3855 north ocoee street, suite 200, cleveland, tn. … · 3855 north ocoee street, suite 200,...
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O lin 3855 NORTH OCOEE STREET SUITE 200 CLEVELAND TN 37312
(423) 336-4000 FAX (423) 336-4166
November 292010
Wilmington MA 01887
Re Residential Well Sampling Program
Dear
Please find enclosed the data validation summaries and laboratory analytical data from the independent laboratory that analyzed the water samples collected in July August and September 20 1 a from your home In the attached information references to samples that were not collected from your property have been blacked out to avoid confusion Also enclosed is a review by the consultant that has been retained to review all data that is related to human health that might be associated with the Olin facilities located at 51 Eames Street
As you can see from the repOli there are two analytes detected outside of their regulatory standard or guideline
NDMA was detected at a concentration of 0000031 milligrams per liter (mgL) in August and 0000017 mgL in September which is above the Massachusetts Department of Environmental Protections (MassDEP) Office of Research and Standards guideline (ORSG) of 000001 mgL in drinking water supplies USEPA previously communicated to you that public water supply operators are required to report concentrations of NDMA detected at or above the 000001 mgL but the MassDEP guidelines does not require that actions be taken to limit exposures Public water supply operators are required to take action if NDMA is detected at or above a concentration of 000005 mgL Your well is below that concentration
Sodium was detected in your well at a maximum concentration of23 mgL in September compared to the MassDEP ORSG guideline of 20 mgL in drinking water The guideline for sodium was established so that people on a salt restricted diet would be aware of the sodium content of their water
REDACTED
Our Wilmington Site Manager Brian Guichard left a voice message on Friday November 19th
to inform you that Olin is willing provide bottled water at this time for your use if you so desire for drinking water purposes Please contact Brian at 978-658shy6121 should there be any questions after you review this information or if you want to arrange for the delivery of bottled water
Sincerely
Steve Morrow Principal Environmental Specialist
cc Jim DiLorenzo USEP A
REDACTED
j MACTEC engineering and constructing a better tomorrow
November 23 2010
Mr Steve Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 3731 2
Subject Residential Well Sampling Olin Chemical Superfund Site 51 Eames Street Wilmington MA
Dear Mr Morrow
Per your request MACTEC Engineering and Consulting has evaluated the chemical data for the water
samples collected in July August and September 2010 from the residence in Wilmington MA under
Olins residential well sampling program This evaluation was performed to confirm the suitability of
drinking water at the residential propelty Chemical concentrations in the well water were compared to
Massachusetts and federal drinking water standards and guidelines
Attached is a table summarizing well monitoring data for the residence The samples were analyzed for
n-nitrosodimethylamine (NDMA) and n-nitrosodi-n-propyl-amine (NDPA) metals and inorganics The table
lists all analytes and their associated concentrations if detected If an analyte is detected the appropriate
standard andor guideline for each parameter is provided for comparison
Two detected analytes had a concentration that is above its respective standard andor guideline The reported
concentration for sodium (23 mgL) is above the concentration of 20 mgL recommended in the
Massachusetts Drinking Water Guidelines (ORSG) There is no federal drinking water standard for sodium
The ORSG guideline was published so that public water supplies could notify people on salt restricted diets
that the water is a source of sodium Residents on salt restricted diets should be aware of the sodium content
ofthe water Elevated sodium concentrations are common in groundwater in the Wilmington area due to road
salting practices
MACTEC Engineering and Consulting Inc 107 Audubon Road Bldg 2 Suite 301 bull Wakefield MA 01880 bull Phone 781-245-6606 bull Fax 781 -246-5060 wwwmccteccom
REDACTED
Residential Well Sampling 151 Eames Street Facility November 22 2010 MACTEC Engineering and Consulting inc Project N1Imber 6107-10-0016 Page 2
The Massachusetts Department of Environmental Protection (MassDEP) has issued a guideline of
000001 mgIL ofNDMA in drinking water supplies The concentrations ofNDMA detected in the
residential well (0000031 mgL in August and 0000017 mgL in September) are above the MassDEP
guideline
If you have any questions about the evaluation or if you require additional information please feel free to
contact Michael Murphy at (781) 245-6606
Sincerely
MACTEC Engineering and Consulting
MACTEC Electronic Signature MACTEC Electronic Signature
Peter Thompson Michael 1 Murphy Project Manager Sr Principal Environmental Scientist
Attachment
cc Project File
[p16 1 071 000 16 - Olin Wilmington CSS 20 I 0110 Project Management Admini strationl l5 Correspondencel 152 Letters 2010 Novemberl letterforJuiyAugSept20 I Odoc 1
REDACTED
REDACTED
Engineering and Consulting Inc 511 Con r s Street PO Bo)( 7050 Ponland Maloo 04112-7050 Te phorle 207f77~5401
MACTEC Fax 207772-4762 Home Page wwwbull netccom
0 StevMo ow rrom Chris Rieardi Date September 0 20 10 SJbj~ t Oljn Chemical Superfund Site July and Augu t 20 I 0 Residential Well Sample Map
24L 194
Datil Vlllidation Summary Test America nata Sets 360-29118 Ilnd 360-29259
10 INTRODUCTION
This sample et contain resultgt from two sampling CVflt at r idcntial ell sample Map _4 Lol 94 coil eted during July and August 20 I O Samples were analyzed by esl America L boraloncs (TAL) alto ali nS in W tlield Ma aehuselts and Vet Sacramento ali fomi bull Samples wer allaJyzod lor the r Ilowing parameters
bull I anilro odimthyl( mine (NOMA) by U EPA mod ified Method 521 bull Mclals (calcium chromium and ~ udium) by SEPA Method 60]013 bull Anions (chloride sulfate nitrate and nillite) by USEPA Method 3000 bull itrogen as Allunonja by LA HAT 107-06-1 B
Samples included in (hi rvicw ar ummlized on Table I V ith lh e cepLiol1 of th item belm n~u1ts ar inl Tprctcd to be usable as reported by the 1 boratory I c mplete summary of final sumpI results i included in Table 2 A lillunary of val idation lcnson code is included in abl 3
Th S sample ar bull sociated with twelve ample thal wcr coll ected from residential wells in two sample rounds oecllning in July and August Rc ults were reporttd by TgtI America in even mple ddjvcry group Dat from all well locations for bolll round wcr DOUr d together and validated in aecordMlce with the Final Project Opcrnlions Piau Volume lTT-B Qual ity A surance Project Plan (QAPP) lMACTEC 2 09) lin L cl [ nl chemistry re iews were c mplctld a de crib~d in Ih QAPP A
para I dalltl valid lion report is pre ented for the Icy wll middotrunplc The othlr residential wel l samples in the group are presented in parat validation report
20 DMA
NDMA analy is wns complel d u ino a modified USEPA Method 521 proccduJ which p ovides vel) lo d middotte tion limits al an ana lytical reporting limit f2 ngIL ND 11 amples are collected in ambershyglass botlle and chilled prior lo analy middotis
Qualily contr 1 C 1IlUltllions were ba ed on project p cifi m Lhlt d periornlance objectives desl1-ibe] In
the Fina Project peratiolls Plan Volum lll-B Quality As ur~mce Pr ~e t Plan (QAPP) [MACTE bull 2009] tll AL or WS-MS-0012 for NO 1A analysi and PJoG ional judgment of the projecl ch middotmist Amllytical packages were rJviewed u~il1g dala qulity ev luation checklists lllUl were dev lop d specifIcally for the lin Chemi al up rfund ile Vulidltltion includ d a full reviw of a ll documental ion and data (lssociald with gtalopl c Ilection shipment and wlalY i The [olio iog items are included in Lh NDM validation
