    from

    Olin Corporation

    [Ref.

    14]. The maximum

    cavern diameters are assumed

    to

    be

    wider; i t is known for

    example,

    that Caverns 1,2 and 3,4 ar e coalesced

    [Ref.

    1].

    One

    conclusion

    based on

    th e above estimates was

    that the map  Fig. 6.12

    in the 198 report probably showed th e cavern extents to be somewhat larger

    in maximum d iame te r t han

    actual ly

    exists . No doubt

    th e

    early

    estimates

    were

    conservative intentionally and probably based on history,

    as revealed

    in the

    ultrawide former

    Olin Caverns

    6

    and 9.

    Although

    Olin Caverns 1-5

    have

    apparently

    been stable for some 4 yrs, uncertainty re.mains.

    Other

    subsidence/collapse  e

    result ing

    from

    mining of sa l t

    or

    sulphur

    has

    occurred

    a t numerous other domes in Texas

    and Louisiana, but

    mining is

    absent a t

    West Hackberry.

      o w e ~ e r cracking

    of

    the

    SPR

    brine pond

    l iner

    in

    1987-1988 may be related to

    local

    subsidence caused

    by cation

    exchange

    reactions in the

    underlying c layey

    soils , upon

    interact ion with

    the

    brine

    in

    ground

    water

    [Ref.

    15].

    This

    l a t te r

    aspect

    is

    discussed

    further

    under

    Environmental Considerations.

    Sea

    Level Rise  d is

    occuring

    in

    the

    Gulf of. Mexico a t a rate nearly

    double th e g lob al rate.

    The mean

    r ise

    in

    the Gulf

    is 0.23

    cm/yr

     0.0075

    f t /yr an a lmost

    ins ignif icant

    amou