6.3 periodic trends - mr. walkmrwalk.com/chapter 6/section 6.3 - periodic trends.pdf · periodic...

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© Copyright Pearson Prentice Hall Slide 1 of 31 Periodic Trends Sodium chloride (table salt) produced the geometric pattern in the photograph. Such a pattern can be used to calculate the position of nuclei in a solid. You will learn how properties such as atomic size are related to the location of elements in the periodic table. 6.3

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© Copyright Pearson Prentice Hall

Slide

1 of 31

Periodic Trends

Sodium chloride (table salt)

produced the geometric

pattern in the photograph.

Such a pattern can be used

to calculate the position of

nuclei in a solid. You will

learn how properties such

as atomic size are related to

the location of elements in

the periodic table.

6.3

© Copyright Pearson Prentice Hall

Periodic Trends >

Slide

2 of 31

Trends in Atomic Size

Trends in Atomic Size

What are the trends among the elements

for atomic size?

6.3

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Periodic Trends > Trends in Atomic Size

The atomic radius is one half of the distance between the nuclei of two atoms of the same element when the atoms are joined.

6.3

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Periodic Trends > Trends in Atomic Size

Group and Periodic Trends in Atomic Size

In general, atomic size:

•Increases from top to bottom within a group

•Decreases from left to right across a period.

6.3

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Periodic Trends > Trends in Atomic Size6.3

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Periodic Trends > Trends in Atomic Size6.3

© Copyright Pearson Prentice Hall

Periodic Trends >

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Ions

Ions

How do ions form?

6.3

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Periodic Trends > Ions

Positive and negative ions form when

electrons are transferred between atoms.

6.3

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Periodic Trends > Ions

Positive and negative ions form when

electrons are transferred between atoms.

6.3

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© Copyright Pearson Prentice Hall

Periodic Trends > Ions

Some compounds are composed of particles

called ions.

•An ion is an atom or group of atoms that has a positive or negative charge.

•A cation is an ion with a positive charge.

•An anion is an ion with a negative charge.

6.3

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Periodic Trends > Ions

Animation 7

Discover the ways that atoms of elements

combine to form compounds.

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Periodic Trends >

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Trends in Ionization Energy

Trends in Ionization Energy

What are the trends among the elements

for first ionization energy, ionic size, and

electronegativity?

6.3

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Periodic Trends > Trends in Ionization Energy

The energy required to remove an electron from

an atom is called ionization energy.

• The energy required to remove the first electron from an atom is called the first

ionization energy.

• The energy required to remove an electron from an ion with a 1+ charge is called the

second ionization energy.

6.3

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Periodic Trends > Trends in Ionization Energy

Group and Periodic Trends in Ionization

Energy

First ionization energy tends to:

•Decrease from top to bottom within a group

•Increase from left to right across a period.

6.3

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Periodic Trends > Trends in Ionization Energy6.3

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© Copyright Pearson Prentice Hall

Periodic Trends > Trends in Ionization Energy6.3

© Copyright Pearson Prentice Hall

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Periodic Trends > Trends in Ionization Energy6.3

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© Copyright Pearson Prentice Hall

Periodic Trends > Trends in Ionic Size

Trends in Ionic Size

During reactions between metals and

nonmetals, metal atoms tend to lose electrons,

and nonmetal atoms tend to gain electrons. The

transfer has a predictable effect on the size of

the ions that form.

6.3

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Periodic Trends > Trends in Ionic Size

•Cations are always smaller than the atoms from which they form.

•Anions are always larger than the atoms from which they form.

6.3

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Periodic Trends > Trends in Ionic Size

Relative Sizes of Some Atoms and Ions

6.3

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Periodic Trends > Trends in Ionic Size

Trends in Ionic Size

6.3Size generally increases

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© Copyright Pearson Prentice Hall

Periodic Trends > Trends in Electronegativity

Trends in Electronegativity

Electronegativity is the ability of an atom of an

element to attract electrons when the atom is in a

compound.

•In general, electronegativity values decrease from top to bottom within a

group.

•For representative elements, the values tend to increase from left to

right across a period.

6.3

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Periodic Trends > Trends in Electronegativity

Representative Elements in Groups 1A through 7A

6.3

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Periodic Trends >

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Summary of Trends

Summary of Trends

What is the underlying cause of periodic

trends?

6.3

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Periodic Trends > Summary of Trends

The trends that exist among these

properties can be explained by

variations in atomic structure.

6.3

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Periodic Trends > Summary of Trends6.3

Atomic Size Increases

Increases

Decreases

Decreases

Size of cationsShieldingNuclear ChargeElectronegativityIonization energySize of anionsIonic size Constant