P 6 Jlt 17 Io[)(I Ih bull Olio Wihll ln lion (51) l lllU 0 I idd md ill laJ-lJlr li 113lt1 TI RIolhJ 41 DJt~ VnhdaltAu~u 1_(1111 Rid IlIbhMcmn-)IIL AUG S I- Ill R~ Well d~llI lt11 r I f1 II
REDACTED
data pmkage cover lett rand narralive ample collect ionchain of eu middottady and h (ding timcl
QC blanks in lrlllmul cruibrntion bull laboratory control sampl (LCS)
internnl standard r co ry bull m chromatogram evaluation row data re ew and calculation chcck
dele tioll limit rcviw 1 ctronic data veri1ication
Validation checks mct proect and method goals
SDG 360-29118
Due to a laboratory ~pikjng error in the initial an lysis ultmple 0 -M2 L94 was fe-extra led eight days beyond technical hold tim TIle rcsult~ from the fe-extraction and r analys S w rco non-lt1etecl and the reporting limi W f qtJllJifi d c tim led (UJ)
30 MET JS
Samples were an Jyzed for tolal calciLun chrollliwl1 and s dillm A Tier 11 vaJjdation was compl l d for the metals samples based on criteria identified in Method 6010B and pro cdurcs de cribed in S PA data validation guideline (USEPA 1996) h loll wing in lonnation wns reviewed during datu
aHdation
data p cknge ever It ll tr md narrative SltUllple coli clio chlljn of cust dy lt nd holding times
QC blanks in trument calibration
laboratory ontrol sample (LCS) matri pikematrillt spike duplicate (MSMSD)
serial dilution
intcrflnnc ch ck mples rni data review and calculation eh ks
deteclionlimit review lcctronic da la e ificalion
Validation checks met projc t 8Jld m thod goals
~~~==--jke dUlJlicalc CMSMSD)
SOC 360-29118
The MS percent rl ov ry for calcium (131) exceeded 111 QC limit of 125 Re It for cal ium were qualifi d c timatcd (J and are potentiully bia d high
MACTEC REDACTED
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Our Wilmington Site Manager Brian Guichard left a voice message on Friday November 19th
to inform you that Olin is willing provide bottled water at this time for your use if you so desire for drinking water purposes Please contact Brian at 978-658shy6121 should there be any questions after you review this information or if you want to arrange for the delivery of bottled water
Sincerely
Steve Morrow Principal Environmental Specialist
cc Jim DiLorenzo USEP A
REDACTED
j MACTEC engineering and constructing a better tomorrow
November 23 2010
Mr Steve Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 3731 2
Subject Residential Well Sampling Olin Chemical Superfund Site 51 Eames Street Wilmington MA
Dear Mr Morrow
Per your request MACTEC Engineering and Consulting has evaluated the chemical data for the water
samples collected in July August and September 2010 from the residence in Wilmington MA under
Olins residential well sampling program This evaluation was performed to confirm the suitability of
drinking water at the residential propelty Chemical concentrations in the well water were compared to
Massachusetts and federal drinking water standards and guidelines
Attached is a table summarizing well monitoring data for the residence The samples were analyzed for
n-nitrosodimethylamine (NDMA) and n-nitrosodi-n-propyl-amine (NDPA) metals and inorganics The table
lists all analytes and their associated concentrations if detected If an analyte is detected the appropriate
standard andor guideline for each parameter is provided for comparison
Two detected analytes had a concentration that is above its respective standard andor guideline The reported
concentration for sodium (23 mgL) is above the concentration of 20 mgL recommended in the
Massachusetts Drinking Water Guidelines (ORSG) There is no federal drinking water standard for sodium
The ORSG guideline was published so that public water supplies could notify people on salt restricted diets
that the water is a source of sodium Residents on salt restricted diets should be aware of the sodium content
ofthe water Elevated sodium concentrations are common in groundwater in the Wilmington area due to road
salting practices
MACTEC Engineering and Consulting Inc 107 Audubon Road Bldg 2 Suite 301 bull Wakefield MA 01880 bull Phone 781-245-6606 bull Fax 781 -246-5060 wwwmccteccom
REDACTED
Residential Well Sampling 151 Eames Street Facility November 22 2010 MACTEC Engineering and Consulting inc Project N1Imber 6107-10-0016 Page 2
The Massachusetts Department of Environmental Protection (MassDEP) has issued a guideline of
000001 mgIL ofNDMA in drinking water supplies The concentrations ofNDMA detected in the
residential well (0000031 mgL in August and 0000017 mgL in September) are above the MassDEP
guideline
If you have any questions about the evaluation or if you require additional information please feel free to
contact Michael Murphy at (781) 245-6606
Sincerely
MACTEC Engineering and Consulting
MACTEC Electronic Signature MACTEC Electronic Signature
Peter Thompson Michael 1 Murphy Project Manager Sr Principal Environmental Scientist
Attachment
cc Project File
[p16 1 071 000 16 - Olin Wilmington CSS 20 I 0110 Project Management Admini strationl l5 Correspondencel 152 Letters 2010 Novemberl letterforJuiyAugSept20 I Odoc 1
REDACTED
REDACTED
Engineering and Consulting Inc 511 Con r s Street PO Bo)( 7050 Ponland Maloo 04112-7050 Te phorle 207f77~5401
MACTEC Fax 207772-4762 Home Page wwwbull netccom
0 StevMo ow rrom Chris Rieardi Date September 0 20 10 SJbj~ t Oljn Chemical Superfund Site July and Augu t 20 I 0 Residential Well Sample Map
24L 194
Datil Vlllidation Summary Test America nata Sets 360-29118 Ilnd 360-29259
10 INTRODUCTION
This sample et contain resultgt from two sampling CVflt at r idcntial ell sample Map _4 Lol 94 coil eted during July and August 20 I O Samples were analyzed by esl America L boraloncs (TAL) alto ali nS in W tlield Ma aehuselts and Vet Sacramento ali fomi bull Samples wer allaJyzod lor the r Ilowing parameters
bull I anilro odimthyl( mine (NOMA) by U EPA mod ified Method 521 bull Mclals (calcium chromium and ~ udium) by SEPA Method 60]013 bull Anions (chloride sulfate nitrate and nillite) by USEPA Method 3000 bull itrogen as Allunonja by LA HAT 107-06-1 B
Samples included in (hi rvicw ar ummlized on Table I V ith lh e cepLiol1 of th item belm n~u1ts ar inl Tprctcd to be usable as reported by the 1 boratory I c mplete summary of final sumpI results i included in Table 2 A lillunary of val idation lcnson code is included in abl 3
Th S sample ar bull sociated with twelve ample thal wcr coll ected from residential wells in two sample rounds oecllning in July and August Rc ults were reporttd by TgtI America in even mple ddjvcry group Dat from all well locations for bolll round wcr DOUr d together and validated in aecordMlce with the Final Project Opcrnlions Piau Volume lTT-B Qual ity A surance Project Plan (QAPP) lMACTEC 2 09) lin L cl [ nl chemistry re iews were c mplctld a de crib~d in Ih QAPP A
para I dalltl valid lion report is pre ented for the Icy wll middotrunplc The othlr residential wel l samples in the group are presented in parat validation report
20 DMA
NDMA analy is wns complel d u ino a modified USEPA Method 521 proccduJ which p ovides vel) lo d middotte tion limits al an ana lytical reporting limit f2 ngIL ND 11 amples are collected in ambershyglass botlle and chilled prior lo analy middotis
Qualily contr 1 C 1IlUltllions were ba ed on project p cifi m Lhlt d periornlance objectives desl1-ibe] In
the Fina Project peratiolls Plan Volum lll-B Quality As ur~mce Pr ~e t Plan (QAPP) [MACTE bull 2009] tll AL or WS-MS-0012 for NO 1A analysi and PJoG ional judgment of the projecl ch middotmist Amllytical packages were rJviewed u~il1g dala qulity ev luation checklists lllUl were dev lop d specifIcally for the lin Chemi al up rfund ile Vulidltltion includ d a full reviw of a ll documental ion and data (lssociald with gtalopl c Ilection shipment and wlalY i The [olio iog items are included in Lh NDM validation
P 6 Jlt 17 Io[)(I Ih bull Olio Wihll ln lion (51) l lllU 0 I idd md ill laJ-lJlr li 113lt1 TI RIolhJ 41 DJt~ VnhdaltAu~u 1_(1111 Rid IlIbhMcmn-)IIL AUG S I- Ill R~ Well d~llI lt11 r I f1 II
REDACTED
data pmkage cover lett rand narralive ample collect ionchain of eu middottady and h (ding timcl
QC blanks in lrlllmul cruibrntion bull laboratory control sampl (LCS)
internnl standard r co ry bull m chromatogram evaluation row data re ew and calculation chcck
dele tioll limit rcviw 1 ctronic data veri1ication
Validation checks mct proect and method goals
SDG 360-29118
Due to a laboratory ~pikjng error in the initial an lysis ultmple 0 -M2 L94 was fe-extra led eight days beyond technical hold tim TIle rcsult~ from the fe-extraction and r analys S w rco non-lt1etecl and the reporting limi W f qtJllJifi d c tim led (UJ)
30 MET JS
Samples were an Jyzed for tolal calciLun chrollliwl1 and s dillm A Tier 11 vaJjdation was compl l d for the metals samples based on criteria identified in Method 6010B and pro cdurcs de cribed in S PA data validation guideline (USEPA 1996) h loll wing in lonnation wns reviewed during datu
aHdation
data p cknge ever It ll tr md narrative SltUllple coli clio chlljn of cust dy lt nd holding times
QC blanks in trument calibration
laboratory ontrol sample (LCS) matri pikematrillt spike duplicate (MSMSD)
serial dilution
intcrflnnc ch ck mples rni data review and calculation eh ks
deteclionlimit review lcctronic da la e ificalion
Validation checks met projc t 8Jld m thod goals
~~~==--jke dUlJlicalc CMSMSD)
SOC 360-29118
The MS percent rl ov ry for calcium (131) exceeded 111 QC limit of 125 Re It for cal ium were qualifi d c timatcd (J and are potentiully bia d high
MACTEC REDACTED
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
j MACTEC engineering and constructing a better tomorrow
November 23 2010
Mr Steve Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 3731 2
Subject Residential Well Sampling Olin Chemical Superfund Site 51 Eames Street Wilmington MA
Dear Mr Morrow
Per your request MACTEC Engineering and Consulting has evaluated the chemical data for the water
samples collected in July August and September 2010 from the residence in Wilmington MA under
Olins residential well sampling program This evaluation was performed to confirm the suitability of
drinking water at the residential propelty Chemical concentrations in the well water were compared to
Massachusetts and federal drinking water standards and guidelines
Attached is a table summarizing well monitoring data for the residence The samples were analyzed for
n-nitrosodimethylamine (NDMA) and n-nitrosodi-n-propyl-amine (NDPA) metals and inorganics The table
lists all analytes and their associated concentrations if detected If an analyte is detected the appropriate
standard andor guideline for each parameter is provided for comparison
Two detected analytes had a concentration that is above its respective standard andor guideline The reported
concentration for sodium (23 mgL) is above the concentration of 20 mgL recommended in the
Massachusetts Drinking Water Guidelines (ORSG) There is no federal drinking water standard for sodium
The ORSG guideline was published so that public water supplies could notify people on salt restricted diets
that the water is a source of sodium Residents on salt restricted diets should be aware of the sodium content
ofthe water Elevated sodium concentrations are common in groundwater in the Wilmington area due to road
salting practices
MACTEC Engineering and Consulting Inc 107 Audubon Road Bldg 2 Suite 301 bull Wakefield MA 01880 bull Phone 781-245-6606 bull Fax 781 -246-5060 wwwmccteccom
REDACTED
Residential Well Sampling 151 Eames Street Facility November 22 2010 MACTEC Engineering and Consulting inc Project N1Imber 6107-10-0016 Page 2
The Massachusetts Department of Environmental Protection (MassDEP) has issued a guideline of
000001 mgIL ofNDMA in drinking water supplies The concentrations ofNDMA detected in the
residential well (0000031 mgL in August and 0000017 mgL in September) are above the MassDEP
guideline
If you have any questions about the evaluation or if you require additional information please feel free to
contact Michael Murphy at (781) 245-6606
Sincerely
MACTEC Engineering and Consulting
MACTEC Electronic Signature MACTEC Electronic Signature
Peter Thompson Michael 1 Murphy Project Manager Sr Principal Environmental Scientist
Attachment
cc Project File
[p16 1 071 000 16 - Olin Wilmington CSS 20 I 0110 Project Management Admini strationl l5 Correspondencel 152 Letters 2010 Novemberl letterforJuiyAugSept20 I Odoc 1
REDACTED
REDACTED
Engineering and Consulting Inc 511 Con r s Street PO Bo)( 7050 Ponland Maloo 04112-7050 Te phorle 207f77~5401
MACTEC Fax 207772-4762 Home Page wwwbull netccom
0 StevMo ow rrom Chris Rieardi Date September 0 20 10 SJbj~ t Oljn Chemical Superfund Site July and Augu t 20 I 0 Residential Well Sample Map
24L 194
Datil Vlllidation Summary Test America nata Sets 360-29118 Ilnd 360-29259
10 INTRODUCTION
This sample et contain resultgt from two sampling CVflt at r idcntial ell sample Map _4 Lol 94 coil eted during July and August 20 I O Samples were analyzed by esl America L boraloncs (TAL) alto ali nS in W tlield Ma aehuselts and Vet Sacramento ali fomi bull Samples wer allaJyzod lor the r Ilowing parameters
bull I anilro odimthyl( mine (NOMA) by U EPA mod ified Method 521 bull Mclals (calcium chromium and ~ udium) by SEPA Method 60]013 bull Anions (chloride sulfate nitrate and nillite) by USEPA Method 3000 bull itrogen as Allunonja by LA HAT 107-06-1 B
Samples included in (hi rvicw ar ummlized on Table I V ith lh e cepLiol1 of th item belm n~u1ts ar inl Tprctcd to be usable as reported by the 1 boratory I c mplete summary of final sumpI results i included in Table 2 A lillunary of val idation lcnson code is included in abl 3
Th S sample ar bull sociated with twelve ample thal wcr coll ected from residential wells in two sample rounds oecllning in July and August Rc ults were reporttd by TgtI America in even mple ddjvcry group Dat from all well locations for bolll round wcr DOUr d together and validated in aecordMlce with the Final Project Opcrnlions Piau Volume lTT-B Qual ity A surance Project Plan (QAPP) lMACTEC 2 09) lin L cl [ nl chemistry re iews were c mplctld a de crib~d in Ih QAPP A
para I dalltl valid lion report is pre ented for the Icy wll middotrunplc The othlr residential wel l samples in the group are presented in parat validation report
20 DMA
NDMA analy is wns complel d u ino a modified USEPA Method 521 proccduJ which p ovides vel) lo d middotte tion limits al an ana lytical reporting limit f2 ngIL ND 11 amples are collected in ambershyglass botlle and chilled prior lo analy middotis
Qualily contr 1 C 1IlUltllions were ba ed on project p cifi m Lhlt d periornlance objectives desl1-ibe] In
the Fina Project peratiolls Plan Volum lll-B Quality As ur~mce Pr ~e t Plan (QAPP) [MACTE bull 2009] tll AL or WS-MS-0012 for NO 1A analysi and PJoG ional judgment of the projecl ch middotmist Amllytical packages were rJviewed u~il1g dala qulity ev luation checklists lllUl were dev lop d specifIcally for the lin Chemi al up rfund ile Vulidltltion includ d a full reviw of a ll documental ion and data (lssociald with gtalopl c Ilection shipment and wlalY i The [olio iog items are included in Lh NDM validation
P 6 Jlt 17 Io[)(I Ih bull Olio Wihll ln lion (51) l lllU 0 I idd md ill laJ-lJlr li 113lt1 TI RIolhJ 41 DJt~ VnhdaltAu~u 1_(1111 Rid IlIbhMcmn-)IIL AUG S I- Ill R~ Well d~llI lt11 r I f1 II
REDACTED
data pmkage cover lett rand narralive ample collect ionchain of eu middottady and h (ding timcl
QC blanks in lrlllmul cruibrntion bull laboratory control sampl (LCS)
internnl standard r co ry bull m chromatogram evaluation row data re ew and calculation chcck
dele tioll limit rcviw 1 ctronic data veri1ication
Validation checks mct proect and method goals
SDG 360-29118
Due to a laboratory ~pikjng error in the initial an lysis ultmple 0 -M2 L94 was fe-extra led eight days beyond technical hold tim TIle rcsult~ from the fe-extraction and r analys S w rco non-lt1etecl and the reporting limi W f qtJllJifi d c tim led (UJ)
30 MET JS
