634 622 engineering change notice

ENGINEERING CHANGE NOTICE O f 2

WHC-SD-FF-PLN-002, Rev 4 186861, 167140, N/A 197952, 604734

12a. Modification Uork 12b. Uork Package 12c. Modification Uork Complete 12d. Restored to Original Condi- tion (Temp. or Standby ECN only) No.

[I Yes (fill out B L ~ . N/A N/A N/A 12b)

12c, 12d) Design Author? tylcog. Engineer

Signature & Date Design AuthoritylCog. Engineer

Signature & Date [XI No (NA Elks. 12b,

13a. Description of Change 13b. Design Baseline Document? [I Yes [ X I NO

This is a total rewrite of the Sampling and Analysis plan in response to, and to ensure compliance with, the State Waste Discharge Permit ST 4501 issued July 31, 1996. This revision describes changes in facility status and implements the requirements of the Permit.

634 6 2 2 ........ - ............ ~ ___.._.____...._ ECN Roj.

14a. Justification (mark one)

Criteria Change [I Design Improvement [I Enviromental [XI Facility Deactivation [ ] As-Found [I Facilitate Const [ ] Const. ErrorIOmission [I Design ErrorlOmission [ ] 14b. Justification Details Provides detailed information concerning methods of implementation of the requirements of State Waste Discharge Permit ST 4501.

,

15. Distribution (include name, MSIN, and no. of copies) Distribution List

I RELEASE STAMP

1. ECN (use no. from pg. 1 )

of 2 634622 ENGINEERING CHANGE NOTICE 16. Design 17. cost Impact 18. schedule Impact (days)

ENGINEERING CONSTRUCTION Verification Required

[ I [I

Additional [ I $ Additional [ I $ Improvement Savings

11 Yes 1x1 No Delay [ I $ Savings

that will be affected by the change described in Block 13.

I 1 $ 19. Change Impact Review: Indicate the related documents (other than the engineering documents identified on Side 1)

Enter the affected document number in Block 20. SDD/DD Functional Design Criteria

Operating Specification

Criticality Specification

Conceptual Design Repart Equipment Spec. Const. Spec.

Procurement Spec. Vendor Information

OM Manual

FSAR/SAR

Safety Equipment List Radiation Work Permit

Environmental Permit

SeismiclStress Analysis StresslDesign Report

Interface Control Drawing

Calibration Procedure

Installation Procedure Maintenance Procedure Engineering Procedure

Operating Instruction Operating Procedure

Operational Safety Requirement lEFD Drawing

Cell Arrangement Drawing Essential Material Specification Fac. Proc. Samp. schedule

Inspection Plan .. r i Inventory Adjustment

Tank Calibration Manual Health Physics Procedure Spares Multiple Unit Listing Test Procedures/Specificatio n Component Index ASME Coded Item Human Factor Consideration Computer Software Electric Circuit Schedule ICRS Procedure

Process Control Manual/Plan Process Flaw Chart Purchxe Requisition

Tickler Fits

Request L J

20. Other Affected Documents: (NOTE: Documents listed below will not be revised by this ECN.) signatures below indicate that the signing 6rgTnirStiZn has been notified of other affected documents Listed below.

Document Number/Revision Document Number/Revision SN-23-13.3 Rev. 0 LO-080-433

Document Number Revision

21. Approvals sigiiature Date

Design Authority w Safetv Environ. N.M. M e n a w Other

Signature Design Agent PE PA safety Design Env i ron . Other

DEPARTMENT OF ENERGY Signature or a Control Number that tracks the Approval signature

Date

ADDITIONAL

A-7900-013-3 (05l96) GEF096

WHC-SD-FF-PLN-002, Rev.5

400 Area Secondary Cooling Water Sampling and Analysis Plan

Lucinda L. Penn Westinghouse Hanford Company, Richland, WA 99352 U.S. Department o f Energy Contract DE-AC06-87RL10930

EDT/ECN: 634622 uc: 2000 Org Code: 10000 Charge Code: BURT B&R Code: ~ ~ 7 0 0 2 0 0 0 Total Pages: 55

Key Words: Wastewater, 400 Area Secondary Cooling Ponds, Process Sewer, 216 Permits, Sampling and Analysis Plan, State Waste Discharge Permit ST 4501.

Abstract: This is a total rewrite of the Sampling and Analysis Plan in response to, and to ensure compliance with, the State Waste Discharge Permit ST 4501 issued on July 31, 1996. in facility status and implements requirements of the permit.

This revision describes changes

TRADEMARK DISCLAIMER. trade name, trademark, manufacturer, or otherwise, does not necessarily constitute hr imply its endorsement, recomnendation, or favoring by the United States Government or any agency thereof or its contractors or subcontractors.

Printed in the United States of America. To obtain copies of this document contact: WHC/BCS Document Control Services, P.O. Box 1970, Mailstop H6-08, Richland WA 99352: Phone (509) 372-2420; Fax (509) 376-4989.

Reference herein to any specific comnercial product, process or service by

#lease Approval Date

Approved for Public Release

A-6400-073 (10/95) GEF321

. CHANGE CONTROL RECi

(3) Revision

. .

RS '

Rev. 2

3 Rev 3

5 Rev 4

i

!S,ev 5

S a except it i s ECN 604734

Incorporate ECN 634622 i p compliance w i t h S t a t e Waste Discharge Permit issued 7/31/96.

dhm- 7. A. Dillhoff

A-7120005 (12A9)

WHC-SD-FF-PLN-002 REV 5

400 AREA SECONDARY COOLING WATER SAMPLING AND ANALYSIS PLAN

i


TABLE OF CONTENTS

A .

B .

C . D .

E . F .

G .

H .

I . J .

INTRODUCTION AND DESCRIPTION OF SAMPLING OBJECTIVES A.l Introduction . . . . . . . . . . . . . . . . A.2 Objectives . . . . . . . . . . . . . . . . . A.3 Approach . . . . . . . . . . . . . . . . . . SITE BACKGROUND . . . . . . . . . . . . . . . . . . B.l 400 Area Facilities Description . . . . . . .

B.l.l Intermittent Batch Source . . . . . . . 8.2 4608 Percolation Ponds B and C Description . B.3 Stream Description . . . . . . . . . . . . . RESPONSIBILITIES . . . . . . . . . . . . . . . . .

. . . . . . . . 1 . . . . . . . . 1 . . . . . . . . 1 . . . . . . . . 2

. . . . . . . . 2 . . . . . . . . 2 . . . . . . . . 5 . . . . . . . . 5 . . . . . . . . 5

. . . . . . . . 13

SAMPLING LOCATION AND FREQUENCY . . . . . . . . . . . . . . . . . . 14 D.l Sampling Location . . . . . . . . . . . . . . . . . . . . . . 14

D.l.l Effluent Sampling . . . . . . . . . . . . . . . . . . . 14 D . 1.2 Groundwater Sampling . . . . . . . . . . . . . . . . . 14 D.1.3 Batch Source Sampling . . . . . . . . . . . . . . . . . 15

D.2 Frequency . . . . . . . . . . . . . . . . . . . . . . . . . . 15

SAMPLE DESIGNATION . . . . . . . . . . . . . . . . . . . . . . . . 16

SAMPLING EQUIPMENT AND PROCEDURES . . . . . . . . . . . . . . . . . 16 F.l Effluent Monitoring . . . . . . . . . . . . . . . . . . . . . 16 F.2 Groundwater Monitoring . . . . . . . . . . . . . . . . . . . 17

SAMPLE HANDLING AND ANALYSIS . . . . . . . . . . . . . . . . . . . 17 G.l Sample Analysis . . . . . . . . . . . . . . . . . . . . . . . 17 6.2 Effluent Analysis . . . . . . . . . . . . . . . . . . . . . . 17 6.3 Groundwater Analysis . . . . . . . . . . . . . . . . . . . . 18 6.4 Batch Source Sampling . . . . . . . . . . . . . . . . . . . . 19 6.5 Sample Handling . . . . . . . . . . . . . . . . . . . . . . . 19

QUALITY ASSURANCE . . . . . . . . . . . . . . . . . . . . . . . . . 21 H.l Objectives . . . . . . . . . . . . . . . . . . . . . . . . . 21 H.2 Procedures . . . . . . . . . . . . . . . . . . . . . . . . . 21

H.2.1 Calibration Procedures . . . . . . . . . . . . . . . . 21 H.2.2 Preventive Maintenance . . . . . . . . . . . . . . . . 21

H.3 Sample Custody . . . . . . . . . . . . . . . . . . . . . . . 22 H.4 Data Validation . . . . . . . . . . . . . . . . . . . . . . . 22 H.5 'Performance and System Audits . . . . . . . . . . . . . . . . 23 H.6 Corrective Action . . . . . . . . . . . . . . . . . . . . . . 23 H.7 Quality Assurance Reports . . . . . . . . . . . . . . . . . . 24

REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25

ACRONYMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27


L I S T OF FIGURES 1. THE 400 AREA PROCESS SEWER MAP OF CONTRIBUTING F A C I L I T I E S

AND EFFLUENT DISCHARGE ROUTE . . . . . . . . . . . . . . . . . . . . . 9

L I S T OF TABLES 1. L I S T OF CONTRIBUTORS TO 400 AREA PROCESS SEWER . . . . . . . . . . . 10

APPENDIX MATERIAL SAFETY DATA SHEETS FOR DEARBORN PRODUCTS . . . . . . . . . 28

i i i

WHC-SD-FF-PLN-002 REV 5 Page 1

A.

A. 1 Introduction

The Hanford Federal Faci 7 ity Agreement and Consent Order (Tri-Party Agreement) was signed by the Washington State Department of Ecology (Ecology), the U.S. Environmental Protection Agency (EPA), and the U.S . Department of Energy, Richland Operations Office, on May 15, 1989. Restrictions on the disposal of liquid effluents to-the soil column at the Hanford Site are found in Tri-Party Agreement Milestone M-17-00 and corresponding interim milestones. and Analysis Plans (SAPs) are required for the 33 Phase I and Phase I1 streams that are discharged to the soil column. approval of EPA and Ecology.

A SAP was prepared for the 400 Area Secondary Cooling Water. The 400 Area Secondary Cooling Water Sampling and Analysis Plan, WHC-SD-FF-PLN-002, establishes the requirements and guide1 ines used by Westinghouse Hanford Company (WHC) in implementing an upgraded liquid effluent sampling program. The 400 Area Secondary Cooling Water is more commonly known as the 400 Area Process Sewer, and the latter terminology will be used in this document. Both titles describe the same system and are interchangeable. Revision 1 of the 400 Area SAP was submitted on April 29, 1992, to fulfill Tri-Party Agreement Milestone M-17-44. This document, Revision 5 of the 400 Area SAP, implements the monitoring, quality assurance (QA), and record keeping requirements of the State Waste Discharge Permit ST 4501, issued July 31, 1996. Guidance from EPA and DOE on the establishment o f Data Quality Objectives has also been incorporated into this document.

This SAP was prepared to include guidelines and requirements for special high quality liquid effluent sampling activities, which include the following: control of samples, laboratory analysis, processing of data, control of data, QA requirements, and corrective actions used in obtaining high quality data for the Liquid Effluent Sampling Program.

A.2 Objectives

This SAP provides information on how sampling and analysis of the 400 Area Process Sewer effluent and groundwater monitoring will be performed to accompl i s h the fol 1 owing objectives :

INTRODUCTION AND DESCRIPTION OF SAMPLING OBJECTIVES

Sampling

These SAPs are subject to the

Support the monitoring requirements of the State Waste Discharge Permit (SWDP) ST 4501.

Routinely monitor the stream for flow-rate and constituents as identified in this document, to ensure that internal limits are met.

Collect data to support implementation of the WAC-173-240 engineering report for the 400 Area Process Sewer.


Provide d a t a on chemical and radiological cons t i tuents t o c a l c u l a t e loading and r a t e of migration t o v e r i f y t h e assessment of impact of continued discharge.

. QA objec t ives f o r t h e sampling a c t i v i t i e s a r e described i n sec t ion H.

A.3 Approach

This SAP has been prepared t o descr ibe a program f o r obtaining high q u a l i t y sampling da ta t h a t wi l l v e r i f y compliance with SWDP ST 4501 monitoring compliance f o r t h e 400 Area Process Sewer discharge. l i q u i d e f f l u e n t samples t h a t have q u a l i t y cont ro l led and v e r i f i a b l e methods f o r c o l l e c t i n g t h e wastewater sample, t ranspor ta t ion of the sample t o t h e ana ly t ica l l abora tory , ana lys i s of the sample, s t a t i s t i c a l evaluat ion of t h e ana ly t ica l r e s u l t s , and the s torage of sample records.

The da ta wi l l come from

This SAP wi l l i d e n t i f y t h e types of contaminants found i n the l i q u i d effluent stream from t h e 400 Area. The da ta wil l come from grab samples and composite samples t h a t have q u a l i t y cont ro l led and v e r i f i a b l e methods f o r c o l l e c t i o n , t r a n s p o r t a t i o n , ana lys i s , s t a t i s t i c a l evaluat ion of ana ly t ica l r e s u l t s , and s torage of sample records.

