a2-10 phenolic line dust extractor 29th november - 1st ... · iso analytical lab technical total...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Stack Emissions Testing Report Commissioned by

29th November - 1st December 2016

Job Reference Number

CDU-0750

Installation Name & Address

Stack Reference

Industrial Emissions Licence: P0057-03

Signature of Report Approver

Version 1

Dates of the Monitoring Campaign

Report Written by

John Glennon

22nd December 2016Report Date

TE1 TE2 TE3 TE4

Version

Team Leader

Deputy Regional Manager

TE1 TE2 TE3 TE4MM 08 922

MCERTS Level 2

Patrick O'Brien

Report Approved by

MM 10 1074MCERTS Level 2

Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11T: +353 86 853 8247

E: [email protected] Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)

Co. MonaghanCastleblaney

Kingspan Insulation Ltd

Kingspan Insulation Ltd

A2-10 Phenolic Line Dust Extractor

CAT-RT (Version BP)CDU-0750 Kingspan Insulation Ltd, A2-10 PLD Extractor Compliance Report

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EPA Export 22-02-2017:02:39:39

TITLE PAGE

CONTENTS

Summary of Sampling Deviations

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

4

2

7

CONTENTS

9

3

5

6

8

The testing performed fully meets the technical requirements in Irish EPA

Guidance Note, AG2.

Opinions and interpretations expressed herein are outside the scope of

Exova Catalyst Ireland's ISO 17025 accreditation.

This test report shall not be reproduced, except in full, without the written

approval of Exova Catalyst Ireland.

CAT-RT (Version BP) of 36

Job Number: CDU-0750, SELECTSample Date/s: INPUT

Irish EPA IPPC Licence: INPUT

Kingspan Insulation LtdCastleblaneyA2-9 Phenolic Line Dust Extractor

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EPA Export 22-02-2017:02:39:39

Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Kingspan Insulation Ltd, Castleblaney



(Page 1 of 7)

Executive Summary

Exova Catalyst Ireland were commissioned by Kingspan Insulation Ltd to carry out stack emissions testing on the A2-10 Phenolic Line

Dust Extractor at Castleblaney.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the

Site's Permit.

There were no special requirements.

Total Particulate Matter | Formaldehyde | Organic Class I | Phenol | Total VOCs (as Carbon) |

MONITORING OBJECTIVES





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EPA Export 22-02-2017:02:39:39

where MU = Measurement Uncertainty associated with the Result

Parameter

Total Particulate Matter ¹

Formaldehyde ¹ - -

Organic Class I ¹ < <

Total VOCs (as Carbon) ¹ - -

Water Vapour

Stack Gas Temperature

Stack Gas Velocity

¹

- -

NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.

MFT=Mass Flow Threshold

1207

(Page 2 of 7)

7.86

0.5

24597

°C

mg/m³

Volumetric Flow Rate (ACTUAL)

Volumetric Flow Rate (REF)

500

m³/hr 25654

m³/hr

15.250 g/hr 193.3

0.11

% v/v

8.9m/s

0.0

18.0

1158

mg/m³

0.44


`

g/hr 4.90.14

+/-

Units Result

Concentration

MULimit

+/-

Units

mg/m³ 3.4

Result MFTMU


-

Executive Summary

Mass Emission

500.20

MONITORING RESULTS

mg/m³ 0.12 0.02 4 g/hr 3.1 4.7 -

g/hr 10.9

-

30000

0.49

200.09 2.2 100





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EPA Export 22-02-2017:02:39:39

Parameter

R1 - -

R1 - -

R1 < <

R1 - -

R1

All results are expressed at the respective reference conditions.

30

7.9 193.3 3016:00 - 16:30

29/11/2016

g/hr

16:00 - 16:300.44

mg/m³

MONITORING DATE(S) & TIMES

mins

Units


(Page 3 of 7)

64

DurationUnits

Total Particulate Matter 0.1 3.4

29/11/2016

09:30 - 10:34



Executive Summary

Sampling

Times

Concentration

01/12/2016

Sampling

Total VOCs (as Carbon) 29/11/2016

g/hr

15:45 - 15:55

16:00 - 16:300.12 g/hr 3.1

mg/m³Organic Class I

Velocity & Volumetric Flow Rate 29/11/2016

mg/m³

10.9

30

Date(s)

Mass Emission

g/hr

Formaldehyde mg/m³





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EPA Export 22-02-2017:02:39:39

Standard Operating Conditions

Process Status



Abatement System

Abatement System Running Status

Plume Appearance

Cyclone

(Page 4 of 7)

Executive Summary

PROCESS DETAILS

Parameter

Capacity (of 100%) and Tonnes / Hour

Continuous or Batch Process

N/A

Not visible

100% of capacity

N/A

Fuel

On

Batch

Normal operation


Feedstock (if applicable)

Value





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EPA Export 22-02-2017:02:39:39

MONITORING & ANALYTICAL METHODS


Deviation

All There were no deviations to report.

Pitot Tube and Thermocouple

All

SUMMARY OF SAMPLING DEVIATIONS

Parameter Run

Procedure Lab

Yes Yes

Analytical LOD


Monitoring

CAT

Parameter

Procedure

CAT-TP-03


(Page 5 of 7)

Testing ISOStandard

CAT-TP-01 Gravimetric

MCERTS

17025

Testing

0.08 mg/m³

Analysis

Analysis

17025 Analysis

Executive Summary

Testing

CAT

(Average)

Yes

AnalyticalISO

Lab

Technical

Total Particulate Matter EN 13284-1

Technique

0.017 mg/m³RPS YesCEN/TS 13649 CAT-TP-16 Yes CAT HPLC A40 Yes

EN 16911-1 (MID) CAT-TP-41 Yes 1.2 m/s

GravimetricWater Vapour

Total VOCs (as Carbon)

ISO 17025 Accreditation Number: 4279

ISO 17025 Accreditation Number: 0605

CAT 0 mg/m³Flame Ionisation Detection by Sick 3006 FID

Velocity & Vol. Flow Rate CAT

RPS Laboratories Ltd (RPS)

Yes

(with short name reference as appears in the table above)

Exova Catalyst (CAT)

EN 12619:2013 CAT-TP-20

ANALYSIS LABORATORIES

CAT-TP-05

Yes

0.1 % v/vCAT-TP-05 YesEN 14790 YesCAT Yes

Yes GC-FIDOrganic Class I

Formaldehyde

P1 RPS

CAT

Yes

YesCEN/TS 13649 CAT-TP-16 YesCAT 0.445 mg/m³





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EPA Export 22-02-2017:02:39:40

Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (from EN 15259)

-

-

-

0.00

-

-

0.00

Yes

Highest Gas Velocity

Area

1.08

°

-Yes

Ratio of Above : 1

< 15°

0.00

-

Platform has chains / self closing gates at top of ladders

-8.89

Pa

-

Value

m

0.80

Orientation of Duct

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

Port Depth

-

Yes

Traverse 1

m/s

< 3 : 1

Easy Access Available

Yes

4" BSP

Lowest Differential Pressure

Depth

9.26

Yes

Yes

SUITABILITY OF SAMPLING LOCATION

Value

-

0.00

-

Yes

9

-

-

-

m²

m

Platform has vertical base boards (approx. 0.25m high)

General Platform Information

Permanent / Temporary Platform

Inside / Outside

-

Vertical

Yes

-

-

8 -

No Local Negative Flow

Mean Velocity

Safe Access Available

The sampling location meets all the requirements specified in Irish EPA Guidance Note AG1 and EN 15259, and therefore there are

no improvement recommendations.

Criteria in EN 15259

-

Parameter

There are no obstructions present which hamper insertion of sampling equipment

-

-

-

Yes

-

> 5 Pa Yes

(Page 6 of 7)

Units

Sample Port Size

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

65.0

Circular

Value

- Required

-

--

Outside

Width

Compliant

m/s

Maximum Angle of Swirl

Executive Summary

cm

Yes

-

Permanent

-

Lowest Gas Velocity

m/s

Yes

-

8.56

-

-

-

-

Units

-

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

-

-

-

Sufficient working area to manipulate probe and operate the measuring instruments

Type

-

1.01





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EPA Export 22-02-2017:02:39:40

Executive Summary

Photo 3

SAMPLE POINTS

Photo 4

Photo 1

PLANT PHOTOS

(Page 7 of 7)

Photo 2

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

= non-isokinetic sample point

Line A

Line B

A1

A2

B1

B2





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EPA Export 22-02-2017:02:39:40

APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDIX CONTENTS

APPENDICES





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EPA Export 22-02-2017:02:39:40

Oven Box (1)

CAT 20.71

Laboratory Balance CAT 1.18 / 1.18a

Tape Measure CAT 16.35

Equipment I.D.

Digital Manometer (1)SELECT Horiba Model (1)

Instrumental Analysers

Name

1m Heated Line (3)

Control Box DGM (1)

-

EN 13284-1

Technical ProcedureStandard

Heated Probe (1)

Mass View (2)

Oven Box (2)

CAT-TP-20

CAT-TP-05

EN 12619:2013

CAT 3.168

Formaldehyde

1m Heated Line (1)

Extractive Sampling

LIST OF EQUIPMENT

MCERTS Accreditation

Single Channel Heater Controller

Barometer

Digital Manometer (2)

Umbilical (1)

Box Thermocouples (2)

Box Thermocouples (1)

S-Pitot (2) CAT 21S.42

Organic Class I

Equipment Type

Hioki 5043 (V)

CAT-TP-16

-

CAT 14.65

-

S-Pitot (1)

L-Pitot

-

CAT 20.71

CAT 23.26

-

-

-

-

CAT 3.59

-

CAT 12.83

-

CAT-TP-01

Parameter

Total Particulate Matter

Bioaerosols Temperature Logger -

Stack Thermocouple (2)

Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

15m Heated Line (1)

CAT 17.24

-

SELECT Gas Conditioning

CAT 13.27

Mass Flow Controller (1)


Technical Endorsements

Team Leader

Equipment Type

CAT 4.605

-

-

Umbilical (2) Servomex 5200MP

Water Vapour

-

CAT 6.1

Bernath 3006 FID CAT 8.16

-

- 1m Heated Line (2)Heated Probe (2)

Equipment Type

Control Box DGM (2)

-

John Glennon MCERTS Level 2

Mass Flow Controller (2) CAT 6.21 -

CAT 11.59

SELECT Logger 2 -

Mass View (1) CAT 25.36

20m Heated Line (2)

Gasmet Sampling SystemCAT 5.3

Digital Temperature Meter

Heated Probe (3)

Tubes Kit Thermocouple CAT 4.0005

EN 14790

Total VOCs (as Carbon)

EN 16911-1 (MID) CAT-TP-41

CEN/TS 13649


Equipment I.D.