Samples were an Jyzed for tolal calciLun chrollliwl1 and s dillm A Tier 11 vaJjdation was compl l d for the metals samples based on criteria identified in Method 6010B and pro cdurcs de cribed in S PA data validation guideline (USEPA 1996) h loll wing in lonnation wns reviewed during datu
aHdation
data p cknge ever It ll tr md narrative SltUllple coli clio chlljn of cust dy lt nd holding times
QC blanks in trument calibration
laboratory ontrol sample (LCS) matri pikematrillt spike duplicate (MSMSD)
serial dilution
intcrflnnc ch ck mples rni data review and calculation eh ks
deteclionlimit review lcctronic da la e ificalion
Validation checks met projc t 8Jld m thod goals
~~~==--jke dUlJlicalc CMSMSD)
SOC 360-29118
The MS percent rl ov ry for calcium (131) exceeded 111 QC limit of 125 Re It for cal ium were qualifi d c timatcd (J and are potentiully bia d high
MACTEC REDACTED
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Residential Well Sampling 151 Eames Street Facility November 22 2010 MACTEC Engineering and Consulting inc Project N1Imber 6107-10-0016 Page 2
The Massachusetts Department of Environmental Protection (MassDEP) has issued a guideline of
000001 mgIL ofNDMA in drinking water supplies The concentrations ofNDMA detected in the
residential well (0000031 mgL in August and 0000017 mgL in September) are above the MassDEP
guideline
If you have any questions about the evaluation or if you require additional information please feel free to
contact Michael Murphy at (781) 245-6606
Sincerely
MACTEC Engineering and Consulting
MACTEC Electronic Signature MACTEC Electronic Signature
Peter Thompson Michael 1 Murphy Project Manager Sr Principal Environmental Scientist
Attachment
cc Project File
[p16 1 071 000 16 - Olin Wilmington CSS 20 I 0110 Project Management Admini strationl l5 Correspondencel 152 Letters 2010 Novemberl letterforJuiyAugSept20 I Odoc 1
REDACTED
REDACTED
Engineering and Consulting Inc 511 Con r s Street PO Bo)( 7050 Ponland Maloo 04112-7050 Te phorle 207f77~5401
MACTEC Fax 207772-4762 Home Page wwwbull netccom
0 StevMo ow rrom Chris Rieardi Date September 0 20 10 SJbj~ t Oljn Chemical Superfund Site July and Augu t 20 I 0 Residential Well Sample Map
24L 194
Datil Vlllidation Summary Test America nata Sets 360-29118 Ilnd 360-29259
10 INTRODUCTION
This sample et contain resultgt from two sampling CVflt at r idcntial ell sample Map _4 Lol 94 coil eted during July and August 20 I O Samples were analyzed by esl America L boraloncs (TAL) alto ali nS in W tlield Ma aehuselts and Vet Sacramento ali fomi bull Samples wer allaJyzod lor the r Ilowing parameters
bull I anilro odimthyl( mine (NOMA) by U EPA mod ified Method 521 bull Mclals (calcium chromium and ~ udium) by SEPA Method 60]013 bull Anions (chloride sulfate nitrate and nillite) by USEPA Method 3000 bull itrogen as Allunonja by LA HAT 107-06-1 B
Samples included in (hi rvicw ar ummlized on Table I V ith lh e cepLiol1 of th item belm n~u1ts ar inl Tprctcd to be usable as reported by the 1 boratory I c mplete summary of final sumpI results i included in Table 2 A lillunary of val idation lcnson code is included in abl 3
Th S sample ar bull sociated with twelve ample thal wcr coll ected from residential wells in two sample rounds oecllning in July and August Rc ults were reporttd by TgtI America in even mple ddjvcry group Dat from all well locations for bolll round wcr DOUr d together and validated in aecordMlce with the Final Project Opcrnlions Piau Volume lTT-B Qual ity A surance Project Plan (QAPP) lMACTEC 2 09) lin L cl [ nl chemistry re iews were c mplctld a de crib~d in Ih QAPP A
para I dalltl valid lion report is pre ented for the Icy wll middotrunplc The othlr residential wel l samples in the group are presented in parat validation report
20 DMA
NDMA analy is wns complel d u ino a modified USEPA Method 521 proccduJ which p ovides vel) lo d middotte tion limits al an ana lytical reporting limit f2 ngIL ND 11 amples are collected in ambershyglass botlle and chilled prior lo analy middotis
Qualily contr 1 C 1IlUltllions were ba ed on project p cifi m Lhlt d periornlance objectives desl1-ibe] In
the Fina Project peratiolls Plan Volum lll-B Quality As ur~mce Pr ~e t Plan (QAPP) [MACTE bull 2009] tll AL or WS-MS-0012 for NO 1A analysi and PJoG ional judgment of the projecl ch middotmist Amllytical packages were rJviewed u~il1g dala qulity ev luation checklists lllUl were dev lop d specifIcally for the lin Chemi al up rfund ile Vulidltltion includ d a full reviw of a ll documental ion and data (lssociald with gtalopl c Ilection shipment and wlalY i The [olio iog items are included in Lh NDM validation
P 6 Jlt 17 Io[)(I Ih bull Olio Wihll ln lion (51) l lllU 0 I idd md ill laJ-lJlr li 113lt1 TI RIolhJ 41 DJt~ VnhdaltAu~u 1_(1111 Rid IlIbhMcmn-)IIL AUG S I- Ill R~ Well d~llI lt11 r I f1 II
REDACTED
data pmkage cover lett rand narralive ample collect ionchain of eu middottady and h (ding timcl
QC blanks in lrlllmul cruibrntion bull laboratory control sampl (LCS)
internnl standard r co ry bull m chromatogram evaluation row data re ew and calculation chcck
dele tioll limit rcviw 1 ctronic data veri1ication
Validation checks mct proect and method goals
SDG 360-29118
Due to a laboratory ~pikjng error in the initial an lysis ultmple 0 -M2 L94 was fe-extra led eight days beyond technical hold tim TIle rcsult~ from the fe-extraction and r analys S w rco non-lt1etecl and the reporting limi W f qtJllJifi d c tim led (UJ)
30 MET JS
Samples were an Jyzed for tolal calciLun chrollliwl1 and s dillm A Tier 11 vaJjdation was compl l d for the metals samples based on criteria identified in Method 6010B and pro cdurcs de cribed in S PA data validation guideline (USEPA 1996) h loll wing in lonnation wns reviewed during datu
aHdation
data p cknge ever It ll tr md narrative SltUllple coli clio chlljn of cust dy lt nd holding times
QC blanks in trument calibration
laboratory ontrol sample (LCS) matri pikematrillt spike duplicate (MSMSD)
serial dilution
intcrflnnc ch ck mples rni data review and calculation eh ks
deteclionlimit review lcctronic da la e ificalion
Validation checks met projc t 8Jld m thod goals
~~~==--jke dUlJlicalc CMSMSD)
SOC 360-29118
The MS percent rl ov ry for calcium (131) exceeded 111 QC limit of 125 Re It for cal ium were qualifi d c timatcd (J and are potentiully bia d high
MACTEC REDACTED
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
REDACTED
Engineering and Consulting Inc 511 Con r s Street PO Bo)( 7050 Ponland Maloo 04112-7050 Te phorle 207f77~5401
MACTEC Fax 207772-4762 Home Page wwwbull netccom
0 StevMo ow rrom Chris Rieardi Date September 0 20 10 SJbj~ t Oljn Chemical Superfund Site July and Augu t 20 I 0 Residential Well Sample Map
24L 194
Datil Vlllidation Summary Test America nata Sets 360-29118 Ilnd 360-29259
10 INTRODUCTION
This sample et contain resultgt from two sampling CVflt at r idcntial ell sample Map _4 Lol 94 coil eted during July and August 20 I O Samples were analyzed by esl America L boraloncs (TAL) alto ali nS in W tlield Ma aehuselts and Vet Sacramento ali fomi bull Samples wer allaJyzod lor the r Ilowing parameters
bull I anilro odimthyl( mine (NOMA) by U EPA mod ified Method 521 bull Mclals (calcium chromium and ~ udium) by SEPA Method 60]013 bull Anions (chloride sulfate nitrate and nillite) by USEPA Method 3000 bull itrogen as Allunonja by LA HAT 107-06-1 B
Samples included in (hi rvicw ar ummlized on Table I V ith lh e cepLiol1 of th item belm n~u1ts ar inl Tprctcd to be usable as reported by the 1 boratory I c mplete summary of final sumpI results i included in Table 2 A lillunary of val idation lcnson code is included in abl 3
Th S sample ar bull sociated with twelve ample thal wcr coll ected from residential wells in two sample rounds oecllning in July and August Rc ults were reporttd by TgtI America in even mple ddjvcry group Dat from all well locations for bolll round wcr DOUr d together and validated in aecordMlce with the Final Project Opcrnlions Piau Volume lTT-B Qual ity A surance Project Plan (QAPP) lMACTEC 2 09) lin L cl [ nl chemistry re iews were c mplctld a de crib~d in Ih QAPP A
