addendum to safety data sheets water sds.pdf · first aid measures. 4.1. description of first aid...

ADDENDUM

TO

SAFETY DATA SHEETS

This addendum is part of the Safety Data Sheets referred to below.

This addendum should be stored with and read in conjunction with the Safety Data

Sheets.

Product Description

Product Name: ENV2.96 – Backpack Lab Water Test Kit

Recommended Use: Water Testing

Manufacturer: Hanna Instruments Inc.

584 Park East Drive, Woonsocket, Rhode Island, USA 02895

Australian Supplier: Southern Biological

1/44 Rushdale Street, Knoxfield, Victoria, 3180

www.southernbiological.com

Phone: (03) 9753-3896

Emergency Contacts: Southern Biological ph (03) 9753-3896

Date Issued April 2016

Document List

Product Name Document Type Number of Pages

ALKALIAZIDE

Alkali Azide Reagent

SDS 7

CALMAGITE10

Calmagite Indicator

SDS 3

DECHLORIN

Dechlorinating Reagent

SDS 3

HI3810-0

Dissolved Oxygen Titrant Solution

SDS 4

HI3811-0

Reagent for Alkalinity Testing

SDS 3

Continued Next Page

Continued from previous page

Product Name Document Type Number of Pages

HI3812-0

HI 3812-0 EDTA Solution

SDS 3

HI3818-0

Solution for CO2 testing

SDS 3

HI3820-0

Solution for acidity testing

SDS 3

MANGANOUS

Manganous Sulfate Solution

SDS 4

SULPHURIC

SULFURIC Acid Solution

SDS 5

Hanna Instruments S.R.L.HI3811-0 - Acid titrant solution

Revision nr.1 Dated 11/29/2016Printed on 11/29/2016Page n. 1 / 9

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EPY 9.2.8 - SDS 1003

Safety data sheet according to U.S.A. Federal Hazcom 2012 and Canadian RegulationSOR/88-66

SECTION 1. Identification of the substance/mixture and of the company/undertaking.1.1. Product identifier.

Code. HI3811-0Product name. Acid titrant solutionChemical name and synonym. HYDROCHLORIC ACID 0,11%

1.2. Relevant identified uses of the substance or mixture and uses advised against.

Intended use. Acid titrant used in the determination of alkalinity in water samples.

1.3. Details of the supplier of the safety data sheet.

Name. Hanna Instruments S.R.L.Full address. str. Hanna Nr 1District and Country. 457260 loc. Nusfalau (Salaj)

RomaniaTel. (+40) 260607700Fax. (+40) 260607700

e-mail address of the competent person.responsible for the Safety Data Sheet. [email protected]

Product distribution by: Hanna Instruments Pty Ltd – 18 Fiveways Blvd Keysborough, Vic 3173, Australia Technical Service Information: +613 9769 0666 (8.30am-5pm Mon-Fri)

1.4. Emergency telephone number.

For urgent inquiries refer to. AUSTRALIA Emergency Contact: +612 9037 2994 (Chemtrec 24 Hr. Emergency) INTERNATIONAL Emergency Contact: +1 7035273887 (Chemtrec 24 Hr. Emergency)

SECTION 2. Hazards identification.2.1. Classification of the substance or mixture.

The product is classified as hazardous pursuant to the provisions set forth in OSHA Hazard Communication Standard (HCS) (29 CFR1910.1200). The product thus requires a safety datasheet. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.

Classification and Hazard Statement.Substance or mixture corrosive to metals, category 1 May be corrosive to metals.Skin corrosion, category 1B Causes severe skin burns and eye damage.

Hazard pictograms:

Signal words: Danger

Hazard statements:H290 May be corrosive to metals.H314 Causes severe skin burns and eye damage.

Precautionary statements:Prevention:

P280 Wear protective gloves, protective clothing, eye protection and face protection.Response:

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water / shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing.



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EPY 9.2.8 - SDS 1003

SECTION 2. Hazards identification. ... / >>

P310 Immediately call a POISON CENTER or doctor.P391 Collect spillage.

Storage:--

Disposal:--

2.2. Other hazards.

Information not available.

SECTION 3. Composition/information on ingredients.3.1. Substances.

The product does not contain substances classified as being hazardous to human health or the environment pursuant to the provisionsRegulation (EU) 1272/2008 (CLP) (and subsequent amendments and supplements) in such quantities as to require the statement.

3.2. Mixtures.

Information not relevant.

SECTION 4. First aid measures.

4.1. Description of first aid measures.Not specifically necessary. Observance of good industrial hygiene is recommended.

4.2. Most important symptoms and effects, both acute and delayed.No episodes of damage to health ascribable to the product have been reported.

4.3. Indication of any immediate medical attention and special treatment needed.Information not available.

SECTION 5. Firefighting measures.

5.1. Extinguishing media.SUITABLE EXTINGUISHING EQUIPMENTThe extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.UNSUITABLE EXTINGUISHING EQUIPMENTNone in particular.

5.2. Special hazards arising from the substance or mixture.HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIREDo not breathe combustion products.

5.3. Advice for firefighters.GENERAL INFORMATIONUse jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous forhealth. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose ofcontaminated water used for extinction and the remains of the fire according to applicable regulations.SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERSNormal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination withself-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

SECTION 6. Accidental release measures.

6.1. Personal precautions, protective equipment and emergency procedures.Block the leakage if there is no hazard.Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) toprevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved inemergency procedures.



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EPY 9.2.8 - SDS 1003

SECTION 6. Accidental release measures. ... / >>

6.2. Environmental precautions.The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up.Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate thecompatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material.Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point13.

6.4. Reference to other sections.Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage.

7.1. Precautions for safe handling.Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into theenvironment. Do not eat, drink or smoke during use.

7.2. Conditions for safe storage, including any incompatibilities.Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s).Information not available.

SECTION 8. Exposure controls/personal protection.

