© 2009 brooks/cole - cengage thermochemistry chapter 6 1
TRANSCRIPT
![Page 1: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/1.jpg)
© 2009 Brooks/Cole - Cengage
Thermochemistry
CHAPTER 6
1
![Page 2: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/2.jpg)
2
© 2009 Brooks/Cole - Cengage
Objectives• Definitions of energy, heat, work and how they
interrelate• 1st Law of Thermodynamics• Heat Capacity• Energy Transfer• Define Universe, System, and Surroundings• Enthalpy• Hess’s Law• Calorimetry
![Page 3: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/3.jpg)
3
© 2009 Brooks/Cole - Cengage
Geothermal power —Wairakei North Island, New Zealand
![Page 4: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/4.jpg)
4
© 2009 Brooks/Cole - Cengage
Ch. 6.1 - Energy & Chemistry
• Burning peanuts supply sufficient energy to boil a cup of water.
• Burning sugar (sugar reacts with KClO3, a strong oxidizing agent)
![Page 5: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/5.jpg)
5
© 2009 Brooks/Cole - Cengage
Energy & Chemistry
• These reactions are PRODUCT FAVORED• They proceed almost completely from reactants
to products, perhaps with some outside assistance.
![Page 6: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/6.jpg)
6
© 2009 Brooks/Cole - Cengage
Energy & Chemistry
ENERGY is the capacity to do work or transfer heat.
HEAT is the form of energy that flows between 2 objects because of their difference in temperature.
Other forms of energy —• light• electrical• kinetic and potential
![Page 7: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/7.jpg)
7
© 2009 Brooks/Cole - Cengage
Potential & Kinetic Energy
Potential energy — energy a motionless body has by virtue of its position.
![Page 8: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/8.jpg)
8
© 2009 Brooks/Cole - Cengage
• Positive and negative particles (ions) attract one another.
• Two atoms can bond
• As the particles attract they have a lower potential energy
Potential Energyon the Atomic
Scale
Potential Energyon the Atomic
Scale
NaCl — composed of Na+ and Cl- ions.
![Page 9: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/9.jpg)
9
© 2009 Brooks/Cole - Cengage
• Positive and negative particles (ions) attract one another.
• Two atoms can bond
• As the particles attract they have a lower potential energy
Potential Energyon the Atomic
Scale
Potential Energyon the Atomic
Scale
![Page 10: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/10.jpg)
10
© 2009 Brooks/Cole - Cengage
Potential & Kinetic EnergyKinetic energy — energy of motion
• Translation
![Page 11: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/11.jpg)
11
© 2009 Brooks/Cole - Cengage
Potential & Kinetic Energy
Kinetic energy — energy of motion.
translate
rotate
vibratetranslate
rotate
vibrate
![Page 12: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/12.jpg)
12
© 2009 Brooks/Cole - Cengage
Kinetic and Potential Energy Summary
• Chemical Energy is due to the potential energy stored in the arrangements of the atoms in a substance.
• If you run a reaction that releases heat, you are releasing the energy stored in the bonds.
• Energy because of temperature is associated with the kinetic (movement) energy of the atoms and molecules.
![Page 13: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/13.jpg)
13
© 2009 Brooks/Cole - Cengage
Internal Energy (E)*Internal Energy (E)*
• PE + KE = Internal energy (E) (1st Law of Thermodynamics)• Internal energy of a chemical
system depends on• number of particles• type of particles• temperature
*Note: Internal energy is sometimes symbolized by U
![Page 14: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/14.jpg)
14
© 2009 Brooks/Cole - Cengage
Internal Energy (E)Internal Energy (E)PE + KE = Internal energy (E)
![Page 15: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/15.jpg)
15
© 2009 Brooks/Cole - Cengage
Internal Energy (E)Internal Energy (E)
• The higher the T the higher the internal energy
• So, use changes in T (∆T) to monitor changes in energy (∆E).
![Page 16: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/16.jpg)
16
© 2009 Brooks/Cole - Cengage
ThermodynamicsThermodynamics• Thermodynamics is the science of
energy transfer as heat.