All charac te r iza t ion sampling work sha l l be performed according t o approved wr i t ten procedures. The procedures sha l l comply with the requirements of Test Methods for Evaluating So7id Waste, EPA SW-846, Supplement 1990, and EPA

A l l personnel associated with co l lec t ion of'samples, processing of t h e samples, processing of the data , and control of records s h a l l comply with the procedures r e l a t e d t o t h e i r r e s p o n s i b i l i t i e s . The personnel s h a l l s ign a document ver i fy ing t h a t they have read and understand the procedures.

The l i q u i d e f f l u e n t sampling u t i l i z e s both grab and time composite samples because some cons t i tuents a r e unstable with time. minimize the hold time from sample co l lec t ion t o labora tory analyses t o prevent a s i g n i f i c a n t l o s s of these unstable analytes .

60014-79-019.

Grab samples a r e used t o


6. SITE BACKGROUND

B . l 400 Area Facilities Description

The 400 Area contains four facilities which contribute to the 400 Area Process Sewer (see Figure 1). These four facilities are not cross-connected by underground piping. The process water flows out from all four facilities through individual pipelines to a sewer main pipe (see Figure 1). Area and discharges the effluent to one of two Percolation Ponds, which will be described at the end of this section.

The four contributing facilities contain 50 active contributors (i.e., points of entry) to the 400 Area Process Sewer. Table 1 identifies all the entry points, locations, and flow rates. Of the 50 active points of entry, nine routine contributors represent greater than 99% of the total water volume currently discharged into the process sewer. The 50 active points of entry and, more specifically, the nine routine points of entry will be discussed further in Section 8.3, "Stream Description." The facility descriptions and their associated points of entry are summarized below.

1. Fuels and Materials Examination Facility (FMEF). The FMEF i s designed and constructed to be a high security, multi-storied structure with the capability to handle low and high exposure radioactive materials. reprocess Fast Flux Test Facility (FFTF) fuel and experiments. Due to program and funding changes, most of the specialized equipment has never been installed and radioactive material has never been introduced to the facility. The facility is used only for personnel offices.

FMEF points of entry. The FMEF contains 41 points of entry to the process sewer. The facility i s equipped with two liquid waste systems (368 and 36D), which provide effluent holding and sampling from areas of the facility where the potential for contamination would be the greatest. Revision 0 of the Phase I1 Liquid Effluent Program Engineering Report (WHC-SD-W252-ER-001), the 368 system was identified as the Retention Liquid Waste System (RLWS). System, originally was intended to contain radioactive waste. However, with the change in mission for the FMEF, this system has not been used for its intended purpose. Waste water from the fire testing system and a lunchroom sink are the only discharges to the 36D system. The 368 system contains discharges from HVAC condensate, electric water cooler discharges, and routine discharges from testing the fire water systems. With this system, all aqueous waste generated in areas served by either the 368 system or the 36D system is collected in one of two 6,000 gallon tanks. Each system has two 6,000 gallon tanks for a total of four tanks. The effluent can be sampled for possible radioactivity and verified to meet acceptable discharge limits before being discharged into the process sewer.

The effluent does not flow from one facility to another.

This sewer main leaves the 400

The original intent was to use FMEF to fabricate and

Four are routine and 37 are infrequent contributors.

In

The 36D, or Radioactive Liquid Waste

Due t o this low volume, the tank contents are


expected to be discharged to the process sewer only one or two times a year, but may be increased to discharge as often as four times per year.

2. Maintenance and Storage Facility (MASF). The MASF consists of a main building and a two story service wing, located within the 400 Area Protected Area. The purpose of this facility i s to provide maintenance, repair, and storage facilities for radioactive or specialized maintenance equipment used in support of FFTF.

MASF points o f entry. process sewer. entry to the process sewer are not located in areas with the potential for radioactive contamination. All contaminated liquid waste is collected in radioactive liquid waste tanks and is not in contact with the process sewer effluent at any point. The radioactive liquid discharge collection system and the process water discharge are separate systems and are not connected. The routine contributor is the cooling water from the building service and instrument air compressor.

3 . 481-A Water Pumphouse. The Water Pumphouse is a concrete block building, on a concrete pad, which was constructed to provide space for a diesel fire pump and two sanitary water pumps. This building is also located within the 400 Area Protected Area. As shown in Figure 1, this facility is detached from the FFTF reactor containment and service building. No radioactive material is in this building.

481-A Water Pumphouse points o f entry. points of entry: one is routine and four are infrequent contributors. These points of entry are all related to the pumps housed in the facility. The four infrequent contributors (floor drains) are protected from contaminants by detailed maintenance procedures in the form of Work Packages with administrative controls. The fourth floor drain, a frequent contributor because of weekly fire pump testing (a National Fire Protection Association [NFPA] requirement) is protected from potential contamination since its inlet is installed above floor level. A 300 gallon fuel tank for the diesel fire pump is installed above floor level on a seismically qualified support (also an NFPA requirement). There is a very minor risk of the introduction of diesel fuel or equipment oil into the process sewer due to maintenance or an emergency in this building.

4. test reactor. allowed accelerated testing of fuels and materials. The reactor is currently transitioning towards shutdown condition.

Eight cooling towers reject heat generated in equipment supporting the FFTF auxiliary systems, such as the heating, ventilation, and air conditioning (HVAC) systems. Adjacent to the cooling towers pad, a support building contains the water treatment equipment, water quality

The MASF contains four points of entry to the One is routine and three are infrequent. The points of

The pumphouse contains five

The Fast Flux Test Facility (FFTF). The FFTF is a sodium cooled The reactor's high neutron flux levels and energies have


monitoring instrumentation, and the process controls for blowdown valves associated with the towers. This system is adjacent to the facility's reactor containment and service buildings within the 400 Area Protected Area. tower system and any radioactive wastes or nuclear materials in the faci 1 i ty . The amount of waste process water discharged is expected to remain at current levels during standby and during possible restart. Since the cooling tower treatment procedures have not changed with the change in plant status, the effluent constituents would also remain unchanged.

FFTF points of entry. The cooling towers have three possible points of entry. All three are considered routine contributors to the process sewer effluent. They are 1) the equipment drain in the water treatment building which receives the effluent wastewater discharged by the cooling tower blowdown system, 2) the drain trench on the north side of the cooling tower pad which handles overflow or draining of the towers and precipitation runoff, and 3) the sink in the water treatment building which the operators use to wash their gloves, glassware, small equipment, hands, and similar items. In the water treatment building, the only chemicals that could be discharged into the sink are those already used to treat the cooling towers (no other chemicals are in the building).

There is no contact between the process sewer and the cooling

B.l.l Intermittent Batch Sources

Three intermittent sources result in batch discharge to the Secondary Cooling Water System. Diameter Cleaning Vessel (LDCV) in MASF, and the mitigation pump bearing cooling water in the 481-A Pumphouse.

These sources are the FMEF 36B system and 36D system, the Large

The intermittent sources are:

1. 2.

3.

FMEF 368 system and 36D system. MASF Large Diameter Cleaning Vessel consisting of water used in the testing of mitigation pumps for Tank Waste Remediation Support. Bearing Cooling Water at approximately 25 gpm (once through cooling) from mitigation pump test runs.

These sources are discharged through flowpaths identified in Table 1. Condensate is discharged through many of the FMEF floor drains in Table 1, the MASF LDCV is discharged through MASF floor drain #63, and the mitigation pump bearing cooling water is discharged through MASF floor drain #77.

B.2

The 4608 Percolation Ponds B and C are engineered structures, located north- northeast of the 400 Area. The unlined ponds are 50x100 ft at the base, and are approximately 4 ft deep. The 400 Area Process Sewer empties into a diversion box built into the earthen wall dividing the two ponds.

FMEF

4608 Percolation Ponds B and C Description

Manually


operated s l i d e ga tes located on e i t h e r s i d e of the d ivers ion box determine the flow t o t h e B o r C pond. The a b i l i t y t o i s o l a t e e i t h e r pond is provided t o allow f o r maintenance.

B.3 Stream Descript ion

Table 1 i d e n t i f i e s a l l t h e poten t ia l cont r ibu tors ( i . e . , po in ts of en t ry) t o t h e 400 Area Process Sewer. Nine rout ine cont r ibu tors represent g r e a t e r than 99% of t h e t o t a l water volume cur ren t ly discharged i n t o t h e process sewer. The nine rout ine cont r ibu tors a r e discussed below. They have been given item numbers i n Table 2 f o r ease of reference.

Five of the rout ine cont r ibu tors , which a r e items 1 through 5 on Table 1, a r e assoc ia ted with the FMEF and FFTF cool ing tower systems. The o ther four rout ine cont r ibu tors , which a re items 6 through 9 on Table 1, a r e associated with a u x i l i a r y f a c i l i t y equipment and cool ing systems. The e f f l u e n t stream has the bas ic c h a r a c t e r i s t i c s of the 400 Area s a n i t a r y (potable) water supply. All of the 400 Area water i s pumped from deep wel ls and ch lor ina ted . e f f l u e n t waste stream div ides i n t o approximately 15% use from equipment and a u x i l i a r y systems cool ing, and 85% from the two cool ing tower systems.

The cool ing tower systems a t FMEF and FFTF have t h e same bas ic design and use the same t reatment chemicals. Cooling towers a t FFTF and FMEF represent t h e source of the majori ty of the water which i s eventual ly discharged t o t h e 400 Area Process Sewer, which may have been the reason f o r descr ibing t h i s discharge a s “400 Area Secondary Cooling Water. a t FMEF and FFTF d i f f e r i n demand, but t h e basic design of the towers and the chemicals used a t both f a c i l i t i e s a r e the same. The cool ing towers a t both f a c i l i t i e s a r e galvanized s t e e l , closed loop evaporat ive cool ing towers. The cool ing systems f o r the f a c i l i t i e s c i r c u l a t e a 40% ethylene glycol so lu t ion from the bui ldings through cool ing c o i l s i n the cool ing towers. Water i s sprayed over c o i l s a s a i r i s blown up through the cool ing towers by fans . evaporation of the spray water provides the cool ing e f f e c t which i s t r a n s f e r r e d through the cool ing c o i l s t o t h e rec i rcu l a ted ethylene glycol s o l u t i o n . sump capac i ty of approximately 2,000 gal lons and per iodica l ly requi re dra in ing f o r maintenance.

The chemical control systems have two object ives: t o control biological growth within t h e tower and t o pro tec t the tower from the e f f e c t s of s c a l e formation.

The b io logica l control i s accomplished by use of two d i f f e r e n t chemicals, a biocide (Dearborn 702) and ( a t FFTF only) a microbicide (sodium hypochlor i te) . Biological growth within the cooling tower i s cont ro l led because detr imental biological spec ies would t h r i v e i n a warm moist environment causing of fens ive odors o r hea l th r i s k s t o personnel. Fouling of the cool ing tower tubes with a lgae would i n h i b i t heat t r a n s f e r from the rec i rcu la ted loop t o the spray water.

The

The cool ing tower operat ions

The

The t h r e e towers a t FMEF and the e i g h t towers a t FFTF each have a


Biological growth control is accomplished by adding the biocide (702) to the sump water on a regular basis to maintain a 25 mg/l concentration in the towers. into the makeup water provided to the towers. At FMEF, however, the biocide is added daily via metering pump into a recirculated stream of water from each cooling tower sump. At FFTF, the addition of sodium hypochlorite is done manually to "shock" the tower only when maintenance requires personnel to physically enter the towers for cleaning (normally done during the spring and summer months). The microbicide sodium hypochlorite will have a concentration of 5 mg/l for the shock treatment and 0.6-0.8 mg/l if the normal 702 metering pump system is inoperative.

At FFTF the biocide (702) is continuously added by a metering pump

Scale formation protection is required due to increasing concentration of naturally occurring salts (typically calcium carbonate) resulting from the evaporation of the tower water. Primary protection is accomplished in both FMEF and FFTF by monitoring the electrical conductivity of the water in the sump. When the water conductivity approaches 1200 micromhos, automatic valving opens to discharge water. This conductivity is 3.5-4 times the average concentration of the incoming water, which corresponds to 2.5-3 cycles (uses) of the water through the cooling towers. Therefore, the concentration of nonvolatile constituents is expected to be at least 2.5 times that of the well water. Due to the discharge of water, the tower sump water level control system will initiate the addition of makeup water. continues until the conductivity of the sump water has fallen to approximately 900 micromhos due to the addition of fresh water.

The discharge of water

A scale inhibitor, Dearborn 878, is added to the towers to maintain concentrations of 50-75 mg/l in order to prevent the formation of scale. Scale inhibitor concentration control at FFTF is accomplished by metering the chemical into the makeup water to a concentration of approximately 40 mg/l. This concentration increases to the required range in the tower because of the evaporation of the water. At FMEF, the control is accomplished by metering the chemical directly into the tower when the conductivity control system opens the valve which blows down the sump water. As an independent operational check, a chemical analysis is performed in the field by the operator to ensure that the proper balance between addition to and discharges from the cooling towers is being maintained.

The chemical testing for scale inhibitor concentration involves the use of the following Dearborn Products:

Dearborn Code 595 Hydrochloric Acid Solution Dearborn Code 904 Thorium Nitrate Solution Dearborn Code 550 Sodium Thiosul fate/Borate Solution Dearborn Code 562 Xylenol Orange Indicator Dearborn Code 899 Beryllium Sulfate Solution Dearborn Code 575 Glacial Acetic Acid


The r e s u l t a n t so lu t ion from the tes t (approximately 50 ml per t e s t ) is not designated a dangerous waste s ince the beryl1 ium concentration i s .00095%, which is <.01% of the repor tab le concentration l e v e l . The r e s u l t a n t so lu t ion a t 0.0068 kglyear of g l ac i a l a c e t i c ac id added i n t o t h e system i s not designated as dangerous waste because t h e equivalent concentration i s l e s s than 0.01%. In conjunction w i t h the washing of gloves, glassware, equipment, hands, t r a c e q u a n t i t i e s of these products, along w i t h t h e o the r cooling tower chemicals described above, a r e subjec t t o disposal v i a the sinks loca ted i n both cooling tower buildings.