Dual Channel Heater Controller -500g / 1Kg Check Weights CAT 17.24

CAT 4.568

ABB AO2020-URAS26

Velocity & Vol. Flow Rate

Eco Physics CLD 822Mh

Last Impinger Arm -

Callipers

- 20m Heated Line (1)

5m Heated Line (1) -

Site Balance

METHODS & TECHNICAL PROCEDURES USED

CAT 7.23

-

CAT 3.59

SELECT FTIR

SELECT Horiba Model (2)

MM 10 1074 TE1 TE2 TE3 TE4

Trainee James O'Connor MCERTS Trainee MM 16 1396 None

Miscellaneous Items

Stopwatch

Servomex 4900

-

CEN/TS 13649 CAT-TP-16

CAT 25.37

-

Position

CAT 3.168-

-

CAT 21P.14

MCERTS Number

M&C PSS

Electronic Refrigerator -





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EPA Export 22-02-2017:02:39:40

General Stack Details

Stack Gas Composition & Molecular Weights

CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

-

1.2498

44.01

24477

Wet Density (STP), P STW

-

Gas Volumetric Flowrate REF ¹

%

0.8037

-0.0

0.49

24597

25654

m³/hr

REF ¹

Gas Volumetric Flowrate (Actual)

kg/m³

18.0

Average Barometric Pressure, Pb

m

Actual

kg/m³

0.7986 28.01

101.3

Result

1.96350.06

18.0

103.5

Temperature

N₂

1.4277 0.28668-

Units

0.00118

Gas Volumetric Flowrate (STP, Wet)

Moisture

kPa

0.0049

19.98

p pi

Units

Average Pitot Tube Calibration Coefficient, Cp

ppm kg/m³

Average Stack Gas Pressure

Conc

0.49

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure

Average Wet Density (Actual), P ActualW

0.49

79.86 0.99813

1.286

79.47

Dry Density (STP), P STD

18.02

Determinand

0.0006

24597

kg/m³

Mass

Component

m³/hr

Result

°C

-

-

Fraction

Density

Dry

0.00390

20.08 32.00

Conc

0.06

0.2008

°C

Average Stack Static Pressure, Pstatic

-

Units

Pa 70.1

Molar Conc

0.80

mStack Width, W

Stack Details (from Traverse)

APPENDIX 2

1.231

Dry Density (Actual), P Actual

m³/hr

Gas Volumetric Flowrate (STP, Dry)

% v/v

Units

kg/m³ 1.284

Duct gas flow conditions

1.233

-

Volume

kPa

kPa

0.84

Value

1.01

103.5

Average Stack Gas Temperature, Ta

0.030

Stack Area, A m²

PRELIMINARY STACK SURVEY: CALCULATIONS

Stack Diameter / Depth, D

Gas Volumetric Flowrate (from Traverse)





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EPA Export 22-02-2017:02:39:40

Parameter Parameter

Date of Survey Initial Pitot Leak Check

Time of Survey Final Pitot Leak Check

Atmospheric Pressure Orientation of Duct

Average Stack Static Pressure Pitot Tube, Cp

Result of Pitot Stagnation Test Number of Lines Available

Are Water Droplets Present? Number of Lines Used

Device Used

-

-

--

-

-

-

-

-

-

--

-

- -

-

8.7668.0

- -

-

-

-

-

-

-

-

-

-

-

-

-

- -

-

--

-

-

- -

-

-

-

-

-

8.98

VelocitySwirl

No

kPa

-

Wet Density

-

71.5

--

-

- -

2.0

-

6.0

2.0

-

68.0

- -

1.231

- --

- -

-

-

-

68.0

-

-

- -

-

-

-

-

-

-

-- -

-

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)

Swirl

Vertical

Pass

1.231

m/sPa

1.231

m

1.2315.0

72.0

8.76

8.81

0.07

9.01

1

1.231

18.00.76

18.0

32.0STATIC (Units: Pa)

Pa

18.0

4

70.0

8.0

28.0

1.2311.231

-

74.0

2

1.231

0.94

Temp

--

15:45 - 15:55

Sampling Line A

kg/m³Point

18.0

18.0

Mean

0.25

18.0

1.0

3

18.0

8.89

8.76

9.14

8.56

18.0

18.0

68.8 18.0

Pass

9.26

Units

°

-

Traverse

1.231

103.5

Pass

∆P

-

(1 of 1)

2

Value

∆P Temp

Sampling Line B

30 -

kg/m³

4.0

°C

6.0

°

76.0

65.0

m/s°C

Wet Density

Pa

2

29/11/2016

Value

-

Units

Depth

-

Velocity

0.84

S-Type Pitot with KIMO MP 200 (500Pa)

APPENDIX 2

1.231





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EPA Export 22-02-2017:02:39:40

0.00053

-

Uc(qV,w)

0.00058

- 379494

- 616.0

Uc,rel(qV,w) 4.71

%

- Static Pressure

Standard uncertainty associated with the density in the duct

Standard uncertainty associated with the absolute pressure in the duct

- Atmospheric Pressure

u(drift) 0.083

- u(qV,w)

Standard uncertainty associated with the volume flow rate (95% Confidence), relative

