csp’s hazard communication program complies with osha ◦ the general classification of hazardous...
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Hazards Communication Standard
CSP’s Hazard Communication Program complies with Osha◦ The general classification of hazardous material includes
9 Hazard Classes:1. Explosives2. Gases3. Flammable & Combustible liquids4. Flammable solid, spontaneously combustible, Dangerous
when wet5. Oxidizers6. Poisonous7. Radioactive8. Corrosives9. Miscellaneous
Hazards Communication Standard
CSP’s Hazard Communication Program complies with Osha’s HCS by communication to employees the hazards associated with materials used and produced in day to day operation.
The program complements the Hazwooper 24 hour course that each employee must complete before initiating activities in the CSP plant
The main aspects covered in this presentation are:◦ Hazardous materials classification◦ NFPA 704 signs◦ Globally Harmonized System – GHS-; MSDS vs SDS◦ DOT Transportation information, identification and
responsibilities
Hazards Communication Standard
The general classification of hazardous material includes 9 Hazard Classes:1. Explosives2. Gases3. Flammable & Combustible liquids4. Flammable solid, spontaneously combustible,
Dangerous when wet5. Oxidizers6. Poisonous7. Radioactive8. Corrosives9. Miscellaneous
Hazard Communication Program
Hazardous materials found in CSP’s day to day operations:◦ Gases:
Chlorine, Nitrogen, Natural gas, Propane◦ Flammable & Combustible liquids
Diesel Fuel, Inhibitors◦ Oxidizers
Hypochlorite◦ Poisonous
Chlorine◦ Corrosives
Hydrochloric Acid, Caustic soda◦ Miscellaneous
Citric Acid, Compressed Air,
Globally Harmonized System (GHS)
Maintaining a Material Safety Data Sheet (MSDS) for every
hazardous chemical and making them available to employees as
part of OSHA’s Hazards Communication Standard’s Right-to-Know
provisions –.
The provision says that employees have the right to know about
the chemicals to which they are exposed – is one of five key
responsibilities employers have under the HCS
Globally Harmonized System (GHS)
Based on the MSDS provisions in HazCom 1994, there are
currently a number of different MSDS styles and formats in use in
the United States, the most common being the 8 section OSHA
MSDS and the 16 section ANSI standard MSDS.
OSHA’s adoption of GHS via HazCom 2012, mandates the use of a
single GHS format for safety data sheets, a format which features
16 sections in a strict ordering.
Globally Harmonized System (GHS)
“Will we have to have two safety data sheet libraries – one for
MSDSs and one for SDSs?”
The answer is no.
During the transition to HazCom 2012, we will have a mix of non-
GHS formatted and GHS formatted safety data sheets until the
transition is complete and chemical manufacturers have
reclassified all of their chemicals using GHS criteria.
The transition must be completed before June 2016
The 16 sections are as follows:
Globally Harmonized System (GHS)
1. Identification includes product identifier; manufacturer or
distributor name, address, phone number; emergency phone
number; recommended use; restrictions on use.
2. Hazard(s) identification includes all hazards regarding the
chemical; required label elements.
3. Composition/information on ingredients includes
information on chemical ingredients; trade secret claims.
4. First-aid measures includes important symptoms/ effects,
acute, delayed; required treatment.
Globally Harmonized System (GHS)
5. Fire-fighting measures lists suitable extinguishing
techniques, equipment; chemical hazards from fire.
6. Accidental release measures lists emergency procedures;
protective equipment; proper methods of containment and
cleanup.
7. Handling and storage lists precautions for safe handling and
storage, including incompatibilities.
8. Exposure controls/personal protection lists OSHA's
Permissible Exposure Limits (PELs); Threshold Limit Values (TLVs);
appropriate engineering controls; personal protective equipment
(PPE).
Globally Harmonized System (GHS)
Section 9, Physical and chemical properties lists the
chemical's characteristics.
Section 10, Stability and reactivity lists chemical stability and
possibility of hazardous reactions.
Section 11, Toxicological information includes routes of
exposure; related symptoms, acute and chronic effects; numerical
measures of toxicity.
Globally Harmonized System (GHS)
Section 12, Ecological information*
Section 13, Disposal considerations*
Section 14, Transport information*
Section 15, Regulatory information*
Section 16, Other information, includes the date of
preparation or last revision.
Hazardous Material Chlorine
Oxidizer, Poisonous, Corrosive
◦ NFPA RATINGS (SCALE 0-4): HEALTH=4, FIRE=0, REACTIVITY=0
◦ EMERGENCY OVERVIEW: COLOR: yellow or green PHYSICAL FORM: gas ODOR: distinct odor, irritating odor
Hazardous Material Chlorine
o POTENTIAL HEALTH EFFECTS: INHALATION:
SHORT TERM EXPOSURE: burns, chest pain, difficulty breathing, headache, dizziness, hyperactivity, emotional disturbances, bluish skin color, lung damage, death
LONG TERM EXPOSURE: burns, skin disorders, lack of sense of smell, lung damage
◦ SKIN CONTACT: SHORT or LONG TERM EXPOSURE: burns
◦ EYE CONTACT: SHORT or LONGTERM EXPOSURE: burns
Hazardous MaterialChlorine
◦ INGESTION: SHORT or LONG TERM EXPOSURE: ingestion of
harmful amounts is unlikely
◦ FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Oxidizer. May ignite or explode on contact with combustible
materials.
◦ EXTINGUISHING MEDIA: water
Hazardous MaterialNitrogen
Simple asphyxiant by oxygen displacement
◦ NFPA RATINGS (SCALE 0-4): HEALTH=3, FIRE=0, REACTIVITY=0
◦ Appearance: Colorless
◦ Physical State: gas
◦ Odor: Odorless
Hazardous MaterialNitrogen
◦ Main Routes of Exposure: Inhalation Acute Toxicity Chronic Effects: None known Aggravated Medic al Conditions: None known.
◦ FIRST AID MEASURES Eye Contact
None required for gas. If frostbite is suspected, flush eyes with cool water for 15 minutes and obtain immediate medical attention.
Hazardous Material Nitrogen
Skin Contact◦ For suspected frostbite, remove contaminated clothing and flush
affected areas with lukewarm water. DO NOT USE HOT WATER. Seek medical assistance
Inhalation◦ Medical assistance is mandatory in all cases of inhalation
overexposure.◦ Rescue personnel requires self-contained breathing apparatus. ◦ Conscious victims should be assisted to an uncontaminated
area and inhale fresh air. If breathing is difficult, administer oxygen.
◦ Unconscious victims should be moved to an uncontaminated area and, as necessary, given artificial resuscitation and supplemental oxygen.
Hazardous MaterialNitrogen
Nitrogen:
◦ Exposure to oxygen-deficient atmosphere (<19.5%) may cause
dizziness, drowsiness, nausea, vomiting, excess salivation,
diminished mental alertness, loss of consciousness and death.
◦ Exposure to atmospheres containing 8-10% or less oxygen will
bring about unconsciousness without warning and so quickly
that the individuals cannot help or protect themselves. Lack of
sufficient oxygen may cause serious injury or death.
◦ Ingestion: Not an expected route of exposure
Hazardous MaterialNatural Gas
◦ NFPA Rating: HEALTH=1, FIRE=4, REACTIVITY=0
◦ Appearance: Colorless gas
◦ Physical state: Gas Compressed
◦ Odor, Odorless to slightly sweet
◦ Hazard Statement:
Extremely flammable gas, Compressed gas may explode if
heated, May displace oxygen and cause rapid suffocation
Keep away from heat, sparks, open flame, hot surfaces. No
smoking.
Hazardous MaterialNatural Gas
First Aid:◦ Inhalation:
Move injured person into fresh air and keep person calm under observation. If breathing is difficult, give oxygen. Get medical attention if discomfort continues
◦ Skin Contact: Frostbite: Do not remove clothes, but flush with copious
amounts of lukewarm water. ◦ Eye Contact:
Immediately flush eyes with plenty of water for at least 15 min. Get medical attention
◦ Ingestion: Ingestion is unlikely
Hazardous Material Propane
◦ NFPA Ratings: HEALTH=2, FIRE=4, REACTIVITY=0
◦ Appearance: Colorless gas◦ Physical state: Gas Compressed◦ Odor, Odorless to slightly sweet
◦ Eye Contact: Direct contact with liquid propane can result in eye burns
◦ Skin Contact Direct contact with liquid propane can result in skin burns
Hazardous MaterialPropane
◦ Inhalation: This product is classified as a simple asphyxiant. High vapor concentrations may produce a reversible
central nervous system depression (anesthesia). Higher concentrations may produce asphyxiation.
◦ Ingestion: Ingestion is unlikely
Hazardous MaterialCompressed Air
EMERGENCY OVERVIEW: High pressure gas, may accelerate combustion.
POTENTIAL HEALTH EFFECTS INFORMATION: ◦ INHALATION:
At atmospheric pressure air has no adverse health effects.
◦ EYE, Skin, Ingestion: Not Applicable.
Flammable and Combustible LiquidsDiesel
CSP uses Diesel in the emergency power generator
◦ Combustible liquid; vapor may cause flash fire.
◦ Harmful or fatal if swallowed
◦ Can cause eye, skin or respiratory tract irritation.
◦ May be harmful if inhaled or absorbed through the skin.
◦ Overexposure can cause central nervous system (CNS),
depression and/or other target organ effects.
◦ Possible Cancer Hazard
◦ Harmful to aquatic organisms.
Flammable & Combustible liquidsDiesel
Eye Contact
◦ This material can cause eye irritation with tearing,
redness, or a stinging or burning feeling.
◦ Further, it can cause swelling of the eyes with blurred
vision. Effects may become serious with repeated contact Skin Contact
◦ Symptoms include redness, itching, and burning.
◦ It can be absorbed by the skin and produce central
nervous system depression (headache, nausea, fatigue
and/or other symptoms including unconsciousness).
Flammable & Combustible liquidsDiesel
Skin Contact◦ If the skin is damaged, absorption increases.◦ Prolonged and/or repeated contact may cause
severe dermatitis and/or more serious skin disorders.
◦ Chronic symptoms may include drying, swelling, scaling, blistering, cracking, and/or severe tissue damage
Flammable & Combustible liquidsDiesel
Ingestion
◦ If swallowed, may irritate the mouth, throat, and esophagus.
◦ It can be absorbed into the blood stream through the stomach.
Symptoms may include a burning sensation of the mouth and
esophagus, nausea and vomiting. It can cause central nervous
system effects characterized by dizziness, staggering,
drowsiness, delirium and/or loss of consciousness.
◦ Because of the low viscosity, it can enter the lungs directly
by aspiration during swallowing or subsequent vomiting.
◦ Aspiration of a small amount of liquid can cause severe
lung damage and/or death.
Flammable & Combustible liquidsDiesel
FIRST AID MEASURES
◦ Inhalation Move victim to fresh air. If victim is not breathing,
immediately begin rescue breathing.
If breathing is difficult, 100 percent humidified oxygen should be administered by a qualified individual.
Seek medical attention immediately. Keep the affected individual warm and at rest
Flammable & Combustible liquidsDiesel
Eye Contact, First Aid Check for and remove contact lenses. Flush eyes with
water for at least 15 minutes while occasionally lifting and lowering eyelids.
Do not use eye ointment unless directed to by a physician.
Seek medical attention if irritation or pain persists. Skin Contact
Remove contaminated shoes and clothing. Flush affected area with large amounts of water. If skin surface is damaged, seek medical attention. Do not use ointments. If skin surface is not damaged,
clean affected area thoroughly with mild soap and water.
Flammable & Combustible liquidsDiesel
Ingestion, First Aid◦ Do not induce vomiting. If spontaneous vomiting is about
to occur, place victim’s head below knees. ◦ If victim is drowsy or unconscious, place on the left side
with head down. ◦ Never give anything by mouth to a person who is not fully
conscious. ◦ Do not leave victim unattended.◦ Seek medical attention immediately
Flammable & Combustible liquidsAdditives
Additives: ◦ As of Oct 2014 CSP handles the following types of
additives for customers buying Hydrochloric Acid :
Citric Acid, Powder diluted in water (See Miscellaneous at the end of this presentation)
Corrosion inhibitor T-HIB AI 5250
Ecopol-FEAC
Econo-CI300
Flammable & Combustible liquidsAdditives
Inhibitor T-HIB AI 250 Econo – C 1300
◦ NFPA Hazard: Health: 2; Flammability: 3; Reactivity: 0
Hazards:◦ Highly flammable.◦ Eye contact:
Corrosive, causes burns, pain, watering and redness
◦ Skin contact:
Corrosive to skin, causes burns. Toxic in contact with skin. Causes
pain or irritation, redness, dryness, cracking and blistering
Flammable & Combustible liquidsAdditives
Inhibitor T-HIB AI 250 Econo – C 1300
◦ Inhalation:
Toxic by inhalation. Can cause central nervous system depression, May
cause respiratory tract irritation, nausea or vomiting, coughing,
headache, drowsiness, fatigue, dizziness, vertigo and unconsciousness.
First Aid Measures◦ Eyes:
Get medical attention immediately. Flush eyes continuously with
lukewarm water, gently flowing water for at least 15 min while holding
the eye lids open.
Flammable & Combustible liquidsInhibitor T-HIB AI 250
Inhibitor T-HIB AI 250 Econo – C 1300
◦ Skin:
wash affected area with soap and water for at least
15 min. Wash clothing before reuse. Get medical
attention
◦ Inhalation: Move exposed person to fresh air. If not breathing, if breathing
is irregular, or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. Loosen tight
clothing, and get medical attention.
Flammable & Combustible liquidsInhibitor T-HIB AI 205
Inhibitor T-HIB AI 250 Econo – C 1300
◦ Ingestion: Wash out mouth with water. Do not induce vomiting unless
directed to do so by medical personnel. Do not give anything by mouth to an unconscious person. Get medical help.
Fire Fighting◦ Extinguishing Media
Fire can be extinguished using: Water spray, fog or mist. Alcohol resistant foam. Dry chemicals, sand, dolomite etc.
◦ Special Fire Fighting Procedures: Use supplied air respirator if substance is involved in a fire.
Cool containers exposed to flames with water until well after the fire is out.
Hazardous MaterialSodium Hypochlorite
Oxydizers NFPA Rating: Health: 3 Flammability: 0 reactivity 0
Health Hazards:
Prolonged skin contact may cause:
Dermatitis (rash).
Red, dry, itching skin.
Prolonged eyes exposure may cause:
Eye damage.
Hazardous MaterialSodium Hypochlorite
Signs and symptoms of short-term (acute) exposure◦ Inhalation
Severely irritating or corrosive. Could result in pulmonary edema (fluid accumulation). Symptoms may be delayed
◦ Skin: Severely irritating or corrosive. Symptoms may include
redness, blistering, pain and swelling. May be harmful if absorbed through the skin.
◦ Eyes Severely irritating or corrosive. May cause irreversible eye
damage. Symptoms may include severe pain, blurred vision, redness and corrosive damage.
◦ Ingestion : Severely irritating or corrosive. Symptoms may include severe
abdominal pain, nausea and vomiting.
Hazardous MaterialSodium Hypochlorite
Effects of long-term (chronic) exposure◦ Skin
Prolonged skin contact may cause dermatitis (rash), characterized by red, dry, itching
◦ Eyes Prolonged exposure may cause eye damage.
Severely irritating or corrosive. May cause irreversible eye damage. Symptoms may include Severe pain, blurred vision, redness and corrosive damage
Hazardous MaterialSodium hypochlorite
First Aid Measures
◦ Inhalation:
Immediately remove person to fresh air. If breathing has
stopped, give artificial respiration. If breathing is difficult, give
oxygen by qualified medical personnel only. Obtain medical
attention immediately.
◦ Skin contact
Immediately remove contaminated clothing and shoes. Flush
affected skin with gently flowing lukewarm water for at least
20 minutes. Launder contaminated clothing before reuse, or
discard. Obtain medical attention immediately.
Hazardous MaterialSodium Hypochlorite
First Aid Measures
◦ Eye Contact
Flush eyes thoroughly with running water for at least 20
minutes, holding eyelids open to ensure complete flushing.
Obtain medical attention immediately.
◦ Ingestion
Do not induce vomiting. Never give anything by mouth to an
unconscious person. If conscious, give the victim plenty of
water to drink. Obtain medical attention immediately..
Symptoms may include severe abdominal pain, nausea and
vomiting.
Hazardous MaterialSodium hypochlorite
Transportation Information DOT UN number UN1791 UN proper shipping name Hypochlorite Solution Class 8 Transport hazard class(es)
◦ Subsidiary risk -◦ Packing group III
Hazardous MaterialHydrochloric Acid
Corrosive NFPA: Health: 3, Fire: 0, Reactivity: 1
◦ Hazard statement
May be corrosive to metals.
Harmful if swallowed.
Causes severe skin burns
Causes serious eye damage.
Toxic if inhaled.
May cause respiratory irritation.
Hazardous MaterialHydrochloric Acid
First-aid measures
◦ Inhalation
Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Oxygen or artificial respiration if
needed. Do not use mouth-to-mouth method if victim inhaled
the substance.
Induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory
medical device. Call a POISON CENTER or doctor/physician.
Hazardous MaterialHydrochloric Acid
First-aid measures
◦ Skin contact
Take off immediately all contaminated clothing. Rinse skin
with water/shower. Call a physician or poison control center
immediately. Chemical burns must be treated by a physician.
Wash contaminated clothing before reuse.
◦ Eye contact
Immediately flush eyes with plenty of water for at least 15
minutes. Remove contact lenses, if present . Continue rinsing.
Call a physician or poison control center immediately.
Hazardous MaterialHydrochloric Acid
Hydrochloric Acid First-aid measures
◦ Ingestion
Call a physician or poison control center immediately. Rinse
mouth. Do not induce vomiting. If vomiting occurs, keep head
low so that stomach content doesn't get into the lungs.
◦ Most important symptoms/effects, acute and
delayed
Burning pain and severe corrosive skin damage. Causes
serious eye damage. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision. Permanent eye damage
including blindness could result.
Hazardous MaterialHydrochloric Acid
TRANSPORTATION INFORMATION DOT UN number UN1789 UN proper shipping name Hydrochloric Acid Class 8 Transport hazard class(es)
◦ Subsidiary risk -◦ Packing group II
Hazardous MaterialCaustic soda
Caustic Soda NFPA: Health: 3, Fire: 0, Reactivity: 1
Hazards Overview◦ Clear liquid. Odorless.◦ DANGER! Corrosive liquid. ◦ Causes severe skin and eye irritation, possible burns on prolonged
contact. ◦ May be harmful if absorbed through the skin. ◦ Inhalation may cause respiratory tract burns. ◦ Harmful if swallowed. May cause chemical burns of the mouth, throat,
esophagus and stomach.
Hazardous MaterialCaustic Soda
Signs and symptoms of short-term (acute) exposure:◦ Skin
Severely irritating or corrosive. Symptoms may include redness, blistering, pain and swelling. May be
harmful if absorbed through the skin.◦ Eyes
Severely irritating or corrosive. May cause irreversible eye damage. Symptoms may include severe pain, blurred vision, redness and corrosive damage.
◦ Ingestion : Severely irritating or corrosive. Symptoms may
include severe abdominal pain, nausea and vomiting.
Hazardous MaterialCaustic Soda
Inhalation: ◦ Severely irritating or corrosive. Could result in
pulmonary edema (fluid accumulation). Symptoms of pulmonary edema (chest pain, shortness of breath) may be delayed.
Hazardous MaterialCaustic Soda
TRANSPORTATION INFORMATION DOT UN number UN1824 UN proper shipping name Hydrochloric Acid Class 8 Transport hazard class(es)
◦ Subsidiary risk -◦ Packing group II
Hazardous MaterialMiscelaneous
CSP uses a great number of substances in day to day activities.
The substances used in largest volumes have been described above.
Other substance included here is citric acid, discussed below.
For substances used in small quantities during lab analysis, refer to the SDS or MSDS for details.
MiscelaneousAdditives
Ecopol – FEAC Citric Acid Solution
◦ Hazard Overview: Danger! Corrosive liquid. May be fatal if swallowed. Causes severe burns to all areas of contact. Harmful if inhaled. Inhalation may cause lung and tooth damage. Immediately wash areas of contact with plenty of
water for at least 15 minutes. If ingested, give large quantity of water. Do not
induce vomiting.
MiscelaneousAdditives
Ecopol – FEAC Citric Acid Solution
◦ Eye Contact:
May cause severe eye damage followed by loss of sight. Vapors may cause
watering and irritation.
◦ Inhalation:
Vapors may damage the lining of the nose, throat and lungs.
◦ Skin Contact:
May cause serious damage to the skin. Redness, pain, burns.
◦ Ingestion:
Can cause injury leading to sore throat, vomiting and death.
MiscelaneousAdditives
Ecopol – FEAC Citric Acid Solution
◦ Chronic Effects/Carcinogenicity:
Repeated exposures may cause erosion of exposed front
teeth, darkening of skin and chronic inflammation of the nose,
throat and bronchial tubes. ◦ First Aid Measures
Eye Contact: Irrigate immediately with large quantity of water for at least 15
minutes. Get medical attention immediately. Inhalation:
Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen.
MiscelaneousAdditives
Ecopol – FEAC Citric Acid Solution
◦ Skin Contact: Flush with plenty of water for at least 15 minutes. Call a
physician if irritation develops. ◦ Ingestion:
Do not induce vomiting. Give large quantity of water. Call a physician immediately.
Fire Fighting Measures
◦ Extinguishing Media:
Use water spray, dry chemical, alcohol foam, or carbon
dioxide . Water spray can be used to dilute spills to non-
flammable mixtures.
MiscelaneousAdditives
Ecopol – FEAC Citric Acid Solution
◦ Fire & Explosion Hazards:
Above flash point, vapor-air mixtures are explosive within flammable limits.
Contact with strong oxidizers may cause fire. Vapors can flow along surfaces to
distant ignition source and flash back. Reacts with most metals to produce
hydrogen gas, which can form explosive mixture with air
Hazardous MaterialPlacards
Interpretation UN/NA numbers (the four digit number) found on bulk placards
refer to specific chemicals or groups of chemicals and are
assigned by the United Nations and/or the United States
Department of Transportation.
The Online USDOT 2004 Emergency Response Guidebook will help
you find out what the four digit numbers you see on placards
mean. Placard Placement requirement
Placards are required to be posted on all four sides of a “bulk
container” (rail car, truck, intermodal container). Four placards
total
Hazardous MaterialPlacards
Colors Red indicates flammable, Green indicates nonflammable, yellow indicates oxidizer, Blue indicates dangerous when wet, White indicates inhalation hazard and poison, black and white indicates corrosive (acid and caustic), Red and white, flammable solid, spontaneously
combustible, Depending on the color pattern on the placard, white and
yellow indicates radiation or radioactive, Orange indicates explosives, White with black stripes, miscellaneous hazardous
materials, A red and white miscellaneous placard may say
“dangerous” on it.