Pas t sampling, ana lys i s and process knowledge have ind ica ted t h a t t h e cons t i t uen t s in this waste stream a r e a t innocuous l eve l s . The cooling tower systems a r e the major cont r ibu tors t o t h e e f f luen t stream and, as shown i n t h e above d iscuss ion of chemical treatment, p resent t h e major po ten t ia l f o r dangerous cons t i t uen t s i n the waste stream. The average d ischarge amount f o r t h e cooling tower systems i s shown i n Table 1. The end-of-pipe d ischarge is not s u b s t a n t i a l l y d i lu t ed by t h e o ther cont r ibu t ing e f f l u e n t . The poten t ia l f o r e f f l u e n t d i l u t i o n wi l l be c lose ly monitored by sampling a t the major con t r ibu t ing po in t s of en t ry , as well a s f ina l discharge poin t . His tor ica l information regarding t h e stream descr ip t ion and pas t sampling da ta can be found i n "400 Area Secondary Cooling Water Stream-Specific Report" (WHC-EP- 0342, Addendum 28).

The o the r po ten t i a l po in ts of en t ry a r e cont ro l led by meaiFof systems such a s t h e FMEF RLWS. In a l l cases poten t ia l hazardous and dangerous mater ia l s a r e s tored away from t h e poin ts of en t ry and a r e cont ro l led by adminis t ra t ive procedures.

Figure 1 provides a map of t h e 400 Area Process Sewer con t r ibu to r s , and the sewer main route t o t h e 4608 Percolation Ponds. As discussed in the f a c i l i t y desc r ip t ions , t h e cont r ibu tors t o the process sewer a r e not cross-connected. The process water from each point of en t ry flows from i t s respec t ive f a c i l i t y through an outgoing 6-inch pipe, which en te r s a 12-inch diameter pipe loca ted i n t h e approximate center of t h e 400 Area. T h i s s ing le outgoing pipe runs ou t s ide of t h e 400 Area Protected Area fence, and discharges t o the one of the two Percola t ion Ponds. The e f f luen t does not flow between f a c i l i t i e s and becomes a s i n g l e waste stream p r io r t o discharge.

The major i ty of t h e poin ts of en t ry a r e inac t ive .


Figure 1. The 400 Area Process Sewer Map of Contributing Facilities and Effluent Discharge Route

S

-

FMEF Ccolinp Towen

0 1

- FenaLino - 4w Area Piccars Sewer Line - Facilii Prcars 5.wr Line

No1 Dnwn lo W e

Percolation Ponds


Page 10

Table 1. List of Contributors to 400 Area Process Sewer.

24 FD FMEFPB 2-13 204 Deleted I X Prows6 waterlcondsnsate

2 5 FD FMEF-PB 2-13 206 Deleted I X P r o c s r waterlmndensata

26 FD F M W B 2-12 3 2 1 Active I X Process watsrlcondensata

2 7 FD FMEFPB 2-13 209 Active I X Process watarlcondansats


Page 11


Process watarlcondsnsate

Process waterlcondensato

Process waterlcondensato

Process waterlcondenrata

Process waterlcondsnsnte

Process waterlcondensnte . .


Page 12


70 JS FFTF-CT 2-17 611 Bermsd R Personnel <1 <'I

71 ED FFTF-CT 2-17 611 ActiW R Cooling tower blowdown 4-25121 10

72 ED FFTF-CT 2-17 Pad Actiw R Overflow and rain 0-10 1

73 Sump FMEF-PB 106 Actiw X X

74 Sump FMEF-PB 105 Actiw X X

Notes: [11 Effluent waste water collected and stored In FMEF retention liquid waste tanks. A l l ow sampling Ifuture) before discharge to process sewer. [21 Variance re~ulfs from ambient conditions IFMEF Cooling Tower 0 flow for Novembar through March). 131 Facility support system intermittent operation. [41 Flow is infrequent and nonroutine. Flowrate h not available.

Legends: FFTF-CT = FFTF cooling tower area on 483 Pad MASF-HB = High-bay area of 437 Bldg. FMEF-MI = 4862 Entry Wina FMEF-PB = 427 Process Bldg. FMEF-CT = FMEF cooling towers area MASF-ER = Equip. room of 437 Bldg. FMEF-FAA = 4862 Fuel Assembly Area ED = Equip. drain FMEFXEW = 427 Emergency Equip. Wing PH.481-A = 4 6 l d P u m p h o ~ e FMEFMEVJ = 427 Mach. Equip. Wing EWC = Electric water cooler FD = Floor drain JS = Janitorlal Sink

C. RESPONSIBILITIES

The responsibility descriptions below are related to wastewater sampling activities occurring at the 400 Area as described in this SAP. responsibilities for other components o f the sampling program are described in the QAPP.

Overall

FFTF Regulatory Compliance personnel will do the following: . . . . . . . . . .

Submit monitoring data to Ecology in compliance with SWDP ST 4501.

Coordinate the overall program.

Maintain the 400 Area Secondary Cooling Water SAP.

Ensure that procedures are prepared to support the sampling activities.

Initiate scheduling of personnel required for sampling.

Provide technical support for sampling activities.

Review data logs and sampling activities.

Oversee Chain-of-Custody activities at the facility.

Review sampling data for completeness and consistency, initiating corrective action if necessary.

Submit copies of analytical results of drinking water to Washington State Department of Health and Ecology.

Coordinate maintenance and surveillance of sampling and monitoring systems.

The Sampling and Mobile Laboratory organization will do the following:

Provides sampling and transportation of routine monitoring program sampl es.

Provides trained samplers for sampling activities.

Provides at least one sampler with a Certificate of Qualification from the Sampling and Mobile Laboratories Group.

Prepares and maintains the 400 Area wastewater sampling and packaging procedure.

Ensures that the certified sampler directs sampling and packaging.

Documents sampling activities in a log book.

0


Transports samples to laboratory or shipping center.

Initiates Chain-of-Custody documentation for samples.

Packages samples for shipping.

Ensures that copies of field logs and other sampling data sheets are filed with FFTF Regulatory Compl lance cognizant engineer.

Analytical Services (AS) performs the following:

Provides data validation services.

Selects a laboratory for analysis of samples.

Tracks, receives and inspects sample analytical records generated in support of this project.

The 400 Area QA organization does the following:

Prepares and maintains the QA Program Plan.

Provides surveillance of the sampling program.

Audits records and procedures.

Issues a stop work order if procedures are not being followed.

D. SAMPLING LOCATION AND FREQUENCY

D.l Sampling Location

D.l.l Effluent Sampling

Effluent sampling activities include composite effluent sampling and continuous pH, flowrate, and conductivity measurements at the North Environmental Monitoring Station, also known as the flow meter hut, Building 46088 (see Sampler Weir on Figure 1). analyzed once every 60 days (hereafter referred to as bi-monthly). (circle chart) pH, flowrate, and conductivity measurements are collected '

weekly. location provides a representation of the total contribution to the 400 Area Process Sewer. The analytes of interest for the bi-monthly composite sample are specified in Section 6.2 of this document.

D. 1.2 Groundwater Sampl ing

Groundwater samples will be taken from two points, 1) FFTF groundwater monitoring well 699-8-17 (upgradient) and 2) FFTF groundwater monitoring well

A composite sample is drawn and Continuous

As discussed in the stream description (Section B . 3 ) , the sampling


699-2-7 (downgradient). The groundwater sample analytes are shown in Section 6.3.

A third well will be operational by July 1998. Sampling of the new well shall commence in the third quarter of 1998 and shall be consistent with the requirements for the other wells.

D. 1.3 Batch Source Sampl ing

Samples of batch discharges from the FMEF 368 System and/or 36D System will be taken and analyzed for the constituents listed in Section 6.4, Analytical Requirements, prior to discharge. The sample analysis will be completed and evaluated prior to discharge.

D.2 Frequency

Bi-monthly composite samples will be taken from the process sewer sampler, located in Building 4608B. The bi-monthly periods are defined as January- February, March-April , May-June, July-August, September-October, and November- December. Composite sampling will consist of collecting no less than 10 ml of effluent per four hour interval. This bi-monthly composite sample will comply with the written facility operating procedures. These procedures specify the appropriate procedure for operating the equipment, using a clean sample bottle, collecting representative effluent, and appropriate transportation to the laboratory. Grab samples will be taken from the effluent stream at the time the composite sample i s collected.

Samples o f batch discharges listed in section D.1.3 will be analyzed on an as needed basis prior to discharging either the 368 system or the 360 system to the 400 Area Secondary Cooling Water System. These discharges can occur once per quarter each.

Quarterly groundwater samples will be taken at the groundwater monitoring wells. The four quarters are defined as January through March, April through June, July through September, and October through December.

Additional sampling events may be conducted for additional verification of constituent analysis. These sampling events will be conducted by the same responsible personnel as described in Section C. Quality control samples such as field duplicates will be taken during each sampling event and will confo;m to the criteria listed in “Test Method for Evaluating Solid Wastes, SW-846.

Field duplicate samples will be taken during each sampling event. Duplicate samples shall be retrieved from the same sampling location at approximately the same time, and under identical conditions and preparation, to verify the repeatability of the laboratory data. independently . Monitoring for the flowrate, pH, and conductivity of the effluent is done on a continuous basis by installed instrumentation. With the exception of

Field duplicates shall be analyzed

VHC-SD-FF-PLN-002 REV 5

Page 16

flowrate, these conditions will also be monitored by the sampling team when those sampling activities are conducted. make the appropriate environmental observations in log books, and used the prescribed control samples to assure a quality data record of the sampling environment.

E. SAMPLE DESIGNATION

For bi-monthly composite samples, the sample is transferred by Mobile Sampling from the sampler receiving bottle into clean, labeled, one liter bottles. The date and time of sample collection, the stream identification, the sampling location, identification of the person in charge of collecting the sample, preservative added, and the analysis to be performed on the sample will be included on the label with the unique identification number.

Liquid effluent and groundwater samples will be assigned a HEIS number by AS.

Sample labels for liquid effluent and groundwater characterization samples will be provided by the sampling team from the Sampling And Mobile Laboratory. In addition, each bottle shall be identified with a bar code sticker attached to the bottle by the bottle manufacturer. The bar code shall identify the bottle lot number and individual bottle number.

The sampling team is also trained to

F. SAMPLING EQUIPMENT AND PROCEDURES

F . l Effluent Monitoring

The routine monitoring of discharges to the 4608 B and C Percolation Ponds is performed in the North Environmental Monitoring Station located north of the 400 Area. As discussed in the stream description above, this location is the representative point to obtain a typical sample of the total facility effluent stream. The characteristics for which the effluent is continuously monitored include pH, flowrate, and conductivity. Where applicable, preventative maintenance and calibration procedures are used to maintain the sampling and monitoring equipment.

The bi-monthly composite effluent samples will be analyzed for the analytes shown in Section 6.2 in accordance with methods from either EPA SW-846, or EPA-600-4-79-019. A state accredited laboratory will perform the analysis using current approved procedures and QA requirements. The data sheets and analytical results from the laboratory will be transmitted to and maintained by FFTF Regulatory Compliance.

Data and record information that has been validated will be transmitted to the Administrative Record or to the HEIS data file when it becomes available.


F.2 Groundwater Monitoring

"Procedure for Collecting RCRA/CERCLA Samples From the 400 Area Secondary Cooling Water (Process Sewer) System" (WHC, LO-080-433A.0) is the facility- specific procedure for effluent characterization sample collection and analysis. requirements, which include the following:

The sampling procedure identifies 400 Area-specific sampling

Sampling location.

A description of sampling equipment, containers, and reagents.

Safety precautions, including personnel protective equipment.

Specific steps for collecting the sample.

Instructions for completing field notebook entries, sample labels, and sample Chain-of-Custody forms.

Field logs will be completed per the "Environmental Investigations and Site Characterizations Manual ," WHC-CM-7-7, procedure E11 1.5 "Field Logbooks", during the sampling event. The logbook shall contain information pertinent to the sampling, including any intermittent sources at the time of sampling.

G. SAMPLE HANDLING AND ANALYSIS

G.l Sample Analysis

The actual analyses for the required analytes are discussed in the WHC-SD-EN-SPP-002, "Data Val idation Procedures for Chemical Analyses." All parameters specified will be analyzed to the PQL values listed in SWDP ST 4501 and according to the required analytical methods specified. Alternate methods may be used as long as PQLs can be met. Certain parameters will be monitored to provide an early warning that allowable limits for discharge to groundwater are being approached. Attainment or exceedance of an Early Warning Value will be reported to Ecology within ten days of detection.