Performance characteristics (Uncertainty Components) UnitsValueUncertainty

%

Standard uncertainty associated with the volume flow rate (95% Confidence)

Pa

u(res) 0.00087

0.658

u(∆pi)

u(k) 0.005

Standard uncertainty associated with the mean velocity (95% Confidence)

Standard uncertainty associated with the mean velocity (95% Confidence), relative

u(pc) 175.694 Pa

u(patm) 175.692

u(pstat) 0.911

u(ρ) 0.00662

Standard Uncertainty on the coefficient of the Pitot Tube

- Resolution

- Calibration

u(M) 0.00002

0.096

u(v) 0.059

Uc(v)

- Drift

- Lack of Fit

m/s

- φO₂,w

-

-

Pa

m/s

-

u(φCO₂,d) 0.002

Standard uncertainty associated with the stack temperature

Standard uncertainty associated with the mean velocity

Uc,rel(v) 1.29

0.115

- Water Vapour

- Oxygen, wet

- Carbon Dioxide, wet

-

- φCO₂,w

- Oxygen, dry

- Carbon Dioxide, dry

u(fit) 0.062

Standard Uncertainty associated with the mean local dynamic pressures

- Overall corrections to dynamic measurements

Standard uncertainty associated with the molar mass of the gas

u(φH₂O) 0.025

u(φO₂,w) 0.612

u(vi)

K

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)

Standard uncertainty associated with the local velocities

u(Cf)

u(cal) 0.512

APPENDIX 2

u(Tc) 1.485

1.288

1207.4 m³/hr

- u²(qV,w)

- u²(a)/a²

- u²(qV,w)/q²V,w

-

19.983

- 0.060

u(φO₂,d) 0.615

u(φCO₂,w) 0.002





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EPA Export 22-02-2017:02:39:40

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -

General Sampling Information

FORMAT: Number Used / Number Required


Reference Conditions

Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.

Parameter Units

Uncertainty ±g/hr

TOTAL PARTICULATE MATTER: RESULTS SUMMARY

Filter Size and Material

In Stack

Technical Procedure


Parameter

Concentration

0.14

Blank 1

Uncertainty


Mean

0.49

Uncertainty ±mg/m³ 0.20 0.20

Units

Parameter

EN 13284-1

Sample Point I.D.'s

0.49

Number of Sampling Lines Used

CAT-TP-01

% v/v

Value

g/hr 3.4

Positioning of Filter

Mean

4.9

0.03 0.03

4.9

±% v/v

1 / 2

Number of Sampling Points Used 8 / 8

Titanium

Filter Housing Material Titanium

Probe Material

Parameter Units

Run 1

Water Vapour

Concentration

Mass Emission

Standard

NOTE: Where the Balance Uncertainty / Limit of Detection is higher than the Blank concentration, the Balance Uncertainty / Limit of Detection concentration has

been reported.

47mm Glass Fibre

0.08

APPENDIX 2

3.4

mg/m³ 0.14

Run 1

Maximum

mg/m³ 0.08

A1 - A8





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EPA Export 22-02-2017:02:39:40

Absolute pressure of stack gas, Ps

Volume of water vapour collected, Vwstd

Volume of gas metered dry, Vmstd

Moisture content, Bwo & Rwv

Bwo as a percentage

Reported Water Vapour, checked with Tables in EN 14790, Rwv

Volume of gas metered wet, Vmstw

Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂

Molecular weight of dry gas stream, Md

CO₂ (Estimated)

O₂ (Estimated)

Molecular weight of stack gas (wet), Ms

Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)

Percent isokinetic, %I

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273)

3.1

Nozzle area, An

N/A

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

0.49

Qa = (60)(As)(Vs)

m³

Total

402.7

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273)

79.14

mm²

% v/v 20.86

% wet oxygen measured in gas stream, ACT%O₂w

0.84

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)

1.6869

Average square root of velocity heads, √∆P

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

Vwstd = (0.001246)(Vlc)

Average dry gas meter temperature, Tm °C

Total mass of liquid collected, Vlc

% v/v

√mmH₂O

APPENDIX 2

% v/v

mmH₂O

% oxygen reference condition, REF%O₂ % v/v N/A

% dry oxygen measured in gas stream, ACT%O₂d

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A

-

% v/v

m³

% v/v

776.5

m³

Average pressure drop across orifice, ∆H 76.2

Stack static pressure, Pstatic

% v/v

4.8

Barometric pressure, Pb

6.6

Nozzle diameter, Dn

mmH₂O

0.0082

Volume of gas sample through gas meter, Vm m³

Gas meter correction factor, Yd

1.2g

N/AVmstd@X%oxygen = (Vmstd) / (O₂REFd)

0.9310

0.49

g

TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS

Test Units

Total mass collected in impingers (liquid trap)

5.4

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

N/A

-

Vmstw = (Vmstd)(100/(100 - Rwv))

Run 1

-

1.7920

% v/v

1.6952

18.0

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps))

6.80

2.61

50.27

m³/min

104.8

m/s

-

8.00

°C

Conversion factor (K/mm.Hg), Cf

Average of velocity heads, ∆Pavg mmH₂O

Total sampling time, q

0.80

% v/v

20.80

Velocity of stack gas, Vs

Velocity pressure coefficient, Cp

m³/min

min 64

m³/min 400.8

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

mmHg

Ps = (Pb + (Pstatic / 13.6)

m³

Total mass collected in impingers (silica trap)

mmHg

g

m³/min

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

Average stack gas temperature, Ts

%

Area of stack, As m²

-

8.74

mm

34.97

0.3592

776.3

m³

g/gmol 28.79

-

0.06

420.2

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)

