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5 Underwood Court, Delran, New Jersey 08075-1229609-461-4003 • 215-238-0338 • Fax 609-461-4916
TTE ASSESSMENT TECHNICAL ASSISTANCE EPA CONTRACT 68-S5-3002
4 June 1997
Mr. CesarLee(3HW21) ' TDD No. 9703-10Remedial Project Manager DCN C0000335U.S. Environmental Protection Agency841 Chestnut BuildingPhiladelphia, PA 19107
Subject: Metals Bank Statistical Analysis and Technical Review of the Metal Bank RiskAssessment and Data Package
Dear Mr. Lee:
As requested, the Roy F. Weston, Inc. (WESTON®), Site Assessment Technical Assistance(SATA) team has performed the statistical analysis and technical review of the risk assessmentdata package documents for the Metal Bank Site in Philadelphia County, Pennsylvania.Attached is SATA's technical review report and the Human Health Risk Assessment Commentsand Responses typed and formatted as per EPA request, and with all the responses EPArequested addressed.
If you have any questions regarding this review, please contact me at (609) 461-4003, Ext. 209, orMarian Murphy at Ext. 243.
Very truly yours,
ROY F. WESTON, INC.
AfifMaroufToxicologist
cc: TDD File
SATA0301457hiiman health risk3
>y F. Weston, Inc.. EDERAL PROGRAMS DIVISIONIn Association with Foster Wheeler Environmental Corporation; Resource Applications, Inc.; C.C. Johnson & Malhotra, P.C.; andPRC Environmental Management Inc.
• P» r\ e~\ i f\ n c\
WESTON / SATA TechnicalReview of Risk AssessmentMetal Bank SitePhiladelphia, Philadelphia Co., PA
4 June 1997
MANAGERS X—^ DESIGNERS/CONSULTANTS
TDD No. 03-9703-10Contract No. 68-S5-3002
JJUUUMJbJNi
METALS BANK SITE ** TDD No. 9703-10PHILADELPHIA, PHILADELPHIA CO., PA__________CONTRACT No. 68-S5-3002
1.0 INTRODUCTION____________________________
On 7 March 1997, the Roy F. Weston, Inc. (WESTON®), Site AssessmentTechnical Assistance (SATA) team was directed by U.S. EnvironmentalProtection Agency (EPA) Remedial Project Manager (RPM) Cesar Lee to performfile reviews of data for the Metals Bank/Cottman Avenue Site located inPhiladelphia, Philadelphia County, Pennsylvania, and to assist EPA withresponses to comments by the property owner on the Human Health RiskAssessment (HHRA) section of the Remedial Investigation (RI) report. Inaddition, SATA was also tasked to verify the cancer risk calculations for the adultand child fish ingestion, future industrial worker ingestion of courtyard surfacesoil and dermal contact of future construction workers to light non-aqueous phaseliquid (LNAPL) in monitoring well MW-6.
2.0 BACKGROUND______________________________
The Metals Bank/Cottman Avenue Site is listed on the National Priorities List(NPL). An RI Report for the Metals Bank/Cottman Avenue NPL Site wasprepared by Earth Tech hi Wayne, Pennsylvania for the Cottman AvenuePotentially Responsible Parties (PRP) Group. The property owner was not partof the PRP Group whose contractor prepared the RI report. .Roy Smith, Ph.D.,senior lexicologist for EPA Region m, prepared the HHRA (EPA, 1995a). Theproperty owner reviewed the report and submitted comments for EPA review.
SATA was tasked to review the property owner's comments related to theHHRA portion of the RI report, search EPA files, verify EPA responses to theowner's comments concerning the HHRA, verify cancer risk calculations forcertain portions of the HHRA noted below and to provide documentation tosupport the statistical methods used by EPA for HHRA calculations.
3:0 HUMAN HEALTH CANCER RISK VERIFICATION__________________
SATA was tasked to verify and support EPA's HHRA findings for the adult andchild fish ingestion, future industrial worker ingestion of courtyard surface soiland dermal contact of future construction workers to LNAPL in monitoring well6. SATA searched site files to verify that the data used hi the HHRA wasaccurate and reflected present site conditions.
SATA0301457westonreportmetlasbank
AR30UO
METALS BANK SITE * TDD No. 9703-10PHILADELPHIA, PHILADELPHIA CO., PA__________CONTRACT No. 68-S5-3002
SATA verified the cancer risks associated with consumption of fish caught inthe Delaware River near the site. Both adult and child fish ingestionpolychlorinated biphenyls (PCB) cancer risk calculations were verified using aslope factor (SF) of 7.7 (the January 1995 SF) and the most current SF of 2 (seeTables A-l and A-2 in Appendix A).
SATA verified the cancer risks to future industrial workers associated with theingestion of surface soils hi the courtyard area at the site using a slope factor of7.7 and the most current slope factor of 2 (see Table A-3 Appendix A).
SATA verified the cancer risks to future construction workers via dermalcontact with LNAPL in the groundwater at the site using a slope factor of 7.7and the most current slope factor of 2 (see Table A-5 Appendix A).
4.0 STATISTICAL EVALUATION OF DATA USED FOR HHRA_________
The reasonable maximum exposure (RME) concentration for PCB in the catfishfillets and surface soils hi the courtyard were checked to verify that the properRME was used hi the cancer risk calculations.
The Aroclor 1242, 1254 and 1260 concentrations for the catfish fillets wereadded to determine the total PCB content. Only Aroclor 1242, 1254 and 1260were used, because these were the only Aroclors detected in the fish or riversediments. If a particular Aroclor concentration was non-detect for a sample,one half of the detection limit of the Aroclor was used as the Aroclorconcentration. The data was checked to determine if it fit a normal or log-normal distribution using the Shapiro-Wilks statistical test for normality (seeTable C-l Appendix C). The data used to calculate the upper confidence limit(UCL) for total PCBs in the catfish fillets fit a log-normal distribution and wasused as the RME concentration, as per EPA protocol (EPA, 1992).
The UCL for Aroclor 1248, 1254 and 1260 concentrations in surface soils hi thecourtyard were calculated by individual Aroclors. Aroclors 1248, 1254 and1260 were used for the RME concentration because these Aroclors weredetected hi the surface soil samples at the site. If a particular Aroclorconcentration was non-detect for a sample, one-half of the detection limit of theAroclor was used as the Aroclor concentration. The data was checked todetermine if it fit a normal or log-normal distribution by the Shapiro-Wilksstatistical test for normality (see Tables C-2 to C-4 in Appendix C). TheAroclor 1248, 1254 and 1260 data fit a log-normal distribution and the UCLwas calculated accordingly. The Aroclor 1248 UCL exceeded the highestsample concentration; therefore, the highest concentration for Arolcor 1248 wasused in the RME calculation, as per EPA HHRA guidance (EPA, 1992).
SATA0301457wcstonreportmetlasbank2
AR301H02
METALS BANK SITE TDD No. 9703-10PHILADELPHIA, PHILADELPHIA CO., PA__________CONTRACT No. 68-S5-3002
5.0 VERIFICATION OF REPORTED PCB CONCENTRATIONS__________
SATA reviewed the site files and verified the concentrations reported in theHHRA for PCBs in the surface soils in the courtyard, catfish fillets and LNAPLfor MW-6. The LNAPL PCB concentration for MW-6, the PCB concentrationfor Catfish #11 Fillet sample and the PCB concentration for Courtyard SurfaceSoil sample MBK TBS2-0.5 were verified.
Example calculations for these PCB concentrations can be found hi Appendix Bof this report. The supporting raw data for each sample calculation checked,along with the Aroclor standard fingerprints for the detected Aroclors, can befound hi Appendix D of this report.
6.0 VERIFICATION OF EPA RESPONSES TO SITE OWNER'S HHRA COMMENTS
SATA verified EPA's responses to the property owner's HHRA comments aboutthe courtyard surface soils, verified the most current PCB slope factors wereused to calculate cancer risks, cited references for property owner's commentsand cited references for EPA responses. In addition, SATA reviewed theproperty owner's comments and suggested additional comments which could beaddressed by EPA.
SATA formatted the EPA responses and added the reference citations as well asany SATA findings which would support EPA's comments. SATA is submittinga diskette of these comments to EPA with this report.
SATA compared the Region UJ Risk-Based Concentration (RBC) table, suppliedas part of Appendix 4 of the HHRA, to the 9 February 1995 RBC table (EPA,1995b) and verified .the most current SF was used.
SATA searched the administrative records and verified the pages EPA cited werecorrect for the HHRA comment responses.
7.0 REFERENCES_____________________________________________
U.S. Environmental Protection Agency (EPA). 1992. Supplemental Guidance to RAGS:Calculating the Concentration Term. Office of Solid Waste and EmergencyResponse. Publication No. 9285.7-081. Washington, D.C. May.
EPA. 1995a. Baseline Human Health Risk Assessment: Cottman Avenue NPLSite. Roy L. Smith, Ph.D. Senior Toxicologist, EPA Region HI.Philadelphia. PA. April.
SATA0301457westonreportmetlasbank3
AR30U03
METALS BANK SITE TDD No. 9703-10PHILADELPHIA. PHILADELPHIA CO., PA__________CONTRACT No. 68-S5-3002
EPA 1995b. EPA Region III Risked-Based Concentration Table. Roy L. Smith,Ph.D. Senior Toxicologist EPA Region DDE. Philadelphia. PA. 9February.
Appendices: Appendix A (Calculations for Cancer Risks)Appendix B (Examples of Data Calculations)Appendix C (Statistical Analysis Data)Appendix D (Raw Data for PCBs hi Courtyard Surface Soils, Fish
and MW-6 LNAPL)Appendix E (EPA Region m RBC Table, 9 February 1995)
S ATA0301457 westonreportmetlasbank4
AR30MOI*
APPENDIX A
CALCULATIONS FOR CANCER RISKS
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APPENDIX B
EXAMPLES OF DATA CALCULATIONS
AR30M 12
Table B-l
Example Calculation for PCBs in the LNAPL in Monitoring Well MW-6Concentrations Calculated From Raw Laboratory Data
All results were reported from the DB608 column.
Aroclor 1248;
414972 area units* X 0.5ug/ml* X 50ml X 10ml X IQOOg = 434,552 ug/Kg477218 area units* 1ml 0.5 g 1 Kg
Where: • = sum of the areas of the Aroclor 1248 peaks* = concentration of Aroclor 1248 standard# = sum of the areas for the Aroclor 1248 standard peaksNote: the sample was diluted 1/50 at the instrument and 0.5 g of sample wereextracted hi 10 ml of solvent (see raw data hi Appendix D).
Aroclor 1260;
1019834 area units* X 0.5 ug/ml* X 5Q_m! X 10 ml X IQOOg = 655,133 ug/Kg778341 area units* 1ml 0.5 g 1 Kg
Where: • = sum of the areas of the Aroclor 1260 peaks* = concentration of Aroclor 1260 standard# = sum of the areas for the Aroclor 1260 standard peaksNote: the sample was diluted 1/50 at the instrument and 0.5 g of sample wereextracted in 10 ml of solvent (see raw data hi Appendix D).
AR30U 13
Table B-2
Example of Calculation for PCBs in Courtyard Soil for Sample MBK TBS2-0.5Concentrations Calculated From Raw Laboratory Data
All results were reported from the DB1701 column.
Aroclor 1248;
5580219 area units* X 0.5 ug/ml* X 10ml X 100ml X IQOOg +0.89®= 140,000 ug/Kg765317 area units* 30 g 1ml 1 Kg
Where: • = sum of the areas of the Aroclor 1248 peaks* = concentration of Aroclor 1248 standard# = sum of the areas for the Aroclor 1248 standard peaks@ = percent solids expressed as a decimalNote: the sample was diluted 1/100 at the instrument and 30 g of sample wereextracted hi 10 ml of solvent (see raw data in Appendix D).
Aroclor 1260 Detection limit Calculation;
0.5 ug/ml* X 10ml X 100 ml X IQOOg * 0.89® = 19,000 ug/Kg30 g 1 ml 1 Kg
Where: • = sum of the areas of the Aroclor 1260 peaks* = concentration of Aroclor 1260 standard# = sum of the areas for the Aroclor 1260 standard peaks@ = percent solids expressed as a decimalNote: the sample was diluted 1/100 at the instrument and 30 g of sample wereextracted in 10 ml of solvent (see raw data in Appendix D).
AR30U IU
Table B-3
Example Calculation of PCB Concentrations in Fish Sample Catfish 11 (Fillet)Concentrations Calculated From Raw Laboratory Data
All results were reported from the DBS column.
Aroclor 1242;
1067731 area units* X 1600 ug/Kg* X 1ml______ X 5ml X = 690 ug/Kg2430198 area units* 20.33 g x 0.27® 1 ml
Where: • = sum of the areas of the Aroclor 1248 sample peaks* = concentration of Aroclor 1248 standard# = sum of the areas for the Aroclor 1248 standard peaks@ = percent solids expressed as a decimalNote: the sample was diluted 1/5 at the instrument and 20.33 g of sample wasextracted in 1 ml of solvent (see raw data in Appendix D).
Aroclor 1260;
924909 area units* X 1050 ug/Kg* X 1ml______ X 5ml X =350 ug/Kg2707132 area units* 20.33 g x 0.27® 1 ml
Where: •= sum of the areas of the Aroclor 1260 peaks* = concentration of Aroclor 1260 standard# = sum of the areas for the Aroclor 1260 standard peaks@ = percent solids expressed as a decimalNote: the sample was diluted 1/5 at the instrument and 20.33 g of sample wasextracted in 1 ml of solvent (see raw data in Appendix D).
JR30U 15
APPENDIX C
STATISTICAL ANALYSIS OF DATA
A R 3 0 t i l 16
Table C-1Shapiro-Wilks Test For Normality of PCBs in Catfish Fillets
Ranki12345678910
Ranki12345678910
Concentration(ppm)x(i)0.410.560.720.790.870.921.041.351.431.48
Concentration(ppm)x(i)
-0.387216143-0.251811973-0.142667504-0.102372909-0.060480747-0.0362121730.0170333390.1303337680.1553360370.170261715
;
Test of normality
x(n-i+1)1.481.431.351.040.920.870.790.720.560.41
x(n-i+1)-x(i)1.070.870.630.250.05-0.05-0.25-0.63-0.87-1.07
Test of lognormality
x(n-i+1)0.1702620.1553360.1303340.017033-0.03621-0.06048-0.10237-0.14267-0.25181-0.38722
x(n-i+1)-x(i)0.55747790.4071480.27300130.11940620.0242686-0.0242686-0.1194062-0.2730013-0.407148-0.5574779
a(n-i+1)0.57390.32910.21410.12240.0399
b(i)0.6140730.2863170.1348830.03060.001995
b=n=
standard deviation2
W=k=
0.94367149
1.06786810
0.366425685
W(0.05,10)=Good Normal Fit
a(n-i+1)0.57390.32910.21410.12240.0399
b(i)0.319936540.133992410.058449570.014615320.00096832
b=n=
standard deviation=
W=k=
0.94888779
0.5279621710
0.180665045
W(0.05,10)=Good Lognormal Fit
0.842
0.842
The data fits both the normal and lognormal distribution because inboth cases W>W(.05,10). However, the lognormal analysis shows ahigher W than the normal analysis. Therefore the lognormaldistribution fits the data better.
