1341 Old Freeport Road Pittsburgh, Pennsylvania 15238

412.963.6562 (T) 412.963.7613 (F)

www.AmelieConstruction.com An Equal Opportunity Employer

SAFETY DATA SHEETS

  

SDS – INDEX  

     

321 Dry Film, Molykote (Lubricant) AC-20 Acetylene Acetylene, Dissolved Aerosol Spray (Speed E-namel) Anti Spall J33 ARMOR ALL Original Protectant Asphalt (Performance Graded) AT-12 (Air Tool Lubricant) Brake Parts Cleaner (NAPA Mac’s) Carbozinc 859 (Zinc Primer) Carboguard 888 (Low Temp Primer) Certi-Vex AC1315 Cleaner/Degreaser (Purple Power) Concrete & Asphalt Cleaner (Quickrete) Diesel 911 Diesel Fuel Diesel Fuel Supplement Elmer’s Carpenter Wood Glue ENVIROSEAL 40 FX-32 Powder (Concrete Admixture) FX-349 Powder (Concrete Admixture) Gasoline General Purpose Adhesive Cleaner (3M) GLB200 – High Hide White (PPG) GoJo Hand Cleaner GREAT STUFF PRO HC Foam Sealant Grinding Wheel, Abrasive

Hammer Honey HIT RE 500 Hot Shot Flying Insect Killer Hydrochloric Acid Hydroseal II (Heavy Duty Parts Cleaner) Hy-Gard Transmission Fluid Insulating Epoxy Coating – Aerosol ISO HEET Gas Line Antifreeze Keligrout 101-P Keligrout 101-Catalyst Kilz 2 (Latex Primer) Klean Strip Lacquer Thinner Klean Strip Zylene Krylon Pro (All Surface Enamel) Kure-N-Seal Lube Plus 4070 Macropoxy 646 (Fast Cure Epoxy) Macropoxy 920 Pre-Prime Marine High Viscosity Gear Lube MasterKure ER 50 MEL-PRIME MEL-ROL (Waterproofing Membrane) Motor Oil (All Grades) MPC Cleaning Solution Never-Seez Regular Grade Compound Oxygen (Compressed Gas) Paint Buster Hand Cleaner Peel Away 1 (Paint Remover)

  

SDS – INDEX  

     

Petroleum No. 2 (Ultra Low Sulfur Diesel) Portland Cement Power Blend (2-Cycle Engine Oil) PREMALUBE PRO-CRYL (Acrylic Primer) Propane Pro-Poxy Type III PYROIL (Low VOC Engine Degreaser) PRYOIL (Regular Starting Fluid) Quickrete Raincoat (Oil Based Water Repellent) Resin Cure J11W RDO 302 ES MW (Rock Drill Oil) RotaMagic (Concentrated Cutting Fluid) Rubber Insulation Adhesive, R-373 Sandpaper Flapper Wheel (3M) Seal Tight 1100 SHER-CRYL HPA (Acrylic Coating) Sigunit L 72 AF (Shotcrete Accelerator) Sika Aramatec 110 Epoxy Cement Sikadur-32, Part A Sikadur-32, Part B Sikaflex 1A Sikaflex-2c SL, Part A Sikaflex-2c SL, Part B SPRED HOUSE Dura-Satin StaBil Fuel Stabilizer – Marine SureGrout SurePoxy 117, Comp A SurePoxy 117, Comp B Tier Mounting/Rubber Lubricant, Ru-Glyde

Vitalife 400 (Lubricant) Welding Rod, SMAW (Hobart) Welding Rod, SMAW (Lincoln) WD-40 (Lubricant) ZINC CLAD IV Primer, Part U Zinc Oxide

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Material Safety Data Sheet

1 - Chemical Product and Company Identification Manufacturer: WD-40 Company Address: 1061 Cudahy Place (92110) P.O. Box 80607 San Diego, California, USA 92138 –0607 Telephone: Emergency only: 1-888-324-7596 (PROSAR) Information: 1-888-324-7596 Chemical Spills: 1-800-424-9300 (Chemtrec) 1-703-527-3887 (International Calls)

