目 录

• 催化基础国家重点实验室第七届学术委员会······································1

• 催化基础国家重点实验室第三届国际顾问委员会································5

• 催化基础国家重点实验室主任及组长···············································6

• 催化基础国家重点实验室 2015 年大事记···········································8

• 催化基础国家重点实验室 2015 年重要科研进展

之一：纳米限域催化理论研究取得新进展···································11

之二：二氧化碳高效电催化还原研究取得进展·····························13

之三：纳米碳材料催化研究取得新进展······································15

之四：宽光谱响应光催化剂分解水研究取得新进展·······················17

之五：多相手性催化研究取得新进展·········································19

之六：宽光谱响应光催化分解水制氢研究取得新进展····················21

之七：实现半导体单晶粒子光催化剂上光生电荷分离各向异性

的原位光电成像··························································23

之八：分子筛膜研究取得新进展···············································25

之九：金属有机骨架分子筛膜研究取得新进展·····························27

• 催化基础国家重点实验室 2015 年发表的综述文章

之一：木质素催化转化···························································29

• 2015 年在国内外杂志发表的文章目录·············································31

• 2015 年在国内外杂志发表的文章首页·············································56

• 催化基础国家重点实验室 2015年专利申请一览表····························277

• 催化基础国家重点实验室 2015年专利授权一览表····························283

• 催化基础国家重点实验室 2015年开放课题一览表····························285

• 催化基础国家重点实验室 2015年自主研究课题一览表······················286

催 化 基 础 国 家 重 点 实 验 室

第 七 届 学 术 委 员 会 名 单

学术委员会主任

副主任

顾 问

委 员

李 灿

丁奎岭

谢在库

蔡启瑞

彭少逸

闵恩泽

徐如人

陈 懿

谢有畅

万惠霖

何鸣元

郑小明

石•米歇尔

林国强

包信和

陈初升

丁维平

胡培君

李静海

院 士

院 士

教授级高工

院 士

院 士

院 士

院 士

院 士

教 授

院 士

院 士

教 授

教 授

院 士

院 士

教 授

教 授

教 授

院 士

中国科学院大连化学物理研究所

中国科学院上海有机化学研究所

中国石油化工集团

厦门大学

中国科学院山西煤炭化学研究所

石油化工科学研究院

吉林大学

南京大学

北京大学

厦门大学

石油化工科学研究院

浙江大学

法国巴黎第六大学

中国科学院上海有机化学研究所

中国科学院大连化学物理研究所

中国科技大学

南京大学

华东理工大学

中国科学院过程工程研究所

（以下按年龄排列）

（以下按音序排列）

刘中民

孙立成

王建国

王 野

吴 凯

夏春谷

徐柏庆

徐 杰

张 涛

赵东元

赵进才

宗保宁

院 士

教 授

研究员

教 授

教 授

研究员

教 授

研究员

院 士

院 士

院 士

高 工

中国科学院大连化学物理研究所

大连理工大学

中国科学院山西煤炭化学研究所

厦门大学

北京大学

中国科学院兰州化学物理研究所

清华大学

中国科学院大连化学物理研究所

中国科学院大连化学物理研究所

复旦大学

中国科学院化学研究所

石油化工科学研究院

1

李 灿

丁奎岭

谢在库

蔡启瑞

彭少逸

闵恩泽

徐如人

陈 懿

谢有畅

万惠霖

何鸣元

郑小明

石•米歇尔

林国强

包信和

陈初升

丁维平

胡培君

李静海

院 士

院 士

教授级高工

院 士

院 士

院 士

院 士

院 士

教 授

院 士

院 士

教 授

教 授

院 士

院 士

教 授

教 授

教 授

院 士

中国科学院大连化学物理研究所

中国科学院上海有机化学研究所

中国石油化工集团

厦门大学

中国科学院山西煤炭化学研究所

石油化工科学研究院

吉林大学

南京大学

北京大学

厦门大学

石油化工科学研究院

浙江大学

法国巴黎第六大学

中国科学院上海有机化学研究所

中国科学院大连化学物理研究所

中国科技大学

南京大学

华东理工大学

中国科学院过程工程研究所

刘中民

孙立成

王建国

王 野

吴 凯

夏春谷

徐柏庆

徐 杰

张 涛

赵东元

赵进才

宗保宁

院 士

教 授

研究员

教 授

教 授

研究员

教 授

研究员

院 士

院 士

院 士

高 工

中国科学院大连化学物理研究所

大连理工大学

中国科学院山西煤炭化学研究所

厦门大学

北京大学

中国科学院兰州化学物理研究所

清华大学

中国科学院大连化学物理研究所

中国科学院大连化学物理研究所

复旦大学

中国科学院化学研究所

石油化工科学研究院

2

State Key Laboratory of CatalysisMembers of Academic Committee

Chairman

Vice Chairmen

Advisory Members

Members

Prof. Can Li

Prof. Kuiling Ding

Prof. Kuzai Xie

Prof. Khi-Rui Cai

Prof. Shaoyi Peng

Prof. Enze Min

Prof. Ruren Xu

Prof. Yi Chen

Prof. Youchang Xie

Prof. Huilin Wan

Prof. Mingyuan He

Prof. Xiaoming Zheng

Prof. Michel Che

Prof. Guoqiang Lin

Prof. Xinhe Bao

Prof. Chusheng Chen

Prof. Weiping Ding

Prof. Peijun Hu

Dalian Institute of Chemical Physics

Shanghai Institute of Organic Chemistry

China Petrochemical Corporation

Xiamen University

Shanxi Institute of Coal Chemistry

SINOPEC Research Institute of Petroleum

Jilin University

Nanjing University

Peking University

Xiamen University

SINOPEC Research Institute of Petroleum

Zhejiang University

Universite Pierre et Marie Curie

Shanghai Institute of Organic Chemistry

Dalian Institute of Chemical Physics

University of Science and Technology of China

Nanjing University

East China University of Science and Technology

3

Prof. Jinghai Li

Prof. Zhongmin Liu

Prof. Licheng Sun

Prof. Jianguo Wang

Prof. Ye Wang

Prof. Kai Wu

Prof. Chungu Xia

Prof. Boqing Xu

Prof. Jie Xu

Prof. Tao Zhang

Prof. Dongyuan Zhao

Prof. Jincai Zhao

Prof. Baoning Zong

Institute of Process Engineering

Dalian Institute of Chemical Physics

Dalian University of Technology

Shanxi Institute of Coal Chemistry

Xiamen University

Peking University

Lanzhou Institute of Chemical Physics

Tsinghua University

Dalian Institute of Chemical Physics

Dalian Institute of Chemical Physics

Fudan University

Institute of Chemistry

SINOPEC Research Institute of Petroleum

4

催化基础国家重点实验室第三届国际顾问委员会名单 The 3rd International Advisory Committee of the State Key Laboratory of Catalysis

Prof. Alexis T. Bell University of California Berkeley, USA

Prof. Martin Muhler Ruhr-Universitaet Bochum Germany

Prof. Jürgen Caro University of Hannover Hannover, Germany

Prof. Jens K. Nörskov Stanford University USA

Prof. Michael Claeys University of Cape Town South Africa

Prof. Valentin N. Parmon Boreskov Institute of Catalysis Novosibirsk, Russia

Prof. Avelino Corma Institute for Chemical Technology Valencia, Spain

Prof. Lachezar A. Petrov King Abdulaziz University Kingdom of Saudi Arabia

Prof. Kazunari Domen The University of Tokyo Tokyo, Japan

Prof. Peter C. Stair Northwestern University USA

Prof. Masatake Haruta Tokyo Metropolitan University Tokyo, Japan

Prof. Rutger A. van Santen Eindhoven University of Technology Eindhoven, The Netherlands

Prof. Graham J. Hutchings Cardiff University Wales, UK

Prof. Bert Weckhuysen Utrecht University The Netherlands

Prof. Jae Sung Lee Pohang University of Science & Technology Korea

Prof. Ganapati D. Yadav Institute of Chemical Technology India

Prof. Thomas Maschmeyer The University of Sydney Australia

5

催化基础国家重点实验室主任及组长

Director and Group Leaders of the State Key Laboratory of Catalysis

主任：申文杰 Director: Prof. Wenjie Shen

• 催化反应化学组，组长：申文杰 Catalytic Reaction Chemistry Group Leader: Prof. Wenjie Shen 金催化研究中心，主任：春田正毅 Gold Catalysis Research Center Group Leader: Prof. Masatake Haruta • 纳米与界面催化组，组长：包信和 Nano and Interfacial Catalysis Group Leader: Prof. Xinhe Bao 能源战略组群

Basic & Strategic Studies on Engergy Team

• 仿生能源材料和系统组，组群组长：傅 强

Biomimetic Energy Materials and Systems Sub-group Leader: Prof. Qiang Fu

• 碳基能源纳米材料组，组群组长：潘秀莲 Nanostructured Carbon Materials for Energy Sub-group Leader: Prof. Xiulian Pan

• 分子催化与原位表征组，组长：李 灿 Molecular Catalysis and In-Situ Characterization Group Leader: Prof. Can Li

太阳能研究组群 Solar Energy Research Team

6

• 光催化分解水组，组群组长：章福祥

Solar Water Splitting Sub-group Leader: Prof. Fuxiang Zhang

• 光催化转化生物质组，组群组长：韩洪宪

Photocatalytic Conversion of Biomass Sub-group Leader: Prof. Hongxian Han

• 光电材料光谱表征组，组群组长：范峰滔

Spectroscopic Characterization of Photoelecreical Materials Sub-group Leader: Dr. Fengtao Fan

• 有机太阳电池组，组群组长：张 坚

Organic Solar Cells Sub-group Leader: Prof. Jian Zhang

• 光电功能纳米材料组，组群组长：张文华

Optoelectronic Nano Materials Sub-group Leader: Prof. Wenhua Zhang

• 无机膜与催化新材料组，组长：杨维慎 Inorganic Membrane and New Catalytic Materials Group Leader: Prof. Weishen Yang

• 有机-无机杂化材料组，组长：杨启华 Organic-Inorganic Hybrid Materials Group Leader: Prof. Qihua Yang

• 理论催化组，组长：李微雪 Theoretical Catalysis

Group Leader: Prof. Weixue Li

• 技术支撑与管理组，组长：胡林彦 Analytical Services and Administration Group Leader: Dr. Linyan Hu

7

催化基础国家重点实验室 2015 年大事记

1. 1 月 13 日，包信和院士带领团队完成的“甲烷高效转化研究获重大突

破”入选 2014 年中国十大科技进展新闻。

2. 2 月 13 日，世界首套采用我室新一代甲醇制烯烃技术（DMTO-Ⅱ）建

设的大型化工业装置，蒲城清洁能源化工有限责任公司（蒲城能化）

DMTO-Ⅱ工业装置顺利打通全流程。

3. 2 月，杨维慎研究员与华南理工大学合作的“基于无机膜和吸附剂的

分离与反应基础研究”荣获广东省自然科学一等奖。

4. 4 月 1 日，兼聘研究员丁云杰参与完成的 3万吨/年乙醇胺临氢氨化制

乙撑胺装置，在山东联盟化工股份有限公司一次投料开车成功，生产

出合格的乙二胺等主副产品。

5. 4 月 10 日，杨启华、李微雪研究员和兼聘研究员田志坚入选大连市第

二批领军人才。

6. 4 月 28 日，兼聘研究员张涛被授予“全国先进工作者”荣誉称号。

7. 4 月 28 日，催化基础国家重点实验室举行研究室主任、研究室学术委

员会主任任免仪式。申文杰研究员和李灿院士分别担任新一届实验室

主任和实验室学术委员会主任。

8. 5 月 23 日，包信和院士因在催化基础研究领域取得的成果荣获“周光

召基金会基础科学奖”。

9. 5 月 28 日至 29 日，我室举行第三届国际顾问委员会会议。12 位国际

顾问委员、实验室主任申文杰研究员、学术委员会主任李灿院士和包

信和院士以及实验室科研人员 70 余人参加会议。

8

10. 7月 10日，近日出版发行的《国家科学评论（National Science Review）》2015 年第二期上发表了由包信和院士担任客座主编的“面向未来的催

化化学”专栏（Special Topic: Catalysis—Facing the Future）。

11. 8月 31日，我室博士生彭媛获得中国科学院院长特别奖；博士生邓浇、

陈闪山获得中国科学院院长优秀奖；杨维慎研究员获得中国科学院优

秀导师奖。

12. 9 月 11 日，博士生刘进勋获得朱李月华优秀博士生奖，兼聘研究员赵

宗保获得朱李月华优秀教师奖；陈燕蝶获得宝洁优秀研究生奖学金。

13. 10 月 8 日，李仁贵博士的学位论文“半导体基光催化剂上分解水探索

研究：晶体及物相因素”（导师：李灿 院士）,被评为中国科学院优秀

博士学位论文。李灿院士被评为中国科学院优秀研究生指导教师。

14. 10 月 22 日，2015 年辽宁省自然科学学术成果奖评选结果日前揭晓，

陈闪山的论文获得一等奖；李忠成的论文获得三等奖。2015 年大连市

自然科学优秀学术论文评选结果公布，陈闪山、高敦峰的论文获得特

等奖；王旺银的论文获得二等奖；

15. 11 月 4 日，兼聘研究员刘中民荣获何梁何利基金科学与技术创新奖的

产业创新奖。

16. 11 月 17 日，李仁贵博士入选 2016 年度中国科学院青年创新促进会会

员。

17. 11月 20日，我室举行纪念郭燮贤院士诞辰九十周年学术思想研讨会。

18. 11 月 24 日，中国科学院人事局公布了 2015 年度“中国科学院特聘研

究员”计划入选者名单。我室包信和院士、李灿院士、杨维慎研究员

和兼聘研究员刘中民、田志坚、张涛入选特聘核心骨干，申文杰研究

员和兼聘研究员丁云杰、王树东、徐杰、徐龙伢、赵宗保、周永贵等

入选特聘骨干人才。

9

19. 12 月 7 日，兼聘研究员刘中民当选中国工程院院士。

20. 12 月，李灿院士和杨启华研究员等人的“纳米反应器中的多相手性催

化研究”荣获 2015 年辽宁省自然科学一等奖。

21. 12 月 15 日，兼聘研究员刘中民完成的 DMTO 技术在神华榆林投料试车

取得圆满成功。

22. 12 月 16 日，杨维慎研究员的“分子尺度分离无机膜材料设计合成及

其分离与催化性能研究”荣获 2015 年度国家自然科学二等奖。

23. 2016 年 1 月 14 日，包信和院士荣获 2015 年度中国科学院杰出科技成

就奖。

10

研究亮点之一

纳米限域催化理论研究取得新进展

催化基础国家重点实验室肖建平、潘秀莲和包信和等基于碳纳米管的纳米

限域催化理论研究取得新进展，相关结果在日前出版的《美国化学会志》(J. Am.

