a new approach to evaluate thermal stress under flame-resistant fabrics exposed to flashover
TRANSCRIPT
A New Approach to Evaluate Thermal Stress under Flame-resistant
Fabrics Exposed to Flashover
Yehu LU 1, a, Xiaohui LI 1, b, Jun LI 1, 2, c and Daiwei WU 1, d
1 Protective Clothing Research Center, Fashion Institute, Donghua University, Shanghai 200051,
China.
2 Key Laboratory of Clothing Design and Technology (Donghua University), Ministry of Education,
Shanghai 200051, China.
[email protected], [email protected], [email protected], [email protected]
Keywords: Thermal stress, Flame-resistant fabric, Flashover, Bio-heat transfer, Air gap
Abstract. Various intensity heat fluxes firefighters encountered will produce thermal stress on skin,
resulting in thermal pain and tissue damage. In this paper, a new approach to evaluate thermal stress
under flashover with short duration was carried out based on plain-stress theory. Instant heat flux
under fabric was calculated so as to determine temperature and thermal stress distribution. The
results obtained were as follows: temperature increased slightly at initial stage and then sharply
increased linearly, moreover, temperature was much higher when sensor directly contacted with
specimen, comparing with that of 6mm air gap; heat flux under fabric quickly reached its maximum,
and higher heat flux was observed as no air gap generated; thermal stress rapidly increased and then
gradually decreased, moreover, higher thermal stress produced without air gap. The newly proposed
method could well distinct heat transfer performance of fabric under different conditions, which
might provide helpful guideline to performance evaluation of thermal protective clothing.
Introduction
Firefighters usually encountered high ambient temperature and radiant heat flux during fire
operation and rescue [1]. Therefore firefighters should be equipped with qualified fire protective
garments to ensure the safety of their lives. However, the higher protection it provided, the less
permeable for body heat and evaporated sweat was the clothing, thus heat storage occurred and
efficiency decreased [2-4]. It was reported that thermal stress was caused by the weight and
insulating properties of protective clothing, environment and exercise performance [5-8]. Therefore,
the modern design philosophy for protective clothing was concentrated on optimized protection and
simultaneously making the wearer more comfortable [9]. The most recent statistics in the United
States reported that 55% of 118 deaths in 2007 were considered as the result of heat stress [10].
Different methods for estimating potential heat stress have been developed in ISO and other
standards by meteorological parameters and physiological variables, including the Wet Bulb Globe
Temperature (WBGT) index, the Required Sweat Rate (SRreq) index and various physiological
measurements, etc [11-13]. However, the WBGT and SRreq indices were not suitable for
firefighters to evaluate heat stress when wearing protective clothing under high radiant heat flux
[14]. Without accurate details of exposure time to a given temperature, it was difficult to determine
whether the physiological strain were the result of physical demands of activities or heat stress
imposed by environment, or a combination of the two. During firefighting activities under different
Advanced Materials Research Vols. 332-334 (2011) pp 1520-1526Online available since 2011/Sep/02 at www.scientific.net© (2011) Trans Tech Publications, Switzerlanddoi:10.4028/www.scientific.net/AMR.332-334.1520
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thermal conditions, the effects of environment and activity should be determined separately [1].
Although a large number of studies have been made [9, 15], no published data existed on
thermoregulatory responses during real life operations, as it was impractical and could be dangerous
to monitor a firefighter with physiological equipment during hazardous activities. Consequently,
study on physiological responses during fire extinguishing activities relied on data collected during
simulations of live fires [8, 16]. Problems existed when monitoring and controlling environment
conditions during fire simulations [17, 18]. Accordingly, the application of heat stress calculated by
physiological indices under simulated conditions was very limited.
Mathematical modeling of thermal responses allowed evaluation of wide performance
limitations in individuals exposed to extreme environment. Some researchers have built heat stress
models applicable for protective clothing to simulate core temperature response [19]. The predicted
heat strain model was also constructed based on heat balance considering sweat evaporation [2, 20].