para I dalltl valid lion report is pre ented for the Icy wll middotrunplc The othlr residential wel l samples in the group are presented in parat validation report
20 DMA
NDMA analy is wns complel d u ino a modified USEPA Method 521 proccduJ which p ovides vel) lo d middotte tion limits al an ana lytical reporting limit f2 ngIL ND 11 amples are collected in ambershyglass botlle and chilled prior lo analy middotis
Qualily contr 1 C 1IlUltllions were ba ed on project p cifi m Lhlt d periornlance objectives desl1-ibe] In
the Fina Project peratiolls Plan Volum lll-B Quality As ur~mce Pr ~e t Plan (QAPP) [MACTE bull 2009] tll AL or WS-MS-0012 for NO 1A analysi and PJoG ional judgment of the projecl ch middotmist Amllytical packages were rJviewed u~il1g dala qulity ev luation checklists lllUl were dev lop d specifIcally for the lin Chemi al up rfund ile Vulidltltion includ d a full reviw of a ll documental ion and data (lssociald with gtalopl c Ilection shipment and wlalY i The [olio iog items are included in Lh NDM validation
P 6 Jlt 17 Io[)(I Ih bull Olio Wihll ln lion (51) l lllU 0 I idd md ill laJ-lJlr li 113lt1 TI RIolhJ 41 DJt~ VnhdaltAu~u 1_(1111 Rid IlIbhMcmn-)IIL AUG S I- Ill R~ Well d~llI lt11 r I f1 II
REDACTED
data pmkage cover lett rand narralive ample collect ionchain of eu middottady and h (ding timcl
QC blanks in lrlllmul cruibrntion bull laboratory control sampl (LCS)
internnl standard r co ry bull m chromatogram evaluation row data re ew and calculation chcck
dele tioll limit rcviw 1 ctronic data veri1ication
Validation checks mct proect and method goals
SDG 360-29118
Due to a laboratory ~pikjng error in the initial an lysis ultmple 0 -M2 L94 was fe-extra led eight days beyond technical hold tim TIle rcsult~ from the fe-extraction and r analys S w rco non-lt1etecl and the reporting limi W f qtJllJifi d c tim led (UJ)
30 MET JS
Samples were an Jyzed for tolal calciLun chrollliwl1 and s dillm A Tier 11 vaJjdation was compl l d for the metals samples based on criteria identified in Method 6010B and pro cdurcs de cribed in S PA data validation guideline (USEPA 1996) h loll wing in lonnation wns reviewed during datu
aHdation
data p cknge ever It ll tr md narrative SltUllple coli clio chlljn of cust dy lt nd holding times
QC blanks in trument calibration
laboratory ontrol sample (LCS) matri pikematrillt spike duplicate (MSMSD)
serial dilution
intcrflnnc ch ck mples rni data review and calculation eh ks
deteclionlimit review lcctronic da la e ificalion
Validation checks met projc t 8Jld m thod goals
~~~==--jke dUlJlicalc CMSMSD)
SOC 360-29118
The MS percent rl ov ry for calcium (131) exceeded 111 QC limit of 125 Re It for cal ium were qualifi d c timatcd (J and are potentiully bia d high
MACTEC REDACTED
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Engineering and Consulting Inc 511 Con r s Street PO Bo)( 7050 Ponland Maloo 04112-7050 Te phorle 207f77~5401
MACTEC Fax 207772-4762 Home Page wwwbull netccom
0 StevMo ow rrom Chris Rieardi Date September 0 20 10 SJbj~ t Oljn Chemical Superfund Site July and Augu t 20 I 0 Residential Well Sample Map
24L 194
Datil Vlllidation Summary Test America nata Sets 360-29118 Ilnd 360-29259
10 INTRODUCTION
This sample et contain resultgt from two sampling CVflt at r idcntial ell sample Map _4 Lol 94 coil eted during July and August 20 I O Samples were analyzed by esl America L boraloncs (TAL) alto ali nS in W tlield Ma aehuselts and Vet Sacramento ali fomi bull Samples wer allaJyzod lor the r Ilowing parameters
bull I anilro odimthyl( mine (NOMA) by U EPA mod ified Method 521 bull Mclals (calcium chromium and ~ udium) by SEPA Method 60]013 bull Anions (chloride sulfate nitrate and nillite) by USEPA Method 3000 bull itrogen as Allunonja by LA HAT 107-06-1 B
Samples included in (hi rvicw ar ummlized on Table I V ith lh e cepLiol1 of th item belm n~u1ts ar inl Tprctcd to be usable as reported by the 1 boratory I c mplete summary of final sumpI results i included in Table 2 A lillunary of val idation lcnson code is included in abl 3
Th S sample ar bull sociated with twelve ample thal wcr coll ected from residential wells in two sample rounds oecllning in July and August Rc ults were reporttd by TgtI America in even mple ddjvcry group Dat from all well locations for bolll round wcr DOUr d together and validated in aecordMlce with the Final Project Opcrnlions Piau Volume lTT-B Qual ity A surance Project Plan (QAPP) lMACTEC 2 09) lin L cl [ nl chemistry re iews were c mplctld a de crib~d in Ih QAPP A
para I dalltl valid lion report is pre ented for the Icy wll middotrunplc The othlr residential wel l samples in the group are presented in parat validation report
20 DMA
NDMA analy is wns complel d u ino a modified USEPA Method 521 proccduJ which p ovides vel) lo d middotte tion limits al an ana lytical reporting limit f2 ngIL ND 11 amples are collected in ambershyglass botlle and chilled prior lo analy middotis
Qualily contr 1 C 1IlUltllions were ba ed on project p cifi m Lhlt d periornlance objectives desl1-ibe] In
the Fina Project peratiolls Plan Volum lll-B Quality As ur~mce Pr ~e t Plan (QAPP) [MACTE bull 2009] tll AL or WS-MS-0012 for NO 1A analysi and PJoG ional judgment of the projecl ch middotmist Amllytical packages were rJviewed u~il1g dala qulity ev luation checklists lllUl were dev lop d specifIcally for the lin Chemi al up rfund ile Vulidltltion includ d a full reviw of a ll documental ion and data (lssociald with gtalopl c Ilection shipment and wlalY i The [olio iog items are included in Lh NDM validation
P 6 Jlt 17 Io[)(I Ih bull Olio Wihll ln lion (51) l lllU 0 I idd md ill laJ-lJlr li 113lt1 TI RIolhJ 41 DJt~ VnhdaltAu~u 1_(1111 Rid IlIbhMcmn-)IIL AUG S I- Ill R~ Well d~llI lt11 r I f1 II
REDACTED
data pmkage cover lett rand narralive ample collect ionchain of eu middottady and h (ding timcl
QC blanks in lrlllmul cruibrntion bull laboratory control sampl (LCS)
internnl standard r co ry bull m chromatogram evaluation row data re ew and calculation chcck
dele tioll limit rcviw 1 ctronic data veri1ication
Validation checks mct proect and method goals
SDG 360-29118
Due to a laboratory ~pikjng error in the initial an lysis ultmple 0 -M2 L94 was fe-extra led eight days beyond technical hold tim TIle rcsult~ from the fe-extraction and r analys S w rco non-lt1etecl and the reporting limi W f qtJllJifi d c tim led (UJ)
30 MET JS
Samples were an Jyzed for tolal calciLun chrollliwl1 and s dillm A Tier 11 vaJjdation was compl l d for the metals samples based on criteria identified in Method 6010B and pro cdurcs de cribed in S PA data validation guideline (USEPA 1996) h loll wing in lonnation wns reviewed during datu
aHdation
data p cknge ever It ll tr md narrative SltUllple coli clio chlljn of cust dy lt nd holding times
QC blanks in trument calibration
laboratory ontrol sample (LCS) matri pikematrillt spike duplicate (MSMSD)
serial dilution
intcrflnnc ch ck mples rni data review and calculation eh ks
deteclionlimit review lcctronic da la e ificalion
Validation checks met projc t 8Jld m thod goals
~~~==--jke dUlJlicalc CMSMSD)
SOC 360-29118
The MS percent rl ov ry for calcium (131) exceeded 111 QC limit of 125 Re It for cal ium were qualifi d c timatcd (J and are potentiully bia d high
MACTEC REDACTED
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
data pmkage cover lett rand narralive ample collect ionchain of eu middottady and h (ding timcl
QC blanks in lrlllmul cruibrntion bull laboratory control sampl (LCS)
internnl standard r co ry bull m chromatogram evaluation row data re ew and calculation chcck
dele tioll limit rcviw 1 ctronic data veri1ication
Validation checks mct proect and method goals
SDG 360-29118
Due to a laboratory ~pikjng error in the initial an lysis ultmple 0 -M2 L94 was fe-extra led eight days beyond technical hold tim TIle rcsult~ from the fe-extraction and r analys S w rco non-lt1etecl and the reporting limi W f qtJllJifi d c tim led (UJ)
30 MET JS