Chem. Soc. 137 ( 2015) 477)发表，并被选为“亮点（spotlight）文章”。

该团队的实验研究发现，由弯曲石墨烯片构成的碳纳米管纳米级管腔，可导致

组装在其内部的金属纳米粒子的特性发生变化，并可能改变分子吸附活化模式

甚至反应路径，从而调变催化反应的性能（PNAS 100 (2013) 14861; Angew. Chem.

Int. Ed. 52 (2013) 317; Energy Environ. Sci. 4 (2011) 4500; J. Am. Chem. Soc. 130

(2008) 9414; Nature Mater. 6 (2007) 507 等），据此，该团队率先提出了碳纳米

管的“协同限域催化”新概念（Chem.Commun. (2008) 6271-6281; Acc. Chem. Res.

44 (2011) 553）。近年来，该团队进一步采用密度泛函理论（Density Functional

Theory），并与实验相结合，研究了碳纳米管的限域效应对一系列过渡金属 Fe、

11

FeCo、RhMn、Ru 等电子结构及其催化性能调变作用的规律和本质，所提出的

限域能的概念可用于预测限域对催化反应性能的调变作用。结果表明，具有独

特电子结构的纳米空间形成了一种限域微环境，导致金属 d 带中心往下移，减

弱了 CO、N2、和 O2等分子的解离吸附，致使催化反应的火山型曲线向高结合

能的方向偏移，偏移程度与金属种类和碳纳米管的管径相关。该研究结果验证

了实验上观察到的限域效应对限域金属氧化还原性能，对 CO 加氢反应、NH3

分解和合成氨等反应的不同调变规律，为未来高效纳米催化剂的设计提供了重

要的科学参考。

12

研究亮点之二

二氧化碳高效电催化还原研究取得进展

催化基础国家重点实验室高敦峰、汪国雄和包信和院士等研究人员与浙江

工业大学王建国教授等合作，在二氧化碳高效电催化还原研究中取得进展，发

现纳米钯电极高效催化二氧化碳还原生成一氧化碳，并且其催化性能与纳米粒

子尺寸有很强的依赖关系。相关结果发表在《美国化学会志》(J. Am. Chem. Soc.

137 ( 2015) 4288)。

近年来，全球二氧化碳排放量的逐年增加对人们赖以生存的生态环境造成

了严重威胁，因此二氧化碳的捕获、存储以及转化受到研究者的广泛关注。在

二氧化碳转化方面，利用传统化学方法还原二氧化碳需要同时提供能量和氢气，

而采用电催化方法还原二氧化碳，与电解水耦合从水中获取氢，可以在比较温

和的反应条件一步直接获得一氧化碳、碳氢化合物和甲醇等高值化学品和液体

13

燃料。同时，该过程与可再生能源或富余核能利用相结合，实现大规模电能存

储，表现出极具潜力的应用前景，当前已成为相关领域一个重要的研究热点。

Pd 是典型的析氢反应催化剂，体相 Pd 电极上的 CO2还原过电势高、竞争

性的析氢反应造成法拉第效率低。该团队的实验研究发现，在 2.4–10.3 nm 范

围内，Pd 纳米粒子的 CO2还原选择性和活性表现了明显的尺寸依赖性。在−0.89

V (vs. RHE)时生成 CO 的法拉第效率从 10.3 nm Pd 上的 5.8%增加到 3.7 nm Pd

上的 91.2%，同时生成 CO 的电流密度增加了 18.4 倍。通过密度泛函理论(DFT)

计算，分析了在三种不同反应位（平面、台阶和角位）上 CO2还原和析氢反应

的自由能，并建立了反应性能与粒度的关系。生成 CO 的转换频率(TOF)与粒径

呈现火山型曲线关系，这表明可以通过改变 Pd 纳米粒子的尺寸来调变 CO2 吸

附、中间物种 COOH*的形成以及 CO*的脱附等，从而实现 Pd 纳米粒子从析氢

催化剂到高效 CO2还原催化剂的转变。

14

研究亮点之三

纳米碳材料催化研究取得新进展

采用廉价和储量丰富的非贵金属替代稀有的贵金属作为催化剂，实现重要

能源和化工过程的高效转化是当今催化科学和化学化工研究的热点。催化基础

国家重点实验室邓德会副研究员和包信和院士带领的研究团队在长期深入研究

纳米碳材料催化的基础上，通过创新二维纳米碳材料（类石墨烯材料）的制备

策略和合成方法，成功实现了均一的超薄石墨烯壳层（一般为 1-3 碳层）对 3d

过渡金属纳米粒子的包裹和封装。理论模拟和实验研究表明，在催化反应过程

中，活性金属纳米粒子催化剂在纳米碳空腔中的封装阻断了其与苛刻反应环境

（如酸性、碱性和强氧化性等）的直接接触，有效地延缓和阻止了催化剂的失

活，同时，被包裹的纳米金属的活性价电子通过与类石墨烯碳层的相互作用“穿

透（penetration）”到外表面，实现了高效催化反应。基于这一原理制备得到的

石墨烯碳层封装的纳米钴 -镍催化剂应用于强酸性条件下电解水制氢反应

（HER），表现出了优异的催化活性和稳定性，在电流密度为 10 mA/cm2 条件

下，电解水阴极过电位仅为 142 mV，性能接近于通常采用的 40%Pt/C 催化剂，

相关结果在《德国应用化学》（Angew. Chem. Int. Ed. 54 (2015) 2100）发表，并

被该期刊选为“热点文章（Hot Paper）”。

类石墨烯碳层保护活性金属纳米粒子和“穿透”电子催化的概念由该研究团

队在研究碳纳米管封装的纳米铁替代传统的贵金属铂作为燃料电池催化剂时首

次提出（Angew. Chem. Int. Ed. 52 (2013) 371），相关的原理得到了国际同行的

认可，并被形象地描述成为催化剂“穿铠甲”（chainmail for catalyst）。近年来，

“铠甲”催化的概念得到了迅速应用和拓展，围绕这一概念国内外众多课题组相

继在电催化、光催化、传统多相催化等体系进行研究。作为这一概念的首创团

队，包信和研究组进行了系统深入的研究，相关研究一直处在引领地位。先后

从实验和理论上发现和验证了石墨烯“铠甲”厚度对非贵金属的电

15

子“穿透”能力，以及对氧还原活性的影响（J. Mater. Chem. A 1 (2013) 14868）；

提出了该类催化剂在酸性条件下催化电解水制氢反应机理（Energy Environ. Sci.

7 (2014) 1919）；与他人合作发现该类催化剂用作染料敏化太阳能电池的对电

极材料，表现出了比贵金属 Pt 更为优异的 I3-还原活性（Angew. Chem. Int. Ed. 53

(2014) 7023）。

16

研究亮点之四

宽光谱响应光催化剂分解水研究取得新进展

催化基础国家重点实验室及洁净能源国家实验室李灿院士和百人计划学者

章福祥研究员负责的宽光谱响应半导体光催化分解水研究取得新进展：通过对

宽光谱捕光材料 Ta3N5 (Eg: 2.1 eV，吸收带边可至 600 nm)与高效氧化助催化剂

CoOx 之间的界面进行 MgO 纳米层修饰，不仅改善了 CoOx 与之的界面接触和

分散状态，而且还对半导体 Ta3N5 表面起到钝化保护作用，使光催化体系在可

见光长波段 500−600 nm 激发条件下的分解水放氧量子效率(AQE)，由文献最高

值 5.2%提升至目前的 11.3%。相关研究结果发表在《德国应用化学》(Angew.

Chem. Int. Ed. 54 (2015) 3047)。

太阳能光催化分解水制氢是实现太阳能光-化学转化的重要反应，被认为是

化学领域的一个“圣杯”式的反应。光催化水分解反应主要涉及质子还原和水氧

化两个半反应，其中水氧化是涉及多电子转移、热力学爬坡的反应，被认为是

17

实现上述太阳能光化学转化的速控步。太阳能光催化转化涉及如何实现太阳能

宽光谱利用、如何实现高效的光生电荷分离以及表面的催化转化等关键科学问

题，然而随着半导体催化剂吸收带边的红移，其驱动光生电荷分离以及水分解

(还原、氧化)的能力就随之变弱。因此，太阳光的充分利用与光生电荷的高效

分离常常不易兼得，要实现宽光谱响应的光催化剂高效水氧化过程是一个非常

挑战的难题。

助催化剂可有效促进光生电荷分离和催化转化，李灿研究团队在国际上明

确提出了双助催化剂策略(Acc. Chem. Res. 46 (2013) 2355)。最近几年，为了攻

克宽光谱响应光催化剂上水氧化这一科学难题，他们发展了高温负载廉价助催

化剂 CoOx的策略，在 LaTiO2N (Eg: 2.1 eV)上取得了比传统贵金属 IrO2和 RuO2

助催化剂更高的放氧性能(J. Am. Chem. Soc. 134 (2012) 8348-8351)，随后又成功

的将这种 CoOx 负载策略拓展到了新开发的宽光谱响应的氮掺杂氧化物

Sr5Ta4O15-xNx 和MgTa2O6−xNx材料体系上(J. Mater. Chem. 12 (2013) 5651；Chem.

Commun. 50 (2014) 14415)。

本研究进一步利用 MgO 纳米层调变宽光谱响应半导体 Ta3N5 与助催化剂

CoOx之间的界面性质，通过改变半导体材料表面的亲疏水性，改善了助催化剂

的纳米分散以及界面间电荷的转移，取得了目前宽光谱响应光催化剂上分解水

放氧反应的最高量子效率，为发展高效的光催化体系提供了新策略。

18

研究亮点之五

多相手性催化研究取得新进展

催化基础国家重点实验室李灿院士、刘研究员等在多相手性催化研究方

面取得新进展：完成了首例高反应活性和对映选择性的碱催化的硫醇对 o-QMs

的加成反应；实现了同时对烷基取代和芳基取代 o-QMs 的广谱的底物范围；为

合成手性 a-苄基硫醇提供了新的方法。相关研究结果发表在《德国应用化学》

(Angew. Chem. Int. Ed. 54 (2015) 4522)。

多相手性催化是绿色合成手性化合物的有效途径之一，开发高活性、高选

择性的多相手性催化剂并应用于不对称催化反应是兼具基础科学和应用背景的

重要研究方向。催化基础国家重点实验室分子催化与原位表征研究组长期致力

于发展新的多相催化方法以及多相手性催化体系，在国际上最早将 Sharpless 催

化 剂 成 功 组 装于 介 孔 MCM-41 形 成 多 相 催 化剂 (Angew. Chem. Int.

Ed. (2002) 821)，另外还进行了纳米孔道中的手性催化，观察到封装于纳米反应

器中的分子催化剂在环氧化合物的手性拆分反应中的双中心耦合加速效应

(Angew. Chem. Int. Ed. (2007) 6861)以及碳纳米管内手性催化性能显著提高的结

果(Angew. Chem. Int. Ed. (2011) 4913)。与此同时，还开展了液-液两相的手性催

化研究，在国际上首次提出乳液催化的概念(Chem. Eur. J. (2004) 2277)，成功的

19

实现了系列的手性 Aldol 反应(J. Catal. ( 2007) 360; Green Chem. (2011) 1983)和

a-酮酸与醛的串联反应(Angew. Chem. Int. Ed. (2012) 13159)。

本研究进一步开发水油两相在催化反应中的优势：Ortho-Quinone methides

(o-QMs)广泛存在于自然界。在生物身体机制的自我保护过程中，这类中间体起

到至关重要的作用；在很多药物对靶点的作用过程中也涉及这类高活性的中间

体。这类高活性的中间体在有机合成中被广泛应用，然而有关对 o-QMs 的手性

催化反应研究只有零星的报道，特别是手性碱催化的 o-QMs 反应研究目前还没

有文献报道。分析其主要原因可能是因为 o-QMs 通常是在碱性条件或酸性条件

下原位产生。如果是手性碱催化，则会带来酸碱中和或消旋的背景反应。而我

们通过水油两相，实现了水相中无机碱，和油相中的手性无机碱及油溶性底物

的空间分离，降低无机碱带来的背景反应，首次实现了碱催化的 o-QMs 手性催

化反应，为基于原位生成 o-QMs 的手性催化反应提供了新的策略，也为发展水

油两相反应提供了新的思路。

20

研究亮点之六

宽光谱响应光催化分解水制氢研究取得新进展

催化基础国家重点实验室及洁净能源国家实验室太阳能研究部李灿院士、

章福祥研究员和陈闪山等与日本东京大学 Kazunari Domen 教授课题组合作，在

可见光驱动光催化 Z 机制完全分解水制氢研究中取得进展。研究结果发现，经

一步氮化合成的 MgTa2O6−xNy/TaON 异质结材料(最长可吸收波长达 570 nm)可

有效促进光生电荷分离，基于此异质结材料构筑的宽光谱响应 Z 机制完全分解

水制氢体系，其表观量子效率达到目前文献报道最高值(AQE: 6.8%@420 nm)。

相关结果发表在《德国应用化学》(Angew. Chem. Int. Ed. 54 (2015) 8498)。

21

光催化分解水制氢是从根本上解决能源危机和环境污染的理想途径之一，

而宽光谱响应半导体材料的开发与应用是实现太阳能高效光化学转化的前提和

基础。近年来，李灿团队致力于新型宽光谱响应半导体材料的开发，通过对系

列层状或隧道状宽禁带半导体材料进行掺氮处理，实现了有效的宽光谱吸收和

利用，并从实验上证实了该类新型半导体为光催化分解水材料的可行性(J.

Mater. Chem. A 12 (2013) 5651；Chem. Commun. 50 (2014) 14415；Chin. J. Catal.