AR30M 17
Table C-2Shapiro-Wilks Test For Normality of Aroclor-1248 In Courtyard Surface Soil
Ranki1234567891011
Ranki1234567891011
Concentration(ppm)x(i)39043046046085095011001150810070000140000
Concentration(ppm)x(i)
2.5910646072.6334684562.6627578322.6627578322.9294189262.9777236053.0413926853.060697843.9084850194.845098045.146128036
Test of normality
x(n-i+1)14000070000810011501100950850460460430390
x(n-i+1)-x(i)1396106957076406902500
-250-690-7640-69570-139610
Test of lognormality
x(n-i+1)5.1461284.8450983.9084853.0606983.0413932.9777242.9294192.6627582.6627582.6334682.591065
x(n-i+1)-x(i)2.55506342.21162961.24572720.397940.1119738
0-0.1119738-0.39794-1.2457272-2.2116296-2.5550634
a(n-i+1)0.56010.33150.2260.14290.0695
b(i)78195.56123062.4551726.6498.60117.375
b=n=
standard deviation=
W=k=
0.53112712
103100.63211
44736.50865
W(0.05,11)=Poor Normal Fit
a(n-i+1)0.56010.33150.2260.14290.0695
b(i)1.431091030.733155210.281534340.056865630.00778218
b=n=
standard deviations
W=k=
2.5104283811
0.91037449
0.85
50.76042347 1 W(0.05, 11)=
Poor Lognormal Fit0.85
The data does not fit either the normal or lognormal distributionbecause in both cases W<W(.05,1 1 ). However, the lognormalanalysis shows a higher W than the normal analysis. Therefore thelognormal distribution fits the data better and will be used to be r~conservative. j~
I i
AR30l*l 18
Table C-3Shapiro-Wilks Test For Normality of Aroclor-1254 In Courtyard Surfsipe Soil
Ranki1 ••234567891011
Ranki1234567891011
Concentration(ppm)x(i)10018019537039043085090095036509000
Concentration (ppm)x(i)2
2.2552725052.2900346112.5682017242.5910646072.6334684562.9294189262.9542425092.9777236053.5622928643.954242509
Test of normality
x(n-i+1)90003650950900850430390370195180100
x(n-i+1)-x(i)890034707555304600
-460-530-755-3470-8900
Test of lognormality
x(n-i+1)3.9542433.5622932.9777242.9542432.9294192.6334682.5910652.5682022.2900352.255273
2
x(n-i+1)-x(i)1.95424251.30702040.6876890.38604080.3383543
0-0.3383543-0.3860408-0.687689-1.3070204-1.9542425
a(n-i+1)0.56010.33150.2260.14290.0695
b(i)4984.891150.305170.6375.73731.97
b=n=
standard deviation=
W=k=
0.57940302
6413.53211
2664.445795
W(0.05,11)=Poor Normal Fit
a(n-i+1)0.56010.33150.2260.14290.0695
b(i)1.094571230.433277250.155417710.055165230.02351563
b=n=
standard deviations
W=k=
0.93882156
1.7619470411
0.575044335
W(0.05,11)=Good Lognormal Fit
0.85
0.85
The data fits lognormal distribution because W>W(.05, 11). However,the data does not fit the normal distribution because W<W(.05, 1 1 )
I
AR30I4I 19
Table C-4Shapiro-Wilks Test For Normality of Aroclor-1260 In Courtyard Surface Soil
Ranki1234567891011
Ranki1234567891011
Concentration(ppm)x(i)10018019537039085085090095036509000
Concentration(ppm)x(i)2
2.2552725052.2900346112.5682017242.5910646072.9294189262.9294189262.9542425092.9777236053.5622928643.954242509
Th€the
Test of normality
x(n-i+1)90003650950900850 .850390370195180100
x(n-i+1)-x(i)890034707555304600
-460-530-755-3470-8900
Test of lognormality
x(n-i+1)3.9542433.5622932.9777242.9542432.9294192.9294192.5910652.5682022.2900352.255273
2
x(n-i+1)-x(i)1.95424251.30702040.6876890.38604080.3383543
0-0.3383543-0.3860408-0.687689-1.3070204-1.9542425
a(n-i+1)0.56010.33150.2260.14290.0695
b(i)4984.891150.305170.6375.73731.97
b=n=
standard deviation=
W=k=
0.58582101
I
6413.53211
2649.810375
W(0.05,11)=Poor Normal Fit
a(n-i+1)0.56010.33150.2260.14290.0695
b(i)1.094571230.433277250.155417710.055165230.02351563
b=n=
standard deviations
W=k=
0.9429346
1.7619470411
0.57378885
W(0.05,11)=Good Lognormal Fit
0.85
0.85
i ij data fits lognormal distribution because W>W(.05, 11). Howevdata does not fit the normal distribution because W<W(.05,1 1)
er, —
AR30M20
APPENDIX D
RAW DATA FOR PCBS INCOURTYARD SURFACE SOILS, FISH AND MW-6 (LNAPL)
AR30M2I
RAW DATAfor
PCBS IN MW-6 LNAPL
AR30U22
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'AR30lii23
ID EPA SAMPLE NO,PESTICIDE ORGANICS ANALYSIS DATA SHEET •„____
a. ,ame: BCM Contract:34749 DL
ab Code: BCK Case No.: SAS No.: SDG No.: W1070atrix: (soil/water) WATER Lab Sample ID: 134749ample wt/vol: (].(;! \. (g/mL)ML Lab File ID: N1119307
^ / //o/ /jn?evel: (low/med) LOW Date Received: 10/25/91Moisture: not dec.100. dec. 0. Date Extracted: 10/30/91xtraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 11/21/91•PC Cleanup: (Y/N) N pH: .0 Dilution Factor: 50.00
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) "TG/L Q
319-84-6 ———— alpha-BHC319-85-7 ———— b«ta-BHC319-86-8 ———— d«lta-BHC58-89-9—— — gamma-BHC (Lindane)76-44-8 ——— Heptachlor309-00-2 ——— Aldrin1024-57-3 ——— Heptachlor epoxide959-98-8 ——— -Endosulfan I60-57-1 ——— Dieldrin72-55-9 ———— 4, 4 '-DDE72-20-8 ——— Endrin
33213-65-9 ——— Endoaulfan II72-54-8 ———— 4 , 4 ' -ODD
1031-07-8—— —Endosulfan sulfate50-29-3 ———— 4,4'-DDT72-43 -5 ——— Methoxychlor
53494-70-5 ——— Endrin k«ton«5103-71-9 ——— alpha-Chlordan*5 10 3 -7 4 -2 —— — gamma-Chlordane8001-35-2-- —— -Toxaphene12674-11-2 ——— Aroclor-101611104-28-2 ——— Aroclor- 122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— ATOClor-125411096-82-5-- —— Aroclor- 1260
3700.3700.3700.3700.3700.3700.3700.3700.7500.7500.7500.7500.7500.7500.7500.37000.7500.37000.37000.75000.37000.37000.37000.37000.320000.75000.490000.
UUuuuuuuuuuuuuuuuuuuuuuuu
FORM I PEST 1/87 Rev,
B OF CURVE UN
0.5 ng/ul STD 1Average retention time 725741
12.35 peakl 7774314.15 peak 2 16972015.69 peak 3 26611316.39 peak 4 10039816.99 peaks 111767
Sum of peak area: 725741Calibration factor: 1.45E+06Average Cf: 1.45E+06Standard Deviation: MA Percent RSD: NA
PCB 1221: 0.5 ng/ul STD 1Average retention time
11.'40 peakl 3520312.06 p«ak2 2953712.35 peak3 9497112.62 peak 4 1247714.09 peak 5 23426
Sum of peak area: 195614Calibration factor: 3.91E+05Average Cf: 3.91 E+05Standard Deviation: NA Percent RSD: NA
DB 1232: 0.5 ng/ul STD 1jige retention time
12.35 peak 1 7762014.15 peak 2 8169215.69 peak 3 11569916.40 peak 4 4233016.99 peak S 49834
Sum of peak area: 367175Calibration factor: 7.34E+05Average Cf: 7.34E+05Standard Deviation: NA Percent RSD: NA
PCB 1242: 0.5 ng/ul STD 1Average retention time
14.15 peak 1 12750615.07 peak 2 3855215.69 peak3 19537516.39 peak 4 7381817.00 peak 5 88336
Sum of peak area: 523567Calibration factor: LOSE+06Averaged: 1.05E+06Standard Deviation: NA Percent RSD: NA
AR30M25
"fa irATloiSs : IS RS AiHii" iPH- ££££> '• -- 'S??;?Bf
jsaas8t8iia S!aiB«i8aasiqfj|pB ^ "" "" •••note that retention times are out of the expected window"note calculations assume equivalent volume injected for standards and samples
calculation: (summed area) (final volume in ulUdilutioni(lug) *conc. in ug/L(Calibration factor PCB)(lOOOng) (inital voi in U . ,
PCB1016:
I
PCB1221:
I
i PCB1232:
I
PCB1242:
I
IPCB 1248:
I
I1 PCB1254:
I
| PCB1260:
I
1
EXPRTWIN12.30 - 12.4014.10 - 14.2015.64 - 15.7416.34 - 16.4416.94 - 17.04
EXPRTWIN11.35 - 11.4512.01 - 12.1112.30 - 12.4012.57 - 12.6714.04 - 14.14
EXPRTWIN12.30 • 12.4014.10 - 14.2015.64 - 15.7416.35 • 16.4516.94 • 17.04
RT0.000.000.000.000.00
RT0.000.000.000.000.00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
RT0.000.000.000.000.00
EXPRTWIN14.10 - 14.2015.02 • 15.1215.64 - 15.7416.34 - 16.4416.95 - 17.05
EXPRTWIN16.97 - 17.0718.35 • 18.4518.86 • 18.9619.40 - 19.5019.67 - 19.77
EXPRTWIN20.01 - 20.1120.24 - 20.3421.95 - 22.0522.39 - 22.4922.84 • 22.94
EXPRTWIN23.11 - 23.2123.42 - 23.5224.25 - 24.3525.21 • 25.3129.75 - 29.85
RT0.000.000.000.000.00
RT16.9818.3918.9119.4519.73
RT0.000.000.000.000.00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
AREA1.28E+057.94E+047.20E+045.33E+048.24E+04
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
01451482
0391228
0734350
01047174
320000414792
954436
TMX cone:DBC cone:
01413498
RT23.1523.4624.2925.2529.78
AREA3.09E+053.80E+051.01E+056.96E+041.60E+05
4900001019834
1556682
TMX cone:DBC cone:
x 500000 x 1, * 1 0 ug/Lx 1000 x 0.00067
NA ug/L
x 500000 x 1 x 1 0 ug/Lx 1000 x 0.00067
NA ug/L
x 500000 x 1 x 1 0 ug/Lx 1000 x 0.00067
NA ug/L
x 500000 x 1 x 1 0 ug/Lx 1000 x 0.00067
NA ug/L
ug/L REPORTED BY LABORATORYx 500000 x 1 x 1 324000 ug/Lx 1000 x 0.00067
NA ug/L144000 ug/L TMX%R86500 ug/L DBC%R
x 500000 x 1 x 1 0 ug/Lx 1000 x 0.00067
NA ug/L
ug/L REPORTED BY LABORATORYx 500000 x 1 x 1 = 489000 ug/Lx 1000 x 0.00067
NA ug/L144000 ug/L TMX %R86500 uQ/L DBC %RB r*^ ^ r*\ • i ^^ AR3Q4 I 26
i
96%58%
96%58%
248: 0.5 ng/ul STD 1n retention time17.03 peak 1 9309718.41 peak 2 7884418.92 peak 3 8639519.46 peak 4 9738319.73 peak 5 121499
Sum of peak area: 477218Calibration factor: 9.54E+05Average a: 9.54E+05Standard Deviation: NA Percent RSD: NA
PCB 1254: 0.5 ng/ul STD 1Average retention time
20.06 peakl 11482220.29 peak 2 13550922.00 peaks 8809822.44 peak 4 23749922.89 peak 5 130821
Sum of peak area: 706749Calibration factor: 1.41E+06Average Cf: 1.41E+06Standard Deviation: NA Percent RSD: NA
OB 1260: 0.5 ng/ul STD 1Average retention time• 23.16 peak 1 179227