Heat energy is associated with molecular motions.
Energy transfers as heat until thermal equilibrium is established.
∆T measures energy transferred.
![Page 17: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/17.jpg)
17
© 2009 Brooks/Cole - Cengage
System and Surroundings
• SYSTEM– The object under study
• SURROUNDINGS– Everything outside the
system
![Page 18: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/18.jpg)
18
© 2009 Brooks/Cole - Cengage
Directionality of Energy Transfer
• Energy transfer as heat is always from a hotter object to a cooler one.
• EXOthermic: energy transfers from SYSTEM to SURROUNDINGS.
T(system) goes downT(surr) goes up
![Page 19: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/19.jpg)
19
© 2009 Brooks/Cole - Cengage
Directionality of Energy Transfer
• Energy transfer at heat is always from a hotter object to a cooler one.
• ENDOthermic: heat transfers from SURROUNDINGS to the SYSTEM.
T(system) goes upT (surr) goes down
![Page 20: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/20.jpg)
20
© 2009 Brooks/Cole - Cengage
Energy and Temperature Summary
1) Temperature determines the direction of thermal energy transfer.
2) The higher the temperature of a given object, the greater the thermal energy (molecular motion) of its atoms, ions, or molecules.
![Page 21: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/21.jpg)
21
© 2009 Brooks/Cole - Cengage
Energy and Temperature Summary
3) Heating and cooling are processes by which energy is transferred as heat from an object at higher temperature to one at lower temperature.
• Heat is not a substance but a ‘process quantity.’ That is heating is a process that changes the energy of a system.
![Page 22: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/22.jpg)
22
© 2009 Brooks/Cole - Cengage
Energy & ChemistryEnergy & Chemistry
All of thermodynamics depends on the law of
CONSERVATION OF ENERGY.
• The total energy is unchanged in a chemical reaction.
• If potential energy (PE) of products is less than reactants, the difference must be released as kinetic energy (KE).
![Page 23: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/23.jpg)
23
© 2009 Brooks/Cole - Cengage
Energy Change in Chemical ProcessesEnergy Change in
Chemical Processes
Reactants
Products
Kinetic Energy
PE
Reactants
Products
Kinetic Energy
PE
PE of system dropped. KE increased. Therefore, you often feel a T increase.
![Page 24: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/24.jpg)
24
© 2009 Brooks/Cole - CengagePote
nti
al en
erg
y
Heat
Exothermic Reaction – reaction give off energy.
CH4 + 2O2 CO2 + 2H2O + Heat
CH4 + 2O2
CO2 + 2H2O
![Page 25: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/25.jpg)
25
© 2009 Brooks/Cole - CengagePote
nti
al en
erg
y
Heat
Endothermic Reaction – requires external energy to proceed. Very strong bonds have low potential
energy. N2 + O2 + Heat 2NO
N2 + O2
2NO
![Page 26: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/26.jpg)
26
© 2009 Brooks/Cole - Cengage
UNITS OF ENERGYUNITS OF ENERGY1 calorie = heat required to
raise temp. of 1.00 g of H2O by 1.0 oC.
1000 cal = 1 kilocalorie = 1 kcal
1 kcal = 1 Calorie (a food
“calorie”)But we use the unit called the JOULE
1 cal = exactly 4.184 joules
James Joule1818-1889
![Page 27: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/27.jpg)
27
© 2009 Brooks/Cole - Cengage
Work vs Energy Flow
Copyright © Cengage Learning. All rights reserved
To play movie you must be in Slide Show Mode
![Page 28: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/28.jpg)
28
© 2009 Brooks/Cole - Cengage
• Work = P × A × Δh = PΔV– P is pressure.– A is area.– Δh is the piston moving a
distance.– ΔV is the change in volume.