35 (2014) 1431)。然而，该类半导体材料仍存在着光生载流子分离效率低的问题。

基于此，该团队一直重视发展构筑异质结、异相结甚至晶面间电荷分离等策略

来从源头上提升材料的光生电荷分离效率。近日，他们进一步设计和发展一种

新的氮化合成策略，成功构筑基于掺氮化合物与氮氧化物的MgTa2O6−xNy/TaON

异质结结构，可大幅提升光生电荷的分离效率和光催化 Z 机制完全分解水制氢

性能，取得了文献报道的粉末光催化 Z 机制分解水体系中最高表观量子效率。

本研究不仅提供了异质结构筑的新方法，而且打通了从新型材料研发到完全分

解水制氢的链条，为今后进一步发展高效可见光完全分解水制氢过程奠定了基

础。

22

研究亮点之七

实现半导体单晶粒子光催化剂上光生电荷

分离各向异性的原位光电成像

催化基础国家重点实验室及洁净能源国家实验室太阳能研究部李灿院士、

所百人计划学者范峰滔研究员和博士生朱剑等在国际上利用自主研制的纳米表

面光电压成像系统，首次实现了单个光催化剂粒子不同晶面的光生电荷的光电

成像，发现半导体粒子不同晶面间存在不同的空间电荷层内建电场可以促进光

生电荷的高度各向异性分离。相关结果发表在《德国应用化学》(Angew. Chem.

Int. Ed. 54 (2015) 9111)。

光催化分解水被普遍认为是未来解决能源危机和环境污染的理想途径之一，

而光生电子-空穴有效分离是实现太阳能光-化学高效转化的关键。构建有效的

23

光生电荷分离及传输的光电体系已成为发展高效人工光合成催化体系的重要措

施，是这一领域科学家努力的重要方向。近年来，李灿院士研究团队为解决这

一核心科学问题进行了不懈努力：通过构筑 CdS/MoS2 异质结取得比传统贵金

属 Pt 负载的 Pt/CdS 光催化剂更好的光催化制氢活性(J. Am. Chem. Soc. 130

(2008) 7176)；利用紫外拉曼光谱对表面物相灵敏的特点，在国际上首次报道构

筑 TiO2不同相之间的表面“异相结”可大幅度提升光催化产氢的活性；以此为基

础，发现以 α,β-Ga2O3为基础的半导体光催化剂构筑的“异相结”可以促进光催化

分解纯水制氢性能，并利用超快光谱初步揭示了其提高光催化活性的本质

(Angew. Chem. Int. Ed. 51 (2012) 13089)；随后，研究组发现具有规则晶面暴露

的BiVO4半导体光催化材料在不同晶面间存在光生电荷分离效应(Nature Comm.

4 (2013) 1432)。

为了更深入地揭示上述体系的关键科学问题——光生电荷分离和迁移的空

间特性，该团队自行发展了针对微纳尺度、单个半导体催化剂晶粒表面光生电

荷空间分布研究的纳米光电成像系统——空间分辨的表面光电压谱。研究人员

利用该仪器观察到 BiVO4粒子上不同晶面的表面电势差异。在光激发下，空间

分辨表面光电压谱揭示出半导体粒子不同晶面存在不同的空间电荷层内建电

场。这种电场的存在可以使单晶粒半导体光催化剂显示超过 70 倍差别的空穴迁

移各向异性，并进一步利用荧光成像佐证了该结果。这种内在物理特性可能是

光生电荷在不同晶面间分离的主要原因。该项工作从微纳尺度上揭示了光催化

剂光生电荷的分离本质，为进一步发展高效太阳能光催化制氢和二氧化碳还原

等人工光合体系提供了科学基础。

24

研究亮点之八

分子筛膜研究取得新进展

催化基础国家重点实验室杨维慎研究员领导的科研团队在分子筛膜合成研

究中取得新进展，利用自行开发的电化学离子热合成方法，原位合成出了具有

优异防腐蚀性能的高度面内取向和无缺陷的分子筛膜。相关结果以通讯形式发

表在《德国应用化学》(Angew. Chem. Int. Ed. 54 (2015) 13032)。

分子筛膜已广泛应用于分离、催化和功能涂层等。然而这些应用都对膜的

取向和缺陷有着很高的要求。在分子筛膜合成领域中，最大的难题在于如何采

用简单的方法合成出高度取向和无缺陷的膜，这也是它大规模应用的关键所在。

目前制备分子筛膜的方法主要有原位结晶法和晶种法。原位结晶法的优势在于

其简单，然而通常得到的是无取向且有大量缺陷的低性能膜。晶种法则将晶体

成核过程和膜生长步骤分开来，通过多步精确控制晶种的微结构或者其在基底

上的预修饰，来获得高度取向和无缺陷的分子筛膜，但是其步骤繁琐，不利于

工业放大。

25

针对上述问题，该研究团队利用外加电场可控的特点，结合离子液体电化

学窗口宽、蒸气压低和热力学稳定性高的特性，成功开发出了原位电化学离子

热合成方法。以金属铝电极作为基底，通过电化学手段活化基底表面而加速其

与磷酸反应来提供铝源，同时利用带负电荷的基底来静电吸附作为模板剂的离

子液体阳离子，在敞口条件下一步合成出高度面内取向的 AlPO4-11 分子筛膜。

值得说明的是，这种电化学合成机理确保了所合成分子筛膜的无缺陷性。直流

极化曲线测试进一步表明，该面内取向分子筛膜没有缺陷并具有优异的防腐蚀

性能。该方法简单、可控、易放大，未来有工业化的可能。

26

研究亮点之九

金属有机骨架分子筛膜研究取得新进展

催化基础国家重点实验室杨维慎研究员和李砚硕研究员带领的研究团队在

金属有机骨架（Metal-organic frameworks, MOFs）分子筛膜领域取得新进展，

研究成果以通讯形式发表于《德国应用化学》(Angew. Chem. Int. Ed. 54 (2015)

15483)。

MOFs 是一类极具潜力的膜分离材料。然而，MOFs 材料的骨架柔性极大

降低了孔道本身的动力学筛分及截留能力，对尺寸相近的气体较难实现基于分

子尺寸的精确筛分。因此，如何实现对 MOFs 材料孔道的精细调变，特别是孔

径的有效调节，是 MOFs 材料在气体分子筛分领域取得突破的关键。研究团队

首次提出“笼占据”来调变 MOFs 材料的笼径，即将空间位阻显著的离子液体（IL）

27

限域负载到 ZIF-8 笼中（IL@ZIF-8），使分子截留关口由常规孔窗转变为空

间受阻孔笼，从而实现对 MOFs 材料分子筛分性能的精确调变。研究团队与

北京化工大学仲崇立教授和阳庆元教授团队合作，理论模拟了材料的笼径变化，

以及离子液体与主体材料的相互作用。

在上述研究基础上，该团队将 IL@ZIF-8 纳米基元与聚合物复合成有机-无

机复合膜，其对 CO2/CH4 和 CO2/N2 混合气体的分离性能显著提高，突破了聚

合物膜的分离性能上限。该项研究不仅在天然气纯化和 CO2燃烧后捕获领域展

现出良好的应用前景，而且有望拓展到其他基于 MOFs 材料的选择性吸附和膜

分离研究中。

28

综述文章之一

木质素催化转化

催化基础国家重点实验室兼聘研究员张涛院士带领的团队在生物质催化转

化领域的系列研究工作受到了国际同行的广泛关注。受邀在 Chemical Reviews

杂志上发表题目为“Catalytic Transformation of Lignin for the Production of

Chemicals and Fuels”的综述文章（Chem. Rev. 115 (2015) 11559）。

木质素是以苯丙烷单元为结构主体的三维网状聚合物，化学性质非常顽固。

作为木质纤维素资源的主要组成部分，木质素占植物干重的 15-30%，具有比纤

维素更高的能量密度，是自然界中唯一可以直接提供芳香环单体的可再生资源。

将木质素催化转化为有重要价值的芳香族化学品和燃料，兼具科学意义和应用

前景。

29

该综述文章首先对木质素结构、性质和分离方法进行了系统阐述，随后根

据木质素催化转化不同解聚策略，总结了酸碱催化解聚、热解、涉氢转化、氧

化解聚、气化、液相重整等最新研究进展。在此基础上，对木质素结构解析新

技术、不同解聚方法的催化反应机理和催化剂设计进行了归纳对比，提出了木

质素催化转化的难点和未来发展趋势。该综述将为发展新的木质素催化转化路

线以及设计更为高效稳定的催化剂体系提供有益参考，同时对生物质催化炼制

技术的发展起到促进作用。

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1. A Schiff base modified gold catalyst for green and efficient H2 production from formic acidQinggang Liu, Xiaofeng Yang, Yanqiang Huang*, Shutao Xu, Xiong Su, Xiaoli Pan,Jinming Xu, Aiqin Wang, Changhai Liang, Xinkui Wang*,Tao Zhang*Energy & Environmental Science 8(2015)3204-3207·····················································56

2. Achieving overall water splitting using titanium dioxide-based photocatalysts of different phasesRengui Li, Yuxiang Weng, Xin Zhou, Xiuli Wang, Yang Mi, Ruifeng Chong,Hongxian Han, Can Li*Energy & Environmental Science 8(2015)2377-2382·····················································57

3. High efficiency flexible perovskite solar cells using superior low temperature TiO2

Dong Yang, Ruixia Yang, Jing Zhang, Zhou Yang, Shengzhong (Frank) Liu*, Can Li*Energy & Environmental Science 8(2015)3208-3214 ·····················································58

4. Triggering the electrocatalytic hydrogen evolution activity of the inert two-dimensional MoS2 surface via single-atom metal dopingJiao Deng, Haobo Li, Jianping Xiao, Yunchuan Tu, Dehui Deng*, Huaixin Yang, Huanfang Tian, Jianqi Li, Pengju Ren, Xinhe Bao*Energy & Environmental Science 8(2015)1594-1601·····················································59

5. Nanoparticles at grain boundaries inhibit the phase transformation of perovskite membraneYan Liu, Xuefeng Zhu, Mingrun Li, Ryan P. O’Hayre, Weishen Yang*Nano Letters 15(2015)7678-7683················································································60

6. Confinement of ionic liquids in nanocages: Tailoring the molecular sieving properties of ZIF-8 for membrane-based CO2 captureYujie Ban, Zhengjie Li, Yanshuo Li*, Yuan Peng, Hua Jin, Wenmei Jiao, Ang Guo, Po Wang, Qingyuan Yang*, Chongli Zhong, Weishen Yang*Angewandte Chemie International Edition 54(2015)15483-15487····································61

7. Efficient visible-light-driven z-scheme overall water splitting using a MgTa2O6-xNy/TaON heterostructure photocatalyst for H2 evolutionShanshan Chen, Yu Qi, Takashi Hisatomi, Qian Ding, Tomohiro Asai, Zheng Li,Su Su Khine Ma, Fuxiang Zhang*, Kazunari Domen, Can Li*Angewandte Chemie International Edition 127(2015)8618-8621······································62

8. Enhanced electron penetration through an ultrathin graphene layer for

31

highly efficient catalysis of the hydrogen evolution reactionJiao Deng, Pengju Ren, Dehui Deng*, Xinhe Bao*Angewandte Chemie International Edition 54(2015)2100-2104········································63

9. In situ electrochemical synthesis of oriented and defect-free AEL molecular-sieve films using ionic liquidsTongwen Yu, Wenling Chu, Rui Cai*, Yanchun Liu, Weishen Yang*Angewandte Chemie International Edition 54(2015)13032-13035····································64

10. Interface engineering of CoOx/Ta3N5 photocatalyst for unprecedented water oxidation performance under visible light irradiationShanshan Chen, Shuai Shen, Guiji Liu, Yu Qi, Fuxiang Zhang*, Can Li*Angewandte Chemie International Edition 54(2015)3047-3051········································65

11. Lithium imide synergy with 3d transition-metal nitrides leading to unprecedented catalytic activities for ammonia decompositionJianping Guo, Peikun Wang, Guotao Wu, Anan Wu, Daqiang Hu, Zhitao Xiong, Junhu Wang, Pei Yu, Fei Chang, Zheng Chen, Ping Chen*Angewandte Chemie International Edition 54(2015)2950-2954········································66

12. Efficiency improved for inverted polymer solar cells with electrostatically self-assembled BenMeIm-Cl ionic liquid layer as cathode interface layerPing Fu, Linquan Huang, WeiYu, Dong Yang, Guiji Liu, Lingyu Zhou, Jian Zhang*, Can Li*Nano Energy 13(2015)575-282···················································································67

13. High-density iron nanoparticles encapsulated within nitrogen-doped carbon nanoshell as efficient oxygen electrocatalyst for zinc-air batteryJing Wang, Haihua Wu, Dunfeng Gao, Shu Miao, Guoxiong Wang*, Xinhe Bao*Nano Energy 13(2015)387-396···················································································68

14. Photovoltaic device based on TiO2 rutile/anatase phase junctions fabricated in coaxial nanorod arraysPengli Yan, XiangWang, Xiaojia Zheng, Rengui Li, Jingfeng Han, Jingying Shi, Ailong Li, Yang Gan*, Can Li*Nano Energy 15(2015)406-412···················································································69

15. Synthesis of oriented TiO2 nanocones with fast charge transfer for perovskite solar cellsDong Zhong, Bing Cai, Xiuli Wang, Zhou Yang, Yedi Xing, Shu Miao, Wenhua Zhang*, Can Li*Nano Energy 11(2015)409-418···················································································70

16. Ag alloyed Pd single-atom catalysts for efficient selective hydrogenation of acetylene to ethylene in excess ethyleneGuang Xian Pei Xiao Yan Liu, Aiqin Wang*, Adam F. Lee, Mark A. Isaacs, Lin Li,Xiaoli Pan, Xiaofeng Yang, Xiaodong Wang, Zhijun Tai, Karen Wilson, Tao Zhang*ACS Catalysis 5(2015)3717-3725················································································71

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17. Cerium-oxide-modi��������������� �-noble metal catalyst for selective decomposition of hydrous hydrazine to hydrogenLei He, Binglian Liang, Lin Li, Xiaofeng Yang, Yanqiang Huang*, Aiqin Wang, Xiaodong Wang, Tao ZhangACS Catalysis 5(2015)1623-1628················································································72

18. Co-N-C catalyst for C-C coupling reactions: On the catalytic performance and active sitesLeilei Zhang, Aiqin Wang*, Wentao Wang, Yanqiang Huang, Xiaoyan Liu, Shu Miao, Jingyue Liu*, Tao Zhang*ACS Catalysis 5(2015)6563-6572················································································73

