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U.S. EPA Region IIIOffice of Analytical Services

&qd Quality AssuranceAnnapolis, Maryland

ANALYTICAL REPORT

KEYSTONE SANITATIONSUPERFUND REMOVAL/REMEDIAL

Account # TFA03N9L9Lab Request # REQ96039

February 27, 1996

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U.S. EPA Region IIIOffice of Analytical Services

and Quality AssuranceAnnapolis, Maryland

t̂ February 27, 1996

;**i-ANALYTICAL RESORTS: KEYSTONE SANITATION [REQ96039]

Dear Chris Corbett^

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Section: INORGANICNarrative Page: 1

METALS DETERMINATION'S

Analysts:

R.T. McClain M.T. Wilkerson J.L. Molnar M.J. ChangLESAT Chemist LESAT Chemist LESAT Chemist LESAT Chemist

Methods: V

Samples 951129-06 through 951129-18, 951130-05 through 951130-12, 951201-09through 951201-14, 951205-06 through 951205-18, 951206-47 through 951206-58,951208-01 through 951208-13, 951215-21 through 951215-30, and 951219-08through 951219-12 from Keystone Sanitation were prepared for analysis by aciddigestion and analyzed by furnace atomic absorption spectroscopy andinductively coupled plasma optical emission spectrometry. The following arethe digestion and analytical techniques and methods employed:

Digestion Methods

Method from CLP SOW 9/91 revision, p. D-5, A.I. for Furnace AAS(excluding antimony)Method from CLP SOW 9/91 revision, p. D-5, A.2. for ICP-AES, Flame AAS,and antimony by Furnace AASMethod 3050, excluding HCl for furnace AAS (excluding antimony) (solidsamples) (1)Method.3Q50, for ICP-AES, Flame AAS, and antimony by Furnace AAS (solidsamples) (1)

Analytical Methods

EPA Method 204.2 and Internal SOP R3-QA132, antimony by Furnace AAS (2)EPA Method 206.2 and Internal SOP R3-QA132, arsenic by Furnace AAS (2)EPA Method 239.2 and Internal SOP R3-QA132, lead by Furnace AAS (2)EPA Method 270.2 and Internal SOP R3-QA132, selenium by Furnace AAS (2)EPA Method 279.2 and Internal SOP R3-QA132, thallium by Furnace AAS (2)EPA Method 200.7 and Internal SOP R3-QA132, remaining elements by ICP-AES (2)

(1) SW-846, 2nd Edition, Test Methods for Evaluating Solid Waste Physical/Chemical Methods

(2) 1979/83 EPA Manual of Methods for Chemical Analysis of Water and Wastes

Results for solid samples are reported in ug/g (ppm) DRY weight at 60 degreescentigrade. This Percent Dry Weight test pertains only to metals results.The drying temperature of 60 degrees centigrade is selected to retain volatileelements. The Percent Dry Weight (60°C) is reported to allow for conversionto wet weight.

AR3I86I5


Quality Control:

Samples analyzed in duplicate (method duplicates) are reported as the Mean andthe Relative Percent Difference (RPD) of the two analytical values. RoutineQuality Control (QC) performed includes preparation and analysis of auditmaterials; check standards; interference check samples (ICS--for ICP-AESonly); method blanks; method spikes; analytical spikes; method duplicates; andanalytical duplicates. Calibration standards for ICP-AES are prepared fromNIST stoetk solutions. Calibration standards for Furnace AAS are prepared fromBaker stocK̂ sSflutions. Method blanks are prepared with each analytical setand are acceptable if they are found to be below the quantification level forthe sample set. '̂ Audit materials are analyzed at the beginning of each run todocument proper instrument calibration. For ICP-AES the acceptable range is90-110% recovery; for other techniques it is the 95* confidence intervalgenerated using the True Values and algorithms from EMSL-Cincinnati. Checkstandards are analyzed periodically (generally a 1/10 frequency) throughoutthe run to document instrumental stability, and are acceptable at 90-110%.The ICS is obtained from EMSL-Las Vegas and is analyzed at the beginning ofeach ICP-AES run to document proper selection of analytical lines, backgroundcorrection factors, and interelement correction factors; it is acceptable at80-120% recovery. The remaining QC items are sample specific and areperformed at a frequency of 1/10 samples for sample sets .> 10 and 1 per sampleset for sample sets


MERCURY DETERMINATIONS

Analyst:

Odis-•*£"±- \LESAT Chemftt

TID #: 03960114

Method:

Samples 951129-06 through 951129-18, 951130-05 through 951130-12, 951201-09through 951201-14, 951205-06 through 951205-18, 951206-47 through 951206-58,951208-01 through 951208-13, 951215-21 through 951215-30 and 951219-08 through951219-12, from Keystone Sanitation were analyzed for total mercury using EPAMethods 245.I1 and 245.51.

Methods for Chemical Analysis of Water and Wastes, EPA 600/4-79-020.

Results for solid samples are reported in ug/g (ppm) DRY weight at 60 degreescentigrade. This Percent Dry Weight test pertains only to metals results.The drying temperature of 60 degrees centigrade is selected to retain volatileelements. The Percent Dry Weight (60°C) is reported to allow for conversionto wet weight.

AR3I86I7


TOTAL CYANIDB DETERMINATIONS

Analyst:*«* - .

Anna Wuerf el"-- - . . Michael ChangLESAT Chemist -.-. LESAT Chemist

\ '

TID #:

03960111

Method:

Samples 951129-06 through 951129-18, 951130-05 through 951130-12, 951201-09through 951201-14, 951205-06 through 951205-18, 951206-47 through 951206-58,951208-01 through 951208-13, 951215-21 through 951215-30, 951219-08 through951219-12 from the Keystone Sanitation site were analyzed for total cyanideusing EPA Method 335.4.

Soil results are reported on a WET weight basis.

The qualifier code "C" was applied to the cyanide results for samples951215-21, 951215-22, 951215-23, 951215-27, 951215-29 because they wereanalyzed two days past holding time.

AR3186I8


PERCENT DRY WEIGHT DETERMINATIONS

Analyst:

William Pabst, IIILESAT Chemist

TID: 03-96'aa>12

Method: ~'\

The soil samples from Keystone Sanitation (Batch ID # REQ96039) were analyzedfor Percent Dry Weight as required by EPA analytical methods. The sampleswere dried at 105°C following the procedure outlined in EPA Region III CentralRegional Laboratory's SOP #R3QA056.0.

These results are to be used to convert analyte concentrations to a dry weightbasis for organic and non-metal analyses. Normally, analytical values arereported on a wet weight basis for organics and non-metals. All metalsreported use a 60°C drying temperature for the percent dry weightdeterminations, as required by the methodology. The 60°C percent dry weightvalues are reported with the metals results, if applicable.

Weighing dishes used for these samples were sequentially numbered, oven-driedovernight at 105°C, and then cooled in a desiccator before the empty dishweight was recorded. Five to ten grams of each sample was then placed on anempty dish and the total weight recorded. The samples were then placed in anoven and oven-dried overnight at 105°C. When the samples were removed fromthe oven they were cooled in a. desiccator before their weight was recorded forthe determination of percent dry weight. All weights were recorded after allappropriate calibration checks were completed on the balance using Class Sweights.

/IR3I86I9

receive'ddear chris corbett^

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