23.47 peak 2 19510724.30 peak 3 6879925.26 peak 4 23668429.80 peaks 98524
Sum of peak area: 778341Calibration factor: 1.56E+06Average a: 1.56E+06Standard Deviation; NA Percent RSD: NA
Surrogates: Average TMX area: 6974100 Average TMX Calibration factor: 6.97E+07Average DBC area: 4391060 Average DBC Calibration factor: 4.39E+07
biLT1 LABUKAIUKltb Peport - LitNib. Medium Area \orrn
e Name : 134/4V 6Ub . o/ML/TUML-lML/lUML ! BA Heport No : aii.UlHSH rUH L'LP Htb I b/PLBb UN ADL-1J Hage iL'ULUflN UB6Ub jUJM X U.T4.J MM U . tO UM h 1 LM 1 U#U33 i'J'J' . 1 NJ 1LAKKltK P-T RI TPbi. I U I RL r LUW ~/Ur1L/MlN tUU ^UUU KANUt Ulul INJtUllUN 1!?UL. Imin ^L/min, ' / L 14M1N
i=!ook.-Page : UlU/'U
Heak Processor : ijjenie M u l t i l e v e l : haise
Instrument : RUU 1^ ' Application : Loop
Calculation : txternalbIL) Uuant 1 1 at ion : AreaUnits
Kesult I- lie : /DA I A/tX I KAL I b/KtbUL I /NlllV^U/. KLb
Kun l i m e : 4U.UU Minutes Iniected on I hu Nov 21, 1VV1 ^:VJ/:^1 pm
Sequence h i l e : /DA I A/tX I KAU I b/bfc-LJUtNLh/bhULLP 1121V1 l^
Subseq/b'amp le : ix / .... Bottle no. :
Ihreshold Min-Ar Pkwidth Kh Unknown.U4U U.UUUt+UU
Kef Udw Abs Kef-KILJ Non Kef Win ttbs Non Kef-KIU) Ident LevelU.UU l.^U U.UU l.'rU 1UUU.UU
f, Uil-hact Smp-Amt btd-Amt % Purity Ini Uo 1 Katio/.462/t+U/ U.UUUUt+UU l.UUUUt*UU 1UU.UUU l.UUU
Fun Status : KunbtatusUKtndUf f base 1 me
limed tvents lime Events Logic Ualue tventUpdate1 U.UU Negat i vePeaks hventUff -l.UU halse'J .1U KesetBLAl lUa 1 ley LventUn -i.UU halse
Pt-« Hi lU-tm HeakLJidth Area Lode AMUUN I Name1 .l.^U . 12 'y **IJ124Vtlb U.UU-UUh+UU
i..''!J .U41V Ibl'Jbb u". UUUUt + UUi . /6 .U4V/ 41^6 bb U. UUUUt + UU
•^ 'J.U1 .UBV/ lUb2/bb U.UUUUt + UU2. IT .Ub/V TITbbb U.UUUUt + UU
^ -.--I .Ubl'J lUTUbb U.UUUUt + UU-'•-'I • iBb^ .^bVbt; U. U U U U t + U U
y 'J.6/ . UobU ,'6V'Jbb U.UUUUt + UUu -.B6 . i/ti/ IVVUbb U . U U U U t + U U
-^ -.1'H .Uo1?^ 'JlTUbb U . U U U U t + UU-1 :•.*?** .UVU-i i^V6bb U.U U U U t + UU--' -•.''> . 'J i<JT 'JUx'&Bb U . U U U U t + UU'-* 4.U1 .1'l U 4Vl^bb U.UUUUt + UU14 4.V4 . 14/.'- 4TT/BB U.UUUUt + UU' '-"' 4.TB . 1JT4 l'4V6bb U.UUUUt + UUio 4./1? .HTb olUVbb U . U U U U t + U U
AR30lf 128
bample Name : 1>4X4V 6U8 .6/ML/TUML-1MLX1UML IBA tieport No : B2.U1MIH t-UK LLP PhblbXPLBb UN AUL-1^ ' " PagePk# HI ID-tm PeakWidth Area Lode AMUUNI NameIX T.J2 .11U4 6^X6BB U.UUUUh+UUIB T.TX .1UBT T4TV1BB U.UUUUh+UU.V o.Uy .122U TU61BB U.UUUUh+UU!U 6.til . 1>T1 46132BB U.UUUUh+UU21 X.TT . 1T4V .5T62BB U.UUUUh+UU.22 X.BB .128.2 24X4BB U.UUUUh + UU•21 B.IT .11*1 11B2BB U.UUUUh + UU24 B.8B .1B42 1T6TBBB U.UUUUh+UU2T y.4y #y.4y .114U 1^4B2^yBB 1.442Xh+UT 2,4,T,6-ItIKALHLUKU-m-XYLt26 y.ya .1U2T ixiyaa u.uuuuh+uu-2X 1U.24 .12y^ 11B12BB U.UUUUh+UU2B 11.18 .1X^1 1V186BB U.UUUUh+UU2y 11.4u . uav^ iai2BB u.uuuuh+uu1U 11.68 .166U 2VT1BB U.UUUUh+UU^1 12.UT .1214 218^BB U.UUUUh+UUy± I'Z.ll .1168 411?U1BB U.UUUUh + UU11 12.TX .11X/ 2U8UBB U.UUUUh+UU14 12.VI .2U^6 416TBB U.UUUUh+UU.•iT 14.14 .l^TT 16816UBB U.UUUUh+UU16 14.61 .1411 14TX4BB U.UUUUh+UUI/ IT.16 .U81B _ 1U13/BB U.UUUUh+UU38 IT.^y . . 1 > 4 U T U U 6 y B B U.UUUUh+UU^y IT.68 .1TT1 ^1262UBB U.UUUUh+UU4U 16. U2 .I.?1?! 21Uy6BB U.UUUUh + UU41 16. IV . 1TU6 6-JUB2BB U.UUUUh+UU42 16.66 .UBT4 >V2yBB U.UUUUh+UU
IX.Ul .16UXTU41BBB U.UUUUh+UU4T6XBB U.UUUUh+UU
1421 Xy42yBB U.UUUUt+UUUB2/ yB2yBB U.UUUUt+UU
4> 16,44 IX.24
18. Ul6 IB.-jy4X 1B.TB48 18.yi' .1V6U X2UU^BB U.UUUUh+UU
liay .J44X8BB U.UUUUh+UUiy.4T' iy.4U .11^2 T^2B8BB 6.66T4h+U^ I leu lac. h lei i—epo* ide
.1 24 B2^XUBB U.UUUUh+UUT2 2U.U6 2U.UX . 126X B6yxiBB l.UU42h+U4 gamrniii Lh lor deneT^ 2U.2y .12BX 1U6X8VBB U.UUUUh+UUT4 2U.6U .1UT2 1BB6BBB U.UUUUt+UUTT 2U.B6 2U.B8 .1^6^ 848iyBB y.^22Uh+U>T6 21.2X .U8U3 22UVBB U.UUUUt+UUTX 21.46 .11T2 1TXUBBB U.UUUUt+UUTB 21.X6 21.XX .12 IT 2TUXUyBB 4.^814h+U4TV 22.UU .UyTy 146>6Bb U.UUUUt+UU6U 22.42 - .14^8 2UT4yyBB U.UUUUt+UU61 22.BT )nl/D . 1V46 16V2U4BB U.UUUUt+UU62
24
^!IM /•SHK,^ U.UUUUt + UUJ>BU1T4BB U.UUUUt+UU
U4 24.U4 . I2V« I'JUTVrtib '_' . XU U2t + !J«1U14J6BB U.UUUUt+UU
66 24.64,^ .ll^b BBT^BB U.UUUUt + UU6X 24.ya .1U2X yt,UB6t,t, U.UUUUt+UU6fa! 2t>.Ul . UB>y 24yU6BB U.UUUUt + UU
flR301t!29
BLM LABUKAIUKlhb Keport - UhNlh Medium Area rorm
bample Name :, 134X4V 6UB . 6XMLXTUML-1MLX1UML IBA Report No : 82. UlMIH rUK LLP PhbIbXPLBb UN AUL-13 ' ' , page <.
HI lU-tm PeakUidth Area Lode AMUUNI Name2T.26 .UyUl 6V6UBbb 1.38yXh+U4
XU 2T.34 . UBV2 3/U42BB U.UUUUh+UUrjt° .114y !Uy4T6BB U.UUUUh+UU1 .1TU1 84484UBB U.UUUUh+UU
26.21 .2UU8 XU6V1BB l.U2U>h+U4 I nrlnn 11 | r ji i _ m r j i L.14V2 2U2>TXBB U.UUUUh+UU
|#2X.26 .!Uy6 TUB6B4BB b.64T2h+U4.1664 2B213BB U.UUUUh+UU•13U4 yT3XTBB U.UUUUh+UU.1128 4U4y/BB U.UUUUh+UU
XI 2T.63X2 2T.yUX3 26.23X4 26.BXXT 2X.2TX6 28.86/X 2y.3 1X8 2y.TT
^_______ U.UUUUh+UU8U 3U.28 .1TT3 6UV1BB U.UUUUh+UU81 3U.TX .42X8 11321BB U.UUUUh+UU82 31.34 .2181 8242UBB U.UUUUh+UU83 32.U8 .2T83 3U812BB U.UUUUh+UU84 32.66 . 2/U4 Wy/tlBB U.UUUUh + UU8T 34.23 .2V33 xdVl/BB U.UUUUh+UU86 3T.44 .2842 286y6yBB U.UUUUh+UU8X 36.81 .288X 4416BB U.UUUUh+UUB8 3X.38 .2T18 1U6TBB U.UUUUh+UU8y 38.3U .34V2 8B16TBB U.UUUUh+UUyu 38.yT .2441 14VXBB U.UUUUh+UU
lotal Area : 8261123 lotal RMUUNI : 36XVUy.6UU
Keport lime : rri Dec 6. lyyi TtT6:il pmMethod : XUAIAXhXIKALIbXMhIHUUXMIHLLp lllVA 13.MIH
%/**) /o s-o_ ,w __ ,,,,__,,
30
I
BLM LABUKAlUKltb Keport - lihN 11 Medium Area rorm
bample Name : 134X4y 6U8 .6/MLXTIJML-1MLX1UML IBA . Tieport No : 82. UlMIH' rUK LLP PhblbXPLBb UN AUL-13 Page 4
1. 3U2
i c *;pj. r «•?**i
! f 6.uy3j- t——— 6.832I f / ^ks IIff k\&h £_ 8.883 _____________________j 'k——————————————————————————————2 . A , 9 , 6- I h I KHLHLUKU-m-XYLhNt
1T.68U
T 'Ti0.- 1"4i£!Uy• Mep^acfr,!or eooxide
1 o rdane'6U1hndosulfan 1
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I _—————————————-—————————————-eH-frtf t v 1 ch 1 orendat et- ^
*: I I ' ) / f
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——— ————— .-..'.COl
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^P1 / 36.811I j .' / . .' B U
BLM LABUKAIUKltb Keport - thNlt Medium Area "horm
bamole Name : 134X4V 6UB .6XML/TUML-1MLX1UML IBA Keport No : 82.Ulr i l H HJK LLP PtblbXPLBb UN AUL-14 Page 1LULUMN UB1XU1 3UM X. U.T3MM 1UM rlLM 1U# U4V3UT2 1NJ I 2TULP-T -TMLXM1N MAbb H LUUJ MAKh UP P-T I-UK IUIAL Uh ~,-'UMLXMlNtLU 3UUL, KANbh U, lul INJhLllUN 1TUL, Imin TL/min, 2XTL
Book/Page : UI1U/U
Peak Processor : Uenie Multi l e v e l : raise
Instrument ' : AUL 14 Application : Loop
Lalculation : hxternalblU Uuantitat ion: AreaUnits
Kesult H i l e : XhXIXMhIHXKhbXUlliy3UX.Khb
Kun lime : 4U.UU Minutes Iniected on Ihu Nov 21, iyyi 3:2X:31 pm
Sequence t-iie: XUA I AXhX I KAL I bXbhUUhNLhXbhULLP 1121V1 14.bhU
bubseqXbample: IX X Bottle no. : TX
Ihreshold Min-Ar Pkwidth Kr UnknownT.U 2.UUUUt+U3 .16U U.UUUh+UU
Kef Wdw Abs Kef-KILJ Non Kef Ulin Abs Non Kef-Kltd Ident LevelU.UU l.TU U.UU l.TU 1UUU.UU
% Uil-ract bmp-Amt btd-Amt % Purity Ini Uo 1 Katio,'.462Xt+UX U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU
Hun Status : KunbtatusUKhndUffBasel me
limed tvents lime tvents Logic Ualue tventUpdate1 U.UU PesetBLAtUa1 ley tventUn -l.UU raise
U.UU NegativePeaks " tventUff -l.UU raise3 T.UU KesetBLAtUa1 ley tventUn -l.UU raise4 1U.UU PesetbLAtUa1 ley tventUn -l.UU raiseT 1T.UU KesetBLAtUa1 ley tventUn -l.UU halse6 2U.UU KesetBLAtUa1 ley tventUn -l.UU raiseX 2T.UU KesetBLAtUa1 ley tventUn -l.UU raiseb' 3 U.UU KesetBLAtUa 1 ley tventUn -l.UU raise
MMt KI lU-tm HeaKUlidth Hrea Lode AMUUNI Name1 1.1X .3Tlo y64VXBU U.UUUUt+UU'J 1.6X . 146T 1?XXU26'JU U.UUUUt + UU
2. IT .ioTi 1U46UUU U . U U U U t + U U4 2.36 .23 IT 4XXTUUU U.UUU U t + UU
-'.''-• . xou; Ti'jyauu L;. uuuut + '.nj6 2.yo .2144 32BT6UU U.UUUUt+UU
3.3X .2120 TU8T2PU U. U U U U t + U UB 3.66 .2368 3y43TUU U.UUUUt+UUu 3.yi .1B24 36y36UU U. U U U U t + U U
1U 4.24 .3V2U 6yi4BUU U.UUUUt+UU
AR30U32
Bi_n L.ABUKH i UK i tis Keport - bhNlh Medium Area rorm
Sample 'Name : 134X4y 6U8 . 6XMLXTUML-1MLX1UML IBA Import No : 82.UlMIH' rUK LLP PhblbXPLBb UN AUL-14 Page 2
Kl lU-tm PeakWidth Area Lode AMUUNI Name11 4.4y .lyUU 33T2UUU U.UUUUh+UU12 4.68 .244U 43T42UU U.UUUUh+UU
4.V6 .1X41 3U164UB U.UUUUh+UUT.4T .1UTX 8XU6UU U.UUUUt+UU
IT T.66 .142X 41X8UU U.UUUUt+UU16 6.Uy .1321 • 13X3 UPU IKUUUUh+UUI/ 6.34 . 32UT ILI/ITUU IT. UliUUh+UU18 6.B6 .1TU8 8X6yV"J U.UUUUh + UUiy X.U3 .13TX 341TUU U.UUUUh+UU2U X.22 . lyyy 6XBUW U.UUUUh + UU21 X.43 .13V6 36TlvX> U.UUUUh+UU22 X.Xy .2233 1UU8TW U.UUUUh+UU23 8.38 .1681 !X332yUU U.UUUUh+UU24 y.By #y.y3 .12U4 1TX6X46PB l./348h+UT 2,4,T,6-ItIKALHLUKU-m-XYLt2T 11.34 .1163 42V8UU U.UUUUh+UU26 11.6U .1U/6 1334/Pv1 U.UUUUh+UU2X 11.y4 . 126T 33/>yu«J U.UUUUh + UU2B 12.1V .1166 3yXllUU U.UUUUh+UU2V 12.T3 .122V 2X64UU U.UUUUh+UU3U 12.B2 . 1T4V 3X21VUU U.UUUUh+UU31 12.yx .11IX 12VB4UU U.UUUUh+UU32 13.28 .11X6 24VUUU U.UUUUh+UU33 13.66 .1333 !Xy2T8PU U.UUUUh+UU34 14.UB .1686 1V3X6UU U.UUUUh+UU3T 14.4U .-Iiy6 46T31UU U.UUUUh + UU36 14.TB .1362 X1T84YV U.UUUUh+UU3X 1T.U8 14.yB .1243 63634PB l.U4UUh+U4 gamma Ul IL t U i iiUane JB 1T.4U .13U4 2TU6T4BU U.UUUUh+UUy IT.By IT. 81 .iy6y BX136UU B.33U4h+U3 Hgpt noh leirU 16.2X .12X6 XXU2TUU U.UUUUh+UU1 16.6B .22BT 1VX3TXUU U.UUUUh + UU2 IX.iy . .16Uy 3Ty6UU U.UUUUh+UU
