2007 global demilitarization symposium and exhibition ...€¦ · pressures above the critical...

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2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION Update on Demil Technology Programs at General Atomics By Stan Rising & Jim Elliott May 16, 2007

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Page 1: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

2007 GLOBAL DEMILITARIZATIONSYMPOSIUM AND EXHIBITION

Update on Demil Technology Programsat General Atomics

ByStan Rising & Jim Elliott

May 16, 2007

Page 2: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

Work SponsorsWork Sponsors

Defense Ammunition Center,Defense Ammunition Center,Joint Munitions Command,Joint Munitions Command,

andandAir Force at Tyndall AFBAir Force at Tyndall AFB

Page 3: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

Stan RisingAir Force Research Laboratory

Tyndall AFB

Page 4: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

BRIEFING OUTLINE

• iSCWO & Hydrolysis overview• Current technology transition projects• FY07/FY08 goals• Conclusions

Page 5: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

iSCWO PROCESS FLOW

AIR /OXIDENT

WASTELIQUID /SLURRY

GAS EFFLUENTDischarge to Atmosphere

LIQUID EFFLUENTMetal Removal

QUENCH WATER

WATER / FUEL

Gas Liquid

SeparatoriSCWO Reactor Pressure

Letdown

Page 6: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

SCWO

• SCWO destroys organics with no production of NOX, SOX, dioxins, furans or greenhouse gasses.

• Wastes are mixed with water and oxidized at 3400 psi and 1200F

• Suitable for pumpable organics including slurry mixtures of solid wastes

• Gaseous effluents dischargable to the air

• Liquid effluents dischargable to the sewer

Environmentally friendly waste processing technology

Page 7: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

History of SCWO

• SCWO technology issues resolved in the 1990’s

• Cost & reliability became impediments to operational demil & commercial applications

• iSCWO developed to resolved cost & operational reliability issues

• iSCWOs now penetrating market for selected demil & commercial applications

• 1st iSCWO undergoing operational tests

Page 8: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

ADVANTAGES OF SCWO

• SCWO oxidizes organic wastes– Oxidation of a combustible material at temperatures and

pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi)

– Complete oxidation to CO2, H2O, and inorganic acids (or salts) for most organic feeds

– No acid gases, dioxins, furans, or particulates discharge– Minimal Gas Discharge - Low NOX, SOX, CO, and TOC

– Destruction of organic wastes occurs very quickly

• Process stability– Fully automated, easy & safe operation

Ultra clean, environmentally friendly waste processing technology

Page 9: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

GA INDUSTRIAL SCWO (i-SCWO)

• Objectives– Simplified design targeted at specific applications– Low capital cost– Easy & quick fabrication– Robust, reliable & industrial hardened– Easy shipment & installation– Small foot print– Readily permitted– Suitable for 7/24 operation– Compatible with future energy conversion, HMRS or special

feed prep modules– Low risk

10 ton/day liquid waste processing unit

Page 10: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

iSCWO EQUIPMENT LAYOUT

Page 11: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

Hydrolysis

Hydrolysis Production Prototype Plant (HPPP)

Located at Tooele Army Depot

Page 12: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

HYDROLYSIS PROCESS FLOW

CAUSTIC

CADs

WATER

HYDROLYZER

LIQUIDSAND

SOLIDS

RECOVERY AND DISPOSAL

POLLUTIONABATEMENT

SYSTEM

RELEASE

GASES

Page 13: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

CAD HPPP FACILITY

Page 14: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

Hydrolysis Production Prototype Plant

Objectives & Status:• Designed for demil of aluminum bodied CADs• Design processing rate = ~2 tons/day• Design & construction complete• Checkout & systemization complete• Optimization testing in progress• Permitting in progress• Adding a PAS

Over 360,000 CADs = 80 tons Demil’d

Page 15: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

CURRENT TECHNOLOGY TRANSITION PROJECTS

• Tooele Army Depot (TEAD)– Base Hydrolysis– 3 GPM iSCWO

• Blue Grass Army Depot (BGAD)– 10 GPM iSCWO

• Alaska iSCWO– 3 GPM iSCWO

Page 16: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

Jim ElliottGeneral Atomics

Page 17: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

STATUS OF TECHNOLOGY TRANSITION PROJECTS (TTPs)

• TEAD– CADs Hydrolysis HPPP – iSCWO (3 GPM)

• BGAD– iSCWO (10 GPM)

• Alaska – iSCWO (3 GPM)

Page 18: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

TEAD TECHNOLOGY TRANSITION PROJECT

• CADs Hydrolysis HPPP • iSCWO (3 GPM)

Page 19: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

TEAD HYDROLYSIS TTP STATUS

• 2006 – Systemization tests & “trial runs” • Dec 2006 – Received 3 NOVs from UTDEQ• Jan 2007 – Submitted CAP• Apr – Jun 2007 – System mods & tests• May 2007 - UTDEQ approval of CAP• Jun 2007 – Update Risk Analysis• Jul/Aug 2007 – Rerunning “trial burns” for UTDEQ• Oct 2007 – Complete all required UTDEQ actions• Mar 2008 - Install PAS• Early 2008 – Permit issuance

Production Demil Operations Early 2008

Page 20: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

TEAD iSCWO TTP STATUS

• 3 GPM iSCWO design complete• iSCWO skid construction partially complete• Building complete• Awaiting further funding

Page 21: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

BGAD TECHNOLOGY TRANSITION PROJECT

• 10 GPM iSCWO• Grind/Slurry feed prep system• Heavy metals removal system

Page 22: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

BGAD TECHNOLOGY TRANSITION PROJECT

• Permitting: RCRA Part B permit application submittal schedule for Jun07

• Testing– Completed scale-up tests– Performed reactor fabrication tests

• 10 gpm iSCWO– Completed equipment design – Completed building design– Cleared site for building construction

• Completed conceptual designs for:– Grind/Slurry system conceptual – Heavy metals removal system

Page 23: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

ALASKA iSCWO TECHNOLOGY TRANSITION PROJECT

• 3 GPM iSCWO design complete• iSCWO skid construction partially complete• iSCWO reactor fabrication nearing

completion• Site purchased – 1 mile from Elmendorf AFB• Building design work in progress• RCRA Part B permit application started

Page 24: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

FY07 & FY08 Plans

• TEAD– Complete CADs HPPP operating permit– Support CADs demil operations– Build & install iSCWO unit

• BGAD– Obtain RCRA Part B permit– Construct the building – Start iSCWO construction

• Alaska– Submit RCRA Part B permit application– Complete iSCWO construction– Complete building construction

• R&D– iSCWO energy recovery– Acid hydrolysis– Analysis & testing of other munitions for hydrolysis

Page 25: 2007 GLOBAL DEMILITARIZATION SYMPOSIUM AND EXHIBITION ...€¦ · pressures above the critical point of water, 374°C and 22.1 MPa (3200 psi) – Complete oxidation to CO 2, H 2O,

CONCLUSIONS

• Current Technology Transition Projects (TTPs)are all going well

– TEAD CADs Hydrolysis Facility– TEAD 2 GPM iSCWO facility– BGAD 10 GPM iSCWO – Alaska 3 GPM iSCWO