6.2 Effluent Analysis

The requirements of this section apply to the bi-monthly composite and grab samples of the 400 Area Secondary Cooling Water System taken from the flow monitoring hut, Building 46086 and, described in Section D.l.1. The bi-monthly effluent samples will be analyzed for the following:

- -. . 15 I 7060/200.8 I toc"

11 Cadmium I 7440-43-9 I 5 -r 60 davs It


Page 18

Chloride Cobalt C.yani de Gross Beta Par t . Act. Lead Manganese Ni t r a t e Ni t r l t e Phosphorus PH Total Di sso l ved Sol i d s Total Organic Hal ides Tritium

7439-92-1 10 7421/200.8 t p c 60 days 7439-96-5 50 6010 tPC 60 days 14797-55-8 100 9056/300 grab 60 days 14797-65-0 100 9056/300 grab 60 days 7723-14-0 50 365 t P C 60 days N/A 0.1 pH units 9040A/150.1 grab/ tpc 60 days N/A 10,000 160.1 tPC 60 days

N/A 20 8260 grab 60 days

N/A 460pCi/L l a b s p e c i f i c grab 60 days __ ~~

* t p c = time proportional composite

6.3 Groundwater Analysis

The requirements of t h i s sec t ion apply t o t h e groundwater monitoring well sample po in t s l i s t e d .in Section D.1.2.

Groundwater samples will be analyzed f o r t h e following:


Page 19

6.4 Batch Source Sampling

The requirements o f t h i s sec t i on apply t o t h e batch samples taken from t h e FMEF 36B system and 36D system as described i n Sect ion D.1.3.

The a n a l y t i c a l requirements p r i o r t o batch d ischarge a re as fo l l ows :

Regulatory Compliance w i l l au tho r i ze t h e discharge o f each batch t o t h e 400 Area Process Sewer upon v e r i f i c a t i o n o f acceptable r e s u l t s from t h e sample analys is . A n a l y t i c a l da ta w i l l be submitted t o Ecology w i t h i n 30 days o f discharge.

6.5 Sample Handl ing

Samples w i l l be c o l l e c t e d i n commerci a1 l y a v a i l able, i n d i v i d u a l l y c e r t i f i e d , precleaned g lass o r p l a s t i c conta iners. The c e r t i f i c a t i o n o f t h e precleaned c o n d i t i o n s h a l l accompany t h e conta iner . The sample volumes and number o f con ta ine rs are p resc r ibed by t h e a n a l y t i c a l l a b o r a t o r y and are sub jec t t o change. Container types and preservat ives are discussed i n t h e f a c i l i t y - s p e c i f i c sampling procedure, From t h e 400 Area Secondary Cooling Water (Process Sewer) System."

Preservat ives requ i red above w i l l be vendor suppl ied and added t o t h e conta iners by Sampling and Mobile Laborator ies personnel. sealed t o t h e con ta ine rs w i t h tamper-evident tape. The p rese rva t i ve w i l l be added t o t h e conta iners i n l a b o r a t o r y environment p r i o r t o be ing taken t o t h e f i e l d . The con ta ine rs w i l l be labeled, then i n d i v i d u a l l y bagged and rebagged. The con ta ine rs w i l l be labeled, then packaged i n accordance w i t h t h e

"Procedure f o r C o l l e c t i n g RCRA/CERCLA Samples

The caps w i l l be

"Hazardous Material Packaging,,and Shipping Manual ," WHC-CM-2-14 and the "Radiation Protection Manual, WHC-CM-4-11.

Sample bottles will also be prepared for field quality control samples. The facility-specific field sampling procedure identifies this preparation and analytes to be evaluated for each field quality control sample.

Field notes will be kept by sampling personnel who will identify date, time, weather conditions, and any other relevant information from each sampling event.

Custody of the samples is initiated at the time of sample collection. sample may consist of several containers. The Chain-of-Custody will account for each container and a separate form will be filled out for each cooler. Once the sample has been drawn, it must be in the physical control or view of the custodian, locked in an area where it can not be tampered with, or prepared for shipping with tamper-evident tape applied. The definition of physical control includes being in the sight of the custodian, being in a room which will signal an alarm when entered, or being locked in a cabinet.

When more than one person is involved in sampling, one person alone shall be designated to sign as sampler. are transferred to another location or group; he or she shall sign when releasing the samples to the designated receiver. transport the samples and Chain-of-Custody documentation shall be bonded.

A

The sampler is the custodian until the samples

Any private carrier used to

The samples will be routed to an approved Hanford Company participant contractor or subcontractor laboratory for analysis consistent with SW-846 or EPA-600/4-79-019 requirements.

The data will be considered representative so long as at least 90 percent of the data points meet the established requirements in the laboratory contract for precision and accuracy. Data which does not meet this objective will be reviewed to determine whether the data can be used or whether corrective action should be taken. Corrective action measures are described in section H.4. If necessary, corrective action will consist of repeating the sampling and/or analysis activity. Validated data will be sent by AS to Administrative Records. The data will be part of the administrative record for Tri-Party Agreement Milestone M-17-16. An electronic database (LEMIS) for management of this data is being developed and will be accessible by EPA and Ecology.

All sampling and analytical data will be maintained by the sampling task leader as quality records. Mobile Laboratories. Custody, and activity screening results will be sent to AS. The original shipping papers will accompany the sample. Copies of the Sample Analysis Request form and Chain-of-Custody form will be returned to AS from the laboratory after the samples are received. The original shipping papers will be kept by the laboratory, and the copies maintained by AS.

The field logs will be maintained by Sampling and Copies of the Sample Analysis Request Form, Chain-of-


H. QUALITY ASSURANCE

H.l Objectives

The QA objectives address the test measures that will be taken to achieve analytical results of known and acceptable quality. The QA objectives, as described in WHC-SD-EN-SPP-002, are target levels for precision, accuracy, representativeness, and completeness.

H.2 Procedures

Effluent sampling will be performed in a manner that provides representative measurements of the volume and concentration of contaminants. All sampling activities will be conducted in accordance with the guidance provided in SW-846, Test Methods for Evaluating Sol id Waste PhysicallChemical Methods (EPA 1897b) and EPA 600/4-82-029, Handbook for Sampling and Sample Preservatfon of Water and Wastewater (EPA 1982b), and shall conform to the latest revision of the "Guidelines Establishing Test Procedures for the Analysis of Pollutants," contained in 40 CFR Part 136.

The samples collected under this program will follow the sampling procedure found in WHC-CM-7-7. Environmental Investigation and Site Characterization Manual and adhere to the requirements of the Manchester Environmental Laboratorv, Lab Users Manual, Washington State Department of Ecology, 4th edition, January 1994.

H.2.1 Calibration Procedures

Calibration of all WHC measuring equipment, whether in the existing inventory or purchased for effluent sampling, shall be controlled as required by WHC-CM-4-2, Westinghouse,,Hanford Company Quality Assurance Manual, QR 12 .O, "Control of Instruments, and "Quality Instruction," Q1 12.2, "Operator Calibrated Measuring and Test Equipment." Equipment calibration will be conducted according to manufacturer's recommendations unless otherwise directed to address unique conditions at the facilities. Also, for some streams the only sampling equipment is a long rod and sample bottles. No calibration procedure will be required for this method.

H.2.2 Preventive Maintenance Procedures

Measurement and testing equipment used in the field and laboratory that directly affect the quality of the analytical data shall be subject to preventive maintenance measures that ensure mlnimization of measurement system downtime and maximize performance. When field equipment maintenance is necessary, instructions shall be as defined by approved procedures. (Flowmeters are not available for some effluent streams. Also, the only sampling equipment for some streams are a long rod and sample bottles. these cases, preventive maintenance will not be required.) be responsible for performing or managing the maintenance of their analytical equipment. Maintenance requirements, spare parts lists, and instructions

For Laboratories shall


Page 22

sha l l be included in individual methods o r in labora tory Quality Assurance/Qual i t y Control (QA/QC) plans subjec t t o RL cont rac tor review and approval.

H.3 Sample Custody

All samples taken by Sampling and Mobile Laboratory during t h e course of t h e cha rac t e r i za t ion program sha l l be cont ro l led by f i e l d t racking documentation from t h e poin t of o r ig in t o t he ana ly t i ca l l abora tory . documentation and guidance i s spec i f ied in WHC-CM-7-7, Environmenta7 Inves t iga t ions and Si te , ,Charac te r iza t ion Manual, Sections E11 5.1, "Chain of Custody," and E11 1.5,

A designated sample custodian accepts custody of t h e shipped samples, v e r i f i e s t h a t t h e sample numbers match those on t h e "Chain of Custody" form, and v e r i f i e s t h a t t h e custody s e a l s were in place and i n t a c t upon r ece ip t of t h e shipping conta iner . cou r i e r is entered in the "remarks" sec t ion . according t o t h e sample custody procedures as spec i f i ed in t h e QA/QC plan f o r t he ana ly t i ca l l abora tory .

H.4 Data Validation

The samples wil l be taken and shipped t o the ana ly t i ca l l abora tory by t h e Sampling and Mobile Laboratory with the coordination of t h e f a c i l i t i e s . Analytical Laboratory sha l l be respons ib le f o r preparing an ana ly t i ca l l abora tory da t a package.

Several l e v e l s of da t a have been developed f o r Resource Conservation and Recovery Act o f 1976 (RCRA) da t a packages. These da t a va l ida t ion pLocedures a r e described in "Data Validation Procedures f o r Chemical Analysis. The da ta package sha l l include the information necessary t o perform da ta va l ida t ion t o t h e ex ten t ind ica ted by the minimum requirements of Validation Level B. The da ta packages sha l l be prepared in l e g i b l e , reproducible format; any changes must be i n i t i a l e d and dated. In genera l , a l l ana ly t i ca l l abora tory da t a packages should include t h e following:

F ie ld t racking

Fie ld Logbooks."

Per t inent information as t o t h e shipment method and The samples a r e then tracked

The

Sample r ece ip t and t racking documentation, including copies of chain of custody forms, i d e n t i f i c a t i o n of t h e organization and ind iv idua ls performing t h e ana lys i s , t he names and s igna tures of t h e respons ib le ana lys t s , sample holding time requirements, re fe rences t o appl icable chain of custody procedures, and t h e da tes of sample r e c e i p t , ex t r ac t ion , and ana lys i s .

Q u a l i t y Control (QC) da ta , as appropr ia te f o r t he methods used, including matrix spike/matrix sp ike dup l i ca t e data , recovery percentages, p rec is ion da ta , l abora tory blank data , and i d e n t i f i c a t i o n of any nonconformance t h a t may have a f fec ted t h e 1 abora tory ' s measurement system during the ana lys i s time period.

The analytical results or data deliverables, including reduced data, reduction formulas, or algorithms.

Results of data assessment including central tendency and dispersion, measures of variability, and significant tests. Also, data quality indicators of precision, accuracy, and completeness will be included.

0 Other supporting information, such as calibration data, reconstructed ion chromatographs, spectrograms, traffic reports, and raw data, needs to be included in the submittal of individual data packages.

All sample data shall be retained by the analytical laboratory and made available for systems or program audits at the request of the RL contractor, EPA, RL, or Ecology representatives. Such data shall be retained by the analytical laboratory through the duration of the authorization work order, or the period of their contractual statement of work; at that point it shall be turned over to archiving within the RL contractor.

The completed data package shall be reviewed and approved by the analytical laboratory's QA manager before submittal for validation. The requirements of this section shall be included in procurement documentation or work orders, as appropriate, in compliance with the standard WHC procurement control procedures.

H.5 Performance and System Audits

In general, analytical samples shall be subject to in-process QC measures in both field and laboratory. Audits, in the form of system surveillances, shall be performed to evaluate field activities for compliance with established QA program and procedure requirements.

System surveillances are performed in accordance with FFTF QA surveillance schedules. System surveillances shall be implemented through the use of WHC-CM-4-5, Qual i ty Assurance Qua l i f ica t ions and Ins t ruc t ions , QAI 10.4, "Surveillance." Additional performance or system audits shall be performed if necessary as a consequence of corrective action requirements.

Any discrepancies observed during the evaluation of performance audit results or during system audit surveillance activities shall be documented on a surveillance report and resolved in compliance with procedure QAI 10.4, "Surveillance."

The internal QC checks performed by the analytical laboratories shall meet the requirements specified in the laboratory QA/QC plan and SW-846 (EPA 1987b).

H.6 Corrective Action

Corrective action required as a result of surveillance or audit activity shall be documented and dispositioned as required by WHC-CM-4-2, Westinghouse Hanford Company Q u a l i t y Assurance Manual, QR 15.0, "Control o f Nonconforming


Page 24

Items;" QI 15.1, "Nonconforming Item Reporting;" QI 15.2, "Nonconformance Report Pr:cessing;" QR 16.0, "Corrective Action;'' QI 16.1, "Trending/Trend Analysis; WHC-CM-4-5, "Quality Assurance Qualifications and Instructions;" QAI 10.4, Surveillance;" and WHC-CM-7-6, Environmental Compliance Verification Program Manual. Copies of all surveillance, nonconformance, audit, and corrective action documentation are QA records and shall be maintained on completion or closure.

H.7 Quality Assurance Reports

As stated in Section 10.0, liquid effluent stream activities shall be regularly assessed by surveillance and auditing processes. nonconformance, audit, and corrective action documentation shall be considered QA records and shall be documented and dispositioned as such. management requirements applicable to subcontractors or participant contractors shall be defined in applicable procurement documents or work orders.