IX.T6 \1(° . 1T63 13424VUU U.UUUUh+UU«4 ix.ay-»T 18.4V46 18.63-4/ IB-8 IV.424y iy.64
.166y y2B83UU U.UUUUt+UU
.1U44 1X2UUPU U.UUUUt+UU18.66 .141U 4U8UyJU y.UX34t+U3 do I t 3 UHL'
• 182X 1836VXUU U.UU-UUt+UUiy. 33 .131V 24T43UU 3.UTTyt + U3 Hep Lac.il lUl
.2284 18yy'14UU U.UUUUt+UU
.IXyi XXT68UB U.UUUUt+UU2U.T2 . lyyx 2XXU1BU 6.863Tt + U3 n«mm=-i>, 21.U1 .13.'6 2T4/B4PU y.l/T8h+U4
• 14xT 'JUBoolUU U.UUUUt + UU
T u iy. ayT i 2 u . T xT2 2U.V6T 3 •_' 1 . 2 4-*>4 21.4« " . i4y? 6yaxxuu u.uuuut + uuTT 'J 1 . /o 'J1.6T . 14X»i 2/' 64T<..'iJ 3.6Ty4t + U4 LJI o 1 cl r T•"6 22. Ul .'J.'T " J.UU/6yjU U.UUUUt + UUl? •' - 2 . .* 'J 'J 2 . J u . 1 „' -.2 -»v xe T MI,' '. 4 3 3 31 + U 3 j nrJ i i IT"•"-' --.^z •-.:__:• • "- _ I'-j"--".!": •.".•"• u. uuuut'+uu•?y 22.yy . IBBT i6ii'4xuu u.uuuut + uuoU 23. I/' . IToo i*43oT2UU U.UUUUt + UU11 23.X6 23.aU . 166t 42TyU6UU 2.1X4Tt+UT62 •J3.ay/] (tt4* .1283 20-4U21VO U . U U U U h + U U
flR30ijl33
L.HDUKM i UK i e.s Keport - btNlt Medium Area rorm
bamole Name : 134X4y 6UB .6XMLXTUML-1MLX1UML IBA "tfeport No : 82.UlMIH rUK LLP PtblbXPLBb UN AUL-14 Page 3Pk# Kl lU-tm PeakUlidth Area Lode AMUUNI Name63 24. UT-64 24.666T 24.yy;06 2T.166X 2T.X36B 2T
24. UX . 16B6 iyyx61W 3.T24Bt+U4 tndosuifan 11. .18V8 T633XVU U.UUUUt+UU
\V» .1U4X 113TUyPB U.UUUUt+UU.U4XX 1TB61BU U.UUUUt+UU.1221 366XBPU U.UUUUt+UU.16X6- T328X8UU U.UUUUh+UU
26.36 .2UU8 X46T3XW l.uyyyh+U6 hndosu1fan suifate#26.X6 .1X33 11TXX46UU 1.464Uh+UT Uibuty1chiorendate
1TXT 24VT21UU U.UUUUh+UU2636 X3UUX1UU U.UUUUh+UU
6y 26.34XU 26.XUXI 2X.U3X2 2X.24X1X3 2X.84 .28Ty 2Uy286"-"J U.UUUUh+UUX4 2B.1V 28.2x .3614 ITxllUVU 2.U3TUh+U4 hndnn ketoneXT 2B.XT ./2y3 44B364UU U.UUUUh+UUX6 2y.y4 .y4Tl 823143UB U.UUUUh+UUXX 31.33 .3U82 26UXU6BU U.UUUUh+UUX8 32.16 .3688 X844XW U.UUUUh + UUXy 34.Uy .TT46 V6X1PU U.UUUUh+UU8U 3T.16 .486U ___2V611W U.UUUUh+UU81 3B.T2 .83VT iy31TBB U.UUUUh+UU
lotal Area : 12yB86T8 lotal AMUUNI : lB662yx.UUU
Keport lime : t- r i Uec 6, lyyi 6:UU:23 pmMethod : XUAIAXhXIKALIbXMhIHUUXMIHLLP 111VA 14.MIH
„ r* . ,,= &<>, *>// ** /L0
l'
BLM LABUKAIUKihb Keport - bhNlh Medium Area rorm*w
Sample Name : 134X4y 6UB .6XMLXTUML-1MLX1UML IBA Keoort No : 82.Ul.MIH I-UK LLP PhblbXPLBS UN AUL-14 Page 4
T }{!~ - 1.1X2 ______—————————————————————————————————————— 1.6X1
HLUKU-m-XYLhNh
7^" 2 4,4'-UUh
Uie 1 dr in22.TT8
4,4'-UUU
—— 16U 24.yyu
i ..•:....——————————••• ' - " —- , ~Sgg3sulfan sulfatei ..-.-.....-.-——————..... _ . ^ ^ ,,.., ,uiuu tylcn lorendate———— -• ' ULlLl " 2X.242
,_ _ 2X. 843hndrin ke t one
i ^—" .' 2 . 1 o U1- fI II J 34.UB8L i.
=/ 3T.1T6I
I
AR30iil35
bample Name : AK1248 2-B3-U3 U.TPPM Keport No : 23. UUMIH'rUK LLP Phb I bXPLBb UN AUL-13 *v Page 1LULUMN UB6U8 l^n X U.T43 MM U.B3 UM r- 1LM 1U*U331222 , 1 NJ I 2TUL'AKKlhK P-T A I TPbl, I U I AL r-LUW -XUMLXM1N hLU 3UUL KANUh Uui iNJhLllUN ITUL', Imin TLXmin, 2XTL 14M1N
BookXPage :
Peak Processor : laenie Multilevel • raise . ,
Instrument : AUL 13 Application : Loop
Lalculation : hxternalblU Uuant i tat ion : RreaUnits
Kesult I- lie : XURI AXhX I KAL I bXKhbULI XNlliyil2 . Khb
Hun lime : 4U.U2 Minutes iniected on Tue Nov IV, 1VV1 6:^3:T4 pm
Sequence rlie: XUA I AXhX I KAL I SXbhUUhNLhXbhULLP lllVVl 13.SahU
bubseqXbample: IX l'2 Bottle no. : 12
Ihreshoid Min-Ar Pkwidth Kl- Unknown2.U l.UUUUh+U3 .U4U U.UUUh+UU
Kef wdw Abs Kef-KIU Non Kef win Abs Non KeF-KIW Ident LevelU.UU l.bU U.UU l.TU 1UUU.UU
\ Uil-ract bmp-Amt btd-Amt % Purity Ini Uo 1 Katiol.UUUUh+U2 U.UUUUh+UU l.UUUUh+UU 1UU.UUU l.UUU
Kun btatus : KunbtatusUKhndUff Basel me
limed tvents lime hvents Logic Ualue hventUpdste1 U.UU Negat ivePeaks hventUff -l.UU raise2 .1U KesetBLAl lUal ley hventUn -l.UU raise
Kl lU-tm PeakUidth Area Lode AMUUN I Name1 1.32 .12U3 6B6X261BS U.UUUUh+UU2 2.TX .124X 38VTBB U.UUUUh+UU3 4.62 .lyUU 1XU3BB U.UUUUh+UU4 T.33 . U888 3322BB U.UUUUh+UUT T.TB .1UX1 131UTBB U.UUUUh+UU6 6.11 .1UB4 1642BB U.UUUUh+UUX 6.84 .1224 1364U3BB U.UUUUh+UUB X.T3 . ITyB 2U2Vbb U.UUUUh+UUy y.TU *y.4y .1141 /3T4BTbb l.UT46h-Ul 2,4,T ,6- I h I KALHLUKU-m-XYLhN
1U 1U.11 .1T1U 2Ullbb U.UUUUh+UU11 1U.3X .1144 16UTBB U.UUUUh+UU12 11. iy .1138 X441BB U.UUUUh+UU13 12.34 .UViy IBByBB U.UUUUh+UU14 12.66 .13XX X412BB U.UUUUh+UUIT 12. y4 .1X24 6131bb U.UUUUh+UU16 13.43 .1BTU 1321bb U.UUUUh+UU
AR30IH36
bample Name : AK1248 2-83-U3 U.TPPM Keport No : 23.UUMIH rUK LLP PhbIbXPLBb UN AUL-13 ^ Page 2
Kl iU-tm PeakWidth Area Lode AMUUNI Name. 1/UT 3348BB U.UUUUh+UU.1338 68V8XBB U.UUUUh+UU. liy/ 2132BB U.UUUUh+UU. 1/b/ 3UT46BB U.UUUUh+UU. 1UT2 11364BB U.UUUUh+UU.l^y/ 18iyi2BB U.UUUUh+UU.124U 41622BB U.UUUUh+UU.1128 11U63BB U.UUUUh+UU.142X V3UVXBB l.T866h-U2 «-WPTn.1463 TV4UTBB U.UUUUh+UU. 133V VU34BB U.UUUUh+UU.123U . X8B44BB U.UUUUh+UU.UByi i2yy?BB u.uuuuh+uu.166U 863yTBti U.UUUUh+UU.126U 6TU43BB U.UUUUh+UU.116U y/383BB U.UUUUh+UU.1313 1214yyBB U.UUUUh+UU _______.122/ 24UV2BB 3.72x4h-U3 ggjiiini LMftrflane.143T 31V68BB U.UUUUh+UU.1142 21VTUBB U.UUUUh+UU.12/8 1U6113BB l.T62Xh-U2.1266 ly^yybb u.uuuuh+uu
2U3/XBB U.UUUUh+UU.UBlb X6UTBB U.UUUUh+UU.1U4V 28XTXBB U.UUUUh+UU.126T 383TUBB U.UUUUh+UU.1136 4V3VBB U.UUUUh+UU.13U8 2U2X6BB U.UUUUh+UU.1U4X !Ty6bB 4.y3TVh-U4. UV48 ^14UyBB U.UUUUh + UU.13Xy 2VT84BB U.UUUUh+UU.UB62 1161BB U.UUUUh+UU.163y 111U2BB 2.yXUUh-U3 ^_jt--11111.1U3U 124TBB U.UUUUh+UU.14XU V144BB U.UUUUh+UU.1TUX 1666VBB U.UUUUh+UU.1XU2 T6UX14BB 1.2/6yh-Ul Uibuty1chlorendate
2.X28B 86T2BB U.UUUUh+UU.24UB yUXUBB U.UUUUh+UU.B4BX 1363BB U.UUUUh+UU•26TV XXT6BB U.UUUUh+UU.284V 13B6BB U.UUUUh+UU
l o t a l Area . : VX6V212 l o t a l AMUUNI : .2/6
Keoort lime : lue Nov iy. 1VV1 x:3T:42 omMethod : XUAIAXhXIKALISXMtIHUUXMIHLLP lliyyi 13.MIH
AR30M37
bample Name : AK1248 2-B3-U3 U.TPPM Keport No : 23.UUMIH rUK LLP Ht b H£ljibJlJN AUL-13 ___ _ ^ Page 3
L j__________________________1 \ i 1.323
"
2 .4.,9 ,6- I h I KHLHLUKU-m-XYLhNh
uioutylchlorendate
I———1_
AR30U38
Sample Name : AK12T4 2-B2-y2 U.TPPM Keport No : 24.UUMIH rUK LLP PhbIbXPLBb UN AUL-13 *v Page 1LULUMN UB6UB 3UM X U.T43 MM U. B3 UM riLM 1U*U331222 , 1NJ I 2TULAKKlhK P-T At TPbl., IUIAL rLUU ~XUMLXM1N hLU 3UUL KANlih Ulul INJhLliUN ITUL', Imin TLXmin., 2XTL 14M1N
okxpage :
Peak Processor : Lrcnie Multilevel '• raise
instrument : AUL 13 Application : Loop
Lalcuiation : hxternalSIU LJuant 11 a t ion: AreaUnits
Kesult rile : XUAIAXhXIKALISXKhbULIXNlliyil3.Khb
Kun lime : 4U.UU Minutes imected on tue Nov iy, lyyi /:3/:i4 pm
bequence rile: /UAIAXhXIKALIbXbhUUhNLhXbhULLP lliyyi 13.bhU|
SubseqXbampie: IX 13 bottle no. : 11
Ihreshold Min-Ar Pkwidth Kr Unknown2.U l.UUUUh+U3 .U4U U.UUUh+UU
Kef Udw Abs Kef-KIU Non Kef Win Abs Non Kef-KIU ident LevelU.UU l.TU U.UU l.TU 1UUU.UU
% Uii-ract bmp-Amt btd-Amt % Purity ini Vo i Katiol.UUUUh+U2 U.UUUUh+UU l.UUUUh+UU 1UU.UUU l.UUU
Kun Status : KunbtatusUKhndUf fBase 1 me
limed hvents lime hvents Logic Uaiue hventUpdate1 U.UU NegativePeaks hventUff -l.UU haise2 .1U KesetBLAllUa1 lev hventUn -l.UU raise
Kl lU-tm PeakUidth Area .Lode AMUUNI Name1 1.2V .UyUX V66U66BB U.UUUUh+UU2 2.TB .3U11 13333BB U.UUUUh+UU> T.33 .UV3X 33B3BB U.UUUUh+UU4 T.T8 .1111 VT3TBB U.UUUUh+UUT 6.1U . .1U11 144TBB U.UUUUh+UU6 6.B3 .12XT BB2T6BB U.UUUUh+UU/ /-1'2 . 1T2V 11X4BB U.UUUUh + UU8 y.4y #y.4y .114y XH2BTBB l.Uiyyh-Ul 2 ,4 ,T ,6-IhlKALHLUKU-m-XYLh!y 1U.36 • .1188 12X2BB U.UUUUh+UU
1U 11.18 .14iy yUV4BB U.UUUUh+UU11 12.U4 .124T 1U3TBB U.UUUUh+UU12 12.66 .13V2 3XTBBB U.UUUUh+UU13 12.yx .23U6 6VT2BB U.UUUUh+UU14 13.X3 .IByT 12BVBB U.UUUUh+UU1* 14.13 .136y 3XBTBB U.UUUUt+UU16 14.yy .U6B6 1T4TBB U.UUUUt+UU
AR30U39
sample name : HKii::?** x-at-ut u.^rrn Keport NO : 24. UUMIH'rUK LLP Phblb/PLbb UN RUL-13 Page 2
Area Lode AMUUN I -Name**23/1BB U.UUUUh+UUTyilBB /.316yh-U4 IfeylULhlor133UBB 2.yiU3h-U4 drt'l ta.HHL1262BB U.UUUUh+UU18TTBB U.UUUUh+UU
/V6/UBB 1.3T/8h-U2 fHtitun/2U6BB U.UUUUh+UU2V31BB U.UUUUh+UU438/3BB U.UUUUh+UU1168VBB U.UUUUh+UU6V/TBB U.UUUUh+UUT46yBBB U.UUUUh+UU13612BB U.UUUUh+UU114822BB l.//6Th-U2 gailllliai"Ulrt Ul'gane13TTUVBB U.UUUUh+UUTUyUUBB U.UUUUh+UU86T1BB 1.2/4Uh-U3 Lirtln ml li^in 1T26V/BB U.UUUUh+UU4/3BTBB l.lUy6h-U2BBUyBBb U.UUUUh+UU23/4yyBB U.UUUUh+UU2T46BB U.UUUUh+UU
13U821BB U.UUUUh+UUB/624BB U.UUUUh+UU123//1BB U.UUUUh+UU//43bB U.UUUUh+UU26B16BB U.UUUUh+UU41/1/BB U.UUUUh+UU24U46BB U.UUUUh+UUT6V/BB U.UUUUh+UU
14/U81BB 3.9>4/t-U21U/UTBB U.UUUUh+UU13443BB U.UUUUh+UU1/2TUBB U.UUUUh+UU
Ul Uibutylchiorendate4VU6BB U.UUUUh+UU
2U614BB U.UUUUh+UUVT36BB U.UUUUh+UU2214BB U.UUUUh+UU
lotal Area : 4U6T643 lotal AMUUNI : .322
Keoort lime : Iue Nov iy, lyyi 8:18:41 pmMethod : XUAIAXhXIKALIbXMhIHUUXMIHLLP lliyyi 13.MIH
flR30l*|l)0
Sample Name : RK12«?4 2-B2-U2 U.bPPM Keport No : 24. UUM!H rUK LLP Phb I b/PLBb UN AUL-13 _____ ** Page 3r i ....... -...--—...- _———__ . —— .- ———————.