Samples were an Jyzed for tolal calciLun chrollliwl1 and s dillm A Tier 11 vaJjdation was compl l d for the metals samples based on criteria identified in Method 6010B and pro cdurcs de cribed in S PA data validation guideline (USEPA 1996) h loll wing in lonnation wns reviewed during datu
aHdation
data p cknge ever It ll tr md narrative SltUllple coli clio chlljn of cust dy lt nd holding times
QC blanks in trument calibration
laboratory ontrol sample (LCS) matri pikematrillt spike duplicate (MSMSD)
serial dilution
intcrflnnc ch ck mples rni data review and calculation eh ks
deteclionlimit review lcctronic da la e ificalion
Validation checks met projc t 8Jld m thod goals
~~~==--jke dUlJlicalc CMSMSD)
SOC 360-29118
The MS percent rl ov ry for calcium (131) exceeded 111 QC limit of 125 Re It for cal ium were qualifi d c timatcd (J and are potentiully bia d high
MACTEC REDACTED
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
40 ANl0NS
An ion data wert )vicltvcd U lng chcckli t~ Identilied for monitoring investigations at Lhe Oli]] Chmical Sup~rfund Site and professional judgment using general chemist r view p ccdurc d cribcd in the QAPP (MA 1 - 2009) The following inf I1nation was reviewed durina data val idation
dats completenes and coe record
samplt coll tioD pre rvation and techn ical hIding till1l$ initial calibral ion veri ficatioll
conlinuing calibration crilicatioD QC blanks laboratory control sampl re u]ll
bull calculation md QC r~port vcrificl lion bull cl ~ct onie d taba e revie
Indicates thut all crit ria were m~t 0 this quality conhul parameter
There were not quality i sues idcntilkd durin d ta val idation and results are interpreted to be usable as rpurled by th labo ato _
50 NITROGEN AS AMMONIA
All1nl nja data was Ttvi wed using checldh~ identit1cd tor monitoring inve tigations at the Olin Chemical Sup Tfund Site and profe _ional judgment 1I ing cherni t review procedure de crib d ill tit QAPP (MACTE 200 ) The fo]lowi ng information was r vi d during data validation
data compl Icne and record sample oll~ lion pr srvation t nd technical hukli ng lime inilial calibrttion cri~ic ti(1n continuing alibra li n verification
blanks laboralory control sample re ults bull calculation and QC report veriticatioll
bull e1e lronic databas rcview
Indicntes that all crit ria VCT bull met for thL qualily control p rameter
There ere not quality is utS identilicd duriug cJala validation and reo ults are in terpreted to be usable a r ported by the laboratory_
MACTEC REDACTED
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Except for the validation actions nOl~d above 1he re ults are interpreted to be u able as reported by Tc tAmcric
93010
DateChris Ricardi NR Senior Chemist
Date Project Principal
References
MACTE 2009 Final Project Opemlion Plan Volume JlIB Quality Assurnnce Project Plan Olin eh mienl uperfuod it 51 UlOl Str t Wilminglon MmsacbusclL August 142009
US Environm ntal Protection Agency (USEPA) 1996 Region I EPA-NL Data Validation Guid lin s For Evaluating WirolIDl 11m I Allal~e n QuUlity urunc Unit SU1JT Office of Environmentnl (casurem ot and valuation December 1990
MACTEC REDACTED
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
RED
ACTED
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Final HeSIllts -umrnalFV
Residentjal Groundwater Olin Cham 1 Sita
Massachusetts
REDACTED
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Table 3 Data Vaihfliltiof1l diolt SlJImmlllPI
julyugust 2010 Rlsidillntial GrlOundiwllIter bull MmiddotMlmiddot94 Olin Superfund Site
Ma$~iII(hil$ett~
RED
ACTED
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Engineering and Consulting Inc 511 Congress Street PO Box 7050 Portland Maine 04112-7050 IIMACTEC Telephone 2071775-5401 Fax 2071772-4762
Home Page wwwmacteccom
To Steve Morrow From Chris Ricardi Date 10291 0 Subject Olin Chemical Superfund Site - September 2010 Residential Well Sample Map 24 Lot 94
DATA VALIDATION SUMMARY OLIN CHEMICAL SUPERFUND SITE WILMINGTON MASSACHUSETTS Test America Data Sets 360-30382
10 INTRODUCTION
This sample set contains results from the sampling event at residential well sample (Map 24 Lot 94) collected September 292010 The sample was analyzed by TestAmerica Laboratories (TAL) at locations in Westfield Massachusetts and West Sacramento California The sample was analyzed for the following parameters
bull N-nitrosodimethylamine (NDMA) by USEPA modified Method 521 bull Metals (calcium chromium and sodium) by USEPA Method 6010B bull Anions (chloride sulfate nitrate and nitrite) by USEPA Method 3000 bull Nitrogen as Ammonia by LACHA T 107-06-1 B
The sample included in this review is summarized on Table 1 With the exception of the items below results are interpreted to be usable as reported by the laboratory A complete summary of f111al sample results is included in Table 2
Results were reported by TAL in sample delivery group 360-30382 Data were validated in accordance with the Final Project Operations Plan Volume III-B Quality Assmance Project Plan (QAPP) [MACTEC 2009] Olin Level I reviews were completed as described in the QAPP
20NDMA
NDMA analysis was completed using a modified USEPA Method 521 procedure which provides very low detection limits at an analytical reporting limit of 2 ngL NDMA samples are collected in ambershyglass bottles and chilled prior to analysis
Quality control evaluations were based on project specific method perfonnance objectives described in the Final Project Operations Plan Volume ITI-B Quality Assurance Project Plan (QAPP) [MACTEC 2009] the TAL SOP WS-MS-0012 for NDMA analysis and professional judgment of the project chemist The analytical package was reviewed using data quality evaluation checkl ists that were developed specifically for the Olin Chemical Superfund Site Validation included a full review of all documentation and data associated with sample collection shipment and analysis The following items are included in the NDMA validation
Data package cover letter and narrative
Sample collectionchain of custody and holding times
QC blanks
Page I
P61 07100016 - Olin Wilmington ess 20 I 030 Field And Site Charaeteri zltion34 Test Results3 41 Data ValidationSeptembcr 20 I 0 Res identiaIMem o-SEPTEMBER- IO Res Well Data Val RcporLDoc
REDACTED
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Instrument calibration Laboratory control sample (LCS)
Internal standard recovelY Mass chromatogram evaluation
Raw data review and calculation checks
Detection limit review
Electronic data verification
Validation checks met project and method goals
21 Validation Observations and Actions
There were not quality issues idelltified during data validation and results are illterpreted to be usable as reported by the laboratory
30 METALS
Samples were analyzed for total calcium chromium and sodium An Olin Level I validation was completed for the metals samples based on criteria identified in Method 601 OB and procedures described in USEPA data validation guidelines (USEPA 1996) The following information was reviewed during data validation
Data package cover letter and nan-ative
Sample collectionchain of custody and holding times QC blanks
Laboratory control sample (LCS) Detection limit review Electronic data verification Validation checks met project and method goals
31 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as repOlied by the laboratory
40 ANIONS
Anion data were reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using general chemist review procedures described in the QAPP (MACTEC 2009) The following information was reviewed during data validation
Data completeness and COC records
Sample collection preservation and teclmical holding times Initial calibration veIification
Continuing calibration verification QC blanks
LaboratOlY control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
IIMACTEC
REDACTED
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
41 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
50 NITROGEN AS AMMONIA
Ammonia data was reviewed using checklists identified for monitoring investigations at the Olin Chemical Superfund Site and professional judgment using chemist review procedures described in the QAPP (MACTEC 2009) The following infonnation was reviewed during data validation
Data completeness and COC records
Sample collection preservation and technical holding times Initial calibration verification
Continuing cal ibration verification
QC blanks
Laboratory control sample results
Calculation and QC report verification Electronic database review Indicates that all criteria were met for this quality control parameter
51 Validation Observations and Actions
There were not quality issues identified during data validation and results are interpreted to be usable as reported by the laboratory
Except for the validation actions noted above the results are interpreted to be usable as reported by TestAmerica
10291 0
Chris Ricardi NRCC-EAC Date Senior Chemist
MiChat~ Project Principal
References
MACTEC 2009 Final Project Operation Plan Volume IIIB Quality Assurance Project Plan Olin Chemical Superfund Site 51 Eames Street Wilmington Massachusetts August 14
uS Environmental Protection Agency (USEPA) 1996 Region 1 EPA-NE Data Validation Guidelines For Evaluating Environmental Analyses Quality Assurance Unit Staff Office of Enviromnental Measurement and Evaluation December
middotIIMACTEC
REDACTED
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Table 1
Sample Summary
Data Validation Report
September 2010 Residential Sampling
Olin Chemical Superfund Site
Wilmington Massachusetts
LAC-I07-06 mod 521 SW6010 E300 (E3501)
Test America Sample Sample ID Location Sample ID Date NDMA Metals Anions Ammoni 360-30382-1 M-24L-94 OC-M24L94 29-Sep-10 2 3 4 1
Notes Prepared byDate KJC 1O22
Number listed under method indicates number of target analytes reported Checked byDate WDC 1025
P6107100016middot Olin Wilmington CSS 201030 Field and Site Characterization34 Test Results341 Data ValidationSeptember 2010 Residential
September 2010 Residential Table lxls Table 1
REDACTED
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Table 2 Final Results Summary
September 2010 Residential Groundwater Olin Chemical Superfund Site Wilmington Massachusetts
Location
cae Sample
Date Sampled
Sample Type
Report Number
Fraction Analysis Method Parameter Name Units
T SW6010 Calcium ugll
T SW6010 Chromium ugll
T SW6010 Sodimn ugl
N E300 Chloride mgll
N E300 Nitrate as N mgll
N E300 Nitrite as N mgll
N LACH_107_06_I_B Nitrogen as Ammonia mgll
N E300 Sulfate mgll
N WS-MS-0012 N-Nitrosodi-n-propylamine ngll
N WS-MS-OOI2 N-Nitrosodimethylamine ngll
Notes
N nonnal
T = total (unfiltered)
FS = field sample
U = not detected value is the detection limit
J = value is estimated
ugll = micrograms per liter
mgll = milligrams per liter Prepared bylDate
ngll = nanobgtrams per liter Checked bylDate
M-24L-94
OC-M24L94
0929110
FS
360-30382-1
Result Qualifier
43000
5 U
23000
35
04
001 U
011
29
89 U
170
KJC 102811 0
WDC 1028110
P6107100016 - Olin Wllmington (55 201030 Field and Site Characterization34 Test Resutts341 Data VatidationSeptember 2010 Residential
September 2010 Residential Table 2xis M02l07E Page 1 of 1
REDACTED
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
LABORATORY ANALYTICAL RESULTS SHOWING DATA VALIDATION
ACTIONS
REDACTED
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
erlca FILE COpy
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number 360-29118-1
SDG Number 360-29118-1
Job Description Olin Chemical Superfund Site
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 8I5I201010021Wt
Designee for j
Becky C Mason Project Manager II
beckymasontestamericainccom 08052010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerica Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericainccom
Page 1 of 1121 08052010
REDACTED
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Mr Steven Morrow Job Number 360-29118-1 Olin Corporation Sdg Number 360-29118-1 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OCmiddotM24L94 Date Sampled 07082010 1050
Lab Sample 10 360middot29118middot2 Date Received 07092010 1010
Client Matrix Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 60108 Date Analyzed 07122010 1604
Prep Method 3010A Date Prepared 07122010 0711 Calcium 35000 ugL 59 400 10
Chromium NO ugL 13 50 10 Sodium 18000 ugL 250 2000 10
Page 24 of 248 08022010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10 OC-M24L94 Lab Sample 10 360-29118-2
Analyte
Method 3000
Sulfate
Nitrate as N
Method 3000
Chloride
Nitrite as N
Method L 107-06-18
Prep Method DistilUAmmonia
Ammonia
ResultlQualifier
24 070
25 ND
ND
Date Sampled
Date Received
Client Matrix
Unit RL
Date Analyzed
mgL 20 mgL 0050
Date Analyzed
mgL 10 mgL 010
Date Analyzed
Date Prepared
mgL 010
Job Number 360-29118-1 Sdg Number 360-29118-1
07082010 1050
07092010 1010
Water
RL Dilution
07092010 1637
20 10 0050 10
07092010 1652
10 10 010 10
07212010 0930
07202010 1346
010 10
Page 25 of 248 08022010 REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
July 29 2010
TestAmerica Project Number GOG090612 POContract 360-29118
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on July 9 2010 These samples are associated with your 360-29118 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
GOG090612 TestAmeriaWfst SicOrarRtntctM6 373 _5600 08052 0jlJt 178 REDACTED
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
TestAmeriea Westfield
Client Sample Ie OC-M24L94 (360-29118-2)
GCMS Semivolatiles
Lot-Sample I GOG090612-002 Work Order i L31582AA Matrixbullbullbullbullbullbullbullbullbull WATER Date Sampledbullbullbull 070810 Date Receivedbullbull 070910 Prep Datebullbullbullbullbullbull 072310 Analysis Date bull 072710 Prep Batch I 0204243 Dilution Factor 096 Methodbullbullbullbullbullbullbull SAC WS-MS-0012
REPORTING PARAMETER RESULT LIMIT UNITS MDL N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
ND3 ND s
19 96
ngL ngL
037 045
amine
PERC~ RECOVERY SURROGATE RECOVERY LIMITS N-Nitrosodimethylamine-d6 38 (25 - lS0) N-Nitrosodi-n-propylamine-d14 82 (25 - 150)
GDG090S12 TestAmerlca~amprsUra~~~Ms) 373 middot5S00 REDACTED
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project
Address 51 Eames Street Project Manager -=j~~l1~~===jF~~~~~~~~~- Analysis Requested Wilmington MA 01887 ~=________--Icheck analysis and specify metho
and analytes in comments section For example
rRequEiSt9(fTuimJtrO~aT~9-----~~~~~~~~~~~C~~~~EE~~~Lj 500-series for drinking waterI 600-series for waste water 10 Business Day (Sid) -XlL- Rush TAT Requested aOOO-series for hazJsolid waste
24 hrs comments section 0 further definE 48 hrs
OW-Drinking water SW-Surfacewater GWmiddotGroundwater AmiddotNr SL-Sludge O-Oil Z-Other
page_~_of~ REDACTED
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
TestAmerica THE LEADER IN ENVIRONMENTAL TESTING
CHECKED FOR COMPLETENESS
ANALYTICAL REPORT ~~~J~BY
~J~toJob Number 360-29529-1
SDG Number 360-29529-1
Job Description Olin Chemical Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release James T Wickham Technology Manager 912720 10 1230 PM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
09272010 Revision 1
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 wwwtestamericajnc com
Page 1 of 1225 09272010
REDACTED
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441middot
Job Number 360middot29529-1 Sdg Number 360-29529middot1
Client Sample 10 Lab Sample 10
OCmiddotM24L94 360middot29529middot6
Date Sampled
Date Received
Client Matrix
08042010 1345
08052010 1045 Water
Analyte ResultQualifier Unit MOL RL Dilution
Method 6010B Prep Method 3010A Calcium
Chromium
Sodium
36000 ND
18000
Date Analyzed
Date Prepared
ugL 23 ugL 10 ugL 250
08202010 1415
08162010 0751
400 50 2000
10 10 10
Page 42 of 359 08302010
REDACTED
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
---------------
Mr Steven Morrow Olin Corporation 3855 North Ocoee Street Suite 200 Cleveland TN 37312-4441
Client Sample 10
Lab Sample 10
OC-M24L94 360-29529-6
Date Sampled
Date Received
Client Matrix
Analyte ResultQualifier Unit RL
Method 3000
Sulfate
Nitrate as N
Chloride
Nitrite as N
24 067 29 ND
Date Analyzed
mgL 20 mgL 0050 mgL 10 mgL 0010
Method L107middot06middot18
Prep Method DistillAmmonia
Ammonia ND
Date Analyzed
Date Prepared