Work
![Page 29: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/29.jpg)
29
© 2009 Brooks/Cole - Cengage Copyright © Cengage Learning. All rights reserved
• For an expanding gas, ΔV is a positive quantity because the volume is increasing. Thus ΔV and w must have opposite signs:
w = –PΔV • To convert between L·atm and Joules, use 1 L·atm =
101.3 J.
Work
![Page 30: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/30.jpg)
30
© 2009 Brooks/Cole - Cengage Copyright © Cengage Learning. All rights reserved
Which of the following performs more work?
a) A gas expanding against a pressure of 2 atm from 1.0 L to 4.0 L.
b) A gas expanding against a pressure of 3 atm from 1.0 L to 3.0 L.
They perform the same amount of work.
Practice
![Page 31: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/31.jpg)
31
© 2009 Brooks/Cole - Cengage
FIRST LAW OF THERMODYNAMICSFIRST LAW OF
THERMODYNAMICS
∆E = q + w
heat energy transferred
energychange
work doneby the system
Energy is conserved!
![Page 32: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/32.jpg)
32
© 2009 Brooks/Cole - Cengage
energy transfer out(exothermic), -q
energy transfer in(endothermic), +q
SYSTEMSYSTEM
∆E = q + w∆E = q + w
w transfer in(+w)
w transfer out(-w)
![Page 33: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/33.jpg)
33
© 2009 Brooks/Cole - Cengage
Practice Problems• Calculate ΔE, and determine whether the process
is endothermic or exothermic for the following cases.
a)q = 1.62 kJ and w = -874 Jb)A system releases 113 kJ of heat to the
surroundings and does 39 kJ of work on the surroundings.
c)The system absorbs 77.5 kJ of heat while doing 63.5 kJ of work on the surroundings.
![Page 34: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/34.jpg)
34
© 2009 Brooks/Cole - Cengage
Ch. 6.2 - HEAT CAPACITY
The heat required to raise an object’s T by 1 ˚C.
Which has the larger heat capacity?
![Page 35: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/35.jpg)
35
© 2009 Brooks/Cole - Cengage
Specific Heat Capacity
Specific Heat Capacity
How much energy is transferred due to T difference?
The heat (q) “lost” or “gained” is related to a) sample massb) change in T and
c) specific heat capacity (Symbolized by s or Cp)Specific heat capacity =
heat lost or gained by substance (J)
(mass, g)(T change, K)
![Page 36: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/36.jpg)
36
© 2009 Brooks/Cole - Cengage
Specific Heat Capacity
Specific Heat Capacity
Substance Spec. Heat (J/g•K)
H2O 4.184
Ethylene glycol2.39Al 0.897glass 0.84
Aluminum
![Page 37: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/37.jpg)
37
© 2009 Brooks/Cole - Cengage
Specific Heat Capacity Example
Specific Heat Capacity Example
If 25.0 g of Al cool from 310oC to 37oC, what amount of energy (J) is lost by the Al?
Specific heat capacity =
heat lost or gained by substance (J)
(mass, g)(T change, K)
![Page 38: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/38.jpg)
38
© 2009 Brooks/Cole - Cengage
Specific Heat Capacity Example
Specific Heat Capacity Example
If 25.0 g of Al cool from 310 oC to 37 oC, what amount of energy (J) has been transferred by the Al?
heat gain/lose = q = (mass)(Sp. Heat)(∆T) or q = m x Cp x ∆T
where ∆T = Tfinal - Tinitial
q = (25.0 g) (0.897 J/g•K)(37 - 310)K
q = - 6120 J
Notice that the negative sign on q signals heat “lost by” or
transferred OUT of Al.
Notice that the negative sign on q signals heat “lost by” or
transferred OUT of Al.
![Page 39: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/39.jpg)
39
© 2009 Brooks/Cole - Cengage
Specific Heat Capacity Practice
Specific Heat Capacity Practice
In an experiment, it was determined that 59.8 J was required to raise the temperature of 25.0 g of ethylene glycol by 1.00 K. Calculate the specific heat capacity of ethylene glycol from these data.
