2observation laboratory performance test sabado 01marzo2014

8/19/2019 2OBSERVATION Laboratory Performance Test Sabado 01marzo2014

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Objective: To follow the EN HP behavior trought the entire cycle of 0.0 MTO to 3 M

1.- To follow deposition rate under laboratory conditions.

Date: 6/28/2013

Responsible R/!"/R#

Key characteristic of EN HP

EN HP make up: --

Bath Volume (lts) 2

Niklad 811A (mililiters) 113.4

Niklad 811B (mililiters) 283.5

H2O (mililiters) 1603.1Ni MTO 0

Nikel (!r"l) 5.#3

$em%. &' 8#%H a tem% del ao 4.#3

%H at 25 &' 4.82

H*%o. 31.05

Orto. ++

0.8

Releni!h"ent: ++

Niklad 811A (mililiters) ++

Niklad 811HA (mililiters) ++,ur-ae treated (dm2) 'u%o/ 1 ++,ur-ae treated (dm2) 'u%o/ 2 ++

,ur-ae treated (dm2) Nut 1 ++,ur-ae treated (dm2) Nut 2 ++

33#+20+543 ++,ur-ae load (dm2 " liter)

e* de o/sumo

Niklad 811A (mililiters " dm2)

Niklad 811HA (mililiters " dm2)

Niklad 811A (mililiters " m)

Niklad 811HA (mililiters " m)

$otal sur-ae %lated (dm2)++

++$otal thik/ess (m)

hos%horous 1 ++ hos%horous 1 ++

hos%horous Aera!e ++e%ositio/ rate 1 (m"hr) ++e%ositio/ rate 2 (m"hr) ++e%ositio/ 7ate Aera!e ++

2.- Record of $ey c%aracteristics in order to identify its influence on deposition rate & µ'/%

3.- #a$e t%e c%aracteri)ation on cupons and iron nut to *erify t%ic$ness and + , content

Make up measured

H2O 'o/dutiit* (µ,"m2)

$hik/ess 1 (µm)

$hik/ess 2 m


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Ob!ervation!

0 0.09 0.19 0.26 0.32 0.38 0.47 0.57 0.74 0.78 0.9 0.97 1.15 1.24 1.32 1.38 1.63 1.67

4.75

4.8

4.85

4.9

4.95

5

5.05

pH of the


3/32

O.

30min 60 min 90 min 120 min 10 min 1!0 min 210 min

-- -- -- -- -- -- --

2 2 2 2 2 2 2

++ ++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++ ++0.0# 0.1# 0.26 0.32 0.38 0.4 0.5

5.81 5.8 5.8 5.8 5.81 5.8 5.#3

8# 88. 8#.2 8# 8# 88.# 8#.2

4.88 4.8# 4.8# 4.# 4.# 4.8# 4.86

4. 4.81 4.8 4.8 4.81 4.8 4.8

++ ++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++ ++

0.8 0.8 0.8 0.8 0.8 0.8 0.8

++ ++ ++ ++ ++ ++ ++

20 25 16 15 15 15 23

40 50 32 30 30 30 460.241126 0.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.241126 0.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

1.1883 1.1883 1.1883 1.1883 1.1883 1.1883 1.1883

0.5661285 0.5661285 0.5661285 0.5661285 0.5661285 0.5661285 0.5661285

2.264514 2.264514 2.264514 2.264514 2.264514 2.264514 2.264514

5.06 5.0# 4.8# 5.1# 4.83 4.5 5.233

5.06 5.12 5.25 5.28 4.# 4.41 5.088

5.06 5.105 5.0 5.235 4.865 4.58 5.16056.22 5 2 5.16 0.88 3.28 4.68

5.25 1.# 1.25 4.85 1.18 2.15 4.#3

5.35 3.485 1.625 5.005 1.03 2.15 4.805

15.18 15.2 14.6 15.5 14.4# 14.25 15.0

15.18 15.36 15.5 15.84 14. 13.23 15.26

15.18 15.315 15.21 15.05 14.5#5 13.4 15.4815

15.36#032142# 15.36#03214 15.36#03214 15.36#03214 15.36#03214 15.36#03214 15.36#03214

our(.