Bwo = Vwstd / (Vmstd + Vwstd) 0.0049

N/A

N/A

g/gmol 28.84

N₂

- N/A

No

Pitot tube velocity constant, Kp





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EPA Export 22-02-2017:02:39:40

Sample Runs

Filter I.D. Number

Probe Rinse I.D. Number

Where: ISO stands for Manual Isokinetic Sampling Train

Blank Runs

Filter I.D. Number

Probe Rinse I.D. Number

2.94172

Total Mass Collected

g

Volume Sampled (REF) m³

0.00001

mg

g

-0.17

0.08

Calculated Concentration

47-36694

g

Start Probe Rinse Mass

g -0.00019

01/12/2016

g

-

Total Mass in Probe Rinse

01/12/2016

1.6952

mg/m³

g

g

APPENDIX 2

-

g

g

End Probe Rinse Mass

End Filter Mass

Total Mass in Probe Rinse

09:30 - 10:34

Sampling Dates

PR-47-36694

mg/m³

m³

Balance Uncertainty / LOD

Calculated Concentration

g

mg

End Filter Mass

-

Parameter

-

End Probe Rinse Mass

Parameter Units

Sampling Times

Blank 1

2.97953

0.23

Start Filter Mass

mg/m³

0.08

Total Mass on Filter

TOTAL PARTICULATE MATTER: SAMPLING DETAILS

Balance Uncertainty / LOD

47-36444

g

g

1.6952

2.94173

Total Mass Collected

0.14877

-

Blank Dates -

0.14748

0.14858

Total Mass on Filter

0.00009

-

Run 1

Average Volume Sampled (REF)

-

2.97967

mg/m³

ISO

Units

0.14739

Sampling Device

Start Probe Rinse Mass

0.00015

0.14

PR-47-36444

Start Filter Mass

-0.10





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EPA Export 22-02-2017:02:39:40

Sample Runs

MU (Concurrent Water Vapour)

Maximum Filter Temperature

Pre-Conditioning Temperature °C

± mg

Run 1

-

Run 1

l/min 0.32

Pre-Sampling Leak Rate l/min 0.20

Overall Weighing Uncertainty

Less than 50% Faded

Units

20

°C

Yes

APPENDIX 2

Isokinetic Criterion Compliance

Units

%

%

Overall Weighing Uncertainty

Run 1

Isokineticity Acceptable - Yes

Run 1

°C

mg/m³ 2.50

Water Droplets

%

Units

Yes

Units Run 1

104.8

0.15

%

Yes

Units

Filter Temperatures

Mean Sampling Rate l/min 26.07

Allowable Leak Rate

Run 1

Measurement Uncertainty (MU)

-

Silica Gel (Concurrent Water Vapour) Units

Allowable Isokinetic Range %

Allowable MU

(PAGE 1 OF 2)

%

6.0

0.52

Are Water Droplets Present - No

Run 1

Post-Sampling Leak Rate

l/min

Leak Test Acceptable

-

Units

Leak Test Results

Yes

Ambient Temperature Recorded?

MU Acceptable

Test Conditions Units

Weighing Uncertainty Acceptable

Isokinetic Variation

Yes

Run 1

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

± mg/m³

18

Allowable Weighing Uncertainty

95 - 115

180

0.25

Weighing Uncertainty Criteria

160Post-Conditioning Temperature

ELV [Daily ELV for IED] mg/m³ 50.00





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EPA Export 22-02-2017:02:39:40

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

Blank Acceptable

25.00

Allowable Blank

l/min

Expected Sampling Rate

-

Yes

l/min

Nature of Deviation

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

2.7

Pre-Sampling Leak Rate

Acetone / Water Rinse Blank

mg/m³

10

Allowable Leak Rate

5.0

Units Blank

l/min

mg/l

Blank Acceptable

- Yes

Yes

Acetone / Water Rinse Value

0.28

(PAGE 2 OF 2)

Validity of Blank vs ELV

Leak Test Results

Allowable Blank

Units

0.50

There are no deviations associated with the sampling employed.

-

Run Number

Leak Test Acceptable

Units Blank 1

APPENDIX 2

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

mg/l

Blank 1

Post-Sampling Leak Rate l/min 0.24





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EPA Export 22-02-2017:02:39:40

Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Mass of Particulate

Uncollected Mass

Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Mass of Particulate

Uncollected Mass

Sampled Volume (STP)

