spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets -...
TRANSCRIPT
![Page 1: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/1.jpg)
SPRAY DRYING
![Page 2: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/2.jpg)
BASIC CONCEPT – SPRAY DRYING
Spray drying - formation of droplets from the bulk liquid – moisture removal
liquid droplets - sprayed –drying chamber the low-humidity hot gas or drying medium is
mixed with the dispersed droplets individual droplets –atomized - by atomizers Spray drying –referred as a suspended
droplet/particle processing technique.
![Page 3: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/3.jpg)
rotary wheel/disc atomizers pressure nozzle or pneumatic-type atomizers. The atomizer is generally located at the top
centre of the drying chamber for most spray drying operations.
The moisture, in the form of vapor, quickly evaporates from the suspended droplets
due to simultaneous and fast heat and mass transfer processes.
![Page 4: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/4.jpg)
Drying of the droplets continues inside the drying chamber - desired particle characteristics are achieved.
The final dried product is produced using a single stage drying process
Separation of the dried particles from the drying gas - cyclones and/or bag-filter houses.
![Page 5: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/5.jpg)
SINGLE STAGE SPRAY DRYER
![Page 6: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/6.jpg)
To produce a hot drying medium, the ambient air ( Tambient) is heated to the desired temperature (Tinlet ).
In modern spray driers, the hot air stream + cooling air stream - to keep the atomizer temperature at a low value
the temperature of the hot air stream is usually kept slightly higher than the temperature required at the atomizer zone.
During this heating, the absolute humidity of the air remains constant while its vapor pressure (RH) is reduced to a very low value
![Page 7: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/7.jpg)
the water activity of the dried product is normally reduced to less than 0.2;
therefore the RH of the air is maintained below 20% RH to reach the desired level of water activity
The outlet air temperature (Toutlet ), which is controlled by the liquid flow, - keep the water activity at the desired level.
At the end of the drying, the drying gas & dried product can approach an equilibrium state.
![Page 8: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/8.jpg)
The rate of evaporation - temperature & vapor pressure differences - surface of the droplets & the drying gas
other important factors: diffusivity of water in air relative velocity of droplet with respect to drying
gas kinematic viscosity conductivity & heat capacity of air
conversion of the liquid droplet to the dried particle weight loss of 50% (due to loss of water) volume loss of 25% (due to shrinkage).
![Page 9: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/9.jpg)
COMPONENTS OF A SPRAY DRYING SYSTEM
drying gas supply and heating system atomization system drying chamber powder separators Additional/Optional
the number of stagesdrying mode - fluidized-bed drier or belt drier
![Page 10: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/10.jpg)
DRYING GAS SUPPLY AND HEATING SYSTEM
ambient air Superheated steam Air – drawn – filtered - heated from 150◦C
to 270◦C Hot air with higher humidity - may result in
a dried product with a slightly higher moisture content.
air dehumidification unit – may be installed
![Page 11: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/11.jpg)
The air can be heated using a direct-contact or an indirect-contact system
Electrical, steam, oil-fired or gas heaters combination of heating methods such as
steam and electrical heating The air pressure inside - slightly lower
than the atmospheric pressure A lower pressure helps to avoid leakage
of product/air from the drier
![Page 12: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/12.jpg)
ATOMIZATION SYSTEM large surface area between the moist droplets and
the drying medium heat and mass transfer processes 1cubic metre of liquid forms approximately 2 × 1012
uniform droplets of 100 μm diameter powder properties and powder collection efficiency –
depends on type of atomizer The atomization process influences
droplet’s size, size distribution, trajectory and velocity, the overall product quality, the drying chamber design energy requirement to form the spray of droplets.
![Page 13: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/13.jpg)
The device - liquid atomization – atomizer Atomizers can be classified based on
the type of the energy used for atomization, the number of orifices the shape of orifice the mode of operation (continuous or intermittent) the geometry of atomizers
Widely used four types of atomizers rotary wheel/disc (centrifugal energy)pressure nozzles (pressure energy)Twofluid nozzles (pressure and gas energy) sonic nozzles (sonic energy)
![Page 14: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/14.jpg)
![Page 15: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/15.jpg)
Rotary atomizers & pressure nozzles – large scale
Pneumatic nozzles – medium scale Sonic atomizers – small scale - use high-
frequency sound energy created by a sonic resonance cup placed in front of the nozzle
Sonic atomizers - difficult to atomize using traditional atomizers and specialty products
Pressure-swirl, sonic and two fluid nozzles - hollow cone-type spray pattern or a fully developed cone
Rotary atomizers produce a wide cone, which is sometimes referred as a ‘spray cloud’
![Page 16: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/16.jpg)
DRYING CHAMBER cylindrical drying chamber with a cone of 40◦–60◦
at the bottom The drier chamber design primarily depends on
the type of the atomizer the trajectory of droplets the properties (such as heat sensitivity, solids
content, etc.) of the material the capacity of the drier single- or two-stage dryingthe cost and the type of air flow (co- or counter-
current) with respect to the feed
![Page 17: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/17.jpg)
To facilitate powder removal and minimize the wall deposition, the drier chambers are usually equipped with an air or mechanical sweeping system
spray driers are mostly operated with a co-current mode - the drying gas and the atomized droplets move in the same direction
When rotary-type atomizers -a rotational airflow is commonly used
provides more uniform temperatures in the drying chamber compared to that of the non-rotational airflow.
![Page 18: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/18.jpg)
POWDER SEPARATORS the air stream from the drying chamber usually
contains about 10–50% of the total powder Powder recovery
economy purposespollution problems
Gravity separators (e.g. cyclones) only or by a combination of gravity and filter separators
![Page 19: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/19.jpg)
SINGLE STAGE SPRAY DRYER
![Page 20: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/20.jpg)
TWO STAGE SPRAY DRYER
![Page 21: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/21.jpg)
cyclone separators
bag filters
wet scrubbers
![Page 22: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/22.jpg)
DRYING OF DROPLETS Drying starts with evaporation of ‘free’ moisture on the droplet surface droplet surface is fully covered with water -the
drying rate = rate for pure water evaporation a droplet that has dissolved or a suspended solid
is being dried - vapor pressure smaller the mass transfer rate gradually becomes lower
![Page 23: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/23.jpg)
drying of the wet ‘porous’ droplets liquid diffusion caused by the liquid density
gradient Vapor diffusion caused by the vapor density
gradient capillary flow caused by the capillary force moisture transfer caused by the internal pressure
gradient moisture transfer caused by evaporation and
condensation in pores
![Page 24: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/24.jpg)
the majority of the free water is removed in a short period of time, leading to a very short (most times negligible) constant-rate drying period
relatively longer falling rate period during drying of small droplets.
spray drying, the maximum water evaporation takes place in a fraction of a second and within a short distance from the atomizer.
![Page 25: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/25.jpg)
![Page 26: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/26.jpg)
MASS AND HEAT BALANCES
in order to evaluate the efficiency of each process independently
Overall mass balance and heat balance
![Page 27: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/27.jpg)
DRIER EFFICIENCY
Tb,i and Tb,o are inlet and outlet drying gas temperatures
Tb,a is the ambient gas temperature adiabatic saturation temperature (Tsat ) corresponding to the inlet air
temperatures
![Page 28: Spray drying - formation of droplets from the bulk liquid – moisture removal liquid droplets - sprayed –drying chamber the low-humidity hot gas](https://reader030.vdocuments.us/reader030/viewer/2022033023/56649eb25503460f94bb9b7e/html5/thumbnails/28.jpg)