fhi tL P-J 6.1U4
/.T2U
L 'r —— 2 , A , 5 , b- 1 1 1 KHLHLUKU-m-XYLtNh! J 1U.361f r 11. 184" I 12.U3T
1- 13.X32\ r 14. 132
L. r Heotachlor[ I ?gn*l5UHL
Uibutvlchlorendate
BLM LABUKAIUKlhb Keport - UhNlh Medium Area rorm
bample Name : AK126U 2-81-U3 U.TPPM Ktfport No : 2T.UUMIH rUK LLP Phb1bXPLBb UN AUL-13 Poge 1LULUMN UB6UB 1UH X U.T43 MM U.83 UM HLM 1U*U331222,1NJ I 2TULAKKlhK P-T A I' TPbl, IUIAL rLUU -XUML/M1N hUU 3UUL KANbh U.ul INJhLllUN 1TULJ Imin TL/min, 2/TL 14M1N
Book/Page :
Peak Processor : Uenie * Multilevel : raise
Instrument : RUL 13 Application : Loop
Lalculation : hxternalblU Uuantitat ion: AreaUnits
Kesuit Kile : /UAIR/hXIKRLIb/KhbULI/NlliyilA.Khb
Kun lime : 4U.UU Minutes Iniected on lue Nov iy , 1VV1 8:2U:3/ pm
bequence rile! /UflIA/hXIKRLIb/bhUUhNLh/bhULLP lliyyi l^.bhU
bubseq/bampie: I/ 14 bottle ho. : 14
Ihreshold Min-Ar Pkwidth Kr Unknown2.U l.UUUUh+U3 .U4U U.UUUh+UU
Kef Udw Abs Kef-KIU Non Kef Uin Rbs Non Kef-KIU Ident LevelU.UU l.TU U.UU l.TU 1UUU.UU
% Uil-ract bmp-Amt btd-Amt X Purity 1m Uo 1 Katiol.UUUUh+U2 U.UUUUh+UU l.UUUUh+UU 1UU.UUU l.UUU
Kun Status : KunbtatusUKhndUffBasel me
limed hvents lime hvents Logic Ualue hwentUpdate1 U.UU NegativePeaks hventUff -l.UU raise2 .1U KesetBLAlIVailey tventUn -l.UU raise
Pkft Kl lU-tm PeakUidth Area Lode AMUUNI Name1 1.3U .Uy/y X3862UBB U.UUUUh+UU'^ 2.13 .U836 1382BB U.UUUUh+UU1 2.TU .12/U V341BB U.UUUUh+UU4 2.BT .liyy 1U1VBB U.UUUUh+UUT 4.61 .1B2U 14V1BB U.UUUUh+UU6 T.33 .U8y/ 3U14BB U.UUUUh+UU/ T.TB .lUy/ 12VU1BB U.UUUUh+UU8 6.1U .1126 16U4BB U.UUUUh+UUy 6.84 .1244 1348y8BB U.UUUUh+UU
1U X.T3 .1462 2U16BB U.UUUUh+UU11 y.4y $y.4y .HTT 6TaXlXBB y.44T2h-U2 2 ,4,T ,6-IhlKALHLUKU-m-XYLhN12 1U.36 .12UU 1U8XBB U.UUUUh+UU1^ 1U.XU .1266 3X16BB U.UUUUt+UU14 11.iy .111U 6UUUBB U.UUUUt+UU
.IT 12.66 .1388 T/7VBB U.UUUUh+UU16 12.y6 .iyy2 T322BB U.UUUUh+UU
BLM LAbUKAIUKlhb Keport - UhNlh Medium Area rorm
Sample Name : AK126U 2-81-U3 U.TPPM W»port No : 2T.UUMIH' rUK LLP Phblb/PLBb UN AUL-13 Page 2
Kl lU-tm PeakUidth Area Lode RMUUNI NameI/ 13./2 .1/yy lT3Tbb U.UUUUh+UU18 14.14 .1444 2UT/bb U.UUUUh+UUy 14.yy .1U3T 28/3bb U.UUUUh+UU
2U 1T./U .183U 36BTBB U.UUUUh+UU21 1/.U1 1/.U3 . 1TB3 V632BB 1.6416h-U322 i/.yy .2T/y I&/BBB u.uuuuh+uu23 iy.46 .1232 11/2BB U.UUUUh+UU24 iy./6 .1283 1UU2BB U.UUUUh+UU2T 2U.U/ 2U.U/ . 123U 44836BB 6.y3/Uh-U326 2U.3U .1181 TT443BB U.UUUUh+UU2/ 21.4/ .1226 23/2BB U.UUUUh+UU28 21./T 21.// .1128 2UU1BB 4.6B/Uh-U42V 22.Ul .12T1 1123UBB U.UUUUh+UU3U 22.42 . 13TB V2/13BB U.UUUUh+UU31 22.BT .2T/3 6312UBB U.UUUUh + UU32 23. lev, .1343 1/V22/BB U.UUUUh+UU33 -21.4/' .134T IVTIU/BB U.UUUUh + UU34 23.88 .1244 /883BB U.UUUUh+UU3T 24.3U/ .13U8 68/yybB U.UUUUh + UU36 24.T6 .111/ 1141BB U.UUUUh+UU3/ 24.88 .U8y4 44T13BB U.UUUUh+UU38 2T.U2 .UB46 11U/3BB U.UUUUh+UU3y 2T.26 S 2T.26 .2UB/ 236684BB 6.331Bh-U2 M j * TJUI4U '2T.63 .1214 T43T1BB U.UUUUh+UU41 2T.86 .134y 3UU2BB U.UUUUh+UU42 26.23 26.21 . IBUV 313UUbB 6.UT4Uh-U3 hnrlnrn I I'mi juM'ate43 26.88 .1116 6T2U6BB U.UUUUh+UU44 2/.26 *2/.26 .1UV6 22U42yBB T.U2UUh-U2 UibutylchlorendateT 28.88 . 1/2T 11/T8BB U.UUUUh + UU6 2V.33 .1TUT 3/234BB U.UUUUh+UU
4/ 2V.T/ x .U836 2441BB U.UUUUh+UU48 2y,8U/ .1T1U y8T24BB U.UUUUh+UU4y 3U.26 .1612 2TUTBB U.UUUUh+UUTU 31.36 .2U6U T6TUBB U.UUUUh+UUTl 32.13 .1/BB 1//4BB U.UUUUh+UUT2 32.6/ .2BUU 123226BB U.UUUUh+UUT3 3T.46 .2/y/ 3U3TVBB U.UUUUh+UUT4 38.3T .3416 446TBB U.UUUUh+UU
l o t a i Area : 331BVU/ lotal AMUUNI : .223
Keport lime : lue Nov iy, iyyi y:U2:U2 pmMethod : XUAIAXhXIKALISXMhIHUUXMIHLLP lliyyi 13.MIH
flR301*|l»3
Sample Name : AK126U 2-B1-U3 U.TPPM Kpport No : 2T.UUMIH rUK LLP Phb I b/PLbb UN AUL-13 * Paae 3
f 4.6U/i
6.1U46.B3T
————— 2 , A, g ,b- I E. I KHLHLUKU-m-XYLhNht f I <A. b* UI IJ m y jJ fjj
Ilil87
1 «I- ( 13.718| f 14.136
i4.yay1T.6VT
Aldrmi/.ya/
gagg y't? lordane
*U«2T.B64EIT."_ hndosulfan sulfate
>f^ » yd ______________________utylchlorendate
AR30I4UI4
RAW DATAfor
PCBS IN COYRTYARD SURFACE SOIL MBK TBS2-0.5
CDra&
Oa.OOO
ioc<
QUlQ.S<
5 E E• 3 C8j; z coco *- "5o °
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F
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00 Ocj
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i
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1
1
1
i
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mon
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:-:,V:
•note that retention times ant out of the expected window"note calculation* assume equivalent volume injected for standards and samples
calculation: (summed arta)(final volume in ul)(dilution)(1ug) -cone, in ug/Kg(Calibration factor PCB)(1000ng) (inital wt in kg)
PCB1016:
PCB1221:
PCB1232:
PCB1242:
PCB124&
PCB1254:
PCB1260:
EXPRTWIN13.45 - 13.5514.98 • 15.0815.68 - 15.7816.29 • 16.3917.67 - 17.77
EXPRTWIN11.66 - 11.76ia05 - 13.1513.40 • 13.5014.97 - 15.0715.67 - 15.77
EXPRTWIN11.65 - 11.75
13.43 • 13.5314.96 • 15.0615.66 - 15.7616.26 - 16.36
RT0.000.000.000.000.00
RT0.000.000.000.000.00
AREAO.OOE+00O.OOE-t-00O.OOE+00O.OOE+00O.OOE+00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
RT0.000.000.000.000.00
EXPRTWIN13.43 - 13.5314.96 - 15.0615.66 - 15.7616.27 - 16.3718.97 - taOT
EXPRTWIN14.93 • 15.0316.25 - 16.3518.12 - 18.2218.93 - 19.0320.07 - 20.17
EXPRTWIN19.31 - 19.4119.55 - 19.6521.68 - 21.7822.13 - 22.2322.69 - 22.79
EXPRTWIN21.65 - 21.7522.38 - 22.4822,70 - 22.8024.46 - 24.5628.71 . 28.31
RT0.000.000.000.000.00
RT15.0116.2818.2019.0120.17
RT0.000.000.000.000.00
RT0.000.000.000.000.00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
AREA1.92E+067.79E+056.01 E+051.13E+061.15E+06
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
AREAO.OOE+00O.OOE+00O.OOE+00O.OOE+00O.OOE+00
0 x 10000 x 100 x 11565066 x 1000 x 0.03
% MOISTURE CORRECTED-
0 x 10000 x 100 x 1456616 x 1000 x 0.03
% MOISTURE CORRECTED -
0 x 10000 x 100 x 11093710 x 1000 x 0.03
% MOISTURE CORRECTED.
0 x 10000 x 100 x 11176370 x 1000 x 0.03
% MOISTURE CORRECTED -
5580219 x 10000 x 100 x 11530634 x 1000 x 0.03
% MOISTURE CORRECTED =TMX cone: 31.9 ug/KgDBC cone: 171 ug/Kg
0 x 10000 x 100 x 12545700 x 1000 x 0.03
% MOISTURE CORRECTED =
0 x 10000 x 100 x 12420974 x 1000 x 0.03
% MOISTURE CORRECTED*
flR
0 ug/Kg
0 ug/Kg
0 ug/Kg
0 ug/Kg
0 ug/Kg
0 ug/Kg
0 ug/Kg
0 ug/Kg
122000 ug/Kg
137000 ug/KgTMX %R 96%DBC%R 513%
0 ug/Kg
0 ug/Kg
0 ug/Kg
0 ug/Kg
inii i it?
BCM LABORATORIES Report - GENIE Medium_Area F6Jrm
Sample Name : 123576 608 30G-10ML X100 S897 Report .No : 267. 01::'H .-Y;R V/L? I-'ESTS/PCBS ON ADC-U"%:.I;XN DBM.-J.S J::.M x n.^j MM .1.^3 -M FTL.X •.D*?O 3312;:^, .'XJ " n^.i)
KK.'rJH P-'i AT '-.PS I, TOTAL .-'LOW •• /OML/M J.N rXD :!)OC KANGc :*
- -i '. : '•"'=•:•• n o 7" : -jeni*? 1J!u 1. 1: i " .? v f ".. : r'.-il;~«r
r..rrt-ur-.er>.r : ADC_'. J Applicsti^r. : Loop
-.I.--;: I -it: ion : u-xremaldTIi ouant i ra t i;>n : AreaJn.ir.L-
.-••-L-t. :.r rile : /DATA/ EXT'AAi;1":.: .- v? r:.-.:.:L'"/x:;bo 5 22 :: . RE.
-:JM :..TI'? : 4().;j2 Minur.es . r. jecte^i on, w^d Aug .' , .'. 'J^i r, :J7:14 am
e-'ruer.ce - i le: /DATA/EXTRACTS /.SEQUENCE /SEgCLlJ_i;tf us y i_l j
.-.r'--.-r:c ". Min-Ar • .-<wii":rr. nr'_ . .; 1 . t)()0(JE+i)3 .;)4() i) . O
-ef wdw Abs Ref-RTW Mon Ref Win Abs Non Sef-HTW Iden•).()() 1.50 (J.t)O l.bC) !()()(). 00
Oil-Fact Smp-Amt -Std-Amt % Purity Inj Vol Ratio:•. 3331-ih;+()ft O.OOOOE-KJO 1 .OQOOE+OO 100.000 1.000
Aun Status : RunStatusOKEndOffBaseline
rimed Events Time Events Logic Value EventUpdate1 0.00 NegativePeaks EventOff -1.00 False2 .10 ResetBLAllValley SventOn -1.00 False
RT ID-tm PeakWidth Area Code AMOUNT Name1 .77 .1633 45827BB O.OOOOE-t-00<: 1.09 31.09 .1045 642048BB 1 . 2644E-02 SOLVENT FRONT^ 1.44 .0649 117025BB O.OOOOE-t-004 l.t>0 .0612 118316BB 0 . OOOOE-t-005 2.51 1.8244 6885BB O.OOOOE-t-006 2.86 .1555 1536BB O.OOOOE-t-007 4.19 .1527 1122BB O.OOOOE+008 5.12 .1118 26407BB O.OOOOE-t-00* b.bl .1291 1260BB 0 . UOOOE + 00
10 t>.33 .1234 . 34284BB O.OOOOE-t-00"••! -'.Ob . Ib61 1086BB O.OOOOEfOOH "'.37 .0994 1902BB O.OOOOE-t-0013 «.89 #«.91 .1316 5602BB 3.1875Ef01 2,4,5,6-TETRACHLORO-m->14 9.78 .1352 206bBB O.OOOOE-t-0015) 10. b9 .1050 3868BB O.OOOOE + 001(5 11.44 .1253 7163BB O.OOOOE-i-00
BCM LABORATORIES Report - GENIE Meaium_Area form
Sample Name : 123576 608 30G-10ML X100 S897 Report No :267/pTMTH FOR CLP PESTS/PCBS ON ADC-13 ' Page 4
..SOLVENT FRONT
- , i , : , .-.-•"STRACHLORO-m-XYLiNh:
L.'). b'H9 . _ - . . ' -
• 1 b . ,
*14-387
Heptachlor
22.1682.721
'-DOTj i "iariY7r*u~te «•|l£||yc|e
' 2f fbygjlchlorendate'
Aldrin1/.2V4 !— —.._ --. .^ 17.689
_ _ , U h i 8 r ° f g o ^ j ^ e
Endosulfan 1!