The validation range on clothing intrinsic thermal insulation was extended to less than 1.0clo [21],
while it was not suitable to evaluate physiological response wearing protective clothing with
thermal insulation more than 2.0clo [22]. Since human skin is the first layer exposing to high heat
flux with short duration, there is no time for the participation of physiological regulation, and thus
the evaluation of thermal stress should be characterized directly by skin thermomechanical response.
Recently, the thermal stress of skin was determined based on plain-stress theory [23]. However,
there was nearly no reports about direct calculation of heat stress in thermal protective clothing.
In this paper, a new methodology to determine thermal stress on skin for firefighters exposed to
high intensity heat flux or flashover was carried out by using numerical methods. It could provide
helpful physiological guideline to the evaluation of thermal protective clothing considering the
thermal stress as protection performance index.
Mathematical model Formulation
Bio-heat Transfer Equations. The prediction of temperature in skin tissue mainly based on Pennes
bio-heat transfer equation [24], given as
( )2
2sk sk sk b b b a m r
T Tc c T T q q
t xρ λ ω ρ
∂ ∂= + − + +
∂ ∂ (1)
where skρ , skc , skλ are the mass density, specific heat and thermal conductivity of skin tissue; bω
is the blood perfusion rate; qm is the metabolic heat generation, qr is the heat source due to external
heating, Ta and T are the temperatures of arterial blood and skin tissue respectively.
In the present study, for simplicity, one-dimensional case was studied, as shown in Fig. 1. Blood
perfusion, thermal conductivity, and heat capacity are assumed to be constant despite of the
temperature rise. Metabolic heat generation was assumed to be zero comparing with external heat
fluxes generated from heating fabrics.
Fig. 1 Structure of multi-layer skin
Advanced Materials Research Vols. 332-334 1521
While exposing to high heat flux, the corresponding boundary conditions are as follows:
( ) 0 / 2sk
Tk q t x L
x
∂+ = = −
∂ (2)
( / 2, ) 37, 0T L t t= > (3)
Initial condition
( ,0) 37T x = (4)
Thermal Stress. During heating, thermally induced mechanical stress arises due to the thermal
denaturation of collagen, resulting in macro scale shrinkage. The stress, temperature and thermal
damage are highly correlated. In fact, skin has a complicated multi-layer structure. As the thermal
properties of the layers have the same order of magnitude, a one-layer continuum model for heat
transfer was assumed. Thermal stress on skin was constructed and the result was given as [23]
( ) ( ) ( ) ( )/2 /2
0 0 0/2 /2
12,
L L
xxL L
E xx t E T T T T dz E T T zdz
L L
λσ λ λ
− −= − − + − + −∫ ∫
(5)
where ( ) ( )2/ 1 , 1E E υ λ υ λ= − = + , E is Young’s modulus, υ is Poisson ratio and λ is
thermal expansion coefficient.
Experimental Procedure and Numerical Method. The determination of temperature
distribution in skin at different time and positions were as follows: A standard TPP testing apparatus
CSI-206 was employed to produce simulated fire environment, and the temperature at back of
testing specimen was recorded with thermal sensor, shown in Fig. 2. The detail description of this
tester was not included here. The test specimen was momentarily exposed to high intense heat flux
about 84kW/m2 for 15s. The copper sensor was contacted with testing sample or located 6mm away
respectively. A kind of Nomex fabric was employed in this study. The detail physical parameters
were as follows: the construction of plain woven fabric, warp density of 253 per 10cm, weft density
of 220 per 10cm, weight of 150g/m2, thickness of 0.36mm, meta-Aramid fabric. In this paper, it was
assumed that copper sensor exhibited a semi infinite behavior, and thus the net heat flux qt exposed
to sensor was calculated as follows:
( ) 4.184n
mC dTq t
K A dtε= × ×
× (6)
where m is mass of copper, C is specific heat capacity of copper, K is conversion coefficient, A
andε are area and absorptivity of copper sensor respectively.
The heat flux data were then introduced to Pennes bio-heat transfer model, and the finite
difference method [25] is used to solve Eq. 1 and determine temperature field in skin tissue.
Subsequently, temperature profiles were used as input to the thermomechanical model given in Eq.
5, and thus the corresponding thermal stress distribution would be obtained. A mathematical
software Matlab7.2 was used to calculate the temperature and thermal stress distribution.
1522 Advanced Textile Materials
For blood, bρ = 1060 kg m−3
and bc = 3770 J kg−1
K−1
were used. The typical thermal physical
parameters for numerical thermal stress analysis are summarized in Table 1 [23, 26], and the
thermal expansion coefficient in all layers are 0.0001/oC.
Fig. 2 Schematic of TPP test
Table 1 Thermal physical properties used in the skin
Thickness
(m)
Specific
heat (J
kg−1
K−1
)
Blood
perfusion
(m3s
−1m
−3)
Thermal
conductivity
(Wm−1
K−1
)
Density
(kgm−3
)
Thermal
expansion
coefficient
(K−1
)
Poisson
ratio
Young’s
modulus
(MPa)
0.0061 3770 0 0.5 1050 0.0001 0.48 0.6
Results and Discussion
Heat Flux Exposed to Skin Surface. Fig. 3 shows the temperature of thermal sensor when the
flame-resistant fabric is exposed to flame and groups of radiant tubes about 84kW/m2 totally with
6mm air gap between fabric and sensor. It is clear in Fig. 3(a) that the temperature increases slightly
during the initial time, and then it rises sharply with the increasing of time. According to the curve
tendency, piecewise linearity method was used to calculate the slope of temperature rise during each
time interval, shown in Fig. 3(b), (c) and (d). It is obviously that the linear regression method can
well describe the temperature rise. The slope is 0.6769, 1.9084 and 3.9956 respectively with very
high R2 >0.96. Similar method was also applied for temperature rise of 6mm air gap. The
temperature gradient was then introduced to Eq. 6, and the heat flux under fabric with 0 and 6mm
air gap was obtained respectively, shown in Fig. 4. The heat flux increases quickly and reaches its
maximum of 44.1 and 62.1kW/m2. It is clear that the final heat flux with no air gap gets higher than
that with 6mm air gap, which means that the heat transferred is much higher when the thermal
sensor contacts with fabric. Fig. 4(a) shows that heat flux quickly gets peak value when thermal
sensor directly contacts with specimen. Comparing with Fig. 4(a), the time of heat flux reaching
maximum prolongs due to existence of 6mm air gap, shown in Fig. 4(b).
The observance of nonlinear increase of temperature versus time during initial stage (shown in
Fig. 3) may be the cause of moisture evaporation and fiber pyrolysis when the fabric is exposed to
high intensity flashover. During this time, dynamic non-steady heat transfer through “flame-heating
fabric-thermal sensor” system works. Subsequently, the specimen is carbonized and combination of
fibers and char forms. The steady heat transfer process emerges, therefore temperature rise curve
presents linearly and constant heat flux under fabric produces (shown in Fig. 4). When thermal
sensor contacts with specimen, heat flux is main transferred by conduction and radiation of fibers,
Advanced Materials Research Vols. 332-334 1523
while the heat transfer style become air conduction and fibers radiation as there is 6mm air gap
between thermal sensor and testing fabric. In one hand, heat flux transferred by conduction greatly
dropped due to low thermal conductivity of air; in other hand, radiation heat transferred decreased
because of reduction of view factor due to air gap increasing. Consequently, heat transfer through
fabric decreases when there is 6mm air gap.