Leak

Mass of Particulate

Uncollected Mass


Leak

Mass of Particulate

Uncollected Mass

O₂ Correction Factor

Stack Gas O₂ Content

MU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen Correction

Expanded uncertainty (95% confidence), with Oxygen Correction

Expanded uncertainty (95% confidence), estimated with Method Deviations

Reported Uncertainty





≤1%

1.00

UCM

mg/m³

-0.17

UCM

L

Vm

% v/v

uρm

1.6869m³

0.0010

<5% of ELV

% 144.6

0.59

mg/m³

K 2.0

1.7920

Tm

mg/m³

Run 1 Units Run 1

%

Vm

0.20

Measured Quantities

uUCM mg -

Units

Run 1

2.00

Parameter Units

uTm

0.10

% 0.17

Lr mg

0.20

-

Run 1 Requirement of Standard

1.0

-0.10

0.72

%

Measured Quantities

mg/m³

uHm

%

Uncertainty as a Percentage

Symbol

APPENDIX 2

TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS

Value Standard uncertainty

0.0358

% N/A

N/A

144.6

kPa

0.08

mg/m³

Units Run 1

mg

Hm

0.23

%

Measured Quantities

% 1.23

Symbol Units

Uncertainty in Measurement Units Sensitivity Coefficient

%

mg/m³ 0.0826

0.0

% v/v N/A

-

mg

0.20

0.001

Units

- N/A

uVm m³

Overall MU For O₂ Measurement

mg/m³

um

≤2%

%

Uncertainty in Result

≤1%

% 1.00

0.14

Measured Quantities Symbol

m

277.8

L 1.23

0.5ρm 103.5

144.6

0.233

0.59

-

0.48

-0.0590

Run 1

≤2%

mg/m³

mg/m³ 0.003

Run 1

N/A

≤1%

mg/m³

%

Run 1

N/A

-uL %

Oxygen Correction Part of MU Budget

Measured Quantities





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EPA Export 22-02-2017:02:39:40

Sample Runs

- -

- -






Formaldehyde mg/m³ 0.12

Value

0.12


Parameter Units Run 1

APPENDIX 2

Name of Analytical Laboratory RPS

Analytical Laboratory's Procedure HPLC

ISO 17025 Accredited Analysis? See Executive Summary

Date of Sample Analysis

Sample Point I.D.'s A4

Stainless Steel

Parameter

Sample Tube Type

Probe Material

Standard CEN/TS 13649

Technical Procedure CAT-TP-16


14/12/2016

Silica Gel

Mean

Dynamic Dilution Employed No

Number of Sampling Lines Used 1 / 1

FORMALDEHYDE : RESULTS SUMMARY






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EPA Export 22-02-2017:02:39:40

Where: MV stands for Mass View (Mass Flow Controller Technology)

- < - - -



Sampling Times -

APPENDIX 2

FORMALDEHYDE : SAMPLING DETAILS

RUN 1

Parameter Units Value

Volume Sampled (REF) m³ 0.0120

Parameter Lab Result

(Front)

µg

- MV

Reported

LOD

mg/m³

Adsorption

Efficiency

%

16:00 - 16:30

Sampling Dates - 29/11/2016

Sampling Device

Lab Result

(Back)

µg

Formaldehyde 0.1 1.5 0.1 0.1 0.2

Reported

Concentration

(Blank Reviewed)

mg/m³

Duration mins 30

N₂ to Stack Gas Dilution Ratio : 1 0

1.4 0.125 0.125 0.017 100.0

Lab Result

(Total)

µg

LOD

(Front)

µg

LOD

(Back)

µg

LOD

(Total)

µg

Concentration

mg/m³





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< < - <



APPENDIX 2

FORMALDEHYDE : SAMPLING DETAILS

BLANK 1



Sampling Device - MV

Average Volume Sampled (REF) m³ 0.0120


(Front)

µg

Lab Result

(Back)

µg

Lab Result

(Total)

µg

Concentration

mg/m³

Formaldehyde 0.1 0.1 0.2 0.017





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Sample Runs

APPENDIX 2

FORMALDEHYDE : QUALITY ASSURANCE(PAGE 1 OF 2)

Leak Test Results Units Run 1


Pre-Sampling Leak Rate l/min


Allowable Leak Rate l/min 0.020

Leak Test Acceptable - Yes

Adsorption Efficiency Units Run 1

Formaldehyde % 100.0

Allowable Adsorption Efficiency % 95

Temperature Acceptable - Yes

0.000

Test Conditions Units Run 1

Ambient Temperature Recorded? - Yes

Adsorption Efficiency Acceptable - Yes

Temperature at Sample Tubes Units Run 1

Temperature °C 10

Allowable Temperature °C 40





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Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

Sampling Leak Rate l/min 0.000



Validity of Blank vs ELV Units

Allowable for Formaldehyde mg/m³

Blank 1 Allowed

0.0 0.4

APPENDIX 2

FORMALDEHYDE : QUALITY ASSURANCE(PAGE 2 OF 2)

Leak Test Results Units Blank 1

Expected Sampling Rate l/min 0.400

Run Number

(x = deviation applies to the associated run)

Nature of Deviation






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Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













NOTE: Uncertainties reported in mg/m ³ are based upon the summation of all Speciated VOCs Measured.

% N/A

Run 1

- N/A

N/A

0.025

mg/m³

0.013

Measured Quantities

Measured Quantities Units Run 1

mg/m³ 0.0125

≤2%

%

Overall MU For O₂ Measurement %

mg/m³

0.00 ≤5%

0.025

mg/m³ 0.000

Measured Quantities

FORMALDEHYDE : MEASUREMENT UNCERTAINTY CALCULATIONS

Symbol Run 1 Symbol Units

% 2.00

Uncertainty in Measurement Units

% 10.00 No Requirement

Measured Quantities Requirement of Standard


Run 1

Units

0.0120

Lr 10.00 uLr % -


uVm m³ 0.0

Run 1

Sensitivity Coefficient

10.45

mg/m³ 0.025

mg/m³

% 20.0

Vm 0.0120

1.00

Lr mg/m³ 0.012

L uL % -0.000

Units Run 1

Vm m³

% v/v N/A



- N/A

APPENDIX 2

L

Measured Quantities Symbol Units Run 1

1.00

Run 1

% 20.0

mg/m³

mg/m³ 0.0025

mg/m³ 0.0000

% 20.0

N/A

Parameter Units





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EPA Export 22-02-2017:02:39:40

Sample Runs

- -

< <

< <






Total mg/m³ 0.44

XAD 7 Tube

Dynamic Dilution Employed No

Number of Sampling Lines Used 1 / 1

Parameter Value

Standard CEN/TS 13649

Technical Procedure CAT-TP-16

Name of Analytical Laboratory RPS

ISO 17025 Accredited Analysis? See Executive Summary

Date of Sample Analysis 14/12/2016

Probe Material Stainless Steel


Sample Point I.D.'s A1

0.44

Sample Tube Type

Analytical Laboratory's Procedure GC-FID

APPENDIX 2

ORGANIC CLASS I : RESULTS SUMMARY



Parameter Units Run 1 Mean

Phenol mg/m³ 0.44 0.44





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< < - < <

- < <



0.0112


(Front)

µg

Lab Result

(Back)

µg

Lab Result

(Total)

µg

LOD

(Front)

µg

Concentration

mg/m³

LOD

(Back)

µg

LOD

(Total)

µg

Reported

Concentration

(Blank Reviewed)

mg/m³

100.02.5 5.0 0.445 0.445 0.445

- 29/11/2016


Total 5.0 5.0 0.445 0.445 0.445 -

Units Value

Sampling Times - 16:00 - 16:30

Sampling Dates

Reported

LOD

mg/m³

Adsorption

Efficiency

%

Phenol 2.5 2.5 5.0 2.5

APPENDIX 2

ORGANIC CLASS I : SAMPLING DETAILS

RUN 1

Parameter

Duration mins 30

N₂ to Stack Gas Dilution Ratio : 1 0

Volume Sampled (REF) m³





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< < - <



APPENDIX 2

ORGANIC CLASS I : SAMPLING DETAILS

BLANK 1




Average Volume Sampled (REF) m³ 0.0112


(Front)

µg

Lab Result

(Back)

µg

Lab Result

(Total)

µg

Concentration

mg/m³

Phenol 2.5 2.5 5.0 0.445





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EPA Export 22-02-2017:02:39:40

Sample Runs

Temperature °C 10

Allowable Temperature °C 40

Temperature Acceptable - Yes

Test Conditions Units Run 1

Ambient Temperature Recorded? - Yes

Allowable Adsorption Efficiency % 95

Adsorption Efficiency Acceptable - Yes

Temperature at Sample Tubes Units Run 1


Adsorption Efficiency Units Run 1

Phenol % 100.0

Leak Test Results Units Run 1


Pre-Sampling Leak Rate l/min 0.000



APPENDIX 2

ORGANIC CLASS I : QUALITY ASSURANCE(PAGE 1 OF 2)





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EPA Export 22-02-2017:02:39:40

Blank Runs

Method Deviations

1

x

- - - - -

- - - - -

- - - - -

0.4 2.0

Nature of Deviation Run Number



Allowable for TOTAL

Validity of Blank vs ELV Units

Allowable for Phenol mg/m³

APPENDIX 2

ORGANIC CLASS I : QUALITY ASSURANCE(PAGE 2 OF 2)

Leak Test Results Units Blank 1

Blank 1

Expected Sampling Rate l/min 0.400

Sampling Leak Rate l/min 0.000



Allowed

mg/m³

N/A0.4





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EPA Export 22-02-2017:02:39:40


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result


Leak

Laboratory Result













NOTE: Uncertainties reported in mg/m ³ are based upon the summation of all Speciated VOCs Measured.

uVm m³ 0.0

39.68

≤5%

%

2.00


Requirement of Standard

%

Units Run 1 Run 1

20.0

mg/m³

mg/m³

0.045

mg/m³

%

Measured Quantities Units Run 1

-

% 20.0

mg/m³ 0.089

% 20.0

N/A

0.089

0.0089

0.000

Symbol


L mg/m³

Uncertainty in Measurement Units Sensitivity Coefficient

≤2%

% 0.00

Run 1

mg/m³

% N/A

0.0445

mg/m³

Parameter Units Run 1

N/A

1.00

No Requirement

Measured Quantities

Measured Quantities

uLL % -

Lr

Units Run 1

0.000

Units


mg/m³ 0.089

Overall MU For O₂ Measurement

1.00

mg/m³

10.00 uLr % -

N/A

%

% v/v N/A

-

0.0000

N/A

10.00

Lr mg/m³ 0.044

Vm m³ 0.0112


Measured Quantities Symbol Run 1 Symbol Units Run 1

APPENDIX 2

ORGANIC CLASS I : MEASUREMENT UNCERTAINTY CALCULATIONS

Vm 0.0112

Measured Quantities





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EPA Export 22-02-2017:02:39:40

Sample Runs

- -

- -

- -

- -

- -






Zero Gas Type

±g/hr 15.2

1 / 1

Span Gas Start Pressure (bar) 80

Gas Cylinder Concentration (ppm)

7.86

CAT-TP-20

180°C

Span Gas Expiry Date

7.86

Number of Sampling Lines Used

86.2

Probe Material Stainless Steel


Heated Line Temperature

CYL 1.0219N

Sample Point I.D.'s

mg/m³

0.49

Span Gas Uncertainty (%)

Mean


EN 12619:2013

Technical Procedure

Run 1

Standard

09/06/2021

Uncertainty


TOTAL VOCs (as CARBON): RESULTS SUMMARY

Uncertainty ±mg/m³

Synthetic Air (5 Grade)

Span Gas Reference Number

N/A

Yes

Parameter Units

A4

Value

Span Gas Set Point (ppm) 86.20

Filtration Type / Size 0.1µm Glass Fibre

15.2

Parameter

Mass Emission

Concentration

g/hr

APPENDIX 2

193.3 193.3

0.49

Heated Head Filter Used

Span Gas Type Propane In Synthetic Air (5 Grade)





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EPA Export 22-02-2017:02:39:40

Graphical Trend of Data

COVER ME WITH CHART/S

APPENDIX 2

TOTAL VOCs (as CARBON): DATA TREND

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

16:0

0

16:0

1

16:0

2

16:0

3

16:0

4

16:0

5

16:0

6

16:0

7

16:0

8

16:0

9

16:1

0

16:1

1

16:1

2

16:1

3

16:1

4

16:1

5

16:1

6

16:1

7

16:1

8

16:1

9

16:2

0

16:2

1

16:2

2

16:2

3

16:2

4

16:2

5

16:2

6

16:2

7

16:2

8

16:2

9

16:3

0

Co

nce

ntr

atio

n (

mg/

m³)

Total VOCs At Reference Conditions

- Run 1





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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Method Deviations

1

x

- - -

- - -

- - -

- - -

- - -

Allowable Span Drift ± ppm

CA

L 1

4.31

Yes-

Units Run 1

°C

Run Number

Test Conditions


Run Ambient Temperature Range 9

ppm 83.80

4.31

Nature of Deviation


Span Drift

Zero Down Sampling Line (Post) ppm

ppm -0.90

Span Down Sampling Line (Pre)

Units

0.20

Allowable Zero Drift ± ppm

Run 1

ppm

Span Drift Acceptable

Units

ppm

Sampling Times -

ppm

84.70

CA

L 1

16:00 - 16:30

Instrument Range ppm 100

0.10

Span Down Sampling Line (Post)

Sampling Dates

Units Run 1

Parameter

Span Gas Value 86.2

Zero Drift Acceptable

Run 1

TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE

Zero Drift

- Yes

-

Zero Down Sampling Line (Pre)

0.10ppm

APPENDIX 2

29/11/2016





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k =

Expanded uncertainty (no O₂) - at 95% Confidence 0.99 % at ELV

Overall Allowable uncertainty (no O₂) - at 95% Confidence 15.0

mg/m³

Combined interference (from MCERTS Certificate) 0.04

mg/m³

% at ELV

Ambient temperature dependence

Expanded uncertainty 1.96 0.50 mg/m³

Uncertainty corrected to std conds. (O₂)

% of value

Zero drift 0.12

30

% full scale

Volume or pressure flow dependence 1.60

% of value/kPa

RUN 1 Units

0.50 mg/m³ (REF)

160.6

Expanded uncertainty (no O₂) - at 95% Confidence 6.30 % of Value

0.00

mg/m³

Drift 0.05

Ambient temperature dependence

Range Used 100.0

% of Value

RUN 1 Units

Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the uncertainty

associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

-

N/A

-

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT

Repeatability at span level 0.00

-

ppm

Performance characteristics RUN 1 Units

TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS

APPENDIX 2

Measured concentration

TGN M2 Allowable MU

Limit value

% full scale

Conversion 1.61

Dependence on voltage

Standard deviation of repeatability at span level

% full scale

Deviation from linearity 0.20

%

7.90 mg/m³ (STP, dry)

Volume or pressure flow dependence 0.00

mg/m³ (REF)

15.0

50.0

RUN 1 Units

Response time 45

mg/m³

ppm to mg/m³

MCERTS Range [B] 15.0

% range

0.50 % full scale/10V

Losses in the line (leak) 1.74 % of value

Uncertainty of calibration gas 2.00 % of value

seconds

Number of readings in measurement

Atmospheric pressure dependence 0.30

ppm

Performance characteristic

Performance characteristics

% full scale

Span drift -1.06

% of full scale

Range Used [A]

mg/m³

Lower of [A] or [B]

mg/m³

mg/m³

Losses in the line (leak) 0.08

0.20

2.00Repeatability at zero

1.40

15.0 mg/m³

Cal gas conc. 138.4

Units

Dependence on voltage 0.06

% full scale/10K

mg/m³

mg/m³

Overall Allowable uncertainty (with O₂) - at 95% Confidence N/A % at ELV

Result of Compliance with Uncertainty Requirement in M2 N/A

mg/m³

mg/m³

Combined interference

Result 7.90 mg/m³

Combined uncertainty 0.25

RUN 1

mg/m³

RUN 1 Units

Standard deviation of repeatability at zero

Expanded uncertainty (with O₂) - at 95% Confidence

Expanded uncertainty (with O₂) - at 95% Confidence N/A % at ELV

Measurement uncertainty

mg/m³

Uncertainty of calibration gas 0.09

use rep at span

Atmospheric pressure dependence 0.01 mg/m³

Lack of fit 0.02

0.45

mg/m³

Cal gas conc. 86.2





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