Chemical Name: Organic Mixture Trade Name: WD-40 Aerosol Product Use: Lubricant, Penetrant, Drives Out Moisture, Removes and Protects Surfaces From Corrosion MSDS Date Of Preparation: 3/11/10

2 – Hazards Identification Emergency Overview: DANGER! Flammable aerosol. Contents under pressure. Harmful or fatal if swallowed. If swallowed, may be aspirated and cause lung damage. May cause eye irritation. Avoid eye contact. Use with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. Symptoms of Overexposure: Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal. Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. Eye Contact: Contact may be irritating to eyes. May cause redness and tearing. Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis, severe lung damage and death. Chronic Effects: None expected. Medical Conditions Aggravated by Exposure: Preexisting eye, skin and respiratory conditions may be aggravated by exposure. Suspected Cancer Agent: Yes No X 3 - Composition/Information on Ingredients

Ingredient CAS # Weight Percent Aliphatic Hydrocarbon 64742-47-8 45-50 Petroleum Base Oil 64742-58-1

64742-53-6 64742-56-9 64742-65-0

<25

LVP Aliphatic Hydrocarbon 64742-47-8 12-18 Carbon Dioxide 124-38-9 2-3 Surfactant Proprietary <2 Non-Hazardous Ingredients Mixture <10 4 – First Aid Measures Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. Eye Contact: Flush thoroughly with water. Remove contact lenses if present after the first 5 minutes and continue flushing for several more minutes. Get medical attention if irritation persists.

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Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention. Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist. 5 – Fire Fighting Measures Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. Special Fire Fighting Procedures: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. Unusual Fire and Explosion Hazards: Contents under pressure. Keep away from ignition sources and open flames. Exposure of containers to extreme heat and flames can cause them to rupture often with violent force. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. 6 – Accidental Release Measures Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. 7 – Handling and Storage Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use only with adequate ventilation. Keep away from heat, sparks, pilot lights, hot surfaces and open flames. Unplug electrical tools, motors and appliances before spraying or bringing the can near any source of electricity. Electricity can burn a hole in the can and cause contents to burst into flames. To avoid serious burn injury, do not let the can touch battery terminals, electrical connections on motors or appliances or any other source of electricity. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep out of the reach of children. Do not puncture, crush or incinerate containers, even when empty. Storage: Store in a cool, well-ventilated area, away from incompatible materials Do not store above 120 F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. 8 – Exposure Controls/Personal Protection Chemical Occupational Exposure Limits Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended) Petroleum Base Oil

5 mg/m3 TWA, 10 mg/m3 STEL ACGIH TLV 5 mg/m3 TWA OSHA PEL

LVP Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended) Carbon Dioxide 5000 ppm TWA (OSHA/ACGIH), 30,000 ppm STEL (ACGIH) Surfactant None Established Non-Hazardous Ingredients None Established The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Always spray away from your face. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation. For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits.

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Personal Protection: Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling. 9 – Physical and Chemical Properties

Boiling Point: 361 - 369 F (183 - 187°C)

Specific Gravity: 0.8 – 0.82 @ 60 F

Solubility in Water: Insoluble pH: Not Applicable Vapor Pressure: 95-115 PSI @ 70 F Vapor Density: Greater than 1 Percent Volatile: 70-75% VOC: 412 grams/liter

(49.5%) Coefficient of Water/Oil Distribution:

Not Determined Appearance/Odor Light amber liquid/mild odor

Flash Point: 122 F (49°C) Tag Open Cup (concentrate)

Flammable Limits: (Solvent Portion)

LEL: 0.6% UEL: 8.0%

Pour Point: -63 C (-81.4 F ) ASTM D-97

Kinematic Viscosity: 2.79-2.96cSt @ 100 F

10 – Stability and Reactivity Stability: Stable Hazardous Polymerization: Will not occur. Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate containers. Incompatibilities: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. 11 – Toxicological Information The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard. 12 – Ecological Information No data is currently available. 13 - Disposal Considerations If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local regulations. 14 – Transportation Information_ DOT Surface Shipping Description: Consumer Commodity, ORM-D IMDG Shipping Description: Un1950, Aerosols, 2.1, LTD QTY 15 – Regulatory Information

U.S. Federal Regulations:

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CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not contain chemicals regulated under California Proposition 65. VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and states adopting the OTC VOC rules. Canadian Environmental Protection Act: One of the components is listed on the NDSL. All of the other ingredients are listed on the Canadian Domestic Substances List or exempt from notification. Canadian WHMIS Classification: Class B-5 (Flammable Aerosol) This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. 16 – Other Information: HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Reactivity – 0 (minimal hazard)

SIGNATURE: TITLE: Director of Global Quality Assurance REVISION DATE: March 2010 SUPERSEDES: August 2009

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HMIS CodesHealth 2*

Flammability 3Reactivity 1

DATE OF PREPARATIONApr 19, 2017

MATERIAL SAFETY DATA SHEET

B69A813 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBERB69A8

PRODUCT NAMEZINC CLAD® IV Primer (Part U), Flat/Gray-Green

MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115

Telephone Numbers and WebsitesProduct Information (800) 524-5979

www.sherwin-williams.comRegulatory Information (216) 566-2902

www.paintdocs.comMedical Emergency (216) 566-2917

Transportation Emergency* (800) 424-9300for Chemical Emergency ONLY (spill, leak, fire, exposure, or *

accident)

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure1 100-41-4 Ethylbenzene

ACGIH TLV 20 PPM 7.1 mmOSHA PEL 100 PPMOSHA PEL 125 PPM STEL

6 1330-20-7 XyleneACGIH TLV 100 PPM 5.9 mmACGIH TLV 150 PPM STELOSHA PEL 100 PPMOSHA PEL 150 PPM STEL

1 110-43-0 Methyl n-Amyl KetoneACGIH TLV 50 PPM 3.855 mmOSHA PEL 100 PPM

4 67924-34-9 Epoxy PolymerACGIH TLV Not AvailableOSHA PEL Not Available

81 7440-66-6 ZincACGIH TLV Not AvailableOSHA PEL Not Available

2 14808-60-7 Crystalline Silica, respirable powderACGIH TLV 0.025 mg/m3 as Resp. DustOSHA PEL 0.1 mg/m3 as Resp. Dust

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:

the liver

B69A8

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UEL7.9

LEL1.0

FLASH POINT80 °F PMCC

the urinary systemthe reproductive system

SIGNS AND SYMPTOMS OF OVEREXPOSUREHeadache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.Redness and itching or burning sensation may indicate eye or excessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSUREMay cause allergic skin reaction in susceptible persons or skin sensitization.

CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.SKIN: Wash affected area thoroughly with soap and water.

If irritation persists or occurs later, get medical attention.Remove contaminated clothing and launder before re-use.

INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

FLAMMABILITY CLASSIFICATIONRED LABEL -- Flammable, Flash below 100 °F (38 °C)

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSClosed containers may explode when exposed to extreme heat.Application to hot surfaces requires special precautions.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately

apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus should be used.Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure

build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORYDOL Storage Class IC

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEContents are FLAMMABLE. Keep away from heat, sparks, and open flame.During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off

stoves, electric tools and appliances, and any other sources of ignition.Consult NFPA Code. Use approved Bonding and Grounding procedures.Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.

Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.Wash hands after using.This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous

levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

VENTILATIONLocal exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure

limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.RESPIRATORY PROTECTION

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.

B69A8

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When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive.

PROTECTIVE GLOVESWear gloves which are recommended by glove supplier for protection against materials in Section 2.

EYE PROTECTIONWear safety spectacles with unperforated sideshields.

OTHER PROTECTIVE EQUIPMENTUse of barrier cream on exposed skin is recommended.

OTHER PRECAUTIONSIntentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 28.32 lb/gal 3394 g/lSPECIFIC GRAVITY 3.41

BOILING POINT 277 - 308 °F 136 - 153 °CMELTING POINT Not Available

VOLATILE VOLUME 35%EVAPORATION RATE Slower than

etherVAPOR DENSITY Heavier than air

SOLUBILITY IN WATER Not AvailableVOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

2.56 lb/gal 307 g/l Less Water and Federally Exempt Solvents2.56 lb/gal 307 g/l Emitted VOC

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — StableCONDITIONS TO AVOID

None known.INCOMPATIBILITY

Contamination with Water, Acids, or Alkalis can cause evolution of hydrogen, which may result in dangerously increased pressures in closed containers.

HAZARDOUS DECOMPOSITION PRODUCTSBy fire: Carbon Dioxide, Carbon Monoxide

HAZARDOUS POLYMERIZATIONWill not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDSReports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient

evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans.

Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer.

TOXICOLOGY DATACAS No. Ingredient Name100-41-4 Ethylbenzene

LC50 RAT 4HR Not AvailableLD50 RAT 3500 mg/kg

1330-20-7 XyleneLC50 RAT 4HR 5000 ppmLD50 RAT 4300 mg/kg

110-43-0 Methyl n-Amyl KetoneLC50 RAT 4HR Not AvailableLD50 RAT 1670 mg/kg

67924-34-9 Epoxy PolymerLC50 RAT 4HR Not AvailableLD50 RAT Not Available

7440-66-6 ZincLC50 RAT 4HR Not AvailableLD50 RAT Not Available

14808-60-7 Crystalline Silica, respirable powderLC50 RAT 4HR Not AvailableLD50 RAT Not Available

B69A8

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SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATIONNo data available.

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHODWaste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local

regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport.

US Ground (DOT)5 Liters (1.3 Gallons) and Less may be Classed as LTD. QTY. (PAINT OR RELATED).Larger Containers are Regulated as:UN1263, PAINT, 3, PG III, (ERG#128)

DOT (Dept of Transportation) Hazardous Substances & Reportable QuantitiesEthylbenzene 1000 lb RQXylenes (mixed isomers) 100 lb RQZinc 1000 lb RQ

Bulk Containers may be Shipped as (check reportable quantities):RQ, UN1263, PAINT, 3, PG III, (ZINC, XYLENES (MIXED ISOMERS)),(ERG#128)

Canada (TDG)UN1263, PAINT, 3, PG III, LIMITED QUANTITY, (ERG#128)

IMO5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity.UN1263, PAINT, 3, PG III (27 C c.c.), EmS F-E, , MARINES-EPOLLUTANT, (ZINC)

IMO5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity.UN1263, PAINT, 3, PG III (27 C c.c.), MARINE POLLUTANT (ZINC), EmSF-E, , MARINE POLLUTANT, (ZINC)S-E

IATA/ICAOUN1263, PAINT, 3, PG III, MARINE POLLUTANT, (ZINC)

SECTION 15 — REGULATORY INFORMATION

SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)CAS No. CHEMICAL/COMPOUND % by WT % Element100-41-4 Ethylbenzene 11330-20-7 Xylene 6

Zinc Compound 2 78.7CALIFORNIA PROPOSITION 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.TSCA CERTIFICATION

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.

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Material Safety Data SheetZinc oxide MSDS

Section 1: Chemical Product and Company Identification

Product Name: Zinc oxide

Catalog Codes: SLZ1009, SLZ1114, SLZ1222, SLZ1057

CAS#: 1314-13-2

RTECS: ZH4810000

TSCA: TSCA 8(b) inventory: Zinc oxide

CI#: Not available.

Synonym: Calamine; Zinc white

Chemical Name: Zinc Oxide

Chemical Formula: ZnO

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Zinc oxide 1314-13-2 100

Toxicological Data on Ingredients: Zinc oxide: ORAL (LD50): Acute: 7950 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic forbacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated orprolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention if irritation occurs.

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Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.

Serious Skin Contact: Not available.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.

Serious Inhalation: Not available.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards: Slow addition of zinc oxide to cover linseed oil varnish causes generation of heat andignition.

Special Remarks on Explosion Hazards:May explode when mixed with chlorinated rubber. Zinc Oxide and Magnesium can react explosively when heated.

Section 6: Accidental Release Measures

Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority requirements.

Large Spill:Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on thecontaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:Keep locked up.. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep awayfrom incompatibles such as acids.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).

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Section 8: Exposure Controls/Personal Protection

Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.

Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:TWA: 5 STEL: 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation TWA: 15 (mg/m3) from OSHA (PEL) [United States]Inhalation Total. TWA: 5 STEL: 10 CEIL: 25 (mg/m3) from NIOSH Inhalation TWA: 5 STEL: 10 (mg/m3) from OSHA (PEL)[United States] Inhalation Respirable.Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Powdered solid.)

Odor: Odorless.

Taste: Bitter.

Molecular Weight: 81.38 g/mole

Color: White to yellowish-white

pH (1% soln/water): Not applicable.

Boiling Point: Not available.

Melting Point: 1975°C (3587°F)

Critical Temperature: Not available.

Specific Gravity: 5.607 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: Is not dispersed in cold water, hot water.

Solubility:Insoluble in cold water, hot water Soluble in dilute acetic acid, or mineral acids, ammonia, ammonium carbonate, fixed alkalihydroxide solution..

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

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Conditions of Instability: Not available.

Incompatibility with various substances: Not available.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:Reacts violently with magnesium, linseed oil. Reacts with hydrochloric acid to produce zinc chloride. Reacts with sulfuricacid to produce zinc sulfate. Reacts with hydrogen fluoride to produce zinc fluoride tetrahydrate. Gradually absorbs CO2 onexposure to air. Sublimes at normal pressure. Zinc Oxide reacts with Carbon Monoxide or hydrogen to produce elementalzinc.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Dermal contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 7950 mg/kg [Mouse].

Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.

Other Toxic Effects on Humans:Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects based on animal data. No human data found at this time. May affect genetic material(mutagenic).

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: May cause mild skin irritation. Eyes: May cause mechanical eye irritation and conjunctivitis.Inhalation: May cause mechanical irritation of the respiratory tract. A few sources claim that finely divided zinc oxide dustcan cause "metal fume fever." Zinc oxide dust is generally considered a nuisance dust; adverse effects are unlikely whenexposures are kept under reasonable control. Inhalation of high concentrations of Zinc Oxide fume or dust may cause "MetalFume Fever." Symptoms of metal fume fever may include a flu-like condition involving headache, chills, fever, sweats, nausea,vomiting, cough, muscle aches and pains, and difficulty breathing, ;ulmonary edema. May also affect the liver. Ingestion: Maycause digestive tract irritation although Zinc oxide has a low toxicity by oral exposure route. Chronic Potential Health Effects:Ingestion: Prolonged or repeated ingestion of zinc oxide may affect blood, metabolism, and the thyroid.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

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Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations:Illinois toxic substances disclosure to employee act: Zinc oxide Rhode Island RTK hazardous substances: Zinc oxidePennsylvania RTK: Zinc oxide Minnesota: Zinc oxide Massachusetts RTK: Zinc oxide New Jersey: Zinc oxide CaliforniaDirector's List of Hazardous Substances: Zinc oxide TSCA 8(b) inventory: Zinc oxide

Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):R40- Possible risks of irreversible effects. S2- Keep out of the reach of children. S36/37- Wear suitable protective clothing andgloves.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 1

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2005 08:34 PM

Last Updated: 05/21/2013 12:00 PM

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their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.