. "ee sheet #$upons characteri%ation#


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1.8 2.03 2.25 2.37 2.54 2.66 2.77 2.97 3.1 3.18 3.35

87.5

88

88.5

89

89.5

90

90.5

91

ath

pH a temp del baño

Temp. °C


5/32

,am%les se/d

,am%les se/d

,am%les -or

2&0 min 2'0 min 300 min 330 min 360 min 390 min &20 min

-- -- -- -- -- -- --

2 2 2 2 2 2 2

++ ++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++ ++0.4 0.8 0.# 0.# 1.15 1.24 1.32

5.46 5.#3 5.64 5.8 5.8 5.8 5.81

88. 8# 88.# 8# #0 8#.5 8#.5

4.# 4.88 4.#1 4.#1 5.02 5.02 4.#

4.8 4. 4.82 4.8 4.#2 4.#1 4.86

33.0 ++ ++ ++ 31.6 ++ ++

++ ++ ++ ++ ++ ++ ++

0.8 0.8 0.8 0.8 0.8 0.8 0.8

++ ++ ++ ++ ++ ++ ++

40 10 30 15 25 20 20

80 20 60 30 50 40 400.241126 0.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.241126 0.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

1.1883 1.1883 1.1883 1.1883 1.1883 1.1883 1.1883

0.5661285 0.5661285 0.5661285 0.5661285 0.5661285 0.5661285 0.5661285

2.264514 2.264514 2.264514 2.264514 2.264514 2.264514 2.264514

4.#56 4.6 5.31 5.14 4.81 5.33 5.36

5.12 4.56 5.1 5.15 4.5# 5.# 5.32

5.064 4.58 5.24 5.145 4. 5.56 5.34.18 3.11 3.1 6.0 1.5 4.# 3.21

5.62 3.4# 3.1# 6. 1.88 4.54 4.

6.40 3.3 3.45 6.42 1.6# 4.55 3.#55

14.8 13.80 15.#3 15.42 14.43 15.## 16.08

15.52 13.68 15.51 15.45 13. 1.3 15.#6

15.1#2 13.4 15.2 15.435 14.1 16.68 16.02

15.36#032143 15.36#03214 15.36#03214 15.36#03214 15.36#032143 15.36#03214 15.36#03214


6/32

:iltratio/$reatme/t

:iltratio/$reatme/t

0.090.190.260.320.380.470.570.740.78 0.9 0.971.151.241.321.381.63 1.67 1.8

0

2

4

6

8

10

12

% Phosphorous


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to aermid -or ,9

to Vore%%e -or ,9

oss+setio/

&0 min &!0 min 10 min &0 min '0 min 600 min 630 min

-- -- -- -- -- -- --

2 2 2 2 2 2 2

++ ++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++ ++1.38 1.63 1.6 1.8 2.03 2.25 2.3

5.8 5.4 5.8 5.6# 6.1 5.## 5.52

#0.1 #0 8#.5 #0 #0.1 8#.# #0.1

4.# 4.#3 4.#3 4.8# 4.# 4.# 4.8#

4.8 4.83 4.82 4.8 4.81 4.81 4.81

++ ++ ++ 32.5 ++ 34.8 ++

++ ++ ++ ++ ++ 63 ++

0.8 0.8 0.8 0.8 0.8 0.8 0.8

++ ++ ++ ++ ++ ++ ++

15 60 10 30 55 45 30

30 120 20 60 110 #0 00.241126 0.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.241126 0.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

1.1883 1.1883 1.1883 1.1883 1.1883 1.4835 1.4835

0.5661285 0.5661285 0.5661285 0.5661285 0.5661285 0.63##285 0.63##285

2.264514 2.264514 2.264514 2.264514 2.264514 2.55#14 2.55#14

5.01 3.4 5.01 4.4 4.45 5.0 6.35

5.04 3.38 4.86 4.#1 4.5 4.354 6.51

5.025 3.3# 4.#35 4.825 4.45 4.12 6.62252.6 3.25 3.462 1.53 5.8 ++ ++3.33 3.#1 .45 1.3# 6.3# ++ ++

3 3.58 5.456 1.46 6.13 ++ ++15.03 15.64 15.03 14.22 13.35 15.21 20.205

15.12 15.5818 14.58 14.3 13.5 13.062 1#.53

15.05 15.62# 14.805 14.45 13.425 14.136 1#.865

15.36#03214 15.36#032142# 15.36#03214 15.36#032143 15.36#032142# 15.36#032142# 15.36#032142#