21.713 j
37.366j /IR30M5
ABCM LABORATORIES Report - GENIE Medium_Area- f»orm
Sample Name : 12-3576 608 30G-10ML XI 00 S897 Report No : 268. 01TH .-.,.-; ,: r- --^jTii/VCBS UN AiJC-14 .-.nc;e 1' :""!.'. 'XX " '-'.'.';'.'' ;;K X ':.-. .'MM ' ' .M K ! I.X !_'? ::•* '7 .".(!'-.". ' N.7 '' -•••••• • -Ml,, Xl..\ MAbS ri.cjw MAKE '..'P J--S rijR TO^AL OF -70ML/MTN
-"I" .' , ,=• A •>.'!:=: , ul T-JJECT ••;•••-,= I- :•-•, :-in -C/mir. . .17= 7
,-.;• : , —« i t? •"''. i ~ i .".••' V(=• '.. : -':: ..." f?
: \~>C_'.-. App*. ication : .".oop
: xr.err.a i.S 'D ;:;ar.r i r.sr.: on : Arefl'/n: -::
r.e.rulr -He : /DATA/EXTRACTS/ KESi.;i,'"/Of;ttt)i:i222 . XES
.-.un •::•(=• : -O.ii.'5. Minutes ;.njecf.ea i->n wed Aug /, '. •?*•)'. -.
.iequirP.-rr -ile : - :.<ATA/EXTRAC7S/3EQUENCE/SEOCLP_';S06y 1_1 i . r:C
• '.i c>=••:.'•- -.~— — : 1 / .•:. 2 .-.'of r I.e r.o . : '.'.
r.rf=-.-r.o"_ • Xin-Ar- Pkwidth SF_Unknown. ;) l.OOOOE-i-03 .040 l) . OOOE-t-00
3ef wdw Abs Ref-RTW \:on Ref Win Abs Non Ref-RTW liler.r Lv-vel0.00 1.50 0.00 1.50 HH)0.:;0
Oil-Fact Smp-Amt Std-Amt % Purity Inj Vol Ratio.1 . .J333E-t-06 O.OOOOE-t-00 1 . OOOOE-t-00 100.000 " i.OOO
Run Status : RunStatusOKEndOffBaseline
Timed Events Time Events Logic Value EventUpdate1 0.00 NegativePeaks EventOff -1.00 ralse2 .10 ResetBLAllValley EventOn -1.00 False
RT ID-tin PeakWidth Area Code AMOUNT Name1 .12 .2041 4277BB O.OOOOE+002 1.40 .0932 1204779BB O.OOOOE+003 2.JO .1302 168919BB O.OOOOE+004 11.51 .0931 154768BB O.OOOOE+005 2.97 .0940 5387BB O.OOOOE+006 3.62 .1418 1770BB O.OOOOE+007 4.b8 .1755 2168BB O.OOOOE+008 5.07 .2135 7813BB O.OOOOE+00y fa.72 .2347 1070BB O.OOOOE+0010 8.14 ' .1080 43257BB O.OOOOE+0011 S.r>2 .1186 1935BB O.OOOOE+0012 9.56 #9.67 .1051 65994BB 2.5197E+02 2,4, 5, 6-TETRACHLORO-m-><13 10.11 .1142 • 1331BB O.OOOOE+0014 10.85 .2008 4320BB O.OOOOE+0015 12.05 .1269 12486BB O.OOOOE+0016 12.79 .1302 50188BB O.OOOOE+00
AR30U52
BCM LABORATORIES Report - GENIE Medium_Area Form,...,-".Sample Name : 123576 608 30G-10ML X100 S897 Report NoMTH FOR CLP PESTS/PCBS ON ADC-14 Page
ID-tm PeakWidth Area Code AMOUNT Name.1254 185134BB O.OOOOE+00.1236 56938BB O.OOOOE+00.1038 • 24b370BB O.OOOOE + 00.1214 200162BB O.OOOOE + OU
----- -.-:39b iai ZiliB. •>. OOOOE+UO.1891 513024BB O.OOOOE + 00. 12b2 /8yi99BB :). OUOOE+')i;.-.1231 . *5.til91BB S . 1170E+0 3 Aitirin.1547 v> i n n v_HgR 2.1969E+05 oeta-BHC.1812 :j^4^Ql !HR ;; . OOOOE+00.0789 76758BB 3.7682E + 02 delta-BHC.1048 271159BB O.OOOOE+00.2083 IJ Ai&ififi. 0. OOOOE+00.0886 17529BB O.OOOOE+00.0798 40680BB 0..OOOOE+00.1520 860175BB O.OOOOE + 00.1258 115749BB 4.7073E+02 alpha-Chlordane.1881 a^7?;q?.BR 1.9233E+03 4,4 '-DDE. Ib24 3900b3BB O.OOOOE+00
222068BB O.OOOOE+0013'Jb 182381BB O.OOOOE+001512 120028BB O.OOOOE+001054 31679BB O.OOOOE+001389 127739BB O.OOOOE+001686 169633BB, O.OOOOE+000808 6028BEF O.OOOOE+005131 870777BB 3.7287E+03 Endrin aldehyde,2317 83376BB O.OOOOE+001623 108369BB O.OOOOE+000814 13666BB 3.2339E+02 Methoxychlor1617 10131BB 5.8163E+01 Dibutylchlorendate,3126 220717BB O.OOOOE+002201 12469BB O.OOOOE+002128 20673BB O.OOOOE+002475 8788BB O.OOOOE+003596 64193BB O.OOOOE+002436 9135BB O.OOOOE+002386 26638BB O.OOOOE+009709 262512BB O.OOOOE+000809 86741BB O.OOOOE+009335 50744BB O.OOOOE+00
Total Area : 16249930 Total AMOUNT : 231938.400
Report Time : Tue Aug 13, 1991 3:24:25 amMethod : /DATA/EXTRACTS/METHOD/MTHCLP_080691_14.MTH
«\
Sample Name : 123576 608 30G-10ML X100 S897 Report No :268~.lMTH FOR CLP PESTS/PCBS ON ADC-14 " Page
1.4 by.bio
-• 7 ?
. 2 , 4 , b , b-TETRACHLORO-m-XYLENE0.1130 . 8 5 2
' C
13.474'____ 14.209 . ;
——————————————. 15.21516.075Aidrin
i-rBHC18.429
19.663alphajChlggdane
=— ' 21.019
Endrin al iehyde
26. 970<' 27.901< 28.434r 28.904';> 29.575('' 30.527
30.960
32.054 I
j
34. 259 '
ia 36.569it
PCB 1016: 0.5 ng/ul STD 1Average retention time
13.50 peak 1 18740515.02 peak 2 28141415.72 puk3 11167016.33 peak 4 11529517.72 peaks 86749
Sum of peak area: 782533Calibration factor: 1.57E+06AvertgtCf: 1.57E+06Standard Deviation: NA Percent RSD: NA
PCB 1221: 0.5 ng/ul STD 1Average retention time
11.71 peakl 14511913.10 peak 2 1308013.45 peakS 3867415.02 peak 4 1869715.72 peak 5 12738
Sum of peak area: 228308Calibration factor: 4.57E+05Average Cf: 4.57E+05Standard Deviation: NA Percent RSD: NA
PCB 1232: 0.5 ng/ul STD 1Average retention time
11.70 peakl 11008313.48 Deak 2 12765815.01 peak 3 17074915.71 peak 4 6941116.31 peaks 68954
Sum of peak area: 546855Calibration factor: 1.Q9E+06Average Cf: 1.09E+06Standard Deviation: NA Percent RSD: NA
PCB 1242: 0.5 ng/ul STD 1Average retention time
13.48 peak 1 13844415.01 peak 2 20830515.71 peak 3 7695416.32 peak 4 8238919.02 peak 5 82093
Sum of peak area: 588185Calibration factor: 1.18E+06Average Cf: 1.18E+06Standard Deviation: NA Percent RSD: NA
AR30M55
m
PCB 1258: 0.5 ng/ul STD 1Average retention time
15.01 peakl 21616516.34 peak 2 14191818.21 peaks 11192919.02 peak 4 15327420.17 peak 5 142031
Sum of peak area: 765317Calibration factor: 1.53E+06Average Cf: 1.53E+06Standard Deviation: NA Percent RSD: NA
PCB 1254: 0.5 ng/ul STD 1Average retention time
19.36 peakl 19117019.60 peak 2 21038121.73 peaks 42298722.18 peak 4 23416022.74 peaks 214152
Sum of peak area: 1272850Calibration factor 2.55E+06Average Cf: Z55E+06Standard Deviation: NA Percent RSD: NA
PCB 1260: 0.5 ng/ul STD 1Average retention time
21.70 peak 1 13915622.43 peak 2 26938722.75 peaks 29172524.51 peak 4 36114928.76 peaks 149070
Sum of peak area: 139156Calibration factor: 2.69E+05Average Cf: 2.42E+06Standard Deviation: NA Percent RSD: NA
Surrogates: Average TMX area: 5858090 Average TMX Calibration factor: 5.86E+07Average DBC area: 5952330 Average DBC Calibration factor: 5.95E+07
A R 3 0 U I 5 6
BLM LftBUKAI UK 1tb Keport - UtN i t Medium Area harm
-amoie Name : AK124a Keoort No '.2.J2.UUJfe-l I-UK LLP Ktb 1 b''KLbb UN AUL-1J' Hage 1^K_UriN L'bbUB : Un Y, U.t4> MM U.'d^ UM r- 1LM i LWJ11 1222 , 1NJ I 2\?UL.ftKKltK H-T Al «?Kbl , IUIAL t-LUW -/UPIL'TIIN LLU .'UUU r-'MNbt U_.ji INJtLllUN i'rUL, imin TU^'min. 'J /•'•:• U i4nir-t
bio ok --'i-'age : - — —
HeaK r'rocesoor : bienie M u l t i l e v e l : halse
Instrument : AUL 1J- Application : LOOD
Lalculstion : LxternalblL) Uuant i t a t ion : rtreaUnits
Hesult I- lie : --'Uft.l «/tX I KH1_ I bXKtbUL I XNU'dU1?! 1'2 . Ktb
Kun l i m e : iij. UU Minutes iniected on Men ftug ^ . IV^'l a:t>/:ua pm
= eauence r-: 1 e : U« I rt--'tX I HAL I b,-'btUUhHLh "itULLK UaU^Vl i.'.bhU
'r.ubr.eq.-'bamp le: l/''l'J bottle no. : 12
ihreshoid Min-rtr Hkwidth Kh Unknown•J . U l.UUUUh+U^ . U4U U.UUUh+UU
Kef Wdw ftbs Kef-KIU Non Kef Win ftbs Non Kef-KIU Ident Level.Ul U.UU .Ul U.UU 1UUU.UU
t,LUl-Hact bmp-rtmt btd-ftmt X Purity In i 'Jo 1 Kat 10.UUUUt+U'J U.UUUUt+UU l.UUUUL + UU 1UU.UUU l.UUU
Status : KunbtatusUKhndUf f basel me
limed hvents \irne tvents Logic Ualue tventUpdate1 U.UU Negat ivePeaks tventUff -l.UU t-alse'2 . 1U KesetbLftl Wal ley tventUn -l.UU halse
Kl lU-tm KeakUidth Area Lode AMUUNI Namei 1.16 . i1?X2 ay^yy/2bb u.uuuut+uu2 2.1U .L'211 2a/Vbb U.UUUUt+UUi 4.a6 •. .uvux .jxiybb u.uuuut+uu ' •- -?.12 .11U1 126^4bb U.UUUUt+UU•? T'.oi .iU4a lyxibb u.uuuut+uu6 6.^^ .1241 ^aUl'ybb U.UUUUt+UU/ a. I1? .2U6U 11/lbb U.UUUUt + UUy a.yu *a.yi .11^4 yu2\?4i?HB i.|p4u/t-ui 2,4 ,T ,6-11 iKALHLUKU-m-y lu.^a .1^21 ioa/UBB u.uuuut+uu
1U 11.44 .llbU 112^Bb U.UUUUt+UU11 11.XU .112U 4b6bB U.UUUUt+UU12 13.iy .1261 244yBB U.UUUUt+UUI."- 1>.4« $11. fti . l^ya a42ai?BB l.a2^at-U2 gamma-BHL t. Lindane)
" 14.:f-y .1X46 346XybB U.UUUUt + UU16 14.X4 . 1U62 l^Xbbb U.UUUUt+UU
AR30ITF57
BUM LABUKAIUKltS Keport - LitNlt Medium Area r-orm
bample Name : AK-124a Keoort No :232.UUMIH I-UK LLH HtblbXKLbb UN AUL-13 Hage 2Hk# Kl /iU-tm KeakUidth Area Lode AMUUNI NameIX i*. Ul/#14.y4 . I'ry/' 21616^?bb -• .4ljyat-U2 HieuiucTi lorla Ib.Xl .12X6 ^UlllBB U.UUUUt+UUiy it.ya x .1113 i2^?2XBB u.uuuut + uu2U 16.34/#16.33 .134-7 14iyiaBB 2.366'?t-U2 MiUI1 ll'i21 16. T6 . 14b4 6ai64BB U.UUUUt+UU f * L \ \22 IX. 2B . 132a lU21!?bb U.UUUUt + UU23 IX.XI .123U yy4!6BB U.UUUUt+UU24 fZrfT&erj*. .uxaa II^UIBB u.uuuut+uu21? Cuu_21/ \ .16^1 Hiy2yBB U.UUUUt+UU26 lb.t?3' .12yx -'X143BB U.UUUUt+UUy 'iw -••A/^ia.6y .lie1? nxb^ybb i.6y?yt-u2
.13Ua 1T32X4BB U.UUUUt+UU
..ia.xoAily.U1/
-• U iy.6U . 14y6 3T46XBB U.UUUUt+UUJi ly.yu y .1143 2auuabb u.uuuut+uu-•2 2U. lX/tt2U. IT .1312 142U31BB l.ytf24t-U2
2U.X4 .1.--41 2aia6BB U.UUUUt'UU-*A 21. U3 $21. UX .1262 23X14BB 3.y364t-U3."? 21.2a .liat) 2X611?bb U.UUUUt+UU>6 21. UX . UXy4 XB34BB U.UUUUt+UU3X 21. X2 .lUaX 4IJ6^abB U.UUUUt + UU>a 22. la .13U6 «?1U4UBB U.UUUUt+UU3y 22.43 .11XU XllXbB U.UUUUt+UU4U 22. XI .143a 2b61Bbb U.UUUUt+UU41 22. yu #22. VI .Uy^2 1X12BB 3.a323t-U442 23.t>6 #23.64 .1243 2y61BB 1?.6X2Xt-U4 '-"-'"-n ' *•' *• —— ' '43 23. yi .1366 44UX1BB U.UUUUt+UU44 24.12 .UXyi 112t?bB U.UUUUt+UU41? 24.1?! #24. f? 3 . 16yy 16t>iybb t>.616Xt-U3 4" . 4 ' - UD I-to 24. ay .1UU4 14B3bb U.UUUUt+UU4X 2^.23 .lUyU 2^2^BU U.UUUUt+UU4a 21?. *?/ . 14yy 2'?X4XBB U.UUUUt+UU4y 26.Ua .Ua2U 14b2bb U.UUUUt+UUt-U 26. 4X #26. 4a . 1^?3X aX3«?6yBB 1.46X6t-Ul U l bu t y i ch 1 orenda t e"?1 2X.61 .2123 iyi2bb U.UUUUt+UU^2 2B.34 #2b.22 . 14B3 16iybB 6.Xll'?t-U4 M« \ h o :r. ycr h-Hrf-*-T3 2a.X1? #2b.y2 .3UU2 lt>XUXBB 2.U6Blt-U3 r rH r i n |— tnnr•74 2y.6*7 .4 22 I?X36BB U.UUUUt+UUb1? 31. 3y .2V2U 1326yBB U.UUUUt+UU•76 32. V2 .21XX 141XBB U.UUUUt + UU^?X 33. yi .2X66 2U"?6BB U.UUUUt + UU
l o t a l Area : 12t?yx^U2 l o t a l AMUUN I : .431
Keoort l i m e : Mon Aug •? , lyyi y:3y:4U pm= 'XUA I AXtX I KAL I bXMt I HUUXM I HLLK UUU^yi 13 - M I H
AR30U58
bLM LAbUKftlUKltb Keport - btNlt Medium Area rorm
sample Name : AK124B . Keport No :232.UUH rUK LLH KtblbXKLbb UN rtUL-13 Kaqe 3
I.