(a)
30
40
50
60
70
80
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Time(s)
Tem
per
ature
(℃)
(b)
T= 0.6769t + 32.855
R2 = 0.9619
32.4
32.8
33.2
33.6
34
34.4
0 0.5 1 1.5 2Time(s)
Tem
per
ature
(℃)
(c)
T = 1.9084t + 30.671
R2 = 0.9821
30
32
34
36
38
40
1.5 2 2.5 3 3.5 4
Time(s)
Tem
per
ature
(℃)
(d)
T = 3.9956t + 21.931
R2 = 0.9985
30
40
50
60
70
80
3 4 5 6 7 8 9 10 11 12 13 14
Time(s)
Tem
per
ature
(℃)
Fig. 3 Temperature rise of thermal sensor versus time with 6mm air gap
(a) sensor contacts with specimen (b) 6mm air gap between specimen and sensor
Fig. 4 Heat flux under fabric at each interval
Thermal Stress on Skin Surface. The heat flux at each interval was considered as boundary
conditions to solve Eq. 1, and temperature distribution was obtained. According to Eq. 5, the
thermal stress distribution can be determined. Fig. 5 shows thermal stress on skin surface under
condition of no air gap and 6mm air gap. It is apparent in Fig. 5 that thermal stress sharply increases
versus time, and then slightly decreases after reaching peak value; moreover, the stronger heat flux
1524 Advanced Textile Materials
is, the higher increment becomes before reaching maximum. Comparing Fig. 5(a) with Fig. 5(b),
time required to reach maximum delayed when there is air gap between fabric and thermal sensor;
thermal stress is also higher when sensor directly contacts with testing specimen.
Thermal-induced mechanical stress arises due to the thermal denaturation of collagen. As
observed above, the final heat flux under fabric without air gap was higher than that with 6mm air
gap, resulting in higher thermal stress, shown in Fig. 5. The newly developed method of thermal
stress evaluation can well distinct heat transfer performance of flame-resistant fabrics exposed to
high intensity flashover with short duration. What deserves attention here is that the mean
mechanical threshold of nociceptors in skin lies in the range of about 0–0.6MPa and mainly
between 0.1–0.2MPa [27]. The numerical results presented above demonstrate that the thermal
stress is 0.048MPa without air gap and 0.038MPa with 6mm air gap, slightly less than 0.1MPa, only
using simple one-layer skin model.
High thermal stress will result in skin shrinkage, protein denaturation, skin pain and even
thermal damage. The thermal stress is a very important index to evaluate thermal protection and
comfort, which is influenced by a number of factors including encountered environment, clothing,
human activity and thermoregulation. In this study, thermal stress only induced by instant flashover
environment was taken into consideration, without including thermoregulation response due to
human activity. The new proposed method can be applied to investigate thermal induced
mechanical stress on skin while wearing thermal protective clothing under various kinds of
condition in the future, considering multi-layer skin tissue.
(a) without air gap (b) with 6mm air gap
Fig. 5 Thermal stress on skin surface
Conclusions
Firefighters usually encountered various high intensity heat fluxes with short duration, which will
results in thermal stress on human skin, leading to thermal pain and tissue damage. In this paper, a
new methodology to calculate thermal stress on skin for firefighters exposed to flashover was
carried out according to plain-stress theory. Piecewise linearity method was employed to determine
heat flux under fabric and then introduced to calculate thermal stress. The results showed that heat
transferred through fabric was higher when thermal sensor directly contacted with specimen, and
thus heat flux under fabric was also much higher, comparing with results under condition of 6mm
air gap. Under higher heat flux, bigger thermal stress and steeper increasing slope was found. The
newly developed evaluation index could well differentiate heat transfer performance of
flame-resistant fabric under different conditions. It might provide helpful guideline to performance
evaluation of thermal protective clothing considering the thermal stress as protection index.
Advanced Materials Research Vols. 332-334 1525
Acknowledgements
This paper was financially supported by Donghua University Ph.D. Thesis innovation funding (NO.
11D10711) and Program for New Century Excellent Talents in University of Ministry of Education
of China.
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Advanced Textile Materials 10.4028/www.scientific.net/AMR.332-334 A New Approach to Evaluate Thermal Stress under Flame-Resistant Fabrics Exposed to Flashover 10.4028/www.scientific.net/AMR.332-334.1520
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