8.1. Control parameters.


8.2. Exposure controls.

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplaceis well aired through effective local aspiration. Personal protective equipment must comply with current regulations.HAND PROTECTIONProtect hands with category III work gloves (OSHA 29 CFR 1910.138).The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear timedepends on the duration and type of use.SKIN PROTECTIONWear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Washbody with soap and water after removing protective clothing.EYE PROTECTIONWear airtight protective goggles (OSHA 29 CFR 1910.133).RESPIRATORY PROTECTIONIf the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with aNIOSH certified filter, whose class must be chosen according to the limit of use concentration (NIOSH 42 CFR 84, OSHA 29 CFR1910.134). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes,mists, etc.) combined filters are required.Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure tothe threshold values considered. The protection provided by masks is in any case limited.If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of anemergency, wear open-circuit compressed air breathing apparatus or external air-intake breathing apparatus. For a correct choice ofrespiratory protection device, see standard NIOSH 42 CFR 84 and OSHA 29 CFR 1910.134.ENVIRONMENTAL EXPOSURE CONTROLS.The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensurecompliance with environmental standards.

SECTION 9. Physical and chemical properties.9.1. Information on basic physical and chemical properties.

Appearance liquidColour colourlessOdour odourless



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EPY 9.2.8 - SDS 1003

SECTION 9. Physical and chemical properties. ... / >>

Odour threshold. Not available.pH. 1.6Melting point / freezing point. Not available.Initial boiling point. Not available.Boiling range. Not available.Flash point. 93 °C. (199,4 °F)>Evaporation rate Not available.Flammability (solid, gas) Not available.Lower inflammability limit. Not available.Upper inflammability limit. Not available.Lower explosive limit. Not available.Upper explosive limit. Not available.Vapour pressure. Not available.Vapour density Not available.Relative density. 1.000Solubility soluble in waterPartition coefficient: n-octanol/water Not available.Auto-ignition temperature. Not available.Decomposition temperature. Not available.Viscosity Not available.Explosive properties Not available.Oxidising properties Not available.

9.2. Other information.Total solids (250°C / 482°F) 0,11 %

SECTION 10. Stability and reactivity.

10.1. Reactivity.

There are no particular risks of reaction with other substances in normal conditions of use.

HYDROCHLORIC ACIDHYDROCHLORIC ACID 37%: Corrosive in contact with metals.

10.2. Chemical stability.

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions.

No hazardous reactions are foreseeable in normal conditions of use and storage.

HYDROCHLORIC ACIDHYDROCHLORIC ACID 37%: Exothermic reaction with: Amines, potassium permanganate, salts of oxyhalogenic acids, semimetallicoxides, semimetallic hydrogen compounds, Aldehydes, vinylmethyl ether, Risk of ignition or formation of inflammable gases or vapourswith: carbides, lithium silicide, Fluorine, Generates dangerous gases or fumes in contact with: Aluminium, hydrides, formaldehyde,Metals, strong alkalis, Sulphides. Risk of explosion with: Alkali metals, conc. sulfuric acid.

10.4. Conditions to avoid.

None in particular. However the usual precautions used for chemical products should be respected.

10.5. Incompatible materials.

HYDROCHLORIC ACIDHYDROCHLORIC ACID 37%: Alkalis, organic substances, strong oxidants and metals.

10.6. Hazardous decomposition products.

HYDROCHLORIC ACIDHYDROCHLORIC ACID 37%: Above decomposition temperature hydrochloric acid fumes may develop.



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EPY 9.2.8 - SDS 1003

SECTION 11. Toxicological information.In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances itcontains, using the criteria specified in the applicable regulation for classification.It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluatethe toxicological effects of exposure to the product.

11.1. Information on toxicological effects.

ACUTE TOXICITY.

LC50 (Inhalation - vapours) of the mixture: Not classified (no significant component).LC50 (Inhalation - mists / powders) of the mixture: Not classified (no significant component).LD50 (Oral) of the mixture: Not classified (no significant component).LD50 (Dermal) of the mixture: Not classified (no significant component).

Carcinogenicity Assessment:7647-01-0 HYDROCHLORIC ACID

IARC:3

SKIN CORROSION / IRRITATION.Corrosive for the skin.

SERIOUS EYE DAMAGE / IRRITATION.Does not meet the classification criteria for this hazard class.

RESPIRATORY OR SKIN SENSITISATION.Does not meet the classification criteria for this hazard class.

GERM CELL MUTAGENICITY.Does not meet the classification criteria for this hazard class.

CARCINOGENICITY.Does not meet the classification criteria for this hazard class.

REPRODUCTIVE TOXICITY.Does not meet the classification criteria for this hazard class.

STOT - SINGLE EXPOSURE.Does not meet the classification criteria for this hazard class.

STOT - REPEATED EXPOSURE.Does not meet the classification criteria for this hazard class.

ASPIRATION HAZARD.Does not meet the classification criteria for this hazard class.

SECTION 12. Ecological information.Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reachwaterways or contaminate soil or vegetation.

12.1. Toxicity.Information not available.

12.2. Persistence and degradability.Information not available.

12.3. Bioaccumulative potential.Information not available.

12.4. Mobility in soil.Information not available.



US

EPY 9.2.8 - SDS 1003

SECTION 12. Ecological information. ... / >>

12.5. Results of PBT and vPvB assessment.

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

12.6. Other adverse effects.


SECTION 13. Disposal considerations.

13.1. Waste treatment methods.Reuse, when possible. Neat product residues should be considered special non-hazardous waste.Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.Waste transportation may be subject to dangerous goods transport regulations.CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

SECTION 14. Transport information.14.1. UN number.

ADR / RID, IMDG, IATA: 1789

14.2. UN proper shipping name.

ADR / RID: HYDROCHLORIC ACID SOLUTIONIMDG: HYDROCHLORIC ACID SOLUTIONIATA: HYDROCHLORIC ACID SOLUTION

14.3. Transport hazard class(es).

ADR / RID: Class: 8 Label: 8

IMDG: Class: 8 Label: 8

IATA: Class: 8 Label: 8

14.4. Packing group.

ADR / RID, IMDG, IATA: III

14.5. Environmental hazards.

ADR / RID: NOIMDG: NOIATA: NO

14.6. Special precautions for user.

ADR / RID: HIN - Kemler: 80 Limited Quantities: 5 L Tunnel restriction code: (E)Special Provision: -

IMDG: EMS: F-A, S-B Limited Quantities: 5 LIATA: Cargo: Maximum quantity: 60 L Packaging instructions: 856

Pass.: Maximum quantity: 5 L Packaging instructions: 852Special Instructions: A3, A803

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code.

Information not relevant.



US

EPY 9.2.8 - SDS 1003

SECTION 15. Regulatory information.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.

U.S. Federal Regulations.

TSCA:All components are listed on TSCA Inventory.

Clean Air Act Section 112(b):7647-01-0 HYDROCHLORIC ACID

Clean Air Act Section 602 Class I Substances:No component(s) listed.

Clean Air Act Section 602 Class II Substances:No component(s) listed.

Clean Water Act – Priority Pollutants:No component(s) listed.

Clean Water Act – Toxic Pollutants:No component(s) listed.

DEA List I Chemicals (Precursor Chemicals):No component(s) listed.

DEA List II Chemicals (Essential Chemicals):7647-01-0 HYDROCHLORIC ACID

EPA List of Lists:313 Category Code:

7647-01-0 HYDROCHLORIC ACID

EPCRA 302 EHS TPQ:No component(s) listed.

EPCRA 304 EHS RQ:No component(s) listed.

CERCLA RQ:7647-01-0 HYDROCHLORIC ACID

EPCRA 313 TRI:7647-01-0 HYDROCHLORIC ACID

RCRA Code:No component(s) listed.

CAA 112 (r) RMP TQ:7647-01-0 HYDROCHLORIC ACID

State Regulations.

Massachussetts:7647-01-0 HYDROCHLORIC ACID

Minnesota:7647-01-0 HYDROCHLORIC ACID

New Jersey:7647-01-0 HYDROCHLORIC ACID

New York:



US

EPY 9.2.8 - SDS 1003

SECTION 15. Regulatory information. ... / >>

7647-01-0 HYDROCHLORIC ACID

Pennsylvania:7647-01-0 HYDROCHLORIC ACID

California:7647-01-0 HYDROCHLORIC ACID

Proposition 65:This product does not contain any substances know to the State of California to cause cancer, reproductive harm or birth defects.

International Regulations.Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:None.

Substances subject to the Rotterdam Convention:None.

Substances subject to the Stockholm Convention:None.

Candadian WHMIS.Information not available.

SECTION 16. Other information.Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Met. Corr. 1 Substance or mixture corrosive to metals, category 1Skin Corr. 1B Skin corrosion, category 1BH290 May be corrosive to metals.H314 Causes severe skin burns and eye damage.

LEGEND:- 313 CATEGORY CODE: Emergency Planning and Community Right-to Know Act Section 313 Category Code- ADR: European Agreement concerning the carriage of Dangerous goods by Road- CAA 112 ® RMP TQ: Risk Management Plan Threshold Quantity (Clean Air Act Section 112®)- CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required to induce a 50% effect)- CERCLA RQ: Reportable Quantity (Comprehensive Environment Response, Compensation, and Liability Act)- CLP: EC Regulation 1272/2008- DEA: Drug Enforcement Administration- EmS: Emergency Schedule- EPA: US Environmental Protection Agency- EPCRA: Emergency Planning and Community Right-to Know Act- EPCRA 302 EHS TPQ: Extremely Hazardous Substance Threshold Planning Quantity (Section 302 Category Code)- EPCRA 304 EHS RQ: Extremely Hazardous Substance Reportable Quantity (Section 304 Category Code)- EPCRA 313 TRI: Toxics Release Inventory (Section 313 Category Code)- GHS: Globally Harmonized System of classification and labeling of chemicals- IATA DGR: International Air Transport Association Dangerous Goods Regulation- IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods- IMO: International Maritime Organization- LC50: Lethal Concentration 50%- LD50: Lethal dose 50%- OEL: Occupational Exposure Level- PEL: Predicted exposure level- RCRA Code: Resource Conservation and Recovery Act Code- REL: Recommended exposure limit- RID: Regulation concerning the international transport of dangerous goods by train- TLV: Threshold Limit Value- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.- TSCA: Toxic Substances Control Act- TWA STEL: Short-term exposure limit- TWA: Time-weighted average exposure limit



US

EPY 9.2.8 - SDS 1003

SECTION 16. Other information. ... / >>

- VOC: Volatile organic Compounds- WHMIS: Workplace Hazardous Materials Information System.

GENERAL BIBLIOGRAPHY:- GHS rev. 3- The Merck Index. 10th Edition- Handling Chemical Safety- Niosh - Registry of Toxic Effects of Chemical Substances- INRS - Fiche Toxicologique (toxicological sheet)- Patty - Industrial Hygiene and Toxicology- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition- ECHA website

- 6 NYCRR part 597- Cal/OSHA website- California Safe Drinking Water and Toxic Enforcement Act- EPA website- Hazard Comunication Standard (HCS 2012)- IARC website- List Of Lists EPA: Consolidated List of Chemicals Subject to EPCRA, CERCLA and Section 112® of the Clean Air Act- Massachussetts 105 CMR Department of public health 670.000: "Right to Know"- Minensota Chapter 5206 Departemnt Of Labor and Industry Hazardous Substances, Employee "Right to Know".- New Jersey Worker and Community Right to know Act N.J.S.A. - NTP. 2011. Report on Carcinogens, 12th Edition.- OSHA website- Pennsylvania, Hazardous Substance List, Chapter 323

Note for users:The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify thesuitability and thoroughness of provided information according to each specific use of the product.This document must not be regarded as a guarantee on any specific product property.The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the currenthealth and safety laws and regulations. The producer is relieved from any liability arising from improper uses.Provide appointed staff with adequate training on how to use chemical products.

Changes to previous review:The following sections were modified:01 / 02 / 03 / 04 / 07 / 08 / 09 / 10 / 11 / 12 / 13 / 14.

HI 3820-0

Solution

Safety Data SheetAccording to Regulation (EC) No. 1907/2006

OSHA Regulation 29 CFR 1910.1200Canadian Regulation SOR/88-66

Revision Date:

Reason for Revision:

2016-06-01

Reviewed Only

SECTION 1: IDENTIFICATION OF THE PRODUCT AND COMPANY

HI 3820-0 Solution

Determination of Acidity in Water Samples

Product Name:

Application:

USA Emergency Contact Information: 1-800-424-9300 (Chemtrec 24Hr. Emergency)

Technical Service Contact Information: 1-800-426-6287 (8:30AM - 5:00PM ET)+1-401-766-4260 (8:30AM - 5:00PM ET)

International Emergency Contact Information: +1-703-527-3887 (Chemtrec 24Hr. Emergency)

Company Information (USA): Hanna Instruments, Inc.584 Park East Dr, Woonsocket, Rhode Island, USA 02895

E-mail Address: [email protected]

SECTION 2: HAZARD IDENTIFICATION

Non-hazardous product as specified in OSHA Regulation 29 CFR 1910.1200.

Non-hazardous product as specified in Canadian Regulation SOR/88-66.

Non-hazardous product as specified in Regulation (EC) 1272/2008.

SECTION 3: COMPOSITION AND COMPONENT INFORMATION

Aqueous Solution

SECTION 4: FIRST AID MEASURES

Not available

Remove to fresh air. Call a physician if breathing becomes difficult.

Wash affected area with water and soap.

Rinse out with plenty of water for at least 15 minutes. If pain persists, summon medical advice.

Wash out mouth with plenty of water, provided person is conscious. Obtain medical attention if feeling unwell.

After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:

General Information:

SECTION 5: FIRE-FIGHTING MEASURES

Water Spray, Foam, Dry Powder, Carbon Dioxide

Non-combustible. Development of hazardous combustion gases or vapors possible in the event of fire. The following may develop in event of fire: Sodium Oxides

Do not stay in dangerous zone without suitable chemical protection clothing and self-contained breathing apparatus.

Contain escaping vapors with water.

Suitable Extinguishing Media:

Special Risks:

Special Protective Equipment:

Additional Information:

Page 1 of 3

HI 3820-0

Solution



SECTION 6: ACCIDENTAL RELEASE MEASURES

None

None

None

Personal Precautions:

Environmental Precautions:

Additional Notes:

SECTION 7: HANDLING AND STORAGE

No restrictions Keep container closed and protected from direct sunlight. Store at room temperature (+15°C to +25°C).

Handling: Storage:

SECTION 8: EXPOSURE CONTROL/PERSONAL PROTECTION

Maintain general industrial hygiene practice.

As appropriate to quantity handled.

Required when vapors/aerosols are generated. Rubber or plastic Goggles or face mask

Change contaminated clothing. Wash hands after working with substance.

Engineering:

Personal Protective Equipment:

Respiratory Protection: Protective Gloves: Eye Protection:

Industrial Hygiene:

SECTION 9: PHYSICAL/CHEMICAL PROPERTIES

Colorless liquid Odorless

SolubleNA 100°C

NA

~12

1 g/cm³

NA NA

Appearance: Odor: Density at 20°C:

Melting Point: Boiling Point: Solubility:

pH at 20°C: Explosion Limit: Flash Point:

Thermal Decomp.:

SECTION 10: STABILITY AND REACTIVITY

Strong Heating (above boiling point). Stable in the recommended storage conditions.

In the event of fire: See section 5.

The generally known reaction partners of water

Not available

Hazardous Decomposition Products:Conditions to be Avoided:

Further Information:

Substances to be Avoided:

Will not occur.

Hazardous Polymerization:

Page 2 of 3

HI 3820-0

Solution



SECTION 11: TOXICOLOGICAL INFORMATION

Product Toxicity

Quantitative data on the toxicity of this product is not available.

Slight irritations.

Slight irritations.

Hazardous properties cannot be excluded, but are relatively improbable due to the low concentration of the dissolved substance. The product should be handled with the usual care when dealing with chemicals.

Component Toxicity

Skin Contact:

Eye Contact:

Further Data:

Additional Data:

Acute Toxicity: Chronic Toxicity:

Not Available Not Available

Not Available

Potential Health Effects:

Quantitative data on the ecological effect of this product is not available.

No ecological problems are to be expected when the product is handled and used with due care and attention.

SECTION 12: ECOLOGICAL INFORMATION

Further Data:

SECTION 13: DISPOSAL CONSIDERATIONS

Can be safely disposed of as ordinary refuse.Waste Disposal:

Not subject to transport regulations Not subject to transport regulations Not subject to transport regulations

SECTION 14: TRANSPORTATION INFORMATION

Land: Sea: Air:

SECTION 15: REGULATORY INFORMATION

Complies with European Regulations (EC) No. 1907/2006 and No. 1272/2008.Complies with OSHA Regulation 29 CFR 1910.1200.Complies with Canadian Regulation SOR/88-66.All chemical substances in this product are listed on the TSCA Inventory.

NA

SECTION 16: OTHER INFORMATION

Text of phrases under Section 3

THE INFORMATION CONTAINED HEREIN IS BASED ON THE PRESENT STATE OF OUR

KNOWLEDGE. IT CHARACTERIZES THE PRODUCT WITH REGARD TO THE

APPROPRIATE SAFETY PRECAUTIONS. IT DOES NOT REPRESENT A GUARANTEE OF

THE PROPERTIES OF THE PRODUCT.

Revision Information

2013-06-11

Reason for revision:

Legend NA: Not ApplicableND: Not Determined

Revision Date:

Supersedes edition of:

2016-06-01

Reviewed Only

Page 3 of 3

Alkali-Azide Reagent



Revision Date:


2016-11-02

Removed DSD/DPD regulation info



Alkali Azide Reagent

Product Name:

Application:






Causes severe skin burns and eye damage. Harmful to aquatic life with long lasting effects. Harmful of swallowed. Contact with acids liberates very toxic gas.


Pictograms:

H314: Causes severe skin burns and eye damage.H412: Harmful to aquatic life with long lasting effects.EUH032: Contact with acids liberates very toxic gas.H302: Harmful if swallowed.

Hazard Statements:

P273: Avoid release to the environment.P280: Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Precaution Statements:

Skin Corrosion (Category 1A)Chronic Aquatic Toxicity (Category 3)Acute Toxicity, Oral (Category 4)

According to Regulation (EC) No. 1272/2008:

DangerSignal Word:

Classification:


Sodium Azide

Sodium Hydroxide

247-852-1

215-185-5

26628-22-8

1310-73-2

Acute Tox. 2Aquatic Acute 1Aquatic Chronic 1

Skin Corr. 1A

H300, H400, H410, EUH032

H314

> 0.1% - < 1%

> 15% - < 35%

Component: EC No: CAS No: Hazard Class: Phrases: Concentration:

Page 1 of 7





Remove contaminated, soaked clothing immediately and dispose of safely.

Remove to fresh air.

Wash affected area with plenty of water. Remove contaminated clothing. Call in physician.

Rinse out with plenty of water with the eyelid held wide open. Call in ophtalmologist.

If victim is still conscious, make him drink plenty of water, induce vomiting, administer activated charcoal (20-40 g in 10% slurry). Immediately call in physician.

After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:



Water spray, Carbon Dioxide, Dry Chemical Powder, Appropriate Foam.

Non-combustible. Development of hazardous combustion gases or vapors possible in the event of fire. The following may develop in the event of fire: Nitrous Gases.


Contain escaping vapors with water. Prevent fire-fighting water from entering surface water or groundwater.


Special Risks:




Do not inhale vapors/aerosols. Avoid substance contact. Ensure supply of fresh air in enclosed rooms. Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves.

Do not allow to enter sewerage system.

Carefully Take up with liquid-absorbent material. Forward for disposal. Clean up affected area.



Additional Notes:


Work under hood. Avoid generation of vapors/aerosols. Do not inhale substance.

Store at room temperature (+15 to +25°C). Tightly closed in a dry and well-ventilated place. Accessible only for authorized persons.

Handling: Storage:

Page 2 of 7





Type Value Source Type Value Source

Sodium Azide

0.1 mg/m³ BelgiumCeiling 0.26 mg/m³ Canada (Ontario)Ceiling

0.3 mg/m³ Canada (Quebec)Ceiling 0.1 mg/m³ FranceTWA (8hr)

0.2 mg/m³ GermanyTWA (8hr) 0.3 mg/m³ GreeceTWA (8hr)

0.1 mg/m³ HungaryTWA (8hr) 0.1 mg/m³ ItalyTWA (8hr)

0.1 mg/m³ NetherlandsTWA (8hr) 0.1 mg/m³ PolandTWA (8hr)

0.29 mg/m³ PortugalTWA (8hr) 0.1 mg/m³ RomaniaTWA (8hr)

0.1 mg/m³ SpainTWA (8hr) 0.1 mg/m³ UKTWA (8hr)

0.29 mg/m³ USA (ACGIH)Ceiling

Sodium Hydroxide

2 mg/m³ AustraliaCeiling 2 mg/m³ BelgiumCeiling

2 mg/m³ Canada (Ontario)Ceiling 2 mg/m³ Canada (Quebec)Ceiling

2 mg/m³ FranceTWA (8hr) 2 mg/m³ GreeceTWA (8hr)

2 mg/m³ HungaryTWA (8hr) 2 mg/m³ New ZealandCeiling

0.5 mg/m³ PolandTWA (8hr) 2 mg/m³ PortugalCeiling

1 mg/m³ RomaniaTWA (8hr) 2 mg/m³ SpainCeiling

2 mg/m³ UKTWA (15min) 2 mg/m³ USA (ACGIH)Ceiling

2 mg/m³ USA (OSHA)TWA (8hr)

Safety shower and eye wash.

Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier.

Required when vapors/aerosols are generated. Work under hood.

Rubber or plastic Goggles or face mask

Immediately change contaminated clothing. Wash hands and face after working with substance. Work under hood. Do not inhale substance. Avoid generation of vapors/aerosols. Under no circumstances eat or drink at workplace.

Engineering:



Industrial Hygiene:



SolubleNA ND

NA

14

1.40 g/cm³

NA NA




Thermal Decomp.:

Page 3 of 7





Heating Toxic gases or vapors in the event of fire, See section 5.

Acids

Not available




Will not occur.


Page 4 of 7





Product Toxicity


Burns of mucosal membranes.

Burns. Danger of skin absorption.

Burns. Risk of blindness!

Burns in mouth, throat, oesophagus and gastrointestinal tract.

The product should be handled with particular care.

APPLICABLE TO PARTIAL COMPONENT: The following applies to Sodium Azide – as the pure substance:Subacute to chronic toxicity No teratogenic effect in animal experiments. Further toxicological information After inhalation of dusts/aerosols: Severe irritations of: mucous membranes, respiratory tract. Possible damages: pulmonary oedema. Latency time until onset of action. After skin contact: Slight irritations. Danger of skin absorption. After eye contact: Slight irritations. After swallowing: irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract. Systemic effects: CNS disorders, cardiovascular failure, tachycardia, drop in blood pressure, coughing, dyspnoea, spasms, headache, dizziness, nausea, vomiting, collapse, unconsciousness

APPLICABLE TO PARTIAL COMPONENT: The following applies to Sodium hydroxide – as the pure substanceAcute toxicity Quantitative data on the toxicity of this product are not available. Specific symptoms in animal studies: Eye irritation test (rabbit): burns. Skin irritation test (rabbit): burns. Subacute to chronic toxicity Mutagenicity (mammal cell test): micronucleus negative. Bacterial mutagenicity: Escherichia coli: negative. Bacterial mutagenicity: Ames test: negative. No teratogenic effect in animal experiments.

Component Toxicity

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

Further Data:

Additional Data:


Not Available


Sodium Azide

Inhalation - Rat - 37 mg/m³LC50:

Oral - Rat - 27 mg/kgLD50:

Dermal - Rat - 50 mg/kgLD50:

Page 5 of 7




Quantitative data on the ecotoxicity of this product is not available.

APPLICABLE TO PARTIAL COMPONENT: The following applies to Sodium Azide – as the pure substance:Ecotoxic effects: Biological effects: Highly toxic for aquatic organisms. May cause long-term adverse effects in the aquatic environment. Forms toxic mixtures in water, dilution measures notwithstanding. Herbicidal effect. Nematocidal effect. Fish toxicity: L.macrochirus LC50 : 0.7 mg/L /96 h Daphnia toxicity: Daphnia pulex EC50 : 4.2 mg/L /96 h Algeal toxicity: mixed culture of green algae IC50 : 272 mg/L Bacterial toxicity: Photobacterium phosphoreum EC50 : 38.5 mg/L Pseudomonas fluorescens EC5 : 2.6 mg/L

APPLICABLE TO PARTIAL COMPONENT: The following applies to Sodium hydroxide – as the pure substanceBiologic degradation: Methods for the determination of biodegradability are not applicable to inorganic substances. Behavior in environmental compartments: Concentration in organisms is not to be expected. Ecotoxic effects: Biological effects: Harmful effect on aquatic organisms. Toxic effect on fish and plankton. Harmful effect due to pH shift. Forms corrosive mixtures with water even if diluted. Does not cause biological oxygen deficit. Neutralization possible in waste water treatment plants. Fish toxicity: Onchorhynchus mykiss LC50 : 45.4 mg/L /96 h (in hard water).L.macrochirus LC50 : 99 mg/L /48h. Daphnia toxicity:Daphnia magna EC50 : 76 mg/L /24 h.

Do not allow to enter waters, waste water, or soil!


Further Data:


Chemical residues are generally classified as special waste and thus covered by local regulations. Contact local authorities or disposal companies for advice. Handle contaminated packaging in the same way as the substance itself.

Waste Disposal:


UN No.: 1824

8Class (Sub Risk):

Sodium hydroxide solutionProper Shipping

Name:

Packing Group: II

Land (ADR/RID): Sea (IMDG): Air (ICAO/IATA):

1824

8

Sodium hydroxide solution

II

1824

8

Sodium hydroxide solution

II

Marine Pollutant: No



Page 6 of 7




H300: Fatal if swallowed.H314: Causes severe skin burns and eye damage.H400: Very toxic to aquatic life.H410: Very toxic to aquatic life with long lasting effects.EUH032: Contact with acids liberates very toxic gas.








2013-11-25



Revision Date:


2016-11-02


Page 7 of 7

CALMAGITE10

Calmagite Indicator



Revision Date:


2016-06-01

Reviewed Only


Calmagite Indicator

Indicator Reagent

Product Name:

Application:











Aqueous Solution


Not available




Wash out mouth with plenty of water. Obtain medical attention if feeling unwell.

After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:




Non-combustible.


Prevent fire-fighting water from entering surface water or groundwater.


Special Risks:



Page 1 of 3

CALMAGITE10

Calmagite Indicator




Take up with liquid-absorbent material. Clean up affected area and dispose according to local regulation.

NA

None



Additional Notes:


Avoid generation of vapors/aerosols. Do not inhale substance.

Tightly closed. In a well-ventilated place at (+15°C to +25°C).

Handling: Storage:



Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled.



Engineering:



Industrial Hygiene:


Dark red liquid Pungent

SolubleNA ~ 100°C

NA

2.5

1.00 g/cm³

NA NA




Thermal Decomp.:


Heating Carbon monoxide, Carbon dioxide, Nitrogen oxides, Sulfur oxides.


Not available




Will not occur.


Page 2 of 3

CALMAGITE10

Calmagite Indicator




Product Toxicity


Hazardous properties cannot be excluded, but are relatively unlikely because of the low concentration of the dissolved substances, when the product is handled appropriately. The product should be handled with the usual care when dealing with chemicals.

Component Toxicity

Further Data:

Additional Data:



Not Available





Further Data:





Land: Sea: Air:



NA








2013-06-07



Revision Date:


2016-06-01

Reviewed Only

Page 3 of 3

HI 3818-0

Solution



Revision Date:


2016-05-06

Updated section 3


HI 3818-0 Solution

Determination of Carbon Dioxide in Water Samples

Product Name:

Application:











Water

Sodium hydroxide

231-791-2

215-185-5

7732-18-5

1310-73-2

-

Skin Corr. 1A

-

H314

> 99.9%

< 0.1%



Not available





After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:




Non-combustible. Development of hazardous combustion gases or vapors possible in the event of fire. The following may develop in event of fire: Sodium Oxides




Special Risks:



Page 1 of 3

HI 3818-0

Solution




None

None

None



Additional Notes:



Handling: Storage:






Engineering:



Industrial Hygiene:



SolubleNA 100°C

NA

~12

1 g/cm³

NA NA




Thermal Decomp.:





Not available




Will not occur.


Page 2 of 3

HI 3818-0

Solution




Product Toxicity


Slight irritations.

Slight irritations.

Hazardous properties cannot be excluded, but are relatively improbable due to the low concentration of the dissolved substance. The product should be handled with the usual care when dealing with chemicals.

Component Toxicity

Skin Contact:

Eye Contact:

Further Data:

Additional Data:



Not Available





Further Data:





Land: Sea: Air:



H314: Causes severe skin burns and eye damage.








2013-06-11



Revision Date:


2016-05-06

Updated section 3

Page 3 of 3

DECHLORIN




Revision Date:


2016-06-01

Reviewed Only



Determination of Acidity in Water Samples

Product Name:

Application:











Aqueous Solution


Not available



Rinse out with plenty of water for at least 15 minutes.

Summon doctor if feeling unwell.

After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:




Non-combustible. Development of hazardous combustion gases or vapors possible in the event of fire. The following may develop in event of fire: Sulfur Dioxide




Special Risks:



Page 1 of 3

DECHLORIN





Do not inhale vapors/aerosols.

NA

Take up with liquid-absorbent material. Forward for disposal. Clean up affected area.



Additional Notes:


Cannot be stored indefinitely. Tightly closed. In a well-ventilated place. At (+15°C to +25°C).

Handling: Storage:






Engineering:



Industrial Hygiene:



SolubleNA ~100°C

NA

7

1.0 g/cm³

NA NA




Thermal Decomp.:


Heating In the event of fire: See section 5.

Strong oxidizing agents

Not available




Will not occur.


Page 2 of 3

DECHLORIN





Product Toxicity


Hazardous properties cannot be excluded but are unlikely when the product is handled appropriately. The product should be handled with the usual care when dealing with chemicals.

Component Toxicity

Further Data:

Additional Data:



Not Available





Further Data:





Land: Sea: Air:



NA








2013-06-07



Revision Date:


2016-06-01

Reviewed Only

Page 3 of 3

HI 3812-0

EDTA Solution



Revision Date:


2016-04-12

Section 3 updated


HI 3812-0 EDTA Solution

Determination of hardness in water samples.

Product Name:

Application:











Water

Disodium dihydrogen ethylenediaminetetraacetate dihydrate

231-791-2

-

7732-18-5

6381-92-6

-

-

-

-

> 99.9%

< 0.1%



Not available


Wash off with plenty of water.

Rinse out with water.

wash out mouth thoroughly with Water and give plenty of water to drink. In severe cases obtain medical attention.

After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:



Water spray, foam, dry powder or carbon dioxide.

NA


Non-combustible.


Special Risks:



Page 1 of 3

HI 3812-0

EDTA Solution




Do not inhale vapors. Avoid substance contact.

None.

None



Additional Notes:


No further requirements. Tightly closed. Store at room temperature (+15°C to +25°C recommended). Protect from light and moisture.

Handling: Storage:







Engineering:



Industrial Hygiene:


Liquid Odorless

SolubleNA NA

NA

4.5

1 g/cm³

NA NA




Thermal Decomp.:


Strong heating. In the event of fire: see section 5.

The generally known reaction partners of water.

Not available




Will not occur.


Page 2 of 3

HI 3812-0

EDTA Solution




Product Toxicity

Quantitative data on the toxicity of this product are not available.

Slight irritations.

Slight irritations.

Slight irritations.

disturbed electrolyte balance, severe irritations in esophagus and stomach, bloody vomiting. After absorption in large amounts: drop in blood pressure, paralysis symptoms, agitation.

Further hazardous properties cannot be excluded. The product should be handled with the care usual when dealing with chemicals.

Component Toxicity

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

Further Data:

Additional Data:



Not Available


Quantitative data on the ecological effect of this product are not available.



Further Data:





Land: Sea: Air:



NA








2013-06-11



Revision Date:


2016-04-12

Section 3 updated

Page 3 of 3




Revision Date:


2016-11-02




Determination of dissolved oxygen in water samples

Product Name:

Application:






May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects


Pictograms:

H373: May cause damage to organs through prolonged or repeated exposure.H412: Harmful to aquatic life with long lasting effects

Hazard Statements:

P273: Avoid release to the environment.P308+P313: IF exposed or concerned: Get medical advice/attention.


Specific Target Organ Toxicity, Repeated Exposure (Category 2)Chronic Aquatic Toxicity (Category 3)


WarningSignal Word:

Classification:


Manganese (II) Sulphate Monohydrate

232-089-9 10034-96-5 STOT RE 2Aquatic Chronic 2

H373, H411 > 10% - < 25%



Not available





After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:


Page 1 of 4






Non-combustible.




Special Risks:




None

None

None



Additional Notes:



Handling: Storage:



Manganous Sulfate Monohydrate

5 mg (Mn)/m³ Canada (Quebec)TWA (8hr) 5 mg (Mn)/m³ HungaryTWA (8hr)

0.3 mg (Mn)/m³ PolandTWA (8hr) 0.2 mg (Mn)/m³ USA (ACGIH)TWA (8hr)

5 mg (Mn)/m³ USA (OSHA)TWA (8hr)





Engineering:



Industrial Hygiene:



SolubleNA > 100 °C

NA

~ 7

1.0 g/cm³

NA NA




Thermal Decomp.:

Page 2 of 4








Not available




Will not occur.



Product Toxicity


Hazardous properties cannot be excluded, but are relatively unlikely because of the low concentration of the dissolved substances, when the product is handled appropriately. The product should be handled with the usual care when dealing with chemicals.

Component Toxicity

Further Data:

Additional Data:



Not Available





Further Data:





Land: Sea: Air:



Page 3 of 4




H373: May cause damage to organs through prolonged or repeated exposure.H411: Toxic to aquatic life with long lasting effects.








2013-11-25



Revision Date:


2016-11-02


Page 4 of 4

HI 3810-0




Revision Date:


2016-06-01

Reviewed Only


HI 3810-0 Dissolved Oxygen Titrant Solution

Dissolved Oxygen via the Winkler Method

Product Name:

Application:











Aqueous Solution


Not available



Rinse out with plenty of water for at least 15 minutes.

Summon doctor if feeling unwell.

After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:




Non-combustible. Development of hazardous combustion gases or vapors possible in the event of fire. The following may develop in event of fire: Sulfur Dioxide




Special Risks:



Page 1 of 4

HI 3810-0





Do not inhale vapors/aerosols.

NA

Take up with liquid-absorbent material. Forward for disposal. Clean up affected area.



Additional Notes:


Cannot be stored indefinitely. Tightly closed. In a well-ventilated place. At +15°C to +25°C.

Handling: Storage:



Chloroform

10 mg/m³ BelgiumTWA (8hr) 49 mg/m³ Canada (Ontario)TWA (8hr)

24.4 mg/m³ Canada (Quebec)TWA (8hr) 10 mg/m³ FranceTWA (8hr)

2.5 mg/m³ GermanyTWA (8hr) 50 mg/m³ GreeceTWA (8hr)

10 mg/m³ HungaryTWA (8hr) 10 mg/m³ ItalyTWA (8hr)

5 mg/m³ NetherlandsTWA (8hr) 8 mg/m³ PolandTWA (8hr)

10 ppm PortugalTWA (8hr) 10 mg/m³ RomaniaTWA (8hr)

10 mg/m³ SpainTWA (8hr) 9.9 mg/m³ UKTWA (8hr)

10 ppm USA (ACGIH)TWA (8hr) 50 ppm USA (OSHA)TWA (8hr)





Engineering:



Industrial Hygiene:



SolubleNA ~100°C

NA

8.2

1.0 g/cm³

NA NA




Thermal Decomp.:

Page 2 of 4

HI 3810-0





Heating In the event of fire: See section 5.

Strong oxidizing agents

Not available




Will not occur.



Product Toxicity

Quantitative data on the toxicity of this product is not available. Hazardous properties cannot be excluded but are unlikely when the product is handled appropriately.

The product should be handled with the usual care when dealing with chemicals.

Component Toxicity

Further Data:

Additional Data:


Not Available


Chloroform



Chloroform

NTP: Reasonably anticipated to be carcinogenic to humans

IARC Group 2B: Possibly carcinogenic to humans

Quantitative data on the ecological effect of this product is not available. No ecological problems are to be expected when the product is handled and used with due care and attention.






Land: Sea: Air:



Page 3 of 4

HI 3810-0




NA








2013-06-11



Revision Date:


2016-06-01

Reviewed Only

Page 4 of 4

SULPHURIC




Revision Date:


2016-08-16

Removed DSD/DPD Regulation Info



Solution Used for Acidification

Product Name:

Application:

SULPHURIC.15






Additional Product Codes:

Causes severe skin burns and eye damage.


Pictograms:

H314: Causes severe skin burns and eye damage.Hazard Statements:

P280: Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.


Skin Corrosion (Category 1A)


DangerSignal Word:

Classification:


Sulphuric acid 231-639-5 7664-93-9 Skin Corr. 1A H314 > 25% - < 50%



Remove contaminated, soaked clothing immediately and dispose of safely.

Remove to fresh air. Summon doctor.

Wash affected area with plenty of water. Immediately remove contaminated clothing.

Rinse out with plenty of water for at least 10 minutes. Immediately call in ophthalmologist.

Drink plenty of water (if necessary several liters), avoid vomiting (risk of perforation!). Immediately seek medical advice. Do not attempt to neutralize.

After Inhalation:

After Skin Contact:

After Eye Contact:

After Swallowing:


Page 1 of 5

SULPHURIC






Non-combustible. Hydrogen may form upon contact with metals (danger of explosion!). Development of hazardous combustion gases or vapors possible in the event of fire. The following may develop in event of fire: Sulfur Oxides


Product itself is non-combustible. Cool container with spray water from a safe distance. Contain escaping vapors with water. Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.


Special Risks:




Take up with liquid-absorbent material. Clean up affected area and dispose according to local regulation.

Do not discharge into the drains/surface waters/groundwater.

Render harmless: neutralize with diluted sodium hydroxide solution or by throwing on lime, lime sand, or sodium carbonate.



Additional Notes:


Avoid generation of vapors/aerosols. Do not inhale substance.

Tightly closed. In a well-ventilated place at +15 to +25 °C. Keep away from sources of ignition and heat. Accessible only for authorized persons.

Handling: Storage:

Page 2 of 5

SULPHURIC






Sulfuric Acid

1 mg/m³ BelgiumTWA (8hr) 0.2 mg/m³ Canada (Ontario)TWA (8hr)

1 mg/m³ Canada (Quebec)TWA (8hr) 1 mg/m³ FranceTWA (8hr)

1 mg/m³ GreeceTWA (8hr) 1 mg/m³ HungaryTWA (8hr)

0.5 mg/m³ PolandTWA (8hr) 0.2 mg/m³ PortugalTWA (8hr)

0.5 mg/m³ RomaniaTWA (8hr) 1 mg/m³ SpainTWA (8hr)

0.2 mg/m³ USA (ACGIH)TWA (8hr) 1 mg/m³ USA (OSHA)TWA (8hr)


Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled.



Immediately change contaminated clothing and immerse in water. Apply skin-protective barrier cream. Wash hands and face after working with substance. Work under hood. Do not inhale substance. Avoid generation of vapors/aerosols. Under no circumstances eat or drink at workplace.

Engineering:



Industrial Hygiene:



Soluble (development of heat)

NA ND

> 338 °C

< 0.5

1.29 g/cm³

NA NA




Thermal Decomp.:


Strong Heating In the event of fire: See section 5.

Combustible substances, water, metals, metal alloys, alkali metals, alkali compounds, alkali hydroxides, alkali oxides, alkaline earth compounds, alkalis, ammonia, nitrates, sodium carbonate, lithium silicide, halogen-halogen compounds, salts of oxyhalogenic acids, bromates, chromates/perchromates, perchlorates, perchloric acid, permanganates, permanganic acid, organic nitro compounds, nonmetals, nonmetallic oxides, picrates, hydrogen peroxide, nitramide, mercury nitride, ammonium iron (III) sulfate dodecahydrate

Hygroscopic. Has a corrosive effect. Incompatible with metals




Will not occur.


Page 3 of 5

SULPHURIC





Product Toxicity


After inhalation of aerosols: damage to the affected mucous membranes.

Severe burns with formation of scabs.

Burns, corneal lesion.

Severe pain (risk of perforation!), nausea, vomiting and diarrhea.

The product should be handled with the usual care when dealing with chemicals.

APPLICABLE TO MAIN COMPONENT: The following applies to Sulfuric acid, as the pure substance:Specific symptoms in animal studies: Eye irritation test (rabbit): burns. Skin irritation test (rabbit): burns. Toxicological values are not available due to other dangerous properties of the substance. Subacute to chronic toxicity Applicable to partial component(s): Bacterial mutagenicity: Ames test: negative. No teratogenic effect in animal experiments.

Component Toxicity

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

Further Data:

Additional Data:



Sulfuric Acid



Sulfuric Acid

NTP: Known to be carcinogenic to humans


APPLICABLE TO MAIN COMPONENT: The following applies to Sulfuric acid, as the pure substance:Biologic degradation: Methods for the determination of biodegradability are not applicable to inorganic substances. Behavior in environmental compartments: Concentration in organisms is not to be expected. Ecotoxic effects: Quantitative data on the ecological effect of this product are not available. Further ecologic data: The following applies to sulfuric acid: biological effects: harmful effect on aquatic organisms. Harmful effect due to pH shift. Toxic effect on fish and algae. Caustic even in diluted form. Does not cause biological oxygen deficit. Endangers drinking water supplies if allowed to enter soil and/or waters in large quantities. Neutralization possible in waste water treatment plants. Daphnia toxicity: Daphnia magna EC 50 : 29 mg/L/24 h (calculated on the pure substance).

DO NOT ALLOW TO ENTER WATERS, WASTE WATERS, OR SOIL!


Further Data:


Chemical residues are generally classified as special waste and thus covered by local regulations. Contact local authorities or disposal companies for advice. Handle contaminated packaging in the same way as the substance itself.

Waste Disposal:

Page 4 of 5

SULPHURIC





UN No.: 2796

8Class (Sub Risk):

Sulphuric acidProper Shipping

Name:

Packing Group: II

Land (ADR/RID): Sea (IMDG): Air (ICAO/IATA):

2796

8

Sulphuric acid

II

2796

8

Sulphuric acid

II

Marine Pollutant: No



H314: Causes severe skin burns and eye damage.








2013-08-20



Revision Date:


2016-08-16

Removed DSD/DPD Regulation Info

Page 5 of 5

addendum to safety data sheets water sds.pdf · first aid measures. 4.1. description of first aid...

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