2 . u y x
•? . 6136.333
. _ . .^ ,^.t-,6- ib.lk'HLHLUKU-m-KYLtNt
r i u . -? a u1 ii:46i.
aamma-BHL CLmdaneJ
epoxide jLhTordane itndosulfan 1 i
__________,___,,,____________UiSuty leh lorfendatei f !j ) 2X.611 ji I Methoxvchlor i! it' tndr in' ketone Ii S ii I 2y.64B ji i ir " i! i " " """" - - - - - - Ii r 31.3yu . ii i - iI I IJ 32.y24 j
33.yU6 I! i ii i i
BLM LABUKAIUKltb Keoort - btN1t Medium Area*rorm
'sample Name : AK12T4 Keoort No :233.UUMIH I-UK LLH KtblbXHLBb UN AUL-13 Page 1LULUMN UB6Ua -'UM ,-. U . "?*3 MM U.a,' UM r i LI"! .i U#U3.' 1222 . i NJ i 2TULAKKltK P-T- Al "?Pbl, I U I AL I-LUW ~X'JMLXM1N tLU 3UUL KANbJt U2.J1 INJtLllUN 1"?UL, 1m in TLXmin, 2XTL 14M1N
c'cokxpaae :
Peak Processor : benie M u l t i l e v e l : l-alse
instrument : AUL 13 Application : Loop
Lalculation : txternalblU Uuantitation: ArcaUnits
Pesult I - i l e : XUA I AXtX I KAL I bXKtbUL I XNUaU*rll3 .-Ktb
Kun l i m e : 4U.UU Minutes Iniected on Mon Hug * . l'jy'l u: 46:43 pm
'reauence r ; 1 e : 'UA I AXtX I PAL ! bXbtUUtMLt/bt'JLLP UbUTV 1 -.' . bt'J
butseaxbamp 1 e: ix 13 Bottle no. : 1.'-
ihreshold Min-Ar Pk width Kl- Unknown2.U l.UUUUt+U3 .U4U U.UUUt+UU
Kef Wdw Abs Kef-KIU Non Kef Win Abs Non Kef-KILO Ident Level.Ul U.UU .Ul U.UU 1UUU.UU
% Uil-hact bmp-Amt btd-Amt % Purity Ini Uo1 Katiol.UUUUt+U2 U.UUUUt+UU 1.UUUUt+UU 1UU.UUU l.UUU
Kun 'status : KunbtatusUKtndUffBasel me
limed tvents lime tvents Logic Value tventUpdate1 U.UU NegativePeaks tventUff -l.UU halse2 .1U KesetbLAllUalley tventUn -l.UU raise
Pk# Kl lU-tm PeakWidth Area Lode AMUUNI Name1 1.13 .16U1? ia3U24ybb U.UUUUt+UU2 2.1U .1U62 212Ubb U.UUUUt+UU3 2.43 .2aU6 1421?2bB U.UUUUt + UU* 2.X6 .1366 1624bb U.UUUUt+UU-* 3.6U .iy21 iy2XBB U.UUUUt+UUD 4.ao .Uy46 4XXVBB U.UUUUt+UUS "?.12 . 122U iy64bbb U.UUUUt + UUy "?.61 .Illy 26B1BB U.UUUUt+UUy 6.33 . 12B2 l.-'?34UBB U.UUUUt+UU
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Page 1
Menzie-Cura Associates Aroclors in Fish (Delaware River)
ANALYSIS REPORT
Analysis D: <44091> 3 1004933F
Acquired on 04-Oct-93 at 18:13:11Reported on 07-Oct-93 at 19:16:50
ANALYSIS INFORMATION
Analysis ID.......: 1004933F-ECDAnalyst name......: TOVLEComment...........: Menzie Cura PCB in Fish AnalysisNumber of samples.: 42Calibration file..: 3100493F Last modified on 07-Oct-93 at 19:03:52Method file.......: PCB1001 Last modified on 07-Oct-93 at 19:00:20Method title......: PCB DB-5 Column, Instrument A (FATE GC)
ANALYSIS SUMMARY
SAMPLE NAME TYPE NUM BN CAL RF UP AMOUNT INJ TCMX SPL1 HEXANE SA 1 1 1.0000 1.0000 1.002 AV14 1232 SA 1 1 1.0000 92.4000 1.003 AV12 1221/1248 SA 1 1 1.0000 92.4000 1.004 AV18 1242/1260 ST 1 1 1 Z 1.0000 92.4000 1.005 AV19 1242/1260 ST 1 1 2 I 1.0000 92.4000 1.006 AV20 1242/1260 ST 1 1 3 I 1.0000 92.4000 1.007 AV21 1242/1260 ST 1 1 4 I 1.0000 101.6400 1.008 AV22 1242/1260 ST 1 1 5 I 1.0000 97.0200 1.009 AV15 1254 ST 1 1 1 Z 1.0000 92.4000 1.0010 AV16 1254 ST 1 1 2 I 1.0000 92.4000 1.0011 AV17 1254 ST 1 1 3 I 1.0000 99.7920 1.0012 AV26 1242/1260 SA 1 1 1.0000 92.4000 1.0013 AV24 1254 SA 1 1 1.0000 92.4000 1.0014 HEXANE SA 1 1 1.0000 ' 1.0000 1.0015 MCPB1 SA 1 1 1.0000 23.1000 5.0016 MCPBS1 SA 1 1 1.0000 23.1000 5.0017 MC001 SA 1 1 1.0000 23.1000 4.0018 MC002 SA 1 1 1.0000 23.1000 4.0019 MC003 SA 1 1 1.0000 23.1000 4.8120 MC004 SA 1 1 1.0000 23.1000 4.0021 MC005 SA 1 1 1.0000 23.1000 4.0022 MC006 SA 1 1 1.0000 23.1000 4.0023 MC007 SA 1 1 1.0000 23.1000 4.0024 MC008 SA 1 1 1.0000 23.1000 4.0025 MC009 SA 1 1 1.0000 23.1000 4.0026 MC010 SA 1 1 1.0000 23.1000 4.0027 HEXANE SA 1 1 1.0000 • 1.0000 1/0028 MC011 SA 1 1 1.0000 23.1000 - 4.0029 MC012 SA 1 1 1.0000 23.1000 4.0030 MC013 SA 1 1 1.0000 23.1000 8.0031 MC014 SA 1 1 1.0000 23.1000 4.0032 MC015 SA 1 1 1.0000 23.1000 8.0033 MC016 SA 1 1 1.0000 23.1000 4.0034 MC017 SA 1 1 1.0000 23.1000 8.0035 MC018 SA 1 1 1.0000 23.1000 ' 8.0036 MC019 SA 1 1 1.0000 23.1000 8.0037 MC018MS SA 1 1 1.0000 23.1000 8.0038 MC018MSD SA 1 1 1.0000 23.1000 4.0039 HEXANE SA 1 1 1.0000 1.0000 1.0040 AV19 1242/1260 SA 1 1 . 1.0000 92.4000 1.00
AR30U68
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SAMPLE NAME TYPE NUM BN CAL RF UP AMOUNT INJ TCMX SPT41 AV16 1254 SA 1 1 1.0000 92.4000 10042 HEXANE SA 1 1 1.0000 1.0000 l!oO
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Page 1»»
Menzie-Cura Associates Aroclors in Fish (Delaware" River)
INJECTION REPORT
Injection D: <44091> 3 1004933F,28,1
Acquired on 05-Oct-93 at 19:06:01Modified on 07-Oct-93 at 09:58:08Reported on 07-Oct-93 at 17:26:35
SAMPLE INFORMATION
Sample name...........................: MC011Sample ID.............................: MC011Sample type...........................: SampleSample amount.........................: 1.0000Number of injections..................: 1Bottle Number.........................: 1
Internal standard amounts:TCMX..................................: 23.100 ng/g
User factors:SPLIT.................................: 4.000DILUTION..............................: 5.000WEIGHT/VOLUME.........................: 20.330
PEAK INFORMATION
RT mlns Area uVs________ne/g Peak name_________________9.909 474115 TCMX18.129 316596 183.449 1242 pkl18.318 232840 173.620 1242 pk218.733 310318 142.688 1242 pk319.824 207976 186.711 1242 pk429.653 251414 121.253 1260 pkl33.909 322765 81.417 1260 pk234.362 139679 64.891 1260 pk334.653 211051 85.261 1260 pk441.087 183559 10.537 DCBP
Total 2650314 1049.827Residual 35878192 0.000
MISSING PEAKS
No missing peaks
PEAK GROUP INFORMATION
Area uVs_________ng/g Peak name___________________1067731 686.468 AROCLOR 1242924909 352.822 AROCLOR 1260
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Page 1
Menzie-Cura Associates Aroclors in Fish (Delaware River)
INJECTION REPORT
Injection D: <44091> 3 1004933F.12.1
Acquired on 05-Oct-93 at 04:21:49Modified on 07-Oct-93 at 09:53:30Reported on 07-Oct-93 at 17:20:22
SAMPLE INFORMATION
Sample name...........................: AV26 1242/1260Sample ID.............................: AV26Sample type...........................: SampleSample amount.........................: 1.0000Number of injections.......,..........: 1Bottle Number.........................: 1
Internal standard amounts:TCMX..................................: 92.400 ng/g
User factors:SPLIT.................................: 1.000DILUTION..............................: 1.000WEIGHT/VOLUME.........................: 1.000
PEAK INFORMATION
RT mins Area uVs________ng/g Peak name___________________9.916 1864528 TCMX18.147 650223 389.542 1242 pkl18.327 534854 412.346 1242 pk218.751 823566 391.526 1242 pk319.836 421554 391.284 1242 pk429.667 535110 266.827 1260 pkl33.922 1077797 281.091 1260 pk234.376 504937 242.532 1260 pk334.671 589287 246.134 1260 pk441.104 1809248 107.375 DCBP
Total 8811105 2728.658Residual 29654362 0.000
MISSING PEAKS
No missing peaks
PEAK GROUP INFORMATION
Area uVs_________ng/g Peak name________^« w-c-_____2430198 1584.698 AROCLOR 1242 ?f 02707132 1036.585 AROCLOR 1260 ^, ^
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APPENDIX E
EPA REGION III RBC TABLE, 9 FEBRUARY 1995
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,3«*>, UNITED STATES ENVIRONMENTAL PROTECTION AGENCYRegion III
841 Chestnut StreetPhiladelphia, Pennsylvania 19107
March 7, 1995
SUBJECT: Risk-Based Concentration Table, January - June 1995
FROM: Roy L. Smith, Ph.D., Senior ToxicologistTechnical Support Section (3HW13)
TO: RBC Table Mailing List
Attached is the EPA Region lH Risk-Based Concentration (RBC) table, which we havedistributed quarterly to all interested panics since 1991. Please see below for sorr.e importantannouncements concerning changes in the Table and administrative issues with our mailing list.
Major Changes in this Issue of the RBC
1. IRIS and HEAST have matured, and EPA has revised them at a decreasing rate over thelast few years. Lately, each quarterly RBC update has been virtually the same as i:spredecessor. Meanwhile, the mailing list for the RBC table has expanded exponentiallyand the quarterly mailings have become a substantial burden to the Region. Uponreflection, we've decided to change to semi-annual distribution. We think this change willextend our ability to keep producing the RBC table, while having little effect on thetable's usefulness. (For example, there have been no changes to toxicity constants in IRISor HEAST in the three months since the 4th quarter table was published.)
2. The RBC table now includes soil screening levels (SSLs) for protection of groundwaterand air. Most of the new entries were taken directly from EPA/OSWER's newly proposedSSL guidance document. We've added some additional SSLs based on the same proposedmethodology. Sources of SSLs are noted in the table. SSLs incorporate all the sameexposure assumptions as RBCs, plus many additional assumptions needed for inter-mediaextrapolation. SSLs are therefore distinct from RBCs, and should be used only in theframework proposed in the OSWER document. If you have not yet seen this proposalyou can obtain it from NTIS (703-487-4650, as document numbers 9355.-M, PB95-963530, or EPA540/R-94/105).
Administrative Issues
Our situation on the administrative front can be summarized in one word--"HELP"!! TheRBC mailing list now includes more than 1300 recipients and we are experiencing significantproblems with our current "delivery system." We would appreciate your suggestions for makingour future mailings more efficient. We are also exploring the possibility of providing access tothe RBC through an electronic bulletin board and would like your feedback on that idea. In themeantime, we will be examining our current mailing list and limiting .future mailings to oneindividual per organization; we need your help in distributing the RBC within your organizationif there are others who would like copies. .