8/32

7ou!hou%o/s

%Had;ustme/t"-iltrati

o/ duemetali


9/32

660 min 690 min '20 min '0 min '!0 min !10 min

-- -- -- -- -- --

2 2 2 2 2 2

++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++

++ ++ ++ ++ ++ ++2.54 2.66 2. 2.# 3.1 3.18

6.1 6.1 5.81 6.05 6.05 6.16

8#. 8#.4 8#.6 8#.5 8#. #0.5

4.8# 4.#2 4.#1 4.#1 4.#3 4.8#

4.81 4.81 4.8 4.8 4.82 4.8

++ ++ 32 ++ ++ ++

++ ++ ++ ++ ++ ++

0.8 0.8 0.8 0.8 0.8 0.8

++ ++ ++ ++ ++ ++

10 60 35 45 40 20

20 120 0 #0 80 400.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.241126 0.241126 0.241126 0.241126 0.241126 0.241126

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81 0.2#6#81

1.4835 1.4835 1.4835 1.4835 1.4835 1.4835

0.63##285 0.63##285 0.63##285 0.63##285 0.63##285 0.63##285

2.55#14 2.55#14 2.55#14 2.55#14 2.55#14 2.55#14

5.13# 2.836 5.368 4.5# 4.382 5.125

5.56 2.#03 5.256 4.32 4.3#2 5.3

5.34#5 2.86#5 5.312 4.4585 4.38 5.25110.5 ++ ++ ++ ++ ++10.6 ++ ++ ++ ++ ++

10.55 ++ ++ ++ ++ ++15.41 1.016 16.104 13. 13.146 15.35

16.68 1.418 15.68 12.#81 13.16 16.131

16.0485 1.21 15.#36 13.355 13.161 15.53

15.36#032142# 15.36#032142# 15.36#032142# 15.36#032142# 15.36#032142# 15.36#032142#


10/32


11/32

!&0 min

--

2

++

++

++3.3#

6.22

#0

4.#1

4.82

++

++

0.8

++

40

800.241126

0.241126

0.2#6#81

0.2#6#81

1.4835

0.63##285

2.55#14

6.343

6.535

6.43#.62

5.6

6.6#

1#.02#

1#.605

1#.31

15.36#032142#

Deposit

6.4


12/32

9/d o- aths li-edue to

%rei%itatio/

0 0.

4.8

5

5.2

5.4

5.6

5.8

6

6.2


13/32

0 0.5 1 1.5 2 2.512

14

16

18

20

Deposition Rate

MTO

ion Rate

Nickel (gr/l


14/32

.09 0.19 0.26 0.32 0.38 0.47 0.57 0.74 0.78 0.9 0.97 1.15 1.24 1.32 1.38 1.63 1.67 1.8 2.03

Filtration treatment

/&ltat&o'teatme't

/&ltat&o'teatme't

/&ltat&o'teatme't


15/32

3


16/32

.25 2.37 2.5


17/32

$a"le E%T& 0.' M ("l) Nic*el +oncentration (g,-)

1 10.0 5.8 5.22 10.0 5.8 5.2

3 10.3 6.05 +1.8

4 10.1 5.#3 2.#

5 #.5 5.58 16.#

6 10.5 6.16 +6.5

10.4 6.10 +4.2

8 10.4 6.10 +4.2

# 10.0 5.8 5.2

10 10.0 5.8 5.2

11 10.5 6.16 +6.5

12 10.0 5.8 5.2

13 #.6 5.64 14.614 10.4 6.10 +4.2

15 10.2 5.## 0.5

16 10 5.8 5.2

1 10.3 6.05 +1.8

18 10.2 5.## 0.5

1# 10 5.8 5.2

20 10.3 6.05 +1.8

21 10.2 5.## 0.5

22 10.1 5.#3 2.#

23 10.3 6.05 +1.8

24 10 5.8 5.2

25 10.3 6.05 +1.8

26 10 5.8 5.2

2 10.4 6.10 +4.2

28 10 5.8 5.2

2# 10.3 6.05 +1.8

30 10.3 6.05 +1.8

31 10 5.8 5.2

32 10.4 6.10 +4.2

33 #.# 5.81 .5

34 #.5 5.58 16.#

35 10.6 6.22 +8.#

36 10.4 6.10 +4.2

3 10.2 5.## 0.5

38 10.3 6.05 +1.8

3# 10 5.8 5.2

40 #. 5.6# 12.2

41 10.3 6.05 +1.8

42 10.2 5.## 0.5

43 10 5.8 5.2

44 10 5.8 5.2

Ni*la E-/ &&ition ("l)