mgL 010
I
1 I lJ11 () ~ ot
J
Job Number 360-29529-1 Sdg Number 360-29529-1
08042010 1345
08052010 1045
Water
RL Dilution
08052010 1954
20 10 0050 10 10 10 0010 10
0820201 ci 1509 08182010 0958
010 10
Page 43 of 359 08302010
REDACTED
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
bullmerlca THE LEADER IN ENVIRONMENTAL TESTING
August 24 2010
TestAmerica Project Number GOH050578 POContract 360-29529
Becky Mason TestAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the samples received under chain of custody by TestAmerica on August 5 2010 These samples are associated with your 360-29529 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
IL~
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 teI9163735600 fax 9163721059 wwwtestamericainccom
09272 degr-dt274GOH050578 REDACTED
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
REDACTED
Lot-Sample bullbullbull GOH050578-005 Date Sampledbullbull 080410 Prep Date bullbull 081010 Prep Batch i 0222212 Dilution Factor 094
PARAMETER N-Nitrosodimethylamine N-Nitrosodi-n-propylshy
amine
SURROGATE N-Nitrosodimethylamine-d6 N-Nitrosodi-n-propylamine-d14
TestAmerica Westfield
Client Sample ID OC-M24L94
GCMS Semivolatiles
Work Order L46M91AA Matrixbullbullbullbullbullbull WG Date Received bull 080510 Analysis Date bull 081910
Method SAC WS-MS-0012
REPORTING RESULT LIMIT UNITS MDL 31 19 ngL 037 ND 94 ngL 044
PERCENT RECOVERY RECOVERY LIMITS 40 (25 - 150) 86 (25 - 150)
Paae 959 of 1225 09272fk1oh74GOH050578 Test America west Sacramento T916 373middot5600
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicalMACTEC
Project -=J~~~~E~~~===~~~~~~~~~Address 51 Eames Street Project Manager _ Analysis Requested
Wilmington MA 01887 Work ID Private Wells Check analysis and specify methoc ~~---------iand analytes in comments section
Phone For example ~4R~equestejd-Trurn~~Fn--------r~jbtr1~wf~~7~~~n~~~~t-i SOOmiddotseries lor drinking water
60Qmiddotseries for waste water 10 Business Day (Std) --X1Lshy Rush TAT Requested SOOOseries for hazlsolid waste 15 Business Day 24 hrs Use comments section to further define
Other 48 hrs
Codes WW-Wastewater DWmiddotDrinking water SWmiddotSurfacewater LWmiddotLabwater GWmiddotGroundwater AmiddotAir SmiddotSolid f Soil SL-Sludge OmiddotOiI ZmiddotOther
Sample 10
by (print)
~elinquished by
telinquished by
~ethod of shipment
Page____ __ of~ REDACTED
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
FILE COPYTestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT CHECKED FOR COMPLETENESS
~~4~Job Number 360-30382-1 y~()
SDG Number 360-30382-1
Job Description Private Wells
For Olin Corporation
3855 North Ocoee Street Suite 200
Cleveland TN 37312-4441
Attention Mr Steven Morrow
Approved for release
James T WicJtham Technology Manager
1OJl8n01Q 1100 AM
Designee for Becky C Mason
Project Manager II beckymasontestamericainccom
10182010
Results relate only to the items tested and the sample(s) as received by the laboratory The test results in this report meet all NELAC requirements for accredited parameters exceptions are noted in this report Pursuant to NELAC this report may not be reproduced except in full and with written approval from the laboratory TestAmerica Westfield Certifications and Approvals MADEP MA014 RIDOH57 CTDPH 0494 VT DECWSD NH DES 2539 NELAP FL E87912 TOX NELAP NJ MA008 TOX NELAP NY 10843 NY ELAP 10843 North Carolina 647 NELAP PA 68-04386 Field sampling is performed under SOPs WE-FLD-001 and WE-FLD-002
TestAmerlca Laboratories Inc
TestAmerica Westfield Westfield Executive Park 53 Southampton Road Westfield MA 01085
Tel (413) 572-4000 Fax (413) 572-3707 WNW testamericajoc com
Page 1 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample ID
Client Matrix
Method
Preparation
Dilution
Date Analyzed
Date Prepared
Analyte
Calcium
Chromium
Sodium
OC-M24L94
360-30382-1
Water
6010B
3010A
10
101062010 1821
09302010 0814
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 09292010 1735
6010B Metals (ICP)
Analysis Batch 360-64160 Instrument ID Varian ICP
Prep Batch 360-63858 Lab File ID 100610gcsv
Initial WeighWolume 50 mL
Final WeighWolume 50 mL
Result (ugL) Qualifier MDL RL
43000 23 400 ND 10 50 23000 250 2000
TestAmerica Westfield Page 11 of 302 10182010
REDACTED
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Analytical Data
Client Olin Corporation Job Number 360-30382-1
Client Sample 10
Lab Sample 10
Client Matrix
Analyte
Nitrate as N
Sulfate
Chloride
Nitrite as N
Ammonia
OC-M24L94
360-30382-1
Water
Result
040
Analysis Batch 360-63927
29
Analysis Batch 360-63990
35
Analysis Batch 360-63990
NO
Analysis Batch 360-63927
011
Analysis Batch 360-64400
Prep Batch 360-64359
General Chemistry
Qual Units RL
mgL 0050
Date Analyzed 101012010 0120
mgL 20
Date Analyzed 101012010 0120
mgL 10
Date Analyzed 1010120100120
mgL 0010
Date Analyzed 101012010 0120
mgL 010
Date Analyzed 10132010 1450
Date Prepared 101320101105
Sdg Number 360-30382-1
Date Sampled 092920101220
Date Received 092920101735
RL Oil Method
0050 10 3000
20 10 3000
10 10 3000
0010 10 3000
010 10 L107-06-1 B
TestAmerica Westfield Page 12 of 302 10182010 REDACTED
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
October 13 2010
TestAmerica Project Number GOl300545 POContract 360-30382
Becky Mason T estAmerica Westfield 53 Southampton Road Westfield MA 01085
Dear Ms Mason
This report contains the analytical results for the sample received under chain of custody by TestAmerica on September 30 2010 This sample is associated with your 360-30382 project
The test results in this report meet all NELAC requirements for parameters that accreditation is required or available Any exceptions to NELAC requirements are noted in the case narrative The case narrative is an integral part of this report
If you have any questions please feel free to call me at (916) 374-4384
Sincerely
Karen Dahl Project Manager
880 Riverside Parkway West Sacramento CA 95605 tel 9163735600 fax 9163721059 wwwtestamericainccom
10182 degr-JbsoGOi300545 REDACTED
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
Client
SemiW)1atiles
GOB00545 Wark Order I Matrix bullbull WATER Date Received bull ~
Date _bull _ Datebullbull
Batch bull Dilution Pacton 89 Methodbullbullbullbullbullbull SAC
17 18 9
amine
RECOVERY
210 REDACTED
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038
------
TestAmerica Laboratories Inc Chain of Custody Form
Client Olin ChemicallMACTEC Project OlOooib 1 ~f) _7e1~-gl Quot~ i~~jadeatalj~s1Qi9fficetlis
Address 51 Eames Street Project Manager ~ttr Thlflsc)i Analysis Requested
Wilmin~ton MA 01887 Work 10 Private Wells Check analysis and specify metho and analytes in comments section
Phone 7 ~l u3-S6 Fax Contact David Chapman For example 500-series for drinking waterRequested Turn Around Time Regulatory Classification I Special Report Format SOO-series for waste water
10 Business Day (Std) ~ Rush TAT Requested NPDES ___ Drinking Water --K- OEP Form(s) -- SOOO-series for hazisolid waste
15 Business Day 24 hrs 72 hrs -- RCRA --- MCPGW1S1 -- MWRA Smart Rpt _ Use comments section to further define-Other 48 hrs 5Day Other MCP QAlQC Rpt XX Sample Type Codes Preservative C)
()()WW-Wastewater cQYY~rink~ SW-Surfacewater 0 c ()Q) N[~ N i=LW-Labwater GW-Groundwater A-Air II) J j Ol $ i= Itgt Jen 0 ~ 2 l -pound til
S-Solid I Soil SL-Sludge 0-011 Z-Other lt Q) r ~ sect sect D Z ~ r 0 j J () 3 2 0 0 ~ 0 ~ (f) t () gg ~ z til
()r Cl-~ Date a s Z 0 ~ ~ Q) 0 s 0 s t - 2 zSample 10 o~ ci ~ ~ (f) () J 0 ~ Q) ~ 1 ()
() oQ) Time tJ bullCi s r Q) g 0 ~ 0 Q) Q) Q) QEo E J 0 0 E 1sect 0 a
lt11gt- ~~ 8 ~ til z ~ (3 til 5i 0 E 2 Cl lt M J c (l)C Collected () ~ N(1)1- 0 8 11 a z J r r z z z laquo i co Z (0 co 0 0 5 e
pvJ ~LVI()DCmiddot 1y L11 Cll I ZZ-C X $ ~ XX X ~ XX XX ~
----r--- shy -~ r--I--tQ ~ - I~v
~ Zlt ~ r- --
---r- --
-r----- I-
Sampled by (print) Chs (Y)eLl-U Jgt ~~
Time DateReli~dbY d ~~ Dat~A It Tim $L()1 24 I () ss- 1~11~~ 9-29-(0 Date Time litedbYRtq~Jd1 ~rO (Z~5 tv lWflM-Y qi~qIID TiT~amp
Metl)6d of shi~ent IfestAmenca-Westfield
page__l __ Of~ REDACTED
- barcodetext SDMS DocID 485038
- barcode 485038