19. Highly active MnN-Li2NH composite catalyst for producing COx-free hydrogenJianping Guo, Fei Chang, Peikun Wang, Daqiang Hu, Pei Yu, Guotao Wu, Zhitao Xiong, Ping Chen*ACS Catalysis 5(2015)2708-2713················································································74

20. Tailoring the oxidation activity of Pt nanoclusters via encapsulationFan Zhang, Feng Jiao, Xiulian Pan*, Kang Gao, Jianping Xiao, Shuo Zhang, Xinhe Bao*ACS Catalysis 5(2015)1381-1385················································································75

21. Versatile nickel-lanthanum(III) catalyst for direct conversion of cellulose to glycolsRuiyan Sun, Tingting Wang, Mingyuan Zheng*, Weiqiao Deng*, Jifeng Pang, Aiqin Wang, Xiaodong Wang,Tao Zhang*ACS Catalysis 5(2015)874-883···················································································76

22. Well-defined BiOCl colloidal ultrathin nanosheets: Synthesis, characterization, and application in photocatalytic aerobic oxidation of secondary aminesYihui Wu, Bo Yuan, Mingrun Li, Wenhua Zhang* Yan Liu*, Can Li*Chemical Science 6(2015)1873-1878···········································································77

23. From layered zeolite precursors to zeolites with a three-dimensional porosity: Textural and structural modifications through alkaline treatmentTrees De Baerdemaeker, Mathias Feyen, Thomas Vanbergen, Ulrich Mu � ��,Bilge Yilmaz, Feng-Shou Xiao, Weiping Zhang, Toshiyuki Yokoi, Xinhe Bao, Dirk E. De Vos*, Hermann GiesChemistry of Materials 27(2015)316-326·····································································78

24. Self-assembly of atomically thin and unusual face-centered cubic Re nanowires within carbon nanotubesFan Zhang, Pengju Ren, Xiulian Pan,* Jingyue Liu,* Mingrun Li, Xinhe BaoChemistry of Materials 27(2015)1569-1573··································································79

25. Polymer@silica composites with tunable outer and inner surface properties: A platform for aqueous asymmetric transfer hydrogenationXiaoming Zhang, Yaopeng Zhao, Juan Peng, Qihua Yang*Green Chemistry 17(2015)1899-1906··········································································80

33

26. Conversion of biomass derivatives to electricity in photo fuel cells using undoped and tungsten-doped bismuth vanadate photoanodesBingqing Zhang, Jingying Shi, Chunmei Ding, Ruifeng Chong, Bao Zhang,Zhiliang Wang, Ailong Li, Zhenxing Liang, Shijun Liao*, Can Li*ChemSusChem 8(2015)4049-4055···············································································81

27. Enhancing the performance of amorphous-silicon photoanodes for photoelectrocatalytic water oxidationWei Qin, Nan Wang, Tingting Yao, Shubo Wang, Hui Wang, Yuexian Cao, Shengzhong (Frank) Liu*, Can Li*ChemSusChem 8(2015)3987-3991···············································································82

28. Significantly enhanced separation using ZIF-8 membranes by partial conversion of calcined layered double hydroxide precursorsYi Liu*, Yuan Peng, Nanyi Wang, Yanshuo Li, Jia Hong Pan, Weishen Yang, Jürgen CaroChemSusChem 8(2015)3582-3586···············································································83

29. A new Pb(IV)-based photocathode material Sr2PbO4 with good light harvesting abilityDan Zhao, Jingfeng Han, Junyan Cui, Xu Zong, Can Li*Journal of Materials Chemistry A 3(2015)12051-12058··················································84

30. Alternating precursor layer deposition for highly stable perovskite films towards efficient solar cells using vacuum depositionDong Yang, Zhou Yang, Wei Qin, Yuliang Zhang, Shengzhong (Frank) Liu*, Can Li*Journal of Materials Chemistry A 3(2015)9401-9405·····················································85

31. Controllable synthesis of silicon nano-particles using a one-step PECVD-ionic liquid strategyWei Qin,Shimin Cheng, Bin Zhou, Yihui Wu, Shengzhong(Frank) Liu, Can Li*Journal of Materials Chemistry A 3(2015)10233-10237··················································86

32. Covalent triazine framework-supported palladium nanoparticles for catalytic hydrogenation of N-heterocyclesTeng He*, Lin Liu, Guotao Wu, Ping ChenJournal of Materials Chemistry A 3(2015)16235 ···························································87

33. Efficiency exceeding 10% for inverted polymer solar cells with ZnO/ionic liquid combined cathode interfacial layerWei Yu, Lei Huang, Dong Yang, Ping Fu, Lingyu Zhou, Jian Zhang*, Can Li*Journal of Materials Chemistry A 3(2015)10660-10665··················································88

34. In situ growth and assembly of microporous aluminophosphate nanosheets into ordered architectures at low temperature and their enhanced catalytic performanceBeibei Gao, Peng Tian, Mingrun Li, Miao Yang, Yuyan Qiao, Linying Wang,Shutao Xu Zhongmin Liu*Journal of Materials Chemistry A 3(2015)7741-7749·····················································89

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35. Lithium amidoborane hydrazinates: synthesis, structure and hydrogen storage propertiesTeng He, Hui Wu, Guotao Wu*, Zhao Li, Wei Zhou, Xiaohua Ju, Dong Xie, Ping ChenJournal of Materials Chemistry A 3(2015)10100-10106··················································90

36. The shape effect of TiO2 in VOx/TiO2 catalysts for selective reduction of NO by NH3

Quanquan Shi,a Yong Li*, Yan Zhou, Shu Miao, Na Ta, Ensheng Zhan, Jingyue (Jimmy) Liu*, Wenjie Shen*Journal of materials chemistry A 3(2015)14409-14415···················································91

37. Theoretical insight into the roles of cocatalysts in the Ni-�����-Ga2O3

photocatalyst for overall water splittingTaifeng Liu, Ionut Tranca, Jingxiu Yang, Xin Zhou*, Can Li*Journal of Materials Chemistry A 3(2015)10309-10319··················································92

38. Three dimensional palladium nanoflowers with enhanced electrocatalytic activity towards the anodic oxidation of formic acidBingqing Zhang, Hongliang Peng, Lijun Yang, Hualing Li, Haoxiong Nan, Zhenxing Liang, Huiyu Song, Huaneng Su, Can Li*, Shijun Liao*Journal of Materials Chemistry A 3(2015)973-977·························································93

39. Zinc-cobalt oxides as efficient water oxidation catalysts: The promotion effect of ZnOFeng Rong, Jiao Zhao, Panpan Su, Yi Yao, Mingrun Li,Qihua Yang*, Can Li*Journal of Materials Chemistry A 3(2015)4010-4017·····················································94

40. Protonated titanate nanotubes as a highly active catalyst for the synthesis of renewable diesel and jet fuel range alkanesShanshan Li, Ning Li*, Guangyi Li, Lin Li, Aiqin Wang, Yu Cong,Xiaodong Wang, Guoliang Xu, Tao Zhang*Applied Catalysis B: Environmental 170(2015)124-134··················································95

41. Ultrastable single-atom gold catalysts with strong covalent metal-support interaction (CMSI)Botao Qiao, Jin-Xia Liang, Aiqin Wang, Cong-Qiao Xu, Jun Li*, Tao Zhang*, Jingyue (Jimmy)Liu*Nano Research 8(2015)2913-2924 ··············································································96

42. Highly dispersed Fe2O3 on carbon nanotubes for low temperature selective catalytic reduction of NO with NH3

Zhenping Qu*, Lei Miao, Hui Wang, Qiang FuChemical Communications 51(2015)956-958································································97

43. Little do more: a highly effective Pt1/FeOx single-atom catalyst for the reduction of NO by H2

Jian Lin, Botao Qiao, Ning Li, Lin Li, Xiucheng Sun, Jingyue Liu,Xiaodong Wang*, Tao Zhang*Chemical Communications 51(2015)7911-7914 ····························································98

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44. N-doped graphene as an electron donor of iron catalysts for CO hydrogenation to light olefinsXiaoqi Chen, Dehui Deng*, Xiulian Pan, Yongfeng Hu, Xinhe Bao*Chemical Communications 51(2015)217-220································································99

45. Photoelectrochemical water splitting promoted with a disordered surface layer created by electrochemical reductionPengli Yan, Guiji Liu, Chunmei Ding, Hongxian Han, Jingying Shi, Yang Gan*, Can Li*ACS Applied Materials & Interfaces 7(2015)3791-3796················································100

46. Preparation of nitrogen-doped carbon nanotubes with different morphologies from melamine-formaldehyde resinYi Yao, Bingqing Zhang, Jingying Shi, Qihua Yang*ACS Applied Materials & Interfaces 7(2015)7413-7420················································101

47. Ammonia borane assisted solid exfoliation of graphite fluoride for facile synthesis of fluorinated graphene nanosheetsLin Liu, Miao Zhang, Zhitao Xiong, Daqiang Hu, Guotao Wu, Ping Chen*Carbon 81(2015)702-709·························································································102

48. A facile top-down protocol for postsynthesis modification of hierarchical aluminum-rich MFI zeolitesLili Yu, Shengjun Huang*, Shu Miao, Fucun Chen, Shuang Zhang, Zhenni Liu, Sujuan Xie, Longya Xu*Chemistry-A European Journal 21(2015)1048-1054·····················································103

49. Efficient hole extraction from a hole-storage-layer-stabilized tantalum nitride photoanode for solar water splittingGuiji Liu, Ping Fu, Lingyu Zhou, Pengli Yan, Chunmei Ding, Jingying Shi*, Can Li*Chemistry-A European Journal 21(2015)9624-9628·····················································104

50. Fabrication of efficient hydrogenation nanoreactors via modifying the freedom of ultrasmall Pt NPs within yolk-shell nanospheresJuan Peng, Guojun Lan, Miao Guo, Xuming Wei, Can Li*, Qihua Yang*Chemistry-A European Journal 21(2015)10490-10497··················································105

51. Monodisperse AgSbS2 nanocrystals: Size-control strategy, large-scale synthesis, and photoelectrochemistryBin Zhou, Mingrun Li, Yihui Wu, Chi Yang, Wen-Hua Zhang*, Can Li*Chemistry-A European Journal 21(2015)11143-11151··················································106

52. Asymmetric hydrogenation by RuCl2(R-binap)(dmf)n encapsulated in silica-based nanoreactorsJuan Peng, Xuefeng Wang, Xiaoming Zhang, Shiyang Bai, Yaopeng Zhao,Can Li*, Qihua Yang*Catalytic Science & Technology 5(2015)666-672·························································107

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53. Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenationXu Wang, Shengmei Lu, Jun Li, Yan Liu*, Can Li*Catalytic Science & Technology 5(2015)2585-2589······················································108

54. Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particlesEnsheng Zhan, Chunhui Chen, Yong Li, Wenjie Shen*Catalysis Science & Technology 5(2015)650-659·························································109

55. Redox properties and catalytic performance of ceria-zirconia nanorodsAling Chen, Yan Zhou, Na Ta, Yong Li, Wenjie Shen*Catalysis Science & Technology 5(2015)4184-4192····················································· 110

56. Degradation and stabilization of perovskite membranes containing silicon impurity at low temperatureYan Liu, Xuefeng Zhu*, Mingrun Li, Wenping Li , Weishen Yang*Journal of Membrane Science 492(2015)173-180·························································111

57. Mixed matrix membranes in corporated with amine-functionalized titanium-based metal-organic frame work for CO2/CH4 separationXiangyu Guo, Hongliang Huang, Yujie Ban, Qingyuan Yang*, Yuanlong Xiao, Yanshuo Li*, Weishen Yang, Chongli ZhongJournal of Membrane Science 478(2015)130-139························································ 112

58. Synergetic effect of conjugated Ni(OH)2/IrO2 cocatalyst on titanium-doped hematite photoanode for solar water splittingZhiliang Wang, Guiji Liu, Chunmei Ding, Zheng Chen, Fuxiang Zhang, Jingying Shi, Can Li*Journal of Physical Chemistry C 119(2015)19607-19612············································· 113

59. Ultrasmall single micelle@resin core-shell nanocarriers as efficient cargo loading vehicles for in vivo biomedical applicationsYan Yang, Xiaojie Song, Yi Yao, Hao Wu, Jian Liu, Yaopeng Zhao, Mingqian Tan*, Qihua Yang*Journal of Materials Chemistry B 3(2015)4671-4678················································ 114

60. Metathesis of 1-butene to propene over Mo/Al2O3@SBA-15: Influence of alumina introduction methods on catalytic performanceDazhou Zhang, Xiujie Li*, Shenglin Liu, Xiangxue Zhu, Fucun Chen, Longya Xu*Chemistry-An Asian Journal 10(2015)1647-1659························································ 115

61. One-step preparation of optically transparent Ni-Fe oxide film electrocatalyst for oxygen evolution reactionDoudou Zhang, Lijian Meng, Jingying Shi*, Nan Wang, Shengzhong Liu*, Can LiElectrochimica Acta 169(2015)402-408····································································· 116

62. Microemulsion-controlled synthesis of one-dimensional Ir nanowires and their catalytic activity in selective hydrogenation of o-chloronitrobenzene

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Ting Lu, Haisheng Wei, Xiaofeng Yang, Jun Li, Xiaodong Wang*, Tao ZhangLangmuir 31(2015)90-95························································································· 117

63. Vanadia directed synthesis of anatase TiO2 truncated bipyramids with preferential exposure of the reactive {001} facetQuanquan Shi, Yong Li*, Ensheng Zhan, Na Ta, Wenjie Shen*CrystEngComm 17(2015)3376-3382·········································································· 118

64. Alkali treatment upon MCM-49 zeolite with various contents of HMI in the presence of CTAB and application in anisole acylation withacetic anhydrideHuijuan Wei, Sujuan Xie, Ningning Gao, Kefeng Liu, Xiaohang Liu,Wenjie Xin, Xiujie Li, Shenglin Liu, Longya Xu*Applied Catalysis A: General 495(2015)152-161························································· 119

65. An approach to prepare nanosized HZSM-22 with enhanced lifetime in the methanol to hydrocarbons (MTH) reactionJinbang Wang, Shutao Xu,Jinzhe Li,Yuchun Zhi,Mozhi Zhang,Yanli He,Yingxu Wei*, Xinwen Guo, Zhongmin Liu*RSC Advances 5(2015)88928-88935·········································································· 120