![Page 40: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/40.jpg)
40
© 2009 Brooks/Cole - Cengage
Energy TransferEnergy Transfer
• Use energy transfer as a way to find specific heat capacity, Cp
• 55.0 g Fe at 99.8 ˚C• Drop into 225 g water at
21.0 ˚C• Water and metal come to
23.1 ˚C• What is the specific heat
capacity of the metal?
![Page 41: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/41.jpg)
41
© 2009 Brooks/Cole - Cengage
Energy Transfer Important Points• Iron and the water are the system, the beaker
holding the water and everything else is the surroundings.
• The iron and water end up at the same temp.• The energy transferred as heat from the iron to the
water is negative (temp of Fe drops). The qwater increase is positive because the temp of water increases.
• The values of qwater and qiron are numerically equal but opposite in sign.
![Page 42: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/42.jpg)
42
© 2009 Brooks/Cole - Cengage
Because of conservation of energy,
q(Fe) = –q(H2O) (energy out of Fe = energy into H2O)
or q(Fe) + q(H2O) = 0
q(Fe) = (55.0 g)(Cp)(23.1 ˚C – 99.8 ˚C)
q(Fe) = –4219 • Cp
q(H2O) = (225 g)(4.184 J/K•g)(23.1 ˚C – 21.0 ˚C)
q(H2O) = 1977 J
q(Fe) + q(H2O) = –4219 Cp + 1977 = 0
Cp = 0.469 J/K•g
Energy TransferEnergy Transfer
![Page 43: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/43.jpg)
43
© 2009 Brooks/Cole - Cengage
ENTHALPYENTHALPYMost chemical reactions occur at constant P, so
and so ∆E = ∆H + w (and w is usually small)
∆H = energy transferred as heat at constant P ≈ ∆E
∆H = change in heat content of the system
∆H = Hfinal - Hinitial
and so ∆E = ∆H + w (and w is usually small)
∆H = energy transferred as heat at constant P ≈ ∆E
∆H = change in heat content of the system
∆H = Hfinal - Hinitial
Heat transferred at constant P = qp
qp = ∆H where H = enthalpy
Heat transferred at constant P = qp
qp = ∆H where H = enthalpy
![Page 44: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/44.jpg)
44
© 2009 Brooks/Cole - Cengage
If Hfinal < Hinitial then ∆H is negative
Process is EXOTHERMIC
If Hfinal < Hinitial then ∆H is negative
Process is EXOTHERMIC
If Hfinal > Hinitial then ∆H is positive
Process is ENDOTHERMIC
If Hfinal > Hinitial then ∆H is positive
Process is ENDOTHERMIC
ENTHALPYENTHALPY∆H = Hfinal – Hinitial
Enthalpy is an extensive property!!
![Page 45: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/45.jpg)
45
© 2009 Brooks/Cole - Cengage
Hydrogen peroxide decomposes to water and oxygen by the following reaction:
2H2O2(l) 2H2O(l) + O2(g) ∆H = -196 kJ–Calculate the value of energy
transferred when 5.00 g of H2O2(l) decomposes at constant pressure.
Hints: What is enthalpy of reaction if only 1 mole of peroxide is decomposed?
Practice Using EnthalpyPractice Using Enthalpy
![Page 46: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/46.jpg)
46
© 2009 Brooks/Cole - Cengage
– Hydrogen peroxide decomposes to water and oxygen by the following reaction:
2H2O2(l) 2H2O(l) + O2(g) ∆H = -196 kJ -196 kJ/2 mol peroxide = -98 kJ/mol of peroxide
5.0 g * (1 mol/34 g H2O2) = 0.147 mol H2O2
= 0.147 mol H2O2 * -98 kJ/mol peroxide
= -14.4 kJHeat is a stoichiometric value which works the
same way as last year.
Practice Using EnthalpyPractice Using Enthalpy
![Page 47: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/47.jpg)
47
© 2009 Brooks/Cole - Cengage
Consider the formation of water
H2(g) + 1/2 O2(g) H2O(g) + 241.8 kJ
USING ENTHALPYUSING ENTHALPY
Exothermic reaction — energy is a “product” and
∆H = – