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PRESENTER: NIELS DEN HEIJER & ARJAN COENRADIE DATE: JUNE 13, 2017 AD & BIOGAS WINNER 2016 BEST PROCESS OPTIMISATION

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Page 1: AD BIOGAS WINNER 2016 BEST PROCESS OPTIMISATION · Biogas (BIO) New plants ... Revised EIGA DOC 70 released in February 2017 Biogas from anaerobic ... • Award winner 2016; Best

PRESENTER: 

NIELS DEN HEIJER & ARJAN

COENRADIE

DATE: JUNE 13, 2017

AD & BIOGAS WINNER 2016BEST PROCESS OPTIMISATION

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PENTAIR 

OUR CAPABILITIES AND RESOURCES SPAN THE GLOBE

~30,000EMPLOYEES

7CONTINENTS

500+PRODUCTLINES

~100MANUFACTURING

FACILITIES

$6.4 BillionANNUAL REVENUE

(2015)

60+SERVICE CENTERS

2

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PENTAIR 

PENTAIR SÜDMO,Riesbürg, Germany

Hamilton, New Zealand

PENTAIR BEVERAGE SYSTEMSEnschede, The Netherlands

PENTAIR FOOD & BEVERAGE PROCESS SOLUTIONSPENTAIR HAFFMANS

Venlo, The Netherlands

• Production of valves, fittings and integrated valve systems

• Provides sustainable processing solutions to maximize production time and operational flexibility, from design through to the final commissioning of your process system.

• Production of quality control and process equipment for the brewing and beverage industries

• Production of CO2 recovery and biogas upgrading solutions for the brewing / beverage, bio‐ethanol and biogas industry

• Production of the  Beer Membrane Filter (BMF) + cellar solutions

• Production of membranes and membrane modules using proprietary production equipment

• Solutions for process, wastewater treatment

3

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PENTAIR 

PENTAIR’s PROCESS TECHNOLOGIES SBU welcomes UNION

STRONG NEW KEY BRAND TO OUR PORTFOLIO 

4

Building towards a great future!

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PENTAIR 

UNION INTRO

Niels den Heijer

World leading supplier of CO2 plants and purification technologiesOverview of Union Engineering’s business and customer segments

Customer segments, sub-segments and customer examples

Business segments

Energy & ChemicalsBeverage

Breweries & Distilleries (BREW)

Soft Drink Bottlers (SOFT)

Desalination (DESAL)Industrial Gases

Large Industrial Gas (LIG)

Independent Gas (INDEP)

Aftermarket services

Sale of spare parts, components and consumables as well as on-site service & RPM

Modifications

Add-on modifications to existing plants, typically aimed at updating technology and prolonging plant life

Core customer segments Growth segments

Petrochemical (PETRO)

Natural Gas (NG)

Biogas (BIO)

New plants

Union engineers, manufactures, installs and commissions a broad range of plants in all sizes for recovery, extraction, generation and purification of CO2, making the Company a preferred one-stop shop

1) 1)

Gas

Bio‐LNG  Samso – june 13, 2017  –

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Pentair Biogas – upgrading &Stirling Cryogenerator

To create:Bio –LNGLiquid CO2

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PENTAIR  7

Page 8: AD BIOGAS WINNER 2016 BEST PROCESS OPTIMISATION · Biogas (BIO) New plants ... Revised EIGA DOC 70 released in February 2017 Biogas from anaerobic ... • Award winner 2016; Best

PENTAIR TECHNOLOGY

BUILDING SOLUTIONS & “SKID ENCLOSURES”

INTERNAL SIDE VIEW

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PENTAIR 

OVERVIEW – FROM FEEDSTOCK TO VALUE

STANDARDMembrane Solution

WithoutCO2‐Liquefaction

<0,5% METHANE LOSS

ADVANCEDMembrane Solution

WithoutCO2‐Liquefaction

0% METHANE LOSS

ADVANCED plusMembrane Solution

Including CO2‐Liquefaction

0% METHANE LOSS

PRODUCT

PRODUCT

S

BIO‐METHANEGRID INJECTION

BIO‐METHANE CNG

FOODGRADE CO2

LNG

BIO‐METHANEGRID INJECTION

BIO‐METHANE CNG

LNG 

BIO‐METHANEGRID INJECTION

BIO‐METHANECNG

LNG 

PRODUCT

S

PRODUCT

S

CURRENT PENTAIR‐HAFFMANS PORTFOLIO

11

ELECTRICITY LOCAL HEAT

PRODUCT

ANAEROBIC DIGESTION

PRE‐TREATMENT (COOLING, HEATING, H2S REMOVAL)

WASTE STREAMS ENERGY CROPS LANDFILL

CHPCHPHAFFMANS BIOGAS UPGRADING – PRODUCT PORTFOLIOHAFFMANS BIOGAS UPGRADING – PRODUCT PORTFOLIO

WASTE WATER MANURE

FEEDSTOCK

VALUE

9

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PENTAIR 

BIOGAS UPGRADING ‐MEMBRANE GAS SEPARATION

10

Page 11: AD BIOGAS WINNER 2016 BEST PROCESS OPTIMISATION · Biogas (BIO) New plants ... Revised EIGA DOC 70 released in February 2017 Biogas from anaerobic ... • Award winner 2016; Best

PENTAIR 

Low Pressure StageScrubberChillerHeater

Activ Carbon(H2S/VOC)

Low PressureConditioning

High Pressure StageCompression High 

PressureConditioning

Membrane Stage 1 & 21st Stage 2nd Stage

Biogas AD

TemperatureConditioning

Revenue StreamQualityControl

Flare

High Pressure StageCompression High 

PressureConditioning

Purification & Liquefaction StageRegenerativeActiv Carbon& Drier

CO2 Liquefier Stripper ‐Reboiler+ Pump

Bio‐LNG

Revenue StreamLiquid CO2 Storage tank

Food‐gradeLiquid CO2

BIOGAS PARTMembrane Separation

CO2 PARTCryogenic Separation

45% v/v CO2

55% v/v CH4

94% v/v CO2

6% v/v CH4

Flare / DigesterMethane Recovery

30% v/v CO2

70% v/v CH4

Fan Blower 

BIOGAS UPGRADING ‐ ADVANCED plus

11

Green CO2 to free air /

Local gas consumption

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CO2 QUALITY

BIOGAS TO GRID & GREEN CO2

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PENTAIR 

EIGA DOC 70/17: FOOD‐GRADE CO2 FROM BIOGAS

Revised EIGA DOC 70 released in February 2017

Biogas from anaerobic digestion listed as carbon dioxide source‐ Biogas from energy crop is handled similar to yeast‐based fermentation (ethanol)

‐ Biogas from bio‐waste digestion or co‐digestion requires greater care in the evaluation

‐ [Biogas from landfills (landfill gas)  with unlimited number of waste types requires extensive risk assessment]

Risk assessment process for AD plants for liquid CO2 for food & beverages‐ The food safety risk analysis (HACCP) includes the digester biogas process

‐ Final product carbon dioxide is always compliant with the Appendix A

‐ Complete on‐line or complete batch analysis of carbon dioxide before supply to customer 

‐ A food safety management system (e.g. ISO 22000) is strongly recommended for the carbon dioxide plant

‐ Compliance of the AD plant (and feedstock) with the EU regulations for animal by‐products

13

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PENTAIR  14

FOOD & BEVERAGE PROCESS SOLUTIONS

Stirling cryogenics

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PENTAIR 

August 28, 201415 Nordic Biogas Conference

Stirling Cryogeneratorsfor bio‐LNG production

• Arjan Coenradie• Samso, June 13th 2017

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PENTAIR 

• Based in Eindhoven, The Netherlands• Successor of Philips Cryogenics, in business since 1955• Installed base: > 3,000 units worldwide• 60 employees• Product brands:

Cryogeneratorsto produce on site cooling power

Special Cryogenic products & solutionsPumps and circulators

Nordic Biogas Conference

DH Industries

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PENTAIR 

Creation of cooling powerGenerally, all cooling is created by compression and expansion

Your fridgeLarge cryogenic systems based on turbinesfor example LNG production in Algeria/Qatar

Stirling is most efficient technique for small & medium scale liquefaction

August 28, 201417 Nordic Biogas Conference

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PENTAIR 

The Stirling cryogenerator

condenser head (cold)

compression space

expansion space

regenerator

gas cooler

displacer

piston

August 28, 201418 Nordic Biogas Conference

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PENTAIR 

The Stirling Cycle• Stirling Thermodynamic Cycle

August 28, 201419 Nordic Biogas Conference

Regenerator

Step 1: CompressionHelium gas is compressedGas temperature rises

Step 2: CoolingCompression heat is removed;The helium gas is pre-cooled in the regenerator before expansion starts

Step 3: ExpansionBy expansion, energy is extracted from the gas and thereby the temperature goes down thus cooling the cold head

Step 4: DisplacementGas is displaced back to the compression space; the cold from the helium gas is stored in the regenerator during displacement to step 1

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PENTAIR 

StirLNG‐4

Capacity: 1.2 ton/dayInput power: 26.5 kW

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PENTAIR 

A StirLNG system will consist of multiple units, rather than one large unit. 

Versatility:• Not all cooling power needs to be produced at all times

– All StirLNG’s operate independently and can be started and stopped as required (starting time = 10 minutes)

– Increased efficiency as power input drops linear with number of units

Scalability:• Capacity of system can grow gradually

Redundancy:• Back up capacity can be 10‐20%, not 200% 

Modular set up

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PENTAIR  22

FOOD & BEVERAGE PROCESS SOLUTIONS

Suggested system for Location Samso‐ 2 stage membrane Bio‐LNG+ Liquid CO2

Two phases advanced :First phase : 330 Nm3/hSecond phase : 530 Nm3/h

Page 23: AD BIOGAS WINNER 2016 BEST PROCESS OPTIMISATION · Biogas (BIO) New plants ... Revised EIGA DOC 70 released in February 2017 Biogas from anaerobic ... • Award winner 2016; Best

PENTAIR 

Full scale 

Capacity: 530 Nm3 /h raw biogas (55% CH4 / 44% CO2 / 1% N2/O2+/- 5 T / day Bio-LNGTotal power consumption +/- 1,2 kw / kg

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PENTAIR 

Full scale footprint 

Length +/- 20 mtrWidth +/- 10 mtrHeight +/- 5 mtr

Page 25: AD BIOGAS WINNER 2016 BEST PROCESS OPTIMISATION · Biogas (BIO) New plants ... Revised EIGA DOC 70 released in February 2017 Biogas from anaerobic ... • Award winner 2016; Best

PENTAIR 

Phase One : first investment 1 Biogas compressor (capacity +/- 330 Nm3/h)1 set membranes3 Stirling generatorLiqui-vap system

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PENTAIR 

No Liquid CO2

Footprint 

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PENTAIR 

Benefits & advantages 

‐ Two major value streams:

‐ Bio LNG

‐ Liquid CO2 (slaughtherhouse – dry ice Harbour)

‐ No methane slippage, all methane goes to Bio‐lng , CO2 100%

‐ Robust system, easy to understand and Maintain

‐ Flexible with turn down, gas capacity & fluctuations

‐ Reduce start costs by modular design

‐ fit for purpose phase one phase two

‐ Service from Denmark (Frederica)

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PENTAIR  28

FOOD & BEVERAGE PROCESS SOLUTIONS

5. SUMMARY & REFERENCES

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PENTAIR 

REFERENCES: ECOFUELS, NL, BIO‐WASTE

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PENTAIR 

BIOGAS UPGRADING

30

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PENTAIR 

BIOGAS UPGRADING – COMPACT ENCLOSED SKID

31

Page 32: AD BIOGAS WINNER 2016 BEST PROCESS OPTIMISATION · Biogas (BIO) New plants ... Revised EIGA DOC 70 released in February 2017 Biogas from anaerobic ... • Award winner 2016; Best

PENTAIR 

TRACK RECORD PENTAIR HAFFMANS

• Food Safety Risk Assessment completed in cooperation with major gas company

• CO2 end quality according EIGA / ISBT

• 24/7 Service desk / Own service team

• In‐house design (incl. membranes) and production

• > 450 CO2 recovery plants operating world‐wide

• 40+ years CO2 recovery

• Award winner 2016; Best Process Optimisation

• 7+ years of service life experience with membranes

• Low membrane pressure and hence low energy consumption

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“PROVEN TECHNOLOGY PROVIDER”EIGA: European Industrial Gases Association – ISBT: International Society of Beverage Technologists

0

2

4

6

8

10

12

14

UK NL USA D F NL PHL SA

33 Biogas Upgrading Projects

Biomethane

Biomethane + CO2

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PENTAIR 

Research project: Acrres the Netherlands

At Agricultural UniversityRan in 2014-2015Tests successfullFunctionality provenLicenses ended

Tests performed by

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PENTAIR 

Project: Utah, USA 

Liquefaction of methaneOperational since 2014

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Thank you for your attention!

35

Niels den Heijer  Arjan [email protected] A.coenradie@dh‐industries.com+31 77 3232396 + 31 402677323

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PENTAIR 

REFERENCE LIST PENTAIR BIOGAS CO2 RECOVERYCUSTOMER PRODUCT COUNTRY START‐UP CAPACITY MARKET  OUTPUT

3 * Non‐disclosedAdvanced 

PlusUSA

Oct‐17Jan‐18

3220 Nm3/h Biogas Non‐disclosed• 2160 Nm3/h Bio‐methane• 1990 kg/h Bio CO2

Helmdon Blackpits Recycling Centre,  Helmdon

Advanced Plus

UK Dec‐16 1160 Nm3/h Biogas Energy Crop• 655 Nm3/h Bio‐methane• 891 kg/h Bio CO2

Euston AD Plant, Euston (Extension)

ExtensionAdvanced 

PlusUK Dec‐16 1120 Nm3/h Biogas Energy Crop

• 640 Nm3/h Bio‐methane• 842kg/h Bio CO2(Added)

Bay Farm, WorlingtonAdvanced 

PlusUK Sep‐16 1160 Nm3/h Biogas Energy Crop

• 657 Nm3/h Bio‐methane• 894 kg/h Bio CO2

Fountain Civil Engineering, Cape Town

Advanced Plus

SA Mar‐17 1600 Nm3/h BiogasFood & vegetable based waste

• 1010 Nm3/h Bio‐methane• 1040 kg/h BioCO2

Apsley Farms, Andover Bolt‐on UK Jun‐16 2000 Nm3/h Biogas Energy Crop • 1600 kg/h Bio CO2

St. Nicholas Court Farms Ltd., St. Nicholas at Wade

Advanced Plus

UK Jun‐16 1160 Nm3/h Biogas Energy Crop• 600 Nm3/h Bio‐methane• 980 kg/h Bio CO2

Aseagas Corporation Bolt‐on PH Mar‐16 2300 Nm3/h Biogas Bioethanol • 1800 kg/h Bio CO2

St. Nicholas Court Farms Ltd, The Brickbarn, St. Nicholas at Wade

Advanced Plus

UK Dec‐15 700 Nm3/h Biogas Energy Crop• 400 Nm3/h Bio‐methane• 550 kg/h Bio CO2

Wight Farm Energy, Isle of Wight

Advanced Plus

UK Dec‐14 1050 Nm3/h Biogas Maize/Grass• 580 Nm3/h Bio‐methane• 810 kg/h Bio CO2

36CO2 Summit Innsbruck  – March 7, 2017  – Uwe Kikillus

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PENTAIR 

REFERENCE LIST PENTAIR BIOGAS CO2 RECOVERYCUSTOMER PRODUCT COUNTRY START‐UP CAPACITY MARKET  OUTPUT

Vale Green Energy, RotherdaleAdvanced 

PlusUK Jun‐14 1800 Nm3/h Biogas Energy Crop

• 1020 Nm3/h Bio‐methane• 1420 kg/h Bio CO2

Attero, WijsterAdvanced 

PlusNL Jun‐14 850 Nm3/h Biogas  Energy Crop

• 525 Nm3/h Bio‐methane• 620 kg/h Bio CO2

Indaver,  Alphen a/d RijnAdvanced 

PlusNL Jun‐14 1050 Nm3/h Biogas

Garden & householdorganic waste 

• 670 Nm3/h Bio‐methane• 775 kg/h Bio CO2

Springhill Farms UK, PershoreAdvanced 

PlusUK Jan‐13 500 Nm3/h Biogas Agriculture 

• 280 Nm3/h Bio‐methane• 390 kg/h Bio CO2

ARN, WeurtAdvanced 

PlusNL Aug‐12 530 Nm3/h Biogas

Garden & household organic waste 

• 320 Nm3/h Bio‐methane• 390 kg/h Bio CO2

Ecofuels, WellAdvanced 

PlusNL Aug‐11 450 Nm3/h Biogas

Vegetable‐Fruit based waste

• 270 Nm3/h Bio‐methane• 330 kg/h Bio CO2

37CO2 Summit Innsbruck  – March 7, 2017  – Uwe Kikillus

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PENTAIR 

UNION INTRO – OVERVIEW OF PLANT TYPESUnion Engineering’s main plant types for each customer segment

Energy & Chemicals

Core customer segments Growth segments

Beverages DesalinationIndustrial Gases

CO2 recovery plantsRecovery of CO2 from the fermentation processes at breweries and distilleries

CO2 recovery plantsRecovery of CO2 from high concentration by-product streams

CO2 generation plantsExtraction of CO2 from a flue gas generated by combustion of fossil fuels

CO2 extraction plantsExtraction of CO2 from low concentration sources (e.g. flue gases)

CO2 generation plantsExtraction of CO2 from a flue gas generated by combustion of fossil fuels

CO2 extraction plantsExtraction of CO2 from low concentration sources (e.g. flue gases)

CO2 recovery plantsRecovery of CO2 from high concentration by-product streams

CO2 sweetening plantsRemoval/extraction of CO2 from gas streams containing low to medium levels of CO2 (e.g. natural gas or biogas)

CO2 extraction plantsExtraction of CO2 from low concentration sources (e.g. flue gases)

Captive: Recovery/generation and usage of CO2 at the same site

Merchant: Traded CO2 (produced by industrial gas companies)

CO2 Summit Innsbruck  – March 7, 2017  – Uwe Kikillus