66. Covalent triazine-based framework as an efficient catalyst support for ammonia decompositionFei Chang, Jianping Guo, Guotao Wu, Lin Liu, Miao Zhang, Teng He, Peikun Wang, Pei Yu, Ping Chen*,RSC Advances 5(2015)3605-3610············································································· 121

67. Cu2O/CuO photocathode with improved stability for photoelectrochemical water reductionJingfeng Han, Xu Zong, Xin Zhoua, Can Li*RSC Advances 5(2015)10790-10794·········································································· 122

68. Enhancing photoresponsivity of self-powered UV photodetectors based on electrochemically reduced TiO2 nanorodsPengli Yan, Yihui Wu, Guiji Liu, Ailong Li, Hongxian Han*, Zhaochi Feng,Jingying Shi, Yang Gan*, Can Li*RSC Advances 5(2015)95939-95942·········································································· 123

69. Formation of uniform hollow nanocages with heteroatom-doped MCM-41 structuresJiazhi Chen, Fang Lu*, Jie Xu*RSC Advances 5(2015)5068-5071············································································· 124

70. One-pot synthesis of NiAl-CO3 LDH anti-corrosion coatings from CO2-saturated precursorsYi Liu Tongwen Yu, Rui Cai, Yanshuo Li, Weishen Yang*, Jürgen CaroRSC Advances 15(2015)29552-29557········································································ 125

71. Polymorphous transformation of rod-shaped iron oxides and their catalytic properties in selective reduction of NO by NH3

38

Xuejiao Wei, Yan Zhou, Yong Li*, Wenjie Shen*RSC Advances 5(2015)66141-66146·········································································· 126

72. Preparing acid-resistant Ru-based catalysts by carbothermal reduction for hydrogenation of itaconic acidQianqian Huang, Weiqiang Yu*, Rui Lu, Fang Lu, Jin Gao, Hong Miao, Jie Xu*RSC Advances 5(2015)97256-97263·········································································· 127

73. Ultra-small Au nanoparticles stabilized by silica hollow nanospheres for styrene oxidation with oxygenYuanyuan Zheng, Xiaoming Zhang, Yi Yao, Xiaohong Chen*, Qihua Yang*RSC Advances 5(2015)105747-105752······································································ 128

74. Yolk-shell nanospheres with soluble aminopolystyrene as a reservoir for Pd NPsGuojun Lan, Xiaoming Zhang, Xiaomin Zhang, Mingrun Li, Ying Li*, Qihua Yang*RSC Advances 5(2015)35730-35736·········································································· 129

75. An efficient polymer solar cell using graphene oxide interface assembled via layer-by-layer depositionLingyu Zhou, Dong Yang, Wei Yu, Jian Zhang*, Can Li*Organic Electronics 23(2015)110-115······································································· 130

76. One-pot fabrication of yolk-shell nanospheres with ultra-small Au nanoparticles for catalysisYi Yao, Xiaoming Zhang, Juan Peng, Qihua Yang*Catalysis Communications 51(2015)3750-3753··························································· 131

77. Towards efficient chemical synthesis via engineering enzyme catalysis in biomimetic nanoreactorsJia Liu, Qihua Yang*, Can Li*Catalysis Communications 51(2015)13731-13739······················································· 132

78. Ultrastable 3V-PPh3 polymers supported single Rh sites for fixed-bed hydroformylation of olefinsMiao Jiang, Li Yan, Yunjie Ding*, Qi Sun, Jia Liu, Hejun Zhu, Ronghe Lin,Fengshou Xiao, Zheng Jiang, Jingyue Liu*Journal of Molecular Catalysis A: Chemical 404-405(2015)211-217······························ 133

79. Two-step thermochemical cycles for CO2 splitting on Zr-doped cobalt ferrite supported on silicaJinhui Tong, Qingqing Jiang, Zhenpan Chen, Zongxuan Jiang, Can Li*Solar Energy 116(2015)133-143··············································································· 134

80. A new zeolite formed from interlayer expansion of the precursor COK-5Chaoqun Bian, Qinming Wu, Jian Zhang, Fang Chen, Shuxiang Pan, Liang Wang, Xiangju Meng, Ulrich Müller, Mathias Feyen, Bilge Yilmaz, Hermann Gies, Weiping Zhang, Xinhe Bao, Dirk De Vos, Toshiyuki Yokoi, Takashi Tatsumi, Feng-Shou Xiao*

39

Microporous and Mesoporous Materials 214(2015)204-209········································· 135

81. Development of hierarchical MCM-49 zeolite with intracrystalline mesopores and improved catalytic performance in liquid alkylation of benzene with ethyleneNingning Gao, Sujuan Xie*, Shenglin Liu, Wenjie Xin, Yang Gao, Xiujie Li,Huijuan Wei, Hui Liu, Longya Xu*Microporous and Mesoporous Materials 212(2015)1-7················································ 136

82. HF-assisted synthesis of ultra-microporous [Mg3(OOCH)6] frameworks for selective adsorption of CH4 over N2

Jiangliang Hua, Tianjun Sun*, Xinyu Ren, Shudong Wang*Microporous and Mesoporous Materials 204(2015)73-80············································· 137

83. Ionothermal syntheses of transition-metal-substituted aluminophosphate molecular sieves in the presence of tetraalkylammonium hydroxidesDawei Li, Yunpeng Xu, Huaijun Ma, Renshun Xu, Yasong Wang, Hao Liu,Bingchun Wang, Zhijian Tian*Microporous and Mesoporous Materials 210(2015)125-132········································· 138

84. Ionothermal synthesis of a CHA-type aluminophosphate molecular sieve membrane and its formation mechanismXiaolei Li, Keda Li, Huaijun Ma, Renshun Xu, Shuo Tao, Zhijian Tian*Microporous and Mesoporous Materials 217(2015)54-62············································· 139

85. Synthesis of discrete aluminophosphate -CLO nanocrystals in a eutectic mixtureShuo Tao, Renshun Xu, Xiaolei Li, Dawei Li, Huaijun Ma, Donge Wang, Yunpeng Xu, Zhijian Tian*Journal of Colloid and Interface Science 451(2015)117-124········································· 140

86. Enhanced performance of solid oxide fuel cells by introducing a transition layer between nanostructured cathode and electrolyteKaiyue Zhu, Huanying Liu, Xuefeng Zhu, Yan Liu, Weishen Yang*International Journal of Hydrogen Energy 40(2015)501-508········································ 141

87. Mixed ionic-electronic conducting (MIEC) membranes for hydrogen production fromwater splittingWenping Li, Xuefeng Zhu*, Zhongwei Cao, Weiping Wang, Weishen Yang*International Journal of Hydrogen Energy 40(2015)3452-3461····································· 142

88. Pd and Pd-Ni alloy composite membranes fabricated by electroless plating ���� �� �����������-Al2O3 substratesHui Lu*, Linlin Zhu, Weiping Wang, Weishen Yang, Jianhua Tong*International Journal of Hydrogen Energy 40(2015)3548-3556····································· 143

89. Synthesis, structures and dehydrogenation of magnesium borohydrideeethylenediamine compositesJuner Chen, Yong Shen Chua, Hui Wu, Zhitao Xiong, Teng He, Wei Zhou, Xiaohua Ju, Minghui Yang, Guotao Wu*, Ping Chen*,

40

International Journal of Hydrogen Energy 40(2015)412-419········································ 144

90. The synthesis, structure and dehydrogenation of calcium borohydride hydrazinatesZhao Li, Teng He*, Guotao Wu, Xiaohua Ju, Ping Chen*International Journal of Hydrogen Energy 40(2015)5333-5339····································· 145

91. Higher-order human telomeric G-quadruplex DNA metalloenzymes enhance enantioselectivity in the diels-alder reactionYinghao Li, Guoqing Jia, Changhao Wang, Mingpan Cheng, Can Li*ChemBioChem 16(2015)618-624·············································································· 146

92. Asymmetric dual-phase membranes prepared via tape-casting and co-lamination for oxygen permeationZhongwei Cao, Xuefeng Zhu*, Wenping Li, Bing Xu, Lina Yang*, Weishen YangMaterials Letters 147(2015)88-91············································································· 147

93. Ionic liquid assisted hydrothermal synthesis of hollow core/shell MoS2 microspheresJiahe Li, DongeWang, Huaijun Ma, Zhendong Pan, Yuxia Jiang, Min Li,Zhijian Tian*Materials Letters 160(2015)550-554········································································· 148

94. Ball-milling MoS2/carbon black hybrid material for catalyzing hydrogen evolution reaction in acidic mediumJiayuan Li, Dunfeng Gao, Jing Wang, Shu Miao, Guoxiong Wang*, XinheBao*Journal of Energy Chemistry 24(2015)608-613··························································· 149

95. Liquid organic hydrogen carriersTeng He, Qijun Pei, Ping Chen*Journal of Energy Chemistry 24(2015)587-594··························································· 150

96. Synthesis and characterization of anatase TiO2 nanosheet arrays on FTO substrateDong Zhong, Qike Jiang, Baokun Huang, Wenhua Zhang*, Can Li*Journal of Energy Chemistry 24(2015)626-631··························································· 151

97. Recovery of HMF from aqueous solution by zeolitic imidazolate frameworksHua Jin, Yanshuo Li*, Xinlei Liu, Yujie Ban, Yuan Peng, Wenmei Jiao, Weishen Yang*Chemical Engineering Science 124(2015)170-178······················································· 152

98. Highly active Au1/Co3O4 single-atom catalyst for CO oxidation at room temperatureBotao Qiao, Jian Lin, Aiqin Wang, Yang Chen, Tao Zhang*, Jingyue LiuChinese Journal of Catalysis 36(2015)1505-1511························································ 153

99. Highly hydrothermally stable FePO4-SBA-15 synthesized using a novel one-pot hydrothermal methodRunqin Wang, Ronghe Lin, Yunjie Ding*, Jia Liu, Wenting Luo, Hong Du, Yuan LüChinese Journal of Catalysis 36(2015)446-453··························································· 154

41

100. Ionothermal synthesis of zeolitic imidazolate frameworks and the synthesis dissolution-crystallization mechanismYasong Wang, Yunpeng Xu, Dawei Li, Hao Liu, Xiaolei Li, Shuo Tao, Zhijian Tian*Chinese Journal of Catalysis 36(2015)855-865··························································· 155

101. Iron catalyst encapsulated in carbon nanotubes for CO hydrogenation to light olefinsXiaoqi Chen, Dehui Deng*, Xiulian Pan, Xinhe Bao*Chinese Journal of Catalysis 36(2015)1631-1637························································ 156

102. Porous carbon in catalytic transformation of celluloseXiaochen Zhao, Jinming Xu, Aiqin Wang, Tao Zhang *Chinese Journal of Catalysis 36(2015)1419-1427························································ 157

103. Rh-PPh3-polymer@mesosilica composite catalyst for the hydroformylation of 1-octeneXiaoming Zhang, Shengmei Lu, Mingmei Zhong, Yaopeng Zhao, Qihua Yang*Chinese Journal of Catalysis 36(2015)168-174··························································· 158

104. Supported Au-Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenesHaisheng Wei, Xing Wei, Xiaofeng Yang, Guangzhao Yin, Aiqin Wang*, Xiaoyan Liu, Yanqiang Huang, Tao Zhang*Chinese Journal of Catalysis 36(2015)160-167··························································· 159

105. Tailored one-pot production of furan-based fuels from fructose in an ionic liquid biphasic solvent systemChangzhi Li, Haile Cai, Bo Zhang, Weizhen Li, Guangxian Pei, Tao Dai, Aiqin Wang, Tao Zhang*Chinese Journal of Catalysis 36(2015)1638-1646························································ 160

106. Tuning the catalytic behavior of metal nanoparticles: The issue of the crystal phaseShuang Liu, Yong Li*, Wenjie Shen*Chinese Journal of Catalysis 36(2015)1409-1418························································ 161

107. Facile oxygen intercalation of full layer graphene grown on Ru(0001) under ambient conditionsAiyi Dong, Qiang Fu*, Mingming Wei, Yun Liu, Yanxiao Ning, Fan Yang, Hendrik Bluhm, Xinhe BaoSurface Science 634(2015)37-43··············································································· 162

108. Fabrication of ZnO with tunable morphology through a facile treatment of Zn-based coordination polymersPanpan Su, Jiao Zhao, Feng Rong, Can Li*, Qihua Yang*Science China Chemistry 58(2015)411-416································································ 163

109. Experimental evaluation of the adsorption, diffusion and separation of CH4/N2 and CH4/CO2 mixtures on Al-BDC MOFTianjun Sun, Jiangliang Hu, Xinyu Ren, Shudong WangSeparation Science and Technology 50(2015)874-885·················································· 164

42

110.,

34(2015)1501-1510················································································· 165

111. CH4/N2, , , *

35(2015)23-29························································································ 166

112. Catalytic reaction processes revealed by scanning probe microscopyPeng Jiang*, Xinhe Bao, Miquel SalmeronAccounts of Chemical Research 48(2015)1524-1531···················································· 167

113. Hexagonal boron nitride cover on Pt(111): A new route to tune moleculemetal interaction and metal-catalyzed reactionsYanhong Zhang, Xuefei Weng Huan Li, Haobo Li, Mingming Wei, Jianping Xiao, Zhi Liu, Mingshu Chen*, Qiang Fu*, Xinhe BaoNano Letters 15(2015)3616-3623·············································································· 168

114. Creating a nanospace under an h-BN cover for adlayer growth on nickel(111)Yang Yang, Qiang Fu*, Haobo Li, Mingming Wei, Jianping Xiao, Wei Wei, Xinhe BaoACS Nano 9(2015)11589-11598 ··············································································· 169

115. Towards fundamentals of confined catalysis in carbon nanotubesJianping Xiao, Xiulian Pan,* Shujing Guo, Pengju Ren, Xinhe Bao*Journal of the American Chemical Society 137(2015)477-482······································· 170

116. Monolayer MoS2 growth on Au foils and on-site domain boundary imagingJianping Shi, Yang Yang, Yu Zhang, Donglin Ma, Wei Wei, Qingqing Ji, Yanshuo Zhang, Xiuju Song, Teng Gao, Cong Li, Xinhe Bao, Zhongfan Liu, Qiang Fu*, Yanfeng Zhang*Advanced Functional Materials 25(2015)842-849······················································· 171

117. Direct imaging of highly anisotropic photogenerated charge separations on different facets of a single BiVO4 photocatalystJian Zhu, Fengtao Fan, Ruotian Chen, Hongyu An, Zhaochi Feng, Can Li*Angewandte Chemie International Edition 54(2015)9111-9114····································· 172

118. Recent advances in the application of mossbauer spectroscopy in heterogeneous catalysisKuo Liu, Alexandre I.Rykova, Junhu Wang*, Tao Zhang*Advances in Catalysis 58(2015)1-142········································································ 173

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119. Exploring the ring current of carbon nanotubes by first-principles calculationsPengju Ren, Anmin Zheng, Jianping Xiao, Xiulian Pan, Xinhe Bao*Chemical Science 6(2015)902-908············································································ 174

120. Visualizing electronic interactions between iron and carbon by X-ray chemical imaging and spectroscopyXiaoqi Chen, Jianping Xiao, Jian Wang, Dehui Deng*, Yongfeng Hu, Jigang Zhou, Liang Yu, Thomas Heine, Xiulian Pan, Xinhe Bao*Chemical Science 6(2015)3262-3267········································································· 175

121. New insights into reaction mechanisms of ethanol steam reforming on Co-ZrO2

Junming Sun, Ayman M. Karim, Donghai Mei, Mark Engelhard, Xinhe Bao, Yong Wang*Applied Catalysis B: Environmental 162(2015)141-148················································ 176

122. Stability of BN/Ru(0001) interfaces in gaseous atmosphereYang Yang, Qiang Fu*, Mingming Wei, Hendrik Bluhm, Xinhe Bao*Nano Research 8(2015)227-237················································································ 177

123. Preferential cleavage of C-C bonds over C-N bonds at interfacial CuO-Cu2O sitesMin Wang, Xiangkui Gu, Haiyan Su, Jianmin Lu, Jiping Ma, Miao Yu, Zhe Zhang, Feng Wang*Journal of Catalysis 330(2015)458-464 ····································································· 178

124. Role of the Al chemical environment in the formation of silver species and its CO oxidation activityZhenping Qu*, Xiaodong Zhang, Fangli Yu, Xianchun Liu, Qiang FuJournal of Catalysis 321(2015)113-122 ····································································· 179

125. A remarkable difference in CO2 hydrogenation to methanol on Pd nanoparticles supported inside and outside of carbon nanotubesJijie Wang, Shengmei Lu, Jun Li, Can Li*Chemical Communications 51(2015)17615-17618······················································· 180

126. Direct electron transfer from photosystem II to hematite in a hybrid photoelectrochemical cellWangyin Wang, Zhiliang Wang, Qingjun Zhu, Guangye Han, Chunmei Ding, Jun Chen, Jianren Shen, Can Li*Chemical Communications 51(2015)16952-16955······················································· 181

127. Direct observation of DME carbonylation in the different channels of H-MOR zeolite by continuous-flow solid-state NMR spectroscopyTing He, Pengju Ren, Xianchun Liu, Shutao Xu, Xiuwen Hana, Xinhe Bao*Chemical Communications 51(2015)16868-16870······················································· 182

128. Electronic promoter or reacting species? The role of LiNH2 on Ru in catalyzing NH3 decompositionJianping Guo, Zheng Chen, Anan Wu*, Fei Chang, Peikun Wang, Daqiang Hu,

44

Guotao Wu, Zhitao Xiong, Pei Yu, Ping Chen*,Chemical Communications 51(2015)15161-15164······················································· 183

129. Hydrogen bonds distinction and activation on catalytic etherification of hydroxyl compoundsPenghua Che, Fang Lu*, Xin Nie, Yizheng Huang, Yanliang Yang, Feng Wang, Jie Xu*Chemical Communications 51(2015)1077-1080·························································· 184

130. Synergetic effect of dual cocatalysts on the activity of p-type Cu2O crystals with anisotropic facetsRengui Li, Xiaoping Tao, Ruotian Chen, Fengtao Fan, Can Li*Chemistry-A European Journal 21(2015)14337-14341················································· 185

131. Dynamic structural changes of SiO2 supported Pt-Ni bimetallic catalysts over redox treatments revealed by NMR and EPRSuochang Xu, Eric D. Walter, Zhenchao Zhao, Mary Y. Hu, Xiuwen Han, Jian Zhi Hu*, Xinhe Bao*························································································ 186Journal of Physical Chemistry C 119(2015)21219-21226

132. Effect of phase junction structure on the photocatalytic performance in overall water splitting: Ga2O3 photocatalyst as an exampleShaoqing Jin, Xiang Wang, Xiuli Wang, Minggang Ju, Shuai Shen, Wanzhen Liang, Yi Zhao, Zhaochi Feng, Helen Y. Playford, Richard I. Walton, Can Li*Journal of Physical Chemistry C 119(2015)18221-18228············································· 187

133. Investigation of the strong Brønsted acidity in a novel SAPO-type molecular sieve DNL-6Xiong Su, Shutao Xu, Peng Tian, Jinzhe Li, Anmin Zheng, Qiang Wang, Miao Yang, Yingxu Wei, Feng Deng, Zhongmin Liu*Journal of Physical Chemistry C 119(2015)2589-2596················································· 188

134. Modulation of surface chemistry of CO on Ni(111) by surface graphene and carbidic carbonMingming Wei, Qiang Fu*, Yang Yang, Wei Wei, Ethan Crumlin, Hendrik Bluhm, Xinhe BaoJournal of Physical Chemistry C 119(2015)13590-13597············································· 189

135. Nature of interface confinement effect in oxide/metal catalystsYanxiao Ning, Mingming Wei, Liang Yu, Fan Yang, Rui Chang, Zhi Liu, Qiang Fu*, Xinhe Bao*Journal of Physical Chemistry C 119(2015)27556-27561············································· 190

136. Relation between the photocatalytic and photoelectrocatalytic performance for the particulate semiconductor-based photoconversion systems with surface phase junction structureXiang Wang, Shaoqing Jin, Hongyu An, Xiuli Wang, Zhaochi Feng, Can Li*Journal of Physical Chemistry C 119(2015)22460-22464············································· 191

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137. Transient absorption spectroscopy of anatase and rutile: The impact of morphology and phase on photocatalytic activityXiuli Wang, Andreas Kafizas*, Xiaoe Li, Savio J. A. Moniz, Philip J. T. Reardon, Junwang Tang, Ivan P. Parkin, James R. Durrant*Journal of Physical Chemistry C 119(2015)10439-10447············································· 192

138. Water oxidation mechanism on alkaline-earth-cation containing birnessite-like manganese oxidesJingxiu Yang, Hongyu An, Xin Zhou*, Can Li*Journal of Physical Chemistry C 119(2015)18487-18494············································· 193

139. The nature of photogenerated charge separation among different crystal facets of BiVO4 studied by a density functional theoryTaifeng Liu, Xin Zhou, Michel Dupuis, Can Li*Physical Chemistry Chemical Physics 17(2015)23503-23510········································ 194

140. The kinetics and mechanism of photo-assisted Ag(I)-catalysed water oxidation with S2O8

2-

Lihong Yu, Jidan Wang, Dan Guo, Wansheng You*, Meiying Liu, Lancui Zhang, Can Li*Dalton Transactions 44(2015)710-717······································································· 195

141. The effect of Fe on Pt particle states in Pt/KL catalystsJie Songa, Huaijun Ma, Zhijian Tiana*, Lijun Yan, Zhusheng Xua,Qianhe Liu, Wei QuApplied Catalysis A: General 492(2015)31-37·····························································196

142. Directly probing redox-linked quinones in photosystem II membrane fragments via UV resonance Raman scatteringJun Chen*, MingdongYao, Cynthia V. Pagba, Yang Zheng, Liping Fei, Zhaochi Feng, BridgetteA. BarryBiochimica et Biophysica Acta 1874(2015)558-564······················································197

143. In-situ 31P MAS NMR probing of the active centers in Ti silicalite molecular sieveJianqin Zhuang*, Xiuwen Hanb, Xinhe BaoCatalysis Communications 62(2015)75-78··································································198

144. Structural stability and Lewis acidity of tetravalent Ti, Sn, or Zr-linkedinterlayer-expanded zeolite COE-4: A DFT studyHaichao Li, Juan Wang, Danhong Zhou, Dongxu Tian, Chuan Shi, Ulrich Müller, Mathias Feyen, Hermann Gies, Feng-Shou Xiao, Dirk De Vos, Toshiyuki Yokoi, Xinhe Bao, Weiping Zhang*Microporous and Mesoporous Materials 218(2015)160-166··········································199

145. Abnormal effects of cations (Li+, Na+, and K+) on photoelectrochemical and electrocatalytic water splittingChunmei Ding, Xin Zhou, Jingying Shi, Pengli Yan, Zhiliang Wang, Guiji Liu, Can Li*Journal of Physical Chemistry B 119(2015)3560-3566··················································200

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146. Degradation mechanism analysis of Ba0.5Sr0.5Co0.8Fe0.2O3-� membranes at intermediate-low temperaturesYan Liu, Xuefeng Zhu, Weishen Yang*AIChE Journal 61(2015)3879-3888···········································································201

147. Kinetic study of the competitive hydrogenation of glycolaldehyde and glucose on Ru/C with or without AMTJunying Zhang, Baolin Hou, Aiqin Wang, Zhenlei Li, Hua Wang, Tao ZhangAIChE Journal 61(2015)224-238···············································································202

148. UV Raman spectroscopic characterization of catalysts and catalytic active sitesShaoqing Jin, Zhaochi Feng, Fengtao Fan*, Can Li*Catalysis Letters 145(2015)468-481···········································································203

149. Catalytic oxidative dehydrogenation of n-butane over V2O5/MO-Al2O3 (M = Mg, Ca, Sr, Ba) catalystsBing Xu, Xuefeng Zhu*, Zhongwei Cao, Lina Yang*, Weishen YangChinese Journal of Catalysis 36(2015)1060-1067························································204

150. Charge separation promoted by phase junctions in photocatalystsYi Ma, Xiuli Wang, Can Li*Chinese Journal of Catalysis 36(2015)1519-1527························································205

151. A comparative study in structure and reactivity of “FeOx-on-Pt” and “NiOx-on-Pt” catalystsRentao Mu, Qiang Fu*, Xiaoguang Guo, Xuejun Xu, Dali Tan, Xinhe Bao*Science China Chemistry 58(2015)162-168·································································206

152. Oxygen intercalation under hexagonal boron nitride (h-BN) on Pt(111)Yanhong Zhang, Mingming Wei, Qiang Fu, Xinhe BaoScience Bulletin 60(2015)1572-1579··········································································207

153. Understanding nano effects in catalysisFan Yang, Dehui Deng, Xiulian Pan, Qiang Fu, Xinhe Bao*National Science Review 2(2015)183-201···································································208

154. Catalytic transformation of lignin for the production of chemicals and fuelsChangzhi Li, Xiaochen Zhao, Aiqin Wang, George W. Huber, Tao Zhang*Chemical Reviews 115(2015)11559-11624··································································209

155. Concise redox deracemization of secondary and tertiary amines with a tetrahydroisoquinoline core via a nonenzymatic processYue Ji, Lei Shi*, Muwang Chen, Guangshou Feng, Yonggui Zhou*

47

Journal of the American Chemical Society 137(2015)10496-10499·································210

156. Size-dependent electrocatalytic reduction of CO2 over Pd nanoparticlesDunfeng Gao, Hu Zhou, Jing Wang, Shu Miao, Fan Yang, Guoxiong Wang*, Jianguo Wang*, Xinhe BaoJournal of the American Chemical Society 137(2015)4288-4291····································211

157. Cuprous oxide catalyzed oxidative C-C bond cleavage for C-N bond formation: Synthesis of cyclic imides from ketones and aminesMin Wang, Jianmin Lu, Jiping Ma, Zhe Zhang, Feng Wang*Angewandte Chemie International Edition 54(2015)14061-4065····································212

158. Enantioselective palladium-catalyzed C-H functionalization of indoles using an axially chiral 2,2’-bipyridine ligandXiang Gao, Bo Wu, Wenxue Huang, Muwang Chen, Yonggui Zhou*Angewandte Chemie International Edition 54(2015)11956-11960···································213

159. Formal asymmetric catalytic thiolation with a bifunctional catalyst at a water-oil interface : Synthesis of benzyl thiolsWengang Guo, Bo Wu, Xin Zhou, Ping Chen, Xu Wang, Yonggui Zhou, YanLiu*, Can Li*Angewandte Chemie International Edition 54(2015)4522-4526······································214

160. Cavity controls the selectivity: Insights of confinement effects on MTO reactionJinzhe Li, Yingxu Wei, Jingrun Chen,Shutao Xu,Peng Tian, Xiaofeng Yang,Bing Li, Jinbang Wang, Zhongmin Liu*ACS Catalysis 5(2015)661-665··················································································215

161. Hydrogenation/hydrolytic ring opening of 5-HMF by Cp*-iridium(III)half-sandwich complexes for bioketones synthesisZhanwei Xu, Peifang Yan, Wenjuan Xu, Xiumei Liu, Zhi Xia, Benjamin Chung, Songyan Jia, Z. Conrad Zhang*ACS Catalysis 5(2015)788-792··················································································216

162. Methanol to olefins (MTO): From fundamentals to commercializationPeng Tian, Yingxu Wei, Mao Ye, Zhongmin Liu*ACS Catalysis 5(2015)1922-1938··············································································217

163. Synthesis of chiral trifluoromethyl-substituted hydrazines via Pd-catalyzed asymmetric hydrogenation and reductive aminationZhangpei Chen, Shubo Hu, Ji Zhou, Yonggui Zhou*ACS Catalysis 5(2015)6086-6089··············································································218

164. Pd-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols via capture of active tautomersZhangpei Chen, Muwang Chen, Lei Shi, Changbin Yu, Yonggui Zhou*Chemical Science 6(2015)3415-3419·········································································219

48

165. Terpyridine-Cu(II) targeting human telomeric DNA to produce highly stereospecific G-quadruplex DNA metalloenzymeYinghao Li, Mingpan Cheng, Jingya Hao, Changhao Wang, Guoqing Jia*, Can Li*Chemical Science 6(2015)5578-5585·········································································220

166. An ionic liquid-organic-water ternary biphasic system enhances the 5-hydroxymethylfurfural yield in catalytic conversion of glucose at high concentrationsJinxia Zhou, Zhi Xia, Tingyu Huang, Peifang Yan, Wenjuan Xu, Zhanwei Xu,Jianji Wang, Z.Conrad Zhang*Green Chemistry 17(2015)4206-4216·········································································221

167. Asymmetric hydrogenation in nanoreactors with encapsulated Rh-MonoPhos catalystMingmei Zhong, Xiaoming Zhang, Yaopeng Zhao, Can Li*, Qihua Yang*Green Chemistry 17(2015)1702-1709·········································································222

168. Depolymerization of cellulose to glucose by oxidation-hydrolysisLipeng Zhou, Xiaomei Yang*, Jiaolong Xu, Meiting Shi, Feng Wang,Chen Chen, Jie XuGreen Chemistry 17(2015)1519-1524·········································································223

169. Lignosulfonate-based resin for synthesis of renewable diesel range branched alkanes with 2-methylfuran and furfuralShanshan Li, Ning Li*, Guangyi Li, Lin Li, Aiqin Wang, Yu Cong,Xiaodong Wang, Tao Zhang*Green Chemistry 17(2015)3644-3652·········································································224

170. Oxidation of refractory sulfur-containing compounds with molecular oxygen catalyzed by vanadoperiodateNanfang Tang, Zongxuan Jiang*, Can Li*Green Chemistry 17(2015)817-820············································································225

171. Selective oxidative C-C bond cleavage of a lignin model compound in the presence of acetic acid with a vanadium catalystYangyang Ma, Zhongtian Du, Junxia Liu, Fei Xiaa, Jie Xu*Green Chemistry 17(2015)4968-4973·········································································226

172. C-N and N-H bond metathesis reactions mediated by carbon dioxideYehong Wang, Jian Zhang, Jing Liu, Chaofeng Zhang, Zhixin Zhang, Jie Xu*, Shutao Xu, Fangjun Wang, Feng Wang*ChemSusChem 8(2015)2066-2072·············································································227

173. Selective oxidation of sulfides on Pt/BiVO4 photocatalyst under visible light irradiation using water as the oxygen source and dioxygen as the electron acceptorBao Zhang, Jun Li, Bingqing Zhang, Ruifeng Chong, Rengui Li, Bo Yuan, Shengmei Lu, Can Li*Journal of Catalysis 332(2015)95-100········································································228

174. Catalytic conversion of isophorone to jet-fuel range aromatic hydrocarbons

49

over a MoOx/SiO2 catalystFang Chen, Ning Li*, Wentao Wang, Aiqin Wang, Yu Cong,Xiaodong Wang, Tao Zhang*Chemical Communications 51(2015)11876-11879························································229

175. Higher-order human telomeric G-quadruplex DNA metalloenzyme catalyzed diels-alder reaction: An unexpected inversion of enantioselectivity modulated by K+ and NH4

+ ionsYinghao Li, Changhao Wang, Jingya Hao, Mingpan Cheng, Guoqing Jia*, Can Li*Chemical Communications 51(2015)13174-13177························································230

176. ���������������������� �������� �� �������������� ��������� �����-MnO2

catalyst and tert-butyl hydroperoxide (TBHP)as an oxidantZhe Zhang, Min Wang, Chaofeng Zhang, Zhixin Zhang, Jianmin Lu, Feng Wang*Chemical Communications 51(2015)9205-9207···························································231

177. Formal palladium-catalyzed asymmetric hydrogenolysis of racemic N-sulfonyloxaziridinesBo Song, Changbin Yu, Wenxue Huang, Muwang Chen, Yonggui Zhou*Organic Letters 17(2015)190-193··············································································232

178. Iridium-catalyzed selective hydrogenation of 3-hydroxypyridinium salts: A facile synthesis of piperidin-3-onesWenxue Huang, Bo Wu, Xiang Gao, Muwang Chen, Baomin Wang*, Yonggui Zhou*Organic Letters 17(2015)1640-1643··········································································233

179. Unprecedentedly high formic acid dehydrogenation activity on an iridium complex with an N, N!-diimine ligand in waterZhijun Wang, Sheng-Mei Lu, Jun Li, Jijie Wang, Can Li*Chemistry-A European Journal 21(2015)12592-12595··················································234

180. Photo-induced H2 production from a CH3OH-H2O solution at insulator surfaceRengui Li, Xiuli Wang, Shaoqing Jin, Xin Zhou, Zhaochi Feng, Zheng Li, Jingying Shi, Qiao Zhang, Can Li*Scientific Reports 5(2015)13475 1-9···········································································235

181. Synthesis of high density aviation fuel with cyclopentanol derived from lignocelluloseXueru Sheng, Ning Li, Guangyi Li, Wentao Wang, Jinfan Yang, Yu Cong, Aiqin Wang, Xiaodong Wang, Tao Zhang*Scientific Reports 5(2015)9565··················································································236

182. pH effect on electrocatalytic reduction of CO2 over Pd and Pt nanoparticlesDunfeng Gao, JingWang, Haihua Wu, Xiaole Jiang, ShuMiao, GuoxiongWang*, Xinhe BaoElectrochemistry Communications 55(2015)1-5···························································237

183. Effects of phosphate additives on the stability of positive electrolytes for vanadium flow batteries

50

Cong Ding, Xiao Ni, Xianfeng Li, Xiaoli Xi, Xiuwen Han, Xinhe Bao*, Huamin Zhang*Electrochimica Acta 164(2015)307-314······································································238

184. Catalytic conversion of cellulosic biomass to ethylene glycol: Effects of inorganicimpurities in biomassJifeng Pang, Mingyuan Zheng*, Ruiyan Sun, Lei Song, Aiqin Wang, Xiaodong Wang, Tao ZhangBioresource Technology 175(2015)424-429································································239

185. Hydrodesulfurization of 4,6-DMDBT on multi-metallic bulk catalyst NiAlZnMoW: Effect of ZnZnYandie Chen, Lu Wang, Xinyi Liu, Tiefeng Liu, Baokun Huang, Ping Li,Zongxuan Jiang*, Can Li*Applied Catalysis A: General 504(2015)319-327·························································240

186. Promoting effect of Al on tethered ligand-modified Rh/SiO2 catalysts for ethylene hydroformylationJia Liu, Li yan, Yunjie Ding*, Miao Jiang, Wenda Dong, Xiangen Song, Tao Liu, Hejun ZhuApplied Catalysis A: General 492(2015)127-132·························································241

187. Remarkable effect of extremely dilute H2SO4 on the cellulose conversion to ethylene glycolGang Xua, Aiqin Wang*, Jifeng Pang, Mingyuan Zheng, Jianzhong Yin*,Tao Zhang*Applied Catalysis A: General 502(2015)65-70·····························································242

188. Selective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol over vanadium modified Ir/SiO2 catalystBoonrat Pholjaroen, Ning Li*, Yanqiang Huang, Lin Li, Aiqin Wang, Tao ZhangCatalysis Today 245(2015)93-99···············································································243

189. Catalytic etherification of hydroxyl compounds to methyl ethers with 1,2-dimethoxyethanePenghua Che, Fang Lu*, Xiaoqin Si, Jie Xu*RSC Advances 5(2015)24139-24143··········································································244

190. Direct hydroxylation of benzene to phenol with molecular oxygen over vanadium oxide nanospheres and study of its mechanismGuanhua Luo, Xuechuan Lv, Xingwang Wang, Su Yan, Xiaohan Gao*, Jie Xu*, Hong Ma, Yujuan Jiao, Fayun Li*, Jinzhu ChenRSC Advances 5(2015)94164-94170··········································································245

191. Microwave-assisted fast depolymerization of lignin model compounds and organosolv lignin over methyltrioxorhenium in ionic liquidsBo Zhang, Changzhi Li, Tao Dai, George W. Huber, Aiqin Wang, Tao Zhang*RSC Advances 5(2015)84967-84973··········································································246

51

192. Solvent-free synthesis of C9 and C10 branched alkanes with furfural and 3-pentanone from lignocelluloseFang Chen, Ning Li*, Shanshan Li, Jinfan Yang, Fei Liu, WentaoWang, AiqinWang, Yu Cong, Xiaodong Wang, Tao Zhang*Catalysis Communications 59(2015)229-232·······························································247

193. Steady-state behavior of liquid fuel hydrazine decomposition in packed bedBaolin Hou, Xiaodong Wang, Tao Li, Tao ZhangAIChE Journal 61(2015)1064-1080···········································································248

194. Solvent mediation for enhanced separation of 5-hydroxymethylfurfural from 1-butyl-3-methylimidazolium chlorideJinxia Zhou, Tingyu Huang, Yuling Zhao, Zhi Xia, Zhanwei Xu, Songyan Jia, Jianji Wang, Z. Conrad Zhang*Industrial & Engineering Chemistry Research 54(2015)7977-7983·································249

195. Synthesis and characterization of poly(ethylene terephthalate)from biomass-based ethylene glycol: Effects of miscellaneous diolsBin Xiao, Mingyuan Zheng*, Jifeng Pang, Yu Jiang, Hua Wang, Ruiyan Sun, Aiqin Wang, Xiaodong Wang, Tao Zhang*Industrial & Engineering Chemistry Research 54(2015)5862-5869·································250

196. Synthesis of jet-fuel range cycloalkanes from the mixtures of cyclopentanone and butanalJinfan Yang, Shanshan Li, Ning Li*, Wentao Wang, Aiqin Wang, Tao Zhang, Yu Cong, Xiaodong Wang, George W.Huber*Industrial & Engineering Chemistry Research 54(2015)11825-11837·····························251

197. Direct amination of 2-(1-tosylalkyl)phenols with aqueous ammonia: A metal-free synthesis of primary aminesBo Wu, Xiang Gao, Muwang Chen, Yonggui Zhou*Tetrahedron Letters 56(2015)1135-1137·····································································252

198. Enantioselective synthesis of functionalized 2-amino-4H-chromenes via the o-quinone methides generated from 2-(1-tosylalkyl)phenolsBo Wua, Xiang Gao, Zhong Yan, Wenxue Huang, Yonggui Zhou*Tetrahedron Letters 56(2015)4334-4338·····································································253

199. One-pot catalytic transformation of dicyclopentadiene to high energy density fuel exo-tetrahydrotricyclopentadieneWentao Wang, Yu Cong, Shuai Chen,Caixia Sun, Xiaodong Wang, Tao ZhangTopics in Catalysis 58(2015)350-358 ·········································································254

200. Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalystJunying Zhang, Baolin Hou, Xuefei Wang, Zhenlei Li, Aiqin Wang*, Tao Zhang*Journal of Energy Chemistry 24(2015)9-14·································································255

52

201. Methane dehydroaromatization with periodic CH4-H2 switch: A promising process for aromatics and hydrogenChangyong Suna, Guangzong Fang, Xiaoguang Guo*, Yuanli Hu, Shuqi Ma, Tianhua Yang, Jie Han, Hao Ma, Dali Tan, Xinhe Bao*Journal of Energy Chemistry 24(2015)257-263····························································256

202. Selective esterification of glycerol with acetic acid to diacetin using antimony pentoxide as reusable catalystWenfei Hu, Yan Zhang, Yizheng Huang, Jiaxi Wang, Jin Gao, Jie Xu*Journal of Energy Chemistry 24(2015)632-636····························································257

203. Effect of desilication on the performance of hierarchical ZSM-11 catalysts for alkylation of benzene with dimethyl etherHui Liu, Shenglin Liu, Sujuan Xie, Chao Song, Wenjie Xin,Longya XuCatalysis Letters 145(2015)1972-1983·······································································258

204. An investigation of the effects of CeO2 crystal planes on the aerobic oxidative synthesis of imines from alcohols and aminesZhixin Zhang, Yehong Wang, Min Wang, Jianmin Lü, Lihua Li, Zhe Zhang, Mingrun Li, jingyang Jiang*, Feng Wang*Chinese Journal of Catalysis 36(2015)1623-1630························································259

205. Fischer-Tropsch synthesis: Characterizing and reaction testing of Co2C/SiO2

and Co2C/Al2O3 catalystsYanpeng Pei, Yunjie Ding*, Juan Zang, Xiangen Song, Wenda Dong, Hejun Zhu, Tao Wang, Weimiao ChenChinese Journal of Catalysis 36(2015)252-259····························································260

206. Methanol to hydrocarbons reaction over HZSM-22 and SAPO-11: Effect of catalyst acid strengthon reaction and deactivation mechanismJinbang Wang, Linzhe Li, Shutao Xu, Yuchun Zhi, Yingxu Wei, Yanli He, Jingrun Chen, Mozhi Zhang, Quanyi Wang, Wenna Zhang, Xinqiang Wu, Xinwen Guo*, Zhongmin LiuChinese Journal of Catalysis 36(2015)1392-1402 ························································261

207. MoOx-promoted Pt catalysts for the water gas shift reaction at low temperaturesXuejun Xu, Qiang Fu*, Xinhe BaoChinese Journal of Catalysis 36(2015)750-756····························································262

208. One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2

Yanpeng Pei, Yunjie Ding*, Hejun Zhu, Hong DuChinese Journal of Catalysis 36(2015)355-361····························································263

53

209. Studies on the roles of vanadyl sulfate and sodium nitrite in catalytic oxidation of benzyl alcohol with molecular oxygenZhongtian Du, Junxia Liu, Tianliang Lu, Yangyang Ma, Jie Xu*Science China Chemistry 58(2015)114-122·································································264

210. Enzymatic allylation of catecholsYixin Zhang, Wujun Liu, Muhammad Sohail, Xueying Wang, Yuxue Liu, Zongbao K. Zhao*Chemistry Letters 44(2015)949-951···········································································265

211. Catalytic hydrogenation of carbon monoxide over Rh-Mn-Li/SiO2 catalyst for the synthesis of C2+ oxygenates: The remarkable effect of urea on the particle size of RhFei Xue, Yunjie Ding,Weimiao Chen, Xiangen Song, Xianbo ChengReaction Kinetics Mechanisms and Catalysis 115(2015)625-634····································266

212. Effect of different synthetic routes on the performance of propylene hydroformylation over 3V-PPh3 polymer supported Rh calalystsMiao Jiang, Li Yan,Xueping Sun, Ronghe Lin, Xiangen Song, Zheng Jiang, Yunjie DingReaction Kinetics Mechanisms and Catalysis 116(2015)223-234····································267

213. CO C2 Rh, , ,

31(2015)1-10···················································································268

214., , , , , *

: 45(2015)526-532·············································································269

215. Co -, , , , ,

44(2015)1467-1474··················································································270

216. Ru/AC 1 2-, , , ,

44(2015)192-197·····················································································271

217., , , ,

: 45(2015)969-975······································································272

218., , , , , , *

37(2015)152-154·····················································································273

219.