18/32

45 10.3 6.05 +1.8

46 10 5.8 5.2

4 10.# 6.40 +15.#

48 10.6 6.22 +8.#

4# 10.3 6.05 +1.8

50 10.1 5.#3 2.#

51 10.4 6.10 +4.2

52 10.1 5.#3 2.#

53 10.3 6.05 +1.8

54 #.# 5.81 .5

55 8.# 5.22 31.0

56 10.6 6.22 +8.#

5 10.8 6.34 +13.6

58 0.00 240.0

5# 0.00 240.0

60 0.00 240.0

61 0.00 240.0

62 0.00 240.0

63 0.00 240.064 0.00 240.0

65 0.00 240.0

66 0.00 240.0

6 0.00 240.0

68 0.00 240.0

6# 0.00 240.0

0 0.00 240.0

1 0.00 240.0

2 0.00 240.0

3 0.00 240.0

4 0.00 240.0

$O$A 65.1

M&E 1P:

Niklad 9V 811 A 240

Niklad 9V 811 B 480


19/32

MTO +OMMENT$

10.4

'.02

6.010.4 6.0

+3. 0.0

5. 3.0

33.# 20.0

+13.1 0.0

+8.4 0.0

+8.4 0.0

10.4 6.0

10.4 6.0

+13.1 0.0

10.4 6.0

2#.2 15.0+8.4 0.0

1.0 0.0

10.4 6.0

+3. 0.0

1.0 0.0

10.40 6.0

+3.6# 0.0

1.01 0.0

5.0 3.0

0.00 0.0

10.40 6.0

+3.6# 0.0

10.40 6.0

+8.38 0.0

10.40 6.0

+3.6# 0.0

+3.6# 0.0

10.40 6.0

+8.38 0.0

15.10 8.0

33.88 1.0

+1.8 0.0

+8.38 0.0

1.01 0.0

+3.6# 0.0

10.40 6.0

24.4# 12.0

+3.6# 0.0

1.01 0.0

10.40 6.0

10.40 6.0

Ni*la E-/ H&&ition ("l)

Ni*la E-/ &&ition ("l)


20/32

+3.6# 0.0

10.40 10.4

+31.86 0.0

+1.8 0.0

+3.6# 3.0

5.0 6.0

+8.38 0.0

5.0 6.0

+3.6# 2.0

15.10 15.0

62.06 50.0

+1.8 0.0

+2.1 0.0

480.00

480.00

480.00

480.00

480.00

480.00480.00

480.00

480.00

480.00

480.00

480.00

480.00

480.00

480.00

480.00

480.00

133.# $1TOT&- 254.4

TOT&- 254.4

ml"

ml"


21/32

12.012.0

0.0

6.0

40.0

0.0

0.0

0.0 50 mi/

12.0 60mi/

12.0 80mi/

0.0

12.0 100mi/

30.0 120mi/0.0 120mi/

0.0 120mi/

12.0

0.0

0.0 140mi/

12.0 140mi/

0.0 140mi/

0.0 160mi/

6.0

0.0 180mi/

12.0 180mi/

0.0 180mi/

12.0 200mi/

0.0 200mi/

12.0 220mi/

0.0 240mi/

0.0 240mi/

12.0 240mi/

0.0 240mi/

16.0 240mi/

34.0

0.0 260mi/

0.0 260mi/

0.0 280mi/

0.0 280mi/

12.0 300mi/

24.0 320mi/

0.0

12.0 320mi/

12.0

12.0 340mi/

Ni*la E-/ H&&ition ("l)

0 1 2 3 4 5 6 8 # 101112131415

5

5.2

5.4

5.6

5.8

6

6.2

6.4

6.6

Nic*el (g,-)


22/32

0.0

20.8 360mi/

0.0 380mi/

0.0 380mi/

6.0 380mi/

12.0 380mi/

0.0 400mi/

12.0 400mi/

4.0 400mi/

30.0 420mi/

100.0 440mi/

0.0

0.0 460>N

0.0

0.0 460>N

0.0

0.0 480mi/

0.0 480mi/

0.0 480mi/0.0 500mi/

0.0 500mi/

0.0 500mi/

0.0 520mi/

0.0 520mi/

0.0 520mi/

0.0 520mi/

0.0 540mi/

0.0

0.0 560mi/

0.0

520.8

520.8


23/32

161181#202122232425262282#303132333435363383#404142434445464484#505152535455565585#6

Nikel 'o/e/tratio/ o- eaker ath (!")