Surveillance,

Records


I . REFERENCES

Ecology 1990, Water Quality Standards for Ground Waters of the State of Washington, WAC 173-200 Washington State Department of Ecology, Olympia, Washington,

Ecology 1994, Manchester Environmental Laboratory. Lab Users Manual I. Washington State Department of Ecology, Olympia, Washington.

Ecology, EPA, and DOE 1989, Hanford Federal Facility Agreement and Consent Order, Washington State Department of Ecology, U. S. Environmental Protection Agency, and U. S. Department of Energy, Olympia, Washington.

EPA 1986, Title 40, Code o f Federal Regulations, Part 264, Appendix IX, as amended, U.S. Environmental Protection Agency, Washington, D.C.

EPA 1987b, Test Methods for Evaluating Solid Waste - Physical/Chemical Methods, SW-846, Rev I , 3rd ed., U.S. Environmental Protection AgencylOffice of Sol id Waste and Emergency Response, Washington, D.C.

U. S. Environmental Protection Agency, Washington, D. C.

U. S. Environmental Protection Agency, Washington, D. C.

SW-846, Second Edition (1982), Update I (April 1984), Update I1 (April 1985), 47 methods of Third Edition and Revision I (December 1987), U.S. Environmental Protection AgencylOffice

EPA 1991, National Primary Drinking Water Regulations, 40 CFR 141,

EPA 1991, National Secondary Drinking Water Regulations, 40 CFR 143,

EPA 1982, 1984, 1985, 1987, Test Methods for Evaluating Solid Wastes,

WHC 1988, Environmental Investigations and Site Characterizations Manual, WHC-CM-7-7, Westinghouse Hanford Company, Richland, Washington.

WHC 1988c, West inghouse Hanford Company Quality Assurance Manual, WHC-CM-4-2, Westinghouse Hanford Company, Richland, Washington.

WHC 1988d, Environmental Compliance Verification Program Manual, WHC-CM-7-6, Westinghouse Hanford Company, Richland, Washington.

WHC 1989, 400 Area Secondary Cooling Water Stream-Specific Report, WHC-EP-O342,,Addendum 28, Westinghouse Hanford Company, Richland, Washington.


WHC 1992, Procedure for Collecting RCRAICERCLA Samples From 400 Area Secondary Cooling Water (Process Sewer) System, LO-080-433A-0, Westinghouse Hanford Company, Richland, Washington.

WHC-SD-EN-SPP-002, Westinghouse Hanford Company, Richland, Washington. WHC 1996, D a t a Validation Procedures f o r Chemical Analyses,


J . ACRONYMS

AS CASN CERCLA

CFR DOE DL Ecology E PA FFTF FMEF HEIS HVAC LDCV LEMIS MASF MSDS NFPA OSM PQL

QWQC QC RCRA RL

RLWS SAP SWDP TDS TOC TOX Tri-Party Agreement

VOA WAC

%PP

Analytical Services Chemical Abstract System Registration Number Comprehensive Environmental Response, Compensation, and Liability Act o f 1980 Code of Federal Regulations U.S. Department of Energy Detection Limit State of Washington Department of Ecology U.S. Environmental Protection Agency Fast Flux Test Facility Fuels and Materials Examination Facility Hanford Environmental Information System Heating, Ventilation and Air Conditioning Large Diameter Cleaning Vessel Liquid Effluent Monitoring Information System Maintenance and Storage Facility Material Safety Data Sheets National Fire Protection Association Office of Sample Management Practical Quantification Levels Quality Assurance Quality Assurance Program Plan Quality Assurance/Quality Control Qual ity Control Resource Conservation and Recovery Act of 1976 U.S . Department of Energy, Richland Operations Office Retention Liquid Waste System Sampling and Analysis Plan State Waste Discharge Permit Total Dissolved Solids Total Organic Carbon Total Organic Hal ides Hanford Federal Facility Agreement and Consent Order Volatile Organic Analysis Washington Administrative Code

APPENDIX

MATERIAL SAFETY DATA SHEETS FOR DEARBORN PRODUCTS

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Customer No. 33337C 01 Ticket NO. 033761 WHC-SD-FF-PLN-002, REV 5

Page 29 MSDS # \07bl .- Material Safety Data Sheet 708-438-1 800

S-ChIoro-2-amthyl-~-I.othl.rolin-3-onr 26112-55-4 1.i5 Total isothiarolines (TUA:O. 1 w/e3)

2-Ket!1yl-+isothS&zol in-3-one 2682-20-4 0.35 {STEL: 0.3 ~ g / r 3 ) (tlanuf. rrcoenrnd. ) , ncgnrriur Chloride 7786-30-3 C 1.0 Not &rblilhed

Hrgneriw Hitrate 10377-60-3 C 3.0 Not Ort ib l i shsd Uater 7732-18-5 (96 .0 Hot crtrbl irhed

8OILING WIt~T.76Omm He 212 F MELTINGPOINT HA FREEZING POINT I. VCPORPRESSC 'RE zwa Ha e57.. SPECIFICGRAVITY IHZO- :I 1. Ql SOtU8IL ITY I N HYO & P P I S a L I I ) l P

SVOLATILES BYVOLUME . . VAPORDENSITVIAIR- I! 0. .St. EVAPORATIONRATL 1 9 u k - I ) Cl PH -

APPEARAMCE & OCOR P r l t rnber to grrcn l i q u i d . pungrnt odor.

AUTO IGNlTlON INAIR%%YVOCUME Haru4tmr-bd+sd product LO&ER ViER TEMP&4TURE

EXTINGOWING MEDIA. FO&n CU2 DRY LaERnrnc SPECIALFIRE FIGHTING PROCEDURES.

Ucrr rrspirrtor (pressure-dmand, sr l f -contained broclthin rpprrrtus, nSHA/HIOSH c provrd or e q u i v r l m t ) and 9 u l l protcctivc g m r . f ire and oxpored oontriners.

h a utter oprry t o cool

UNUSUALFIRE ANDEXPLOSION HAZARD$

Avoid cxporurm to f a n and vapors fro. i firs--oin pocsfbly inoludo uulfur dioxide, hydrogen chlnridc , 4nd oxldrs a t n l t r o g m .

HAZARDOUS DECOMPOSITION PRODUCTS

Therm1 dmoonpouitlon produets BbL! lnolod. hydrogrtt chlor ide , O l i d e . Df' sulfur dnd oxides o9 nitrogen.

._. CONDillONS TO AVOID

G R G E Dearborn Dwri#rn DMilmn W. R Gmw I GY. . Conn., 3GU Genesas Smet, lake Zurich, IL 60047 (708) 438-1803

89/84/96

- .'

-""L - - - - ---

e INI(AL.A'CION INGESTION: . Harmful 1:' s i m l l o w d SKId CONTACT: Corrosive t u rk?n& crises b u r n 8 EYE COHTACT:

t n h d l a t i o a af mist 6riII i r r i t r t e r e s p i r a t o r y p r s s a g r s . Harmful iC a b c o r b r d through skis

Cotrosi\e to G e r i causes p e r s i r a n t , i r r w c r s i b l c ryo inJiJry . DELeYEO EFFECTS: S v b s t e n C t oda GJUS, a l l c r g i a ¶kin t e r c t f o n . ----- - --__-

EMERGENCY AND FIRSTAIDPROCCDURES

Ulhar p ~ Q t m c t i V ~ c l o t h i n g . s l ash-proof go g l w L in c r v i o u u a v e r s h o e s . Rseave c o n t r a i n r t e d c l o t h i n g prompt ly ; l i u n d r r tt?qrouphly !.Fare r e u 8 r . Urrh a f f e o t w l s k i n w e a s ugth soap and uatmr CAUTION: kea s p i l l s o u t of s u n i e i p r l wuws and open b o d l a 8 of u r t w . Dike 'and r b r c r b 8 p i f 1 v i t h i n r r t a r t r r i a l (dry e a r t h , FJiId). Shovel a l l c a n t r s i n d t a d solids ( d i t i n m a t e r i a l , r b r o r b s n t and sell) i n t o cor ros lon-proof drums for s t o r a g e u n t i l i iqosa l .

WASTE DISPOSAL METHOD Recoeosnded method of e i s p o s r l : d i k i n g n r t s r i r l , b t 4 p r r a i t t e d f l e i l l t y , i n rOCOcdJnCC u i t h F a d r r r l , loedl. and s t a t , r r g u l a t i o n 8 . Rmfer t o p r o d u c t l a b e l for a d d i t i o n a l d i s p o s a l i n f o r r a t i o n .

i n o i n e r r t s u n u a n t d p w d u o t and o o n t r a i n a t o d

T h i s p r o d u c t is not. formula ted u i t h o h r m i c r l r rubjoct t o t h o r e p o r t i n g r e y u i r e a e n t o a f S e c t i o n 313 a+ t h o Erergoicy P l a n n i n g 4nd C m a u n i t y Right-to-Kaou ~ c t of 1986 and 06 40 CFR 352.

r K L L . h Y l r U N D I V S t I A K C N IN HANDLINGANDSTCRAGE

Do n o t c a n t r m i n r t r Uiter, faod or f w d by rtarr or di8pOSbl Keep oantriners o l o s c d uhen not i n use Do not store p r a d u c t i n steel c o n t a i n e r s .

Wash doroughly ret& h a n d l i n g .

' - . harborn Dlui6lon W. R Grace h Co. - Conn., 300 Geneses S!met, Lob Zurich, IL 60047 (7081 438-1800

.. . .. .. .... I

09/04/96 13:48:54 1-589-376-212E-> 5091763941 Page EO5

WHC-SD-FF-PLN-002, REV 5 Paoe 31

Sodium ThicrulPate Sodiur Borate

Urtcr

10lQZ-17-2 CQ.5 k t ertrbIished 1330-43-4 C Q . 35 ! b o t e s t a b l i s h e d

7732-18-5 > 99 N o t rpplicsble

M S D S # 012925

SOlUfvG POINT. 760 mm Hg 218 f ?&LilNG POINT HA V 4 W R PRESSURE NU

VAPCR GENSITI (A IR- nV EVAPORATION KATE, .Bu A<-11 LA rlC GRAVITf IHIC- 1 j I . v SCL&lilW I N HZO

-?RE~ZNG P O W nlro-&oAe

%VUWTILES SV VOLUME TU OH u - LV APPEAMNCE S COOR Clear, qolorlzss l iqu id .

”ASH POlM 18 MElHC3 USED) FAhWBLE .IMITS .N AKYBY VWJME AUTO IGYlIlDN

~XTINGUISHING MEDIA: unitn cl lu - Firef i htere shculd wear fvll protec t ive gear including self contained breathqng apparatus.

SPECIAL F I E FIGHTING PR&EDU?ES:

VNLISL‘AL FIRE A N 3 EXP!OSIC,N HALLPD. None knoun

STABILIW a 2 i T . L CONIXIONS)

iVCOWATl8lUlY INA:ERIALS ‘0 AVOIC)

Acids. alkrloidrlt s n t a l l i o s a l t s and silver halidor

HAZkRDDUS DECOMPOSITION RODUClS H o w knocn

Gwx;E Dearborn W. R. Orcca L Co. . Conn.. ?W C+nesea Skeet, Lohc Zdrieh, IL 620-47-2158

No TLV e s t a b l i s h e d For p r o d u c t .

I N H A L A T I O N :

INGESTION: SKIN CONTACT:

See S e c t i o n 2 ?or component i n f o r m a t i o n . EFFECTS OF CVEBEXPOBURE:

Avoid b r e r t h i n g vapors or mist rrhich may i r r i t a t a r e s p i r a t o r y passdgas. nay be h o r n f u l i f s u a l l c u e d . Pro longed or P r e o u r n t s k i n c o n t a c t may c a u s e i r r i t a t i o n .

0 1 2 9 2 5 SMIBGENCY AND FIRST A I D BOCEOURES

II1HILATICN: INGESTION: C a l l p h y s i c i a n . SKIN COWTACT: F l u s h s k i n u i t h Urter, t h e n Uash u i t h soap znd u r t e r .

EYE CONTACT:

MSDS $# Rcrrovs a f f e c t e d p e r r o n s t o f r e s h a i r .

Uash c o n t a a i n d t e d c l o t h i n g before reuse.

I n m e d i a t e l y fTosh eyes w i t h u r t a r f o r 15 minutes . C a l l p h y s i c i a n .

D i l u t e u i t h l a r g e amount of u a t c r . Slash 4oun d r a i n u i t h excess uater.

T/A%i DISPOSAL METklOD

Dtsoose of in a c c o r 4 o n c e u i t h f e d e r a l . s t a t e and l o c a ? r e g u l a t i o n s . This p r o d u c t is n3C f o r m u i a t r d u i t h =heaica:s 3 U b J e c t t o t h e r e p o r t i n g requirecmts a f S e c t i o n 313 of the Emergency Planning and Comaunity Right-to-Knou Act of 1986 and of 40 CFR 372.

h g r e d i e n t s c l a s s i i i e d as EPA hazardous L 'as tc under 40 CFR 261: a n t r p p l i o a b l e CERCLA r e p o r t a b l e q u a n t i t y 00 p r o d u c t : none

ag/e4/9fi i3:4z:z9 l-S99-3?6-ZlZE-i 5893763941 WHC-SD-FF-PLN-002, REV 5

Page 33

Pase 888

USNUMEEX X EXPOSURE CR!lERlA

Hudroohlorio a c i d

Uater

7647-01-0 C5 Ceiling limit: 5 ppm

7732-18-5 > 95 Not established

g s ~ s # 6 1 2 9 2 7

Calorless to p r l o yel?ou liquid uith pungent 3dor

@WEZ APPER

ilcl i cs FLU - LXTlNGYISHiNG MEDIA: SPECIAL ilQE FIGHTING PRCCEDLRES:

Firefighters should vear Full pritecrivcr gear.

UNL'SUAL FIRE A N 5 EXPLOSION HAZnfiD. None knoun. ,

S i l v e r , l ead. mercury salts , metals, s t rcng a l k a l i

HAZARDOUS DECOMPOSITIGN P1ODUCIS

Chiorinr gas, hydrogen gas if dllOUed to react with net r l .

GR!GE Dearborn W. R. Ora:9 6 Co. . Conn.. 300 Gcmerea S r r a i , toke Zur'ch, IC brB47.2rCB [798)~Ja.!BM

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WHC-SD-FF-PLN-002, REV 5 Page 34 * - ’ . . - . . .-

TOXlCllY INFORMATION Exposure l e v e l n o t e s t a b l i s h e d f cr p r o d u c t . a n f o r a s t i o n .

E f F M S OF OVEREXKXURE

INHALATIOH: Inhdld t iCP 09 mist may i r r i t a t e r e s p i r d t o r y p r e s a g e s . INBESTION: HrrmPul if c u r l l v u e d i s o r r c s i v c l iquid say c a u s a t i s u e ddeage.

Sea S e c t i o n 2 for component

MsDs#O12927.

SKIN CUNTfiCT: Prolcnged or f r e q u e n t s k i n c o n t a c t uFlZ cau%e i r r i t a t i o n EYE CONTACT: Will cauae i r r i t a t i o n )

EMtilGiNCY AND FIRST AIC PROCEDURES

i n $ CdUSC chmmaoa? burn,. mdy be severe and lrry c a u s e tissue ddarge .

INHALATIOH: Remvr a f f e c t e d prrscnr t o Fresh a i r i n d t re r t symptoms. INBESTION: DO NOT i r d u o e v c m i t l n Dive large q u a n t i t i e s o f water . Give a t

SKIN CONTACT:

EYE CCNTACT: Flush e y e s u l t h u r t e r f c r 15 minutes. C a l l p h p i c i r n .

least one ounce of m i l k of irgnesia in a n e q u a l m o u n t e+ water , cr t h r e e e g g , y h i t e r . C a l l p h y s i c i d n F l u s h s k i n uirh urter t h e n uash uith‘soap and tJrt.Fr. Launder c o n t d a i n d t e d c l o t h i n g before reuse.

V hiilLA’10N REQUIREM hTS Jse a d a u r t e n c e h n i c r l v e n t t z a t i o n . KfiRATO& P R C T E C ~ S P P C I F Y TYPE)

-YE PRO:SC.i!y~ LOVES F a c e sttie d or c h i a i o r l g o g g l e s OTHER W07ECTlVE C?CR,Iffi AND iSUPMENi

riocd recoasandcd D i s g o s s f b l e l a t e x

STEPS ‘0 TdKE IF MTERIAL IS ZELE4SE3 CR S11:LED Neutralize s p i l l u i t h sodium b i c I r b o n a t C ox a soda ash-s laked l i m e a i x t u r e ( 5 0 - 5 0 ) . , nix t o f o r a a s l u - r Scoop dRd Udsh doun the c r d i n tJith excess water. Ash site os s p i l l wirh soda and a s h s o l u t i o n .

- W45TE CISPOSAL MfTHOD

Dispose o f i n a c c w d r n c e u i t h faderil, s t a t e and l o c a l r a g u l r t i o n s . ’ U n t r e a t e d p r o d u c t is c o n s i d e r e d dn EPt? c o r r o s i v e h a z a r d o u s Udste. DOOZ

(40 CFR 261), a t d i s p o s a l . C o n t a i n s C SX of h! jdrochlor ic a c i d , CAS HO. 7647-.31-0~ uhioh ady r e q u i r e report ing un@w section 313 oe SARA T i t l e I11 and 40 CFH 378. CERtLA rRpOrtdble q u a n t i t y of p r o d u c t : 1115 g a l .

?REC4UTICNS T O BE TAKEN Ih iANCLNC AND STOPAGE

Store c o n t a i n e r s c l o s e d w a y f r c a extreae t e a p c r r t u r r s .

OTHER PRECAUT!ONS

FOR INDUSTRIAL USE 3 N Y . KEEP OUT OF REACH JF CHILDREN.

http://tJrt.Fr

89/84/96 i4:ze:n 1-589-376-2128-> se9376394i Page e11

WHC-SD-FF-PLN-002, REV 5 Page 35

Emagoncy- Material Safetv Data She&

OerylIium Sulfite 13510-43-1 C 5 NA - 0.002 sg/r3 (1% Re)

(See Section 6)

MSDS # 0 1 2 9 2 8

:Xerr. colorless^ odorless l i q u i d

Not applicable H&OWE~ NHaDEi l

- EXTlNGLtlSHiNG MED'A: U A I ~ K ~L)II runn LUC-ALHL SPEClCl PIRE FIGHTiNG PPOCEDVRES:

Firefighters should uedr full protectiva gear including self contained breath ing apparatus .

UNUSUAL FIRE AND EXROSION HAZARD: None knoua

Caostio

HAZARCCUS DECOMPOSITON PRODUGS

Sulfur oxides

C N ITIONS TO AVO k? detarmzneP

GRACE Dearborn W R. Groca dr Co. . Conn., 300 Genesee krsct, toke Zurich, IL 43047-2458 !7081d38-1@02

89/84/96 14:28:46 1-589-376-2128-> 5~~3763941 Page E12


T XIC lY INFOfMATIPN P x c d s u r e eve no es I b r . i s h c d f o r p r o d u c t Sea S e c t i o n 2 for component i n f o r m a t i o n . oara inogan .

EFFECTS Cf OVEREXPOSURE INHALATION: I n h a l a t i o n of m i s t n a y i r r i t a t e r e s p i r a t o r y parsa$er.

Barylliuo is l i s t e d by IARC ;nd NTP as a s u s p e c t animal

I H G E S T I O N : nay be harmful i F s u a l l o u s d . MSDS#G12928 SKIN CONTACT: Prolonged or f r e q u e n t s k i n c o n t a c t may CIUSQ i r r i t a t i o n . EYE CONTACT: Kay cause i r r i t a t i o n on direct c o n t a c t .

INHALATION: Relnovc a f f e c t e d person t o f r e s h air and t r e a t s y n p t c a s . INBESTION: If consc ious , g i v e u i t e r t o d i l u t e and o o n t d c t p h y s i c i a n

rmmsdi r t r ly . SKIN CONTACT: Uash d q f e c t e d d r e a u i t h soap and water. Remove

contaminated o l o t h i n g and l a u n d e r beiore reuse. EYE CONTACT: Flush ui:h u r t e r f o r 15 m i n u t e s and seek a c d i c d l a t t e n t i o n .

EMERGEXCY AUO FIRST AID PROCEDLRES

VENTIW ON 9 QUIREM UIS U$e a!d&atc e e c k d n i s a l v e n t i l a t i o n ( l a b hood) to remai? below exporure cr i ter id R SPIRATO Y PR r crioh I ~ ~ ~ ~ i ~ ~ VP $ar NI%sH%:~SH~ approved HPFA respirator if m i s t i n g o f r e a g e n t occurs. C?hjleo%a~I%:gg l e s S u t y i Rubber

E E P R TE G OVES

OhER ??O7bXVE CLOTHING ;ND EQLIPMENT

3 i t t3 1 0 ' A K t I? I M i E R I I \ L 15 RELEASED OR FILLED

Col lec t . on a b s o r b e n t paper 4 n d dispose of u i t h l a b o r a t o r y IJsste. Ydsh area o f spill u i t h u r t e r .

WASTE DISPOSAL METHOD

Dispose o f i n accordance u i t h f e d e r r l a s t a t e and l o c a l r e g u l a t i o n s . C o n t a i n s C 5% of b e r \ ; l l l u m sulfate, ChS NU. 13S10-49-1, u h i c h ma r e u i r t r e p o r t i n g under S e c t i o n 313 o f SARA Title IIL and 40 CFR 372 as !ery?liua. The CERCLR r e p o r t r b l e q u a n t i t y Of b e r y l l i u m compounds is 1 Ib. I n g r e d i e n t s c l a ? i s i f i a d Is EPC( h i r a r d c u s u a s t e under 40 CFR 261: b e r y l l l u e (POIS).

83/84/96 15:27:27 1-589-376-2128-> 5893763941 Paye 817

WHC-SD-FF-PLN-002, REV 5 Paae 37

Potassium Chloride Xylenol Orange

7447-40-7 199 Not established 3518-43-7 (0. 1 NO'. eltablished

016069 USDS #

EXI;NC-LIISH hG MEDIA. UIILK SPECIAL FiRE F t G i T I N G XCCt3;RES:

Fireeighters shculd uedr full p r o t e c t i v e gear including self contdined b r e a t h i n g apparatus .

UVUSUAL FIRE AN3 EXPLCSICN A A ~ R D :

None knoun.

:NCOMPAIIBIUTI (MATERIAU 7C AVOID)

iilvcr solutions .

HAZMDOUS CECCMPOS~:ICN P k 0 0 U C S

Not datereined

C V W I G N 0 V ID 8ibi 'appli&?e MALARWUS POLIMERI24lION ,

U a l l not oocur

Dearborn 9d. ?. Grocs B Co. . Conn.. 300 Genesee Sirrrt, lake Zurich, It 60047.2458 (708) ~38.1800

n9/8w96 i5:2;1:83 1-589-376-2128-> 5893763941 WHC-SD-FF-PLN-002 Page 818 Matenal Safety Data sheel :cw:.Y,K) CODE 562 REV pG 38 C O N T 3 U E O

No TLU e s t a b l i s h e d f o r p roduc t . S e e S e c t i o n 2 for component i n f o r a r t i o n . EFFECTS OF OVEREXPOSURE:

:NHALATION: SKIN CONTACT: Pro longed o r f r e q u e n t s k i n c o n t a c t mag c a u s e i r r i t a t i o n . INGESTION: flay be harmful i f sua l l cued .

I n h a l a t i o n 3f powder msy i r r i t a t e r e s p i r a t o r y t r a c t .

VAEQGENCY A N C FIRST AID PROCEDLRES INHALATION: Renave d f f e C t e d p e r s o n s t o f r e s h a i r and t r e a t symptoms. INGESTION: Give large q u a n t i t i e s of uater or milk. C d l l p h y s i c i a n . WIN CONTACT: F l u s h w i t h u a t e r f o r !5 minutes. Wash n ' i t h soap and wa te r .

EYE CONTACT: Inmedia te ly f l u s h IJith u a t e r For 15 rs inutes . C a l l phys ic ian . Remove COntdmlndted c l o t h i n g and rrrsh b e f o r e r euse .

Flush t o d r d i n : J i th e x c e s s u a t e r

Wk5lE DiSPOSAL MEMOD

Dispose of i n d c c o r d s n c t u i i h =edera l< s t a t e a34 l o c a l r e g u l a t i o n s . T h i s p r o d u c t is n o t i o r n u l a t e d with c h e n i c a l s s u b j e c t t o t h e rsporting

r e q u i r e c e n t s 09 S e c t i o n 313 of t h e Emergency F l a n n i n g .and Community .Yight-to-Knou Act of 1986 and o f 40 CFR 371.

I n g r e d i e n t s c l a s s i f i e d as EPA h r r a r d o u s u a 5 t e u n a e r 4 0 CFR P b l : n a t a p p l i c a S l e CERCLA r e p o r t d b l e q u a n t i t y of produc t . none

XKAUJ!OHS TO BE TAKEN iN HANDLNG 4ND STCRAGE

S t o r e c o n t a i n e r s closed duay from extreme tempera tures .

- OME~~CAUIICNS F5R INDUSTRIAL USE ONLY. KEEP OUT 3F REACH OF CHILDREN.

GRACE Dearborn W. P. Grocs & Co, . tom., 300 Ocneies Sceei, Lskc Luiich, IL 40047.2658 17CEIa38.1803

89/84/96 15:29:42 1-589-376-2128-> 5893763941 Fage 821 CODE 904 rnw iuiicn

PG 39 WHC-SD-FF-PLN-002, REV 5

IOXIC,N ,NFCR&A:ION No SLY e s t a b l i s h e d f o r produc t .

EFFECTS OF CNEPEXPOSURE: INHALATION: I n h r l d t i o n o f mast ad4 i r r i t a t e r e s p i r a t o r y p t r sdges ; INOEBTION: nay b e ,hrrmful if suallaued.

SKIN CONTACT: Prolonged or f r e q u e n t a k i n contac t may cause i r r i t a t i o n . EYE CONTACT: Will cduse i r r i t a t r o n .

EMEPGENCY AGD FIRST AlD,P%XEDWES INHALATIEJN: R~dlovs a f f e c t e d Forroar to f r e s h a i r & t r e a t symptoms. INGGESTIO#: If conscious, g i v e uater to d i l u t e h contact phys ic ian . SKIN CONTACT: Flush s k i n . u i t h u a t e r t h e n wash u i t h soap dnd Uitdr. Wash

COntdlslndted c l o t h i n g b e f o r e r euse . EYE CONTACT: I Q Q e d i a t e l y f l u s h eyes u a t h u a t e r for 15 a i n u t e s .

Call phys ic ian .

See Section 2 f o r component in format ion .

01634-&

VCNIIU-ION PECUIRWEN-S

?ESPIRATCEY P K V C'K)N SFECiFY R?E)

EYE PROTEC7ON GLCVES S a f e t y giasses DispO%ablC l a t e x OTPER ?RO-ECII\.E CLGTHIW AND ECUI?Id..E1\1

Ute r d e q u a t c neehai i c s 1 yen t i l a t i o n . None specla!-

Dilute u i t h l a r g e amount o f u a t e r . Uash down d r a i n u i t h excess wa te r .

WASrE DIS?OSCC METHOD

Dispose of i n dccorddnee u i t h f e d e r a l . s t a t e and local r e g u l a t i o p s . Check u i t h s ta te or l o c a l d e p d r t a e n t cf r r d i d t i o n G o n t r o l i p r o d u c t IS NOT c l a s s i f i e d as a r a d i c a c t i v e u r s t e . C o n t a i n s CO. 05% o f thorlur n i t r a t e , CAS NO. 13823-29-5, n i t r a t e compounds ( u a t e r d i r r c c i r b l c ) , uh ich mry r e q u i r e r e p o r t i n g under s e c t i o n 313 o f SARA Title 111 and 40 CFR 372.

i n a o s t s t a t e s t h i s

PRfCAJIICNS TO 6E TA<EN IN H4NCLlNO AND S i 3 U G i

Store c o n t a i n e r s c l o s e d w r y frcm ext reme tempera tures .

GWCE Dearborn W. R. Grace 8 Co. . Conn., 200 Geneses Street, Lais Zur'ch, it 6COd7.2d58 (7081 438-18M

. . ..._

09/53/96 15:29:86 1-583-376-2128-> 5593763941 Page 825

WHC-SD-FF-PLN-002, REV $ Page 40

WT SHIPPING NAME CHERICPILS, NOI, W7ER TESTING REAGENTS

1 CAS NUMBER X EXPOSilRE CRtTERIA

rhoriun Nitra te 13623-29-5 CO.QS Not e s t i b l i r h e d U d t W 7732-18-5 > 99 Hot es tab l i shed The l e v e l a+ alpha r a d i a t i o n o f Code 904 thorium n i tra te i s equivalent t o Q.OQOOZS microcur:rr per grra . Alpha rsd idt ion d ie s not penetrate the s k i n .

016348 MSDS #

331UNG ?DIM, 760 mm *a 21,. F Mfi?Inh’G PO:NT ND ‘REEZI’.IG PClNl YAPOR PPESS W E flu 3APOR DENSITY IAiR-II .iU EVAPCRA’IIDN ?A-E, IBu Ac-ll ‘.l

, KVGlAlltES SY VOLLNE J Y Y 4-a A P P W N C E b OWR

DH

-It G?.AVIN ;H?O=’ I I. u S0LUB:LITY .N HN m i 5 c : ~ i e

Clear, colorless, cdor le s s so lu t ion .

‘LASH ?Oh1 [S MLE’k05 USE)! ‘L4MMAB.E LIMITS .N A.RX BY ‘JOL’J.ME AL-0 IGNITICN N O t dpplicdble NA LOVIER NII LPPER N&EMPERLTURE

s-XFSRmsWk?E4l: ______ . 1 CK F U> S P t i i A r FIRE ilGhl1NS %KCiDUP.EE.

breathing rpparatur. F ire f ighters should tiedr f u l l pro tec t ive gear including self contdioed

IJNUSUAL i . R E AND EX~LOSIGN HAZAi(D.

Nons s p e c i a l

INCWATIBILITY IM4TERIALS TO AVO Dl Soluble Fluorides

HAZARKXS DECOMPCSlTlrJN PGDUCTS Not determined

GRplcf Dearborn

89/84/96 :5:38:53 1-589-376-2128-> 5B9376334 1 Page 823


Materiat Safety Data Sheet 708-438-1 800

Pat*r.iur otrloridw 7447-40-7 0.05 Not estrbli8hrd Wter 773t-16-5 3 W Not established

TE PERATVRE Nut epplls4bcla NR NA lit

LOWER

-- ~ X l i N G U I S H l N S EDIA: S E C I A L F I R E F I G ~

F lrr f i htrrr should umr tu11 prot tot ivc grrr lboluding self aontrined Srrrthfnp apparatus.

UNbSUAL FIRE AND EXPLOSION H A U \ R D :

NDnc knoun

Strong oxidizing rpretr

HAZARDOUS DECOMPOSITION PRODUCTS

Hot drterninmd F

HAZ4ROOU 5 POLYMEIIZATION CONDITIONS TO AVOID c at a

GRACE Dearborn W, R. Grcce I Co.. Conn., 300 Gensrce Slmf Lake Zurich, It 60047-2458 (708) 439.1600

BEST LE COPY

83/84/96 15:31:39 1-589-376-2128-> 589376341 WHC-SD-FF-PI N-002 P a w 824

ErposIJre level l o t estab1;shed for produvl EFFECIS OF OVEREXPOSURE,

INHALATXON: I n h a l a t i o n of aist 0.y i r r i t a te r e s p i r a t o r y passages. INGESTION: nay be harmful if aurl1ou.d. SKIN C0NTI)CT: Prolonged or frequent skin COnt8Ct ~ a y owIr i r r i t a t i o n . EYEXMIWT: D s r r o t nULWYrriPrLtrtion.

EMERGENCY AND FIRST AIDPROCEDURES

INHALATION:

INGESTION: If conscious, giw uster t o d i l u t e I c o n t a c t phys ic lan . SKIN CONTACT: Uash u i t h soap L water. Reaovr o o ~ t m i n a t m d c l o t h i n g rnd wash

EYE CONTRCT: F lush rgec u i t h u r t r r f o r 1S ainutes.

ReRWe a f f c c t r d persons t o frosh air and t r r r t s y r p t o s s .

bsfore reus.. C o n t a c t phys ic ian .

VENT1 ATION EQUIR M E N S

RESPIRATORY PR~lECTlON (SPCCIFY TYPE) Use ahmuat5 w o i a n i c a ~ vratilrtioa.

GLOY 5 Oiworrbie l a t e x

OTHER PROTECTIVE CLOTHING AND CPU!PMLNT

A. STEPSTOTAKE IFMATERIAL IS OELEASEDORSPliLED

D i l u t r uith larpm r r ~ u n t o f w a t r r . U1.h down P r a t n w i t h riots8 wtw.

WASTE DISPOSAL METHOD

D i s p o r c o f la rooordrnte u i t h h d e r a l t t t r ta and lac41 r e g u l a t i o n s . T h i s produot i s not f O V w l # t e d w i t h ahemioals subjeot t o t h e r e p o r t i n g rrquirenmto of Srctioa 313 of t h e Eeergcnoy Planning and C o a r u n l t y Right-tO-Knou bot o f 1W6 aRd c+ 40 CFR 372.

Product 4s sold n o t w n s l d e r t d rn EPA hazirdcus waste nor d o r s it oontdfn l a p r r d i ~ n t s , o l a s s i t l t d r s herardous wstr i n 40 CFR 261.

, ..__ - -_ . . ....__..._..,._ -.-. ".__ S t o r e o o n t a l n e r s olored awry fro. extresr k m p c r a t u r m s .

OTHER PRECAUTIONS

FOR INDUSTRIAL USE ONLY. KEEP OUT O f REACH OF CHILDREII.

PREPARED BY: K. R U t m ..-

GWGE Dearborn W. R, Grace & C1. . Conn., 333 Geneses Strest, lake ZJrich, It 60047-2458 (7C8) 458-1BGO

89/84/96 15:33:83 1-%9-376-2128-> 5893763941


C3JS-F NO. 935370 01 Ticket No. 062765

@

Organophosphonia ac id , p o t a s s l u m s a l t 67955-76-8 C 10 Nat rstablished

- Pale yellow liquid

TEMPERATURE NR LCWER NA UPPER NR,udter-bdsed product

~ I N G U I S H hGX%DR--- SPEC At FIRE FIGHTINmCEOURES

___ - T m n T - - ~ u t us: LnkniLa --

Firefighters should uear full protective gear Including self c o n t a i n e d braathxng apparatus.

--- -- _-_ UNUSLAL FIRE AND EXPLOSIOKhAZMD

Nane knoun

Raids, o x i d i z e r s

.- - I. _- -. .. -.. - ., HAUPSDOIJS DECOMPOSlllOll lXODUClS

Tkrrnrl decoepositlon p r o d u o t s r a y iRclUdE c a r b o n m o n o x i d e a n d carbon dioxide.

HTGRWUS POLYUERIZATIOV COND,I,GNS __ ToAVC)!@ ..- . .... .. .. _. . ..

Will n o t a m u r Not r p p l i - b l S ..

; ' ( i: ;- ' . , .. W . K. Grice & Co. . Csnn., 3:Y) Gereree :Ireel. LcCe Zurich, iL 60047,7458 iSC7168~1300

89/84/96 15 :34 : 14 1-589-376-2128-> 5893763941 WHC-SD-FF-PLN-002 Page 827

a

M$@@-y'?v Data sheet b=:cmhr.ued) DEARBORN 87B REV 5 PG 44 CONTlNUED

TOXlWY INFORMA:I@N. 3,. 1 I '.,.! ?. J{ c,i!

, . (. . r . Sec+io"6jI,j .* __ Exposure level n o t e s t a b l i s h e d f o r product .

4. !:: . .J. >>.I *.' * *:' K?:. I I ,3 <

, . . . , -

MSDS # 022946 5FFECT.5 OF CWEREXPOSUXE:

INHALdTION: I n h a l a t i o n of m i s t may i r r i t a t e r e s p i r a t o r y p r s s r i c r . INGESTION: nay be hdrBfXJ1 i f s u a l l o u r d . SKIN CONTACT: Prolonged or f r e q u t n t skin c o n t a c t ray c a u s e i + r i t # t i o n . E.YL.COHTACT: Direct c o n t a c t u i t h p r o d u c t r r y . p ~ u ~ ~ r . r _ j & a t i o n . . tMtRGtNCY AND H Y S I Al:! PKOCtUUKtS

IHHNATION: Remove a t f c o t a d peCron t o f r e s h a i r and t r e a t syaptoos . INGESTION: If consc ious , g i v e u d t e r t o d i l u t e and c c n t a o t p h y s i c i a n

SKIN COHTACT: Uash u i t h soap L urtcr . Remove oontaEina tad o l o t h i n g and

€YE CONTACT: Flush u i t h u r t c r f o r IS r i n u t e s and srak E e d i C r l a t t e n t i o n .

i r B r d i a t e 1 y .

wash b e f o r e reuse .

5 : o V E S _. Impervious (Rubber recommended)

V n E R PRVIECI!VE CLWHiNG AND :OJIPME,ILpIT

MA EQ A L IS RELEASED OR SP'LlE3

Flush drea O ? . S p i l l u i t h u a t e r . Wear r o t e o t i v e o l o t h i n D i k e s p i l l and soak up on an i n e r t d b s o r b e n t n a t a r f a l .

-__.-__ %-@SAL METHOD

Dispose of i n rocordance u i t h f r d c r r l t s t a t e and l o c a l r e g u l a t i o n s . This p r o d u c t is not fOrSUldted u i t h Ohe8iCdlS SUbJeot t o t h e r e p o r t i n g r e q u i r e a e n t s of S e c t l o n 313 o f the Eaergency Pldnning and Community Right-to-Knou Act OF 1986 and OF 40 CFR 372. Product ab sold not cons idered an EPd hazardous u a s t e nor d o e s it c o n t a i n i n g r e d i e n t s c l a s s i f i e d as hazardous u a s t e i n 40 CFR 961.

Store c o n t a i n c r s c l o s e d away from e r t r e r c tempera tures .

OTHER PRECAUTIONS

FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILOREN.

PREPAREDBY: Jeff H a w s . na,F 77fi79~--------~ __

G R A a ' W. f i . Grace 8 Co. ' Coni.. 300 Cmerse %re=:. Loke Zvr:ch, I1 60047 2459 :a471 4 ? 8 . ! 3 ~

1-589-3?6-2128-> 5893763341 Page 023 83/04./96 ?5:36:16 , . . . . . , - , 3.:-Di . . : - ' : : - '> ,,.:<,;.a ..&A. .-.>. -".L--> .il .-c-,-* .- .. .' WHC-SO-FF-PLN-002, REV 5

Page 45 Van Waters & Rogers Inc. ** Material Safety Data Sheet ** * '

h t e ; 0 5 / 1 9 / 9 6 Tknw l?rS3r21

Fax: 1509-373-0559

6100 Van Watetr &

Caril lon Point , V N X W

206-889-3100

85/84/96 15:36:39 1-589-376-2128-> 589376394 1 Page 838 WHC-SD-FF-PLN-002, REV 5 , ' c i - & ~ . - / ~ , , L a a,..<,:, ..=..a, . ' . S I .',.>-,a Q -..,:-.> 1 L

Page 46 . 033 04/21/83 Xl31C1J HYXCELOX'PE 7 - : 5 h

PRC;DVCT w: 'IODIVX EYPOCELORIPJZ 7-154

WOE W: OXG22680

1. PRODUCT LDLNZIFICA210N

PRODUCT W: SODIUM EYPCCXLORITE 7-158 EYWONYKE: ti uid ehlozLnc, liquid bloach, Puce Chlor, lenny Po: IS0 QlMICAL F d t Y : Xypechlorlto rARIxa: Naocl i n uatar OGPCRSPTIOH: Briruntnp 001 chlorinator, Wcrcbiooido 0189 Bum CLl#I1F'1C&ON: OYldCrer, unetrble (rriatlua), carrasiuh

to skin and u p s , Lung toxin

MSDS # 023398

BULK CE!lfifTY Not Appiicrble L ORPRESSURE I 23 t 8 S . C : N o Da:i IOLVB1L:TY I N WATZ1: Xl~oibla YOLRTILES, P E W ! BY VOLUIIE: 87.5-94.5 ZV&&'OSAATIDN RAZZ: NO Dat8 VIOOR DENSIfY: Yo Data XOLEcULLR WEIGHT: 7 4 . 5 ( i ce lv r ingradlcnc-NmCl) ODOR: Chlorino-llka COPFFICIIZN'E Or OIL/WA2PX DIPIP.IBUTION: No Data

m B 2s DBC.C. > 11

~~

Page 47

MSDS # 023398

v. PUUW P~~OTECTIM r e u z m WQWI-S PIPSONIL PR~TBCZICII rorr ROVTIPZ us1 or P ~ U C T :

xP,sPrRRTo?iY PI1DTLCTrw: Rarpirrrot prorecrlon nor noraully rince the v o l a t i l i t y and toxicity ar. la. If vapor., ml~tr, or aaro.olr a m Seneratcd, wear a Nromn/ MXA apprwd c o # p i r a t ~ r .

YEh'TILkTIGN: Local exhaumt vantilition rrcamndrd i f vapor., mieta or a.roaol8 a m genrtatmd. Othorwfra, ura 9ener.l exhauat ventilation.

6KIN PROTECTIVE Z Q U I ~ N T : Uno ch~aLoa1 srfoty yogp1.m a n d f m p n r r b l m g1ovc..

RPimIRn'fCR 2Yp1:

CLOVB TYPE: H s u ~ r r n o

EQWIPKPFT SPLCIrT~TIONs: NIOOH/WZ& apprwmd rmrpirifor aquippd with ahamioal oartridgar fer protaotion againat ohlarina gas and du.t m i a t prr-filtsr..

BWT TXPL: r r o i n o r m r ~ y nu- APm T U C : Not norm l l y naarkd PROTICBIVL 8'J:B: Wot normally n u d d

.

83/84/96 15:38:52 1-589-376-2128-> 5893763941 P a w 832

VXIZ. t1aw 1.1) EYES: I m m o a i a t i l y llush w l t h large amounts of v a t a r ror a t l a a r t IS

minutma, o c c a s i o n r l l y l f f t t a g t h e upper rnd lower ayalidr. Call p h y s i s i a n a t oaaa.

BXIN: ~aaadiatoly flush with w a t e r t o r r t least 15 minutar. Call a p h y s i o i a n . If c l o t h i n g O O N ~ i n ovntaot with tha prcduot, tho o f o t h i n g ahould b. r o r o o v d inmodittaly aad should b. laoadsrad lmfori ri-ura .

INOPIQTION: I m n u d i a t o l v o m l t i n p . a l l a phymfc lan a t onao. DO WUJ! wive a n y t h i n g Ly mouth if t h e p r a m i r u n c o n r c i o u a or i r hrving coapulrions.

ZNBAGATIOH: If p e r s o n r x p r i o n o a r n a u m a , haadmhe or dirrinarr, preron should atop work innudiatdlp nnd m v a ta fraak sir unttl t h a x a emtoms disappear. I: b r r a t h l n p 11 ditZioult, rdmlnirter oxy en, kea t h a paraon nitm and rf rcit. Call 8 p l r y r i a l r a . In !ha even! that a n i n d i v i d u a l inhales 8nough v i p o r to 108. c c n r c l o u s a e r a , pizron should bm movrd to fresh a i r a t o n c e and n physioiaa should bo oa11.d innnrdimtmly. If b r o m t h i n g has n t o p p d , a r t i f i c i a l r a c p l r r t i a n rheuld im g i v e n irrmudlrtrly. I n all onre#, ansura rdeguato uent lht ion and pswida r o r p l r a t o r y p r o t e a t l o n bcforo tha p a x r o n r u t l f n s t o work,

drink lar a q u a n t i t l a s of watar. Do MOT lnduoo

1%. ZOXCOZOQY &!!3 K W T K XHTO-TIQT IUWTBS or IIBPOMTION

I n h a l a t i o n , alcln, aym, ingastion RUNIMO ITXItbItNTS AKD RWINQ PRO?LR?IES

Zbl ZYPILZD OX i Y Q S O L D . -4 i P ULPOPZD a0 SKIN dR S M S . H W TXKWHOLD RCSPONSZ DATA

ODOR TIIRIltlSOGD; A p p r o r i i u t a l y 0 . 9 rg/d ( 0 . 3 ppm) b a s a d on do: of ohlorlno.

IlcRlTITICw THXEBEOLD: X'hrr* 18 no data Zor lrrltrtion thrirhold. S d l W h p p o c h l o t i t a hrr t h e p t a n t i a l to b6 inmodiataly d a n p r s o u s Co l $ f F 01 h a a l t h .

MQS # 023.39 8 p i t s , s ~ ~ . AND m m s or mosura - .NEzaZioH mJ!rz:

Inhalation of this m t e r i a l i s i r r i n a t i n g to t h r nose, mOuth, t h r o a t a n d lungs. It may m h o caws burn. to t h o r r s p i r r t c c y trrct w i t h thm p r o d u c t i o n of lung .dZm WhIch c r n r e a u l t la r h o r t n e r r of breath, aherting, choking, chert win, and iicp.irmmt of luna f u n a t i o n . I n h a l a t i o n of h i g h aono*n t ra t l anm ean r e r u l t i n p r r r m n e n t lung dampa.

Zkpmat rd i n h m l a t k m u p c r u r e M Y csur iqmirmnt o f l u n g f u n c t i o n and p u m n i n t l u n g d.rcrga.

CHAONIC:

W E

SKIN

S a v a r e i r r i t a t i o n and/oz burns o m OCCU: followin C o n t a a t m y a a u m i n p i r m a n t o f v i s i o n and 4ezna.P &nus*. ACvTa:

eyr oxpo.u=a.

O.rt0.1 ixpoaura aaa owasa mavara i r e i t a t i o n and/or b u r n s o h a r a a t e r i ~ o d by rulnisr, awallinp and acab t o r n ~ r l o n . PreLongd r k i n .rporurr r a y cause d - m t r u o t l o n o f the d a r a i s w i t h i q s a i r l b s n t of t h a s k l n st s i b of c o n t a c t to r a g e n a r a t a .

Xffaet . from chronle s k i n e 0rur6 would ba simllrr t o tho.. f r o m s i n g 1 e a * p o s u r c axcapt f a r 31eots 6econdary to t i m u o d a s t r u o t i o n .

I r t l t a t l o n a n d / o r burn. c x n occur to tha mtlra g r a t r o i n t r r t i a r l t r r o t , i n d u d i n 9 t h o 6 t a w o h and i r t e s t i n e s a h a r r o t e r t r d by n a u u r , vomiting, d i a r r h a a , a h b d n r l prin,. b luQi4 , andfor tlssua u l c e r a t i o n .

cxm1c:

INQIITICO( A m :

CEza?IC:

89/84/96 15:48:29 1-589-376-2128-> 5893763941 Page a33 . a7i-&;: -d. ,c> s / . . i / $ z ..A a:. ~ ' ' 1 -.':;-a ..: ,?- 'a~-yS ,- o WHC-SD-FF-PLN-002, REV 5 PG 49 ?bere l i re no knmn o r saported efff'ucte f!xcm altronio utporure.

b t h m a and rerpiratury and cardiovaruular diseaue IKPERILCB:ONE w ~ z z OTXER UILHICPJ.~ (IRICB LN~RNCE ~ooxxczmr

tione known o r reportad. AHtMRrl ToxIcooooy ACUTE 5'OXICIrn:

f KEDICAL CDN3fTIWI AGORXVAPBD FI WPOtllRI? . MSDS # 023398

I N E U A Z I O N W 5 0 : NO avrilrblr C C a - DE= LD50: > 2 g/kg ( rabbi t )

Aquatic LCSO - approxim~t~ly 0.6 sq/l (bkwgilll

'Ebara a m na knann ar rspar tad e f faa ta fram r a p a t e d axpaaura. REPRDWCTIVC TOXICITY:

?hero azo no known or reported a f f a c t s an rtpcoductiva funct ion or f a t a l developnmt . Thir produot has been shown a c t t o bo oarcinoganic. T t i r not inotuded aa a carcinogen by IARC, OS%, NT?, or t P L

Bodium hyp6shlorite has h e n #hewn t o produae &rug. t o genetio mater ia l when tes ted i n v i t r o . Studlea i n vivo have ahown no widanoe of mutaganlo potan t ia l for t h i s inat.t?.*l. Chedca l r with pot.nt b iooida l ao t iv i ty , typ ioa l of bypoohlorit. ooapounda, MY ownprodre chm l n t e g r l t y of mrng of che zrrat .d cmllr which ramin vlablr during an i n v i t r o arsay. This rerult would l i k e l y produce c e l l u l a r o h a n p a giving r i m t o 1 rarpans. ind ia i t ive o f meation. I t l a 5.adg.d t h a t the risk o f genetla daMge ID Ic r ign i f lorn t f o r rodiua hypcchlcrltm because o f its biocidal a c t i v i t , lack o f nutagenis i ty in vivo, and f a i l u r e t o produce a csroincqenYo rerpcnra.

O W GD50: Approxinutely 1-5 gfkg ( r a t )

Causa. burn. t o eyer and rkin AQVXEIC TOXICITT:

approximately 1 rq/l [eapbnlr, 48 houcr) CBRONIC TOXICIlY:

CARCINO3ENTCIZI:

WTAGZNICIZY:

ZAUilD wLBIL/PLAcxRD: CORAOGIVZ RXUPORTWD QUANTITY: 100 lba. R5RGEtZCX GUIDE NO: 60

( F a r 43 C?R 172.101, A p n d l x )

XI. SPILL AND L.CAXAS2: PRDUDUWG ?OR u& z x m a P o m T m xc:Dma, cul~ cxacmc AT L O O - ~ ~ ~ - S ~ O O WOR2AELI QVMZITY(POVWDS)! 100 lbr. (Per 40 CIR 301.4) EPILL MITIO1TION PROCZDURLB: Kazardoum conaeatrat ions i n a i r nay b. found i n 100.1 spill araa and i m d i a t e l y downwind. AIR %LEASE: V.potr I M Y be r w r e # H d by the US. O f I Water f o g . ClptUre

all run o f f natar f o r t a a t m n t end die oral. WATLR RELEkSX: This mrtcriil i. roluble i n watar. dk. o r oonti in

nacer la l vir uu o f conparlble rbrorluner. m e material with use cf vacuum o r o eration and t rut h f o r e disposi t ion. Thir natcri%% !.rmful t o aquat ic lire.

LAND EPILL: Comp.tible abrorbents: Srnd, clay aoL1, colaaurcial

Dimpore o f par guidel iner u n b r Section XII,

Rasponam t o thi. matarla1 roquirer tha use of self contain& breathing apparatus (a=) . AdditlOn.1 pZot*OtiVe olothlng murt be worn t o p r w a n t p r r o n a l contaot with t h i s Iruterhl. these items i n c l u b but arm not Limited t o boots,

absorbentr EPILt RSLIIDtnS:

DI6P06Y. PSMCWAL P=CTIOK rox EKZROXNCY SPILL llib rIrz-rtaziNa I I T ~ I W S !

83/84/96 15:41:41 1-589-376-2128-> 5893763441 Pngc 634 a * < : - z > : . - i . < z >,;.C/S> .+i.. .'*..j-o i >-,\-& o '3 WHC-SD-FF-PLN-002, REV 5

' p.1cv.s. ha-d hat , i n p m i u u r c1othnr.g. i.0. ch*tdcal ly iwraulbla au i t . PG 50. t Cn?npIt:bl.a nlt*rlaln for rcapnirr t c t t h l a rnter:.al arm nreprana, butyl

MSDS# 023398 , d k r , vlkvn and rmranrx.

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, * * * L N D O ? M i D l * * *

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WHC-SD-FF-PLN-002, Rev. 5 9/96

MSIN

J. Wilkinson Confederated Tribes of the Umatilla Indian Nation P. 0. Box 638 Pendleton, Oregon 97801

D. Powaukee Nez Perce Tribe P. 0. Box 365 Lapwai, Idaho 93540

R. Jim, Manager Environmental Restoration/

Yakama Indian Nation P. 0. Box 151 Toppenish, Washington 98948

Waste Management Program

ONSITE

Y.S. Denartment ofE= Richland Op erations Office

D. H. Chapin R. N. Krekel J. E. Rasmussen 8ErTy2)

Westinhouse &&brd C omnany

T. A. Dillhoff R. D. Haggard E. F. Loika N. M. Menard L. L. Perm J. K. Perry B. D. Williamson Central Fi 1 es

R3-79 A5-15 A5-15 -E644

N2-57 H6-25 N2-5 1 H6-24 N2-57 H6-25 B3-11

A3-88