54

*, , , , , ,37(2015)759-761·····················································································274

220. Enantioselective synthesis of trifluoromethyl substituted piperidines with multiple stereogeni centers via hydrogenation of pyridinium hydrochloridesMuwang Chen, Zhishi Ye, Zhangpei Chen, Bo Wu, Yonggui Zhou*Organic Chemistry Frontiers 2(2015)586-589·····························································275

221. Photocatalysis in solar fuel productionHongxian Han, Can Li*National Science Review 2(2015)145-147···································································276

55

催化基础国家重点实验室 2015 年专利申请一览表

序号 专利名称 专利申请号 申请日期 发明人 专利

类型 国别

1 Synthesis of olefins from oxygen-free direct conversion of methane and its catalysts

JP2015-533419 2015-01-30 包信和,郭晓光,方光宗,邓德

会,马昊,谭大力 国际 日本

2 一种二烯烃选择加氢催化剂及

制备和应用 US14419433 2015-02-03 李灿,蒋宗轩,陈燕蝶,刘铁峰 国际 美国

3 层状结构超深度加氢脱硫多金

属本体催化剂及制备和应用 US14420167 2015-02-06 李灿,蒋宗轩,陈燕蝶,刘铁峰 国际 美国

4 Synthesis of olefins from oxygen-free direct conversion of methane and its catalysts

RU 2015106364 2015-02-25 包信和,郭晓光,方光宗,邓德

会,马昊,谭大力 国际

俄罗斯 联邦

5 一种铂/碳纳米管催化剂及其制

备方法和应用 US14673427 2015-03-30 李灿,陈志坚 国际 美国

6 金属-氧化铈催化剂的制备及其

在二氧化碳电催化还原中的应

用 201510240669.2 2015-05-12 汪国雄,高敦峰,姜晓乐,包信

和 发明 中国

7 一种用于合成气甲烷化反应的

金属@BN 核-壳结构纳米催化

剂及其制备方法 201510229155.7 2015-05-12 傅强,高丽君,包信和 发明 中国

277

序号 专利名称 专利申请号 申请日期 发明人 专利

类型 国别

8 一种用于超深度脱硫脱氮的多

金属本体催化剂及其制法和应

用 201510251270.4 2015-05-22 李灿,蒋宗轩,刘欣毅,刘铁峰 发明 中国

9 一种汽油选择性加氢脱硫体相

催化剂及其制备方法和应用 201510304797.9 2015-06-08 李灿,蒋宗轩,李萍,刘铁峰 发明 中国

10 自呼吸式光助生物质燃料电池

及其应用 201510337590.1 2015-06-18 李灿,张丙青,施晶莹 发明 中国

11 种汽油选择性加氢脱硫催化剂

的制备和应用 201510359889.7 2015-06-26 李灿,蒋宗轩,李萍,刘铁峰 发明 中国

12 一种用于二氧化碳加氢合成低

碳醇的催化剂及制备方法和应

用 201510388581.5 2015-07-02 李灿,王集杰,蒋宗轩,陈燕蝶 发明 中国

13 一种光电化学催化氧化 Ce（Ⅲ）

方法及其应用 201510383355.8 2015-07-03 李灿,王志君,王楠,丁春梅,

施晶莹 发明 中国

14 一种基于水溶性快速反应动力

学氧化还原电对的光电化学储

能电池 201510387909.1 2015-07-06 李灿,陈剑,廖世潮,施晶莹,

宗旭,董延宝 发明 中国

15 一种常压下二氧化碳加氢合成

甲醇的催化剂及其制备方法和

应用 201510388397 2015-07-06 李灿,王集杰,卢胜梅,李军,

王志君 发明 中国

278

序号 专利名称 专利申请号 申请日期 发明人 专利

类型 国别

16 一 种 光 电 化 学 分 解 水 的

GaN-ZnO 光阳极的制备方法 201510392338 2015-07-07 李灿,王志亮,韩晶峰,宗旭 发明 中国

17 一种深紫外-可见区（170-520 nm）波长连续可调纳秒及皮秒

脉冲宽度的脉冲激光器 201510412569.3 2015-07-15 李灿,冯兆池,金少青,张莹 发明 中国

18 手性有机碱在水油两相体系中

制备手性含硫吲哚化合物的应

用 201510431625.8 2015-07-22 李灿,刘,陈萍 发明 中国

19 一种自驱动的TiO2紫外探测器

件及其制备方法 201510461063.1 2015-07-31 李灿,严鹏丽,韩洪宪,甘阳,

吴义辉,冯兆池 发明 中国

20 CO 促进醋酸酯加氢制备乙醇

的铜基催化剂及应用 201510583455.5 2015-09-14 黄秀敏,申文杰,马猛,薛会福 发明 中国

21 Synthesis of olefins from oxygen-free direct conversion of methane and its catalysts

QA/201510/00445 2015-10-12 包信和,郭晓光,方光宗,邓德

会,马昊,谭大力 国际 卡塔尔

22 一种催化剂及由合成气一步法

直接制备低碳烯烃的方法 PCT/CN2015/092091 2015-10-16 潘秀莲,李津京,焦峰,包信和 国际 中国

23 一种催化剂及由合成气一步法

直接制备低碳烯烃的方法 201510676457.9 2015-10-16 潘秀莲,李津京,焦峰,包信和 发明 中国

24 复合分离膜 201510690171.6 2015-10-20 杨维慎,班宇杰,李砚硕 发明 中国

279

序号 专利名称 专利申请号 申请日期 发明人 专利

类型 国别

25 丙烷一步氧化制备丙烯酸的系

统及方法 201510593298.6 2015-10-22 杨维慎,楚文玲,王红心,刘延

纯,李清强,李旭,王宏奎 发明 中国

26 一种 Ta3N5 光电极的制备方法 201510741556 2015-11-05 李灿,邵晨熠,宗旭 发明 中国

27 一种 ZSM-5 分子筛的合成方法 201510852504 2015-11-30 展恩胜,申文杰,李勇 发明 中国

28 一种纳米 ZSM-5 分子筛的合成

方法 2015108617273 2015-11-30 展恩胜,申文杰,李勇 发明 中国

29 一种基于超高真空条件下固体

表面接触角的测量装置 201510870358.4 2015-12-02 傅强,吴昊（联）,包信和 发明 中国

30 一种适用于水油两相体系手性

催化剂的制备及应用 201510863628.9 2015-12-02 李灿,陈萍,刘,郭文岗,张

博宇 发明 中国

31 一种超薄沸石咪唑酯骨架杂化

膜及其制备方法 201510886177 2015-12-04 杨维慎,彭媛,李砚硕 发明 中国

32 碳分子筛膜缺陷的填补方法 201510886176.6 2015-12-04 杨维慎,矫文美,李砚硕 发明 中国

33 金属有机骨架杂化膜、其制备

方法及应用 201510883685.3 2015-12-04 杨维慎,金花,李砚硕 发明 中国

34 Synthesis of olefins from oxygen-free direct conversion of methane and its catalysts

EP 13884408.9 2015-12-10 包信和,郭晓光,方光宗,邓德

会,马昊,谭大力 国际 欧洲

35 一种烯烃氢甲酰化有机-无机复

合催化剂的制备方法及应用 2015109173782 2015-12-11 杨启华,赵耀鹏 发明 中国

280

序号 专利名称 专利申请号 申请日期 发明人 专利

类型 国别

36

一种以碳纳米管作为载体担载

铁-氮-碳活性组分用于硝基苯

衍生物氢化反应的催化剂制备

方法

2015109209303 2015-12-11 杨启华,姚毅,郑圆圆 发明 中国

37 一种氧吸附剂 201510927399.2 2015-12-12 杨维慎,鲁辉,张晋娜 发明 中国

38 一种析氧反应电催化剂及其制

备方法 201510918893.2 2015-12-12 杨维慎,朱凯月,朱雪峰 发明 中国

39 一种微孔聚合物膜、其制备方

法及应用 201510927396.9 2015-12-12 杨维慎,王泼,李砚硕 发明 中国

40 同时制备氨合成气和液体燃料

合成气的系统及方法 201510918918.9 2015-12-12 杨维慎,李文平,朱雪峰 发明 中国

41 短波长手性拉曼光谱仪 201510925965.6 2015-12-13 李灿,冯兆池,王鹏,张莹,唐

宇轩 发明 中国

42 催化剂焙烧容器 201510930207.3 2015-12-14 杨维慎,王红心,楚文玲 发明 中国

43 一种用于金属氧化物纳米簇的

合成方法及其在水氧化中的应

用 201510924710.8 2015-12-15 李灿,管景奇,韩洪宪,章福祥 发明 中国

44 一种用于乙炔法制氯乙烯的碳

基无金属催化剂、制备方法及

再生方法 201510946590.1 2015-12-16 包信和,马昊,潘秀莲,李攀,

丁民正 发明 中国

281

序号 专利名称 专利申请号 申请日期 发明人 专利

类型 国别

45 一种氧掺杂二硫化钼热电材料

及其制备方法 201510961008.9 2015-12-17 姜鹏,孔爽,包信和 发明 中国

46 一种金属掺杂的二硫化钨热电

材料及制备方法 201510962265.4 2015-12-18 姜鹏,黄志伟,包信和 发明 中国

47 一种甲烷无氧直接制烯烃的方

法及其催化剂 201511003407 2015-12-28 方光宗,于琴琴,郭晓光,谭大

力,包信和 发明

282

催化基础国家重点实验室 2015 年专利授权一览表

序号 专利名称 专利号 发明人 专利

类型 国别

1 一种计算机监控的高通量多功能微反应系统 201210414322.1 谭大力,郭晓光,马书启,傅强;

包信和 发明 中国

2 一种豆荚状碳纳米管封装非贵金属纳米颗粒

的制备方法 201110435881.6 包信和,邓德会,潘秀莲,陈晓琪 发明 中国

3 一种全馏分 FCC 汽油超深度脱硫组合方法 201210339817.2

沈浩,李灿,袁定雄,王思晨（王

总）,罗万明,金总,赵小平,王军

峰,李铖,蒋宗轩,刘铁峰,李鸿

雄,张荣

发明 中国

4 一种二烯烃选择加氢催化剂及制法和应用 201210315165.9 李灿,蒋宗轩,陈燕蝶,刘铁峰,

杨民 发明 中国

5 钙钛矿类（ABO3）化合物做为活性材料用于

两步热化学循环分解 CO2 制备 CO 201210108926.3 李灿,蒋青青,蒋宗轩,童金辉,

李真 发明 中国

6 一种柴油的超深度氧化脱硫方法 201210289149.7 李灿,蒋宗轩,唐南方,林峰 发明 中国

7 一种以氧气为氧化剂的超深度脱除柴油中硫

化物的方法 201110226034.9 李灿,蒋宗轩,唐南方 发明 中国

8 一种二维层状金属有机骨架的开层及应用 201210568632.9 杨维慎,彭媛,李砚硕,刘杰 发明 中国

9 一种固体氧化物燃料电池纳米阴极的制备方

法 201210566897.5 杨维慎,刘焕英,朱凯月,朱雪

峰,丛铀,刘妍 发明 中国

283

序号 专利名称 专利号 发明人 专利

类型 国别

10 一种离子热合成磷酸铝 AlPO4-n 分子筛膜的

方法 201210011136.3 蔡睿,楚文玲,杨维慎,刘延纯,

俞同文 发明 中国

11 一种磷铝分子筛膜的电化学合成方法 201210253140.0 蔡睿,俞同文,楚文玲,刘延纯,

杨维慎 发明 中国

12 微米级花状复合金属碱式碳酸盐的制备方法 201110006161.8 杨维慎,刘焕英,朱雪峰,丛铀 发明 中国

13 微米级花状复合金属氧化物的制备方法 201010599832.1 杨维慎,刘焕英,朱雪峰,丛铀 发明 中国

14 高含氮量管径可调碳纳米管及其制备方法 201310064115.2 杨启华,李灿,苏盼盼 发明 中国

15 一种用于拆分外消旋环氧烷烃的催化剂 201210069711.5 杨启华,李灿,白诗扬 发明 中国

284

催化基础国家重点实验室 2015 年开放课题一览

课题号 项 目 名 称 申请者 所在单位

N-15-01 高分散 Cu/SiO2 催化剂的超临界

可控制备及其在 DMO 加氢制备

乙二醇反应中的应用 徐琴琴 大连理工大学

N-15-02 Pb(IV)基氧化物材料的设计合成

与光催化分解水性能研究 赵 丹 河南理工大学

N-15-03 碳纳米管限域效应的核磁共振研

究 申万岭 河南工业大学

N-15-04 温和条件下由生物质基甘油与苯

胺高效合成 3-甲基吲哚的催化剂

的设计、制备及催化机理研究 石 雷 辽宁师范大学

N-15-05 合成气制备异丁烷高选择性催化

剂制备及催化机理 李聪明 太原理工大学

N-15-06 燃油超深度脱硫三元可见光催化

剂的设计构建与性能研究 林 峰 大连民族大学

N-15-07 二氧化碳加氢合成甲酸多相催化

剂的构建 王新葵 大连理工大学

N-15-08 双功能含钒分子筛催化材料的合

成、表征及其在乙烷氧化脱氢中

的应用 金少青

中国石化上海石油化

工研究院

N-15-09 钛酸锶光催化材料微结构调控及

其光催化性能研究 贾玉帅 江西师范大学

N-15-10 Bi2O3、WO3 材料中“异相结”结构

的构建与光催化性能研究 张 静 辽宁石油化工大学

285

催化基础国家重点实验室 2015年自主研究课题一览表

课题号 研 究 课 题 负责人

R201501 新型功能化共价有机框架（COFs）材料催化甲醇经三聚

甲醛制备柴油添加剂 DMMn 的催化性能研究 高艳安

R201502 共轭微孔高分子负载锌催化甲醇制 Triptane 李兴伟

R201503 纳米反应器中的费托合成 杨启华

R201504 催化活化甲烷无氧直接制乙烯的机理研究 唐紫超

R201505 水蒸气和二氧化碳共电解制备合成气研究 程谟杰

R201506 甲醇下游产品转化制备二元醇 王峰

R201507 多相催化过程的“在线”紫外拉曼光谱瞬态动力学分析研

究 范峰滔

R201501 新型功能化共价有机框架（COFs）材料催化甲醇经三聚

甲醛制备柴油添加剂 DMMn 的催化性能研究 苗 澍

286