$a"le


24/32


25/32

6162636465666686#012345


26/32


27/32

epos&t&o' (ate Temp 88

11.75036 pH 4.78


28/32

T Th&*+'ess ,µm %P (ad&all ( %P (ad&all P

0.09 5.06 5.735 10.36

0.26 5.07 1.625

0.38 4.865 1.03

0.74 5.064 6.4

0.97 5.145 6.421.15 4.7 1.69 10.47

1.32 5.34 3.955

1.63 3.39 3.58 9.83

1.67 4.935 7.45 10.09

1.8 4.825 1.46 10.06

2.03 4.475 6.13 11.83

2.54 5.349 10.55

3.1 4.387

3.35 6.439 6.69


29/32


30/32

Ni MTO Nikel $em% %H 7ate o'e

0 5.#3 8# 4.#3 ++

0.0# 5.81 8# 4.88 15.18 o'e

0.1# 5.8 88. 4.8# 15.32 o'e

0.26 5.8 8#.2 4.8# 15.21 o'e

0.32 5.8 8# 4.# 15.1 o'e0.38 5.81 8# 4.# 14.60 o'e

0.4 5.8 88.# 4.8# 13.4 o'e

0.5 5.#3 8#.2 4.86 15.48 o'e

0.4 5.46 88. 4.# 15.1#

0.8 5.#3 8# 4.88 13.4

0.# 5.64 88.# 4.#1 15.2 o'e

0.# 5.8 8# 4.#1 15.44

1.15 5.8 #0 5.02 14.10

1.24 5.8 8#.5 5.02 16.68

1.32 5.81 8#.5 4.# 16.021.38 5.8 #0.1 4.# 15.08

1.63 5.4 #0 4.#3 15.63

1.6 5.8 8#.5 4.#3 14.81

1.8 5.6# #0 4.8# 14.48 o'e

2.03 6.1 #0.1 4.# 13.43 o'e

2.25 5.## 8#.# 4.# 14.14 o'e

2.3 5.52 #0.1 4.8# 1#.8

2.54 6.1 8#. 4.8# 16.05 o'e

2.66 6.1 8#.4 4.#2 1.22 o'e

2. 5.81 8#.6 4.#1 15.#4 o'e

2.# 6.05 8#.5 4.#1 13.38

3.1 6.05 8#. 4.#3 13.16

3.18 6.16 #0.5 4.8# 15.5 o'e

3.35 6.22 #0 4.#1 1#.32


31/32

Tem Coe epos&t&o' (ate

Co'sta't 44458.2 14.3591632088

Tempeat!e 493.689 14.4712166484

pH 8642.24 14.8574070258

)&*+el 7518.82 14.792810604

T 90061.4 14.597259168 TemppH 95.9317 14.7267839558

Temp)& 83.4947 14.8942287155

TempT 1011.86 12.7864720992

pH)& 1463.06 15.0325990688

pHT 18555.6 14.2230953024

)&T 14673.5 15.1402308706

TemppH)& 16.2467 17.90746244

TemppHT 208.489 17.2378762292

Temp)&T 164.811 16.6644986358

pH)&T 3025.61 15.5829270224 TemppH)&T 33.9854 19.06424164

16.043362275

15.99062942

14.240364682

14.9968303451

17.2929124365

14.5277396392

15.6270505408

16.2600873888

15.4051687696

15.5532998179

11.6025248016

12.7749286802


32/32

Tem Coe epos&t&o' (ate

Co'sta't 1.6894 14.949954304

pH 2.71875 14.983585292

T 36.4484 14.983400268

pHT 7.45312 15.03427916

15.0385924414.982845196

14.773570024

15.06447212

14.896703968

15.17023978

15.180489124

16.44872676

16.535690376

15.985147948

15.1104804415.574472508

15.586291772

14.97932974

15.15720764

15.173023

14.977823116

14.977373772

15.653378064

15.444043684

15.473327524

16.00883046

14.975682124

15.52896682

2observation laboratory performance test sabado 01marzo2014

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