a more complicated example on z- vs. e- stereochemistry
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![Page 1: A more complicated example on Z- vs. E- stereochemistry](https://reader034.vdocuments.us/reader034/viewer/2022042721/6267ac975e2e1b6ce37a67cb/html5/thumbnails/1.jpg)
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A more complicated example on Z- vs. E- stereochemistry
![Page 2: A more complicated example on Z- vs. E- stereochemistry](https://reader034.vdocuments.us/reader034/viewer/2022042721/6267ac975e2e1b6ce37a67cb/html5/thumbnails/2.jpg)
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impossible for triple bonds to exist (and be stable) for anything smaller than a cyclooctyne
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![Page 4: A more complicated example on Z- vs. E- stereochemistry](https://reader034.vdocuments.us/reader034/viewer/2022042721/6267ac975e2e1b6ce37a67cb/html5/thumbnails/4.jpg)
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Oval
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but
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C-C-C angles about 88o , so not as bad as cyclopropane
![Page 5: A more complicated example on Z- vs. E- stereochemistry](https://reader034.vdocuments.us/reader034/viewer/2022042721/6267ac975e2e1b6ce37a67cb/html5/thumbnails/5.jpg)
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C-C-C bond angles at ca. 104o, only 5.5o off perfection
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so no angle strain to speak of in simple cyclohexanes