EPA Region III Risk-Based Concentrations: R.L Smith (3/7/95) 2
We have installed a new phone line to help with your questions about the RBC: 215-597-1116. This is Anna Poulton's number and it has a voice-mail system to take your calls if we'renot available. Please limit your quesaons to RBC issues; if you have a question about applyingthe RBC to a site, please call the EPA Regional office handling the project.
Thanks for your patience and cooperation with these administrative issues!
Minor Changes
1. As many have requested, the soil ingestion rate for commercial/industrial exposure hasbeen revised to include EPA's national default assumption that only 50% of ingested soilis associated with work. The worker soil exposure is now fully consistent with EPA'sstandard exposure factors for Superfund.
2. Many callers have complained about the lower case 'e' and 'o' notations on the table,which can't be easily distinguished. All such notations have been capitalized.
~:ill the Same
The table contains reference doses and carcinogenic potency slopes (obtained from IRISthrough January 1, 1995, HEAST through March 1994, the Superfund Health Risk TechnicalSupport Center, and other EPA sources) for nearly 600 chemicals. These toxicity constants havebeen combined with "standard" exposure scenarios to calculate RBCs - chemical concentrationscorresponding to fixed levels of risk (i.e., a hazard quotient of 1, or lifetime cancer risk of 10"*,whichever occurs at a lower concentration) in water, air, fish tissue, and soil.
Tne Region III toxicologists use the table to screen sites not yet on the NPL, respondrapidly to citizen inquiries, and spot-check formal baseline risk assessments. The backgroundmaterials provide the complete basis for all the calculations, with the intent of showing usersexactly how the RBCs were developed. Simply put, RBCs are risk assessments run in reverse.For a single contaminant in a single medium, under standard default exposure assumptions, theRBC corresponds to the target risk or hazard quotient.
The RBCs also have several important limitations. Specifically excluded fromconsideration are (1) transfers from soil to air and groundwater, and (2) cumulative risk frommultiple contaminants or media. Also, the toxicity information in the table has been assembledby hand, and (despite extensive checking and years of use) may contain errors. It's advisable tocross-check before relying on any RfDs or CPSs in the table. If you find any errors, please sendme a note.
Many people want to know if the risk-based concentrations can be used as valid no-actionlevels or cleanup levels, especially for soils. The answer is a bit complex. First, it is importantto realize that the RBC table does not constitute regulation or guidance, and should not be viewedas a substitute for a site-specific risk assessment. For sites where:
1. A single medium is contaminated;
AR3QU76 I
EPA Region 111 Risk-Based Concentrations: R.L Smith (3/7/95) 3
2. A single contaminant contributes nearly all of the health risk;
3. Volatilization or leaching of that contaminant from soil is expected not to besignificant;
4. The exposure scenarios used in the RBC table are appropriate for the site;
5. The fixed risk levels used in the RBC table are appropriate for the site; and
6. Risk to ecological receptors is expected not to be significant;
the risk-based concentrations would probably be protective as no-action levels or cleanup goals.However, to the extent that a site deviates from this description, as most do, the RBCs would notnecessarily be appropriate.
To summarize, the table should generally not be used to (1) set cleanup or no-actionlevels at CERCLA or RCRA Corrective Action sites, (2) substitute for EPA guidance forpreparing baseline risk assessments, or (3) determine if a waste is hazardous under RCRA.
Attachment
EPA Region HI Risk-Based Concentration TableBackground Information
Roy L. Smith, Ph.D.Senior ToxicologistFebruary 9,f/EPA
Development of Risk-Based Concentrations
General
Separate carcinogenic and non-carcinogenic risk-based concentrations were calculated foreach compound for each pathway. The concentration in the table is the lower of the two,rounded to two significant figures. The following terms and values were used in the calcu-lations:
Exposure variables . Value SymbolGeneral:Carcinogenic potency slope oral (risk per mg/kg/d): * CPSoCarcinogenic potency slope inhaled (risk per mg/kg/d): * CPSiReference dose oral (mg/kg/d): * RfDoReference dose inhaled (mg/kg'd): * RfDiTarget ca-car risk: le-06 TRTarget hazard quotient: . 1 THQBody weirht, adult (kg): 70 BWaBody weirit, age 1-6 (kg): 15 BWcAveraging lime carcinogens (d): 25550 ATcAveraging time non-carcinogens (d): ED*365 ATnInhalation, adult (m3/d): 20 IRAaInhalation, child (m3/d): 12 IRAcInhalation factor, age-adjusted (m3-y/kg-d): 11.66 IFAadjTap water iagestion, adult (IVd): 2 IRWaTap water iagestion, age 1-6 (L'd): 1 IRWcTap water ingestion factor, age-adjusted (L-y/kg-d): 1.09 IFWadjFish ingestion (g'd): ' 54 IRFSofl ingesiisn, adult (mg/d): 100 IRSaSofl ingesuon, age 1-6 (mg/d): 200 IRScSoil ingest:3n factor, age adjusted (mg-y/kg-d): 114.29 IFSadj
Residential:Exposure frequency (dfy): 350 EFrExposure duration, total (y): 30 EDtotExposure duration, age 1-6 (y): 6 EDcVolatilization factor (L'm3): 0.5 'K
AR30M78
EPA Regian HI Risk-Based Conceraraaon Table: JLL Smith (February 9, 1995)
Exposure variables ."-i ' r:: • %;; ' Value SymbolOccupational:Exposure frequency (d/y): 250 EFoExposure duration (y): 25 EDoFraction of contaminated soil ingested (unitless) 0- PC
*: Contaminant-specific lexicological constants. The priority among sources of lexicological constants was asfollows: (1) IRIS, (2) HEAST, (3) HEAST alternate method, (4) EPA Superfund Health Risk TechnicalSupport Center, (5) withdrawn from IRIS or HEAST, and (6) other EPA documents. Each source was usedonly if numbers from higher-priority sources were unavailable. The EPA Superfund Health Risk TechnicalSupport Center, part of the Chemical Mixtures Branch of ECAO-Cincinnati, develops provisional RfDs andCPSs on request for contaminants not in IRIS or HEAST. These provisional values are labeled "E = EPA-ECAO provisional" in the table. It is possible they may be obsolete. If one of the "E" constants is importantto a Superfund risk assessment, consider requesting, through a Regional risk assessor, a new provisional value.
Age-adjusted factors
Because contact rates with tap water, ambient air, and residential soil are different forchildren and adults, carcinogenic risks during the first 30 years of life were calculated usingage-adjusted factors. These factors approximated the integrated exposure from birth untilage 30 by combining contact rates, body weights, and exposure durations for two age groups- small children and adults. The age-adjusted factor for soil was obtained from RAGS IB;the others were developed by analogy.
Air inhalation-)-v _ EDc • IRAc (EDtot-ED$ • IRAaIFAadj BWc BWa
Tap water ingestion*•'* - ED c- IRWc ( EDtot - ED$•_?. ~ —— BWc + ——— . BWa
Soil ingestionEDc ' &SC , (EDtot-EDd) • IRSa- BWc + ——— - ———
Residential water
Volatilization terms were calculated only for compounds with a mark in the "VOC" column.Compounds having a Henry's Law constant greater than 10"5 were considered volatile. Thelist may be incomplete, but is unlikely to include false positives. The equations and thevolatilization factor (K, above) were obtained from RAGS IB. Oral potency slopes andreference doses were used for both oral and inhaled exposures for volatile compoundslacking inhalation values. Inhaled potency slopes were substituted for unavailable oralpotency slopes only for volatile compounds; inhaled RfDs were substituted for unavailable
AR30U78A
EPA Region III Risk-Based. Concentration Table: RJL Smith (February 9, 1995) • 3
oral RfDs for both volatile and non-volatile compounds. RBCs for-carcinogens were basedon combined childhood and adult exposure; for n on -carcinogens RBCs were based on adultexposure.
Carcinogens
73? •_
L EFr • ( [ K- IFAadj • CPSi] + [ IFWadj • CPSo] )
Non-carcinogensTHQ- BWa- ATn - 1000 &
ET->»—» / A * JJ\A3 , JJ\ rr_7|A h. . . ^ ' hrar iscyAmbient air
Oral potency slopes and references were used where inhalation values were not available.RBCs for carcinogens were based on combined childhood and adult exposure; for non-carcinogens RBCs were based on adult exposure.
CarcinogensTR-ATc-lOOQ
.? EFr • IFAadj • CPSi
Non-carcinogensTHQ RfDi • BWa- ATn • 1000
EFr • EDtot • JRAa
Edible fish
All RBCs were based on adult exposure.
Carcinogens«r _ _______TR- BWa- ATckg ~ EFr • EDtot • ^ • CPSo
1000 4-
Non-carcinogensas _ THQ- RfDo • BWa- ATn-kg —~
1000 -.
EPA Region III Risk-Based Concentration Table: R.L. Smith (February 9, 1995) 4
Commercial/industrial soil ingestion
RBCs were * r-ed on adult occupational exposure, including an assumption that only 50%of total soil estion is work-related.
Carcinogens73? BWa ATcRBC
EFo- EDo- • PC- CPSo10 6 -Sf
kg
Non-carcinogensRfDo • BWa- ATnRBC
** EFo -EDo- IRSa - FC106 _2fkg
Residential «oil ingestion
RBCs for c..~dnogens were based on combined childhood and adult exposure: RBCs fornon-carcincrt-ns were based on childhood exposure only.
CarcinogensTR- ATcRBC kg EF_ . IFSadj . cpso106 &
kg
Non-carcinogensvnr m -my RfD0 ' BWc' ATnJUft, -£ = ————————————————____———
s EFr • EDc • _£_!££_10« mkg
Develop, at of Soil Screening Levels
General
In December 1994 the EPA Office of Solid Waste and Emergency Response proposed SoilScreening Guidance (Document9355.4-l,PB95-963530,EPA540/R-94/101, available throughNTIS at 703-487-4650). This draft document provides (1) a framework in which soilscreening levels are to be used, (2) a detailed methodology for calculating soil screeninglevels, and (3) soil screening levels for 107 substances.
Consistent with this new guidance, the risk-based concentration table now includes twocolumns of generic soil screening levels (SSLs). OSWER's 107 proposed soil screeninglevels have been added verbatim. In addition, the proposed SSL methodology has beenused to calculate soil screening levels for more substances, which are also included in the
EPA Region III Risk-Based Concentration Table: R.L. Smith (February 9, 1995) 5
new table. The table clearly distinguishes the OSWER SSLs from the "unofficial" ones.
These SSLs provide reasonable maximum estimates of transfers of contaminants from soilto other media. One column contains soil concentrations protective of groundwater quality;the other contains soil concentrations protective of air quality. "Protective" is defined in thesame terms as the risk-based concentrations for tap water and air -- that residential contactscenarios will yield a fixed upper bound risk of 10"6 or a fixed hazard quotient of 1(whichever occurs at the lower concentration).
OSWER's SSLs should be used only within the framework proposed in the guidance document.The additional SSLs included in the RBC table are intended for the same uses (although theyobviously carry less weight than the formally proposed numbers).
The SSLs are based on the following assumptions:
Input variablesSurface sofl moislure content (g'g)Vadose zone sofl moisture content (kg-kg)Surface sofl bulk density (g-on3)Vadose zone sofl bulk density (kg!)Surface soil panicle density (g-'cnr)Vadose zone sofl panicle density (g;cm!)Total surface soil porosity (L pore .L sofl)Total vadose zone sofl porosity (L pore/L sofl)Air-filled surface sofl porosity (L air.L sofl)Water-filled surface sofl porosity (L water/L sofl)Air-fflled vadose zone sofl porosity (L air/L sofl)Water-filled vadose zone sofl porosity (L water/L sofl)Organic carbon fraction of surface sofl (g-'g)Organic carbon fraction of vadose zone sofl (g/g)Dispersion factor for 0.5 acres (g'nrs per kg;m3)Paniculate emission factor (mVkg)Exposure interval (s)Dflution-attenuation factor (unitless)
Value Symbol*0.1 W,0.2 W,
' 1-5 P.1-' P*165 p.2.65 Pw0.43 N,0.43 Nv0.2S _}„
0-1-* *,0.13 0W0.30 ^0.006 FOC,0.002 FOQ,35.1 Q/C
6.79e+08 PEF9-50e+08 T
10 DAF
*: Symbols were adjusted, variables were rearranged, and derived and chemical-specific variables were omittedfor simplicity and clarity. Presentation of the input variables in a single table using the same terms as in theOSWER SSL document would have been confusing. The terms used here are generally simflar to OSWER's,and can easily be compared with the SSL guidance document.
With two exceptions described in the following section, SSL calculations were based on thesame algorithms presented in the OSWER draft SSL guidance document For details of thecalculations (and for general background information on SSLs), I strongly recommend
AR30U8I
EPA Region III Risk-Based, Concentration Table: RJ~ Smah (February 9, 1995) 6
consulting that document The "unofficial" SSLs were developed under the followingconditions:
Soil Screening Levels for Inhalation
Inhaled reference doses and potency slopes were used if available. If inhalation values werenot available, oral RfDs and potency slopes were substituted. SSLs were calculated only forsubstances for which aqueous solubility, Koc, Henry's Law constant, and diffusivity in airwere available. SSLs were calculated only for substances for which a volatilization factorcould be calculated. This was done because OSWER's large proposed paniculate emissionfactor rendered it pointless to estimate SSLs for particulate emissions alone. The finalcalculated SSL shown in the RBC table is the smaller of the risk-based SSL and the soflsaturation concentration. All calculated SSLs were rounded to 2 significant figures.
The OSWER risk algorithms for inhalation were revised in order to be consistent with therest of the RBC table. Only calculated SSLs were affected by this; SSLs proposed byOSWER are presented verbatim. Calculated SSLs for inhalation of carcinogens were basedon an integrated lifetime exposure rather than adult exposure. SSLs for inhalation ofnoncarcinogens were based on adult exposure for 350 days per year rather than 365 days peryear. The following algorithms were used to calculate inhalation SSLs:
CarcinoensSSI m^ - 'J-'-K ' ATc
EFr • IFAadj • -L.+ -L.J . CPSi
***•!&* -nu»-
Non-carcinogensSSL
Soil Screening Levels for Groundwater Use
All algorithms were as proposed by OSWER. MCLs were used as target groundwaterconcentrations if available. If MCLs were unavailable the risk-based concentration in the"tap water" column of the RBC table was used as the target groundwater concentration. AllSSLs for groundwater are based on a dilution-attenuation factor (DAP) of 10. Since theseSSLs scale linearly with DAF, the SSLs for DAF=1 would be ten times lower. They wereomitted to conserve space. All groundwater SSLs were rounded to 2 significant figures andcapped at unity.
Basis :
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effects
1E- EPA draft Soil Sc
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Regional Support provisional value
O=Othtr EPA rforumrnti.
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Ixvcli- |
Risk-Based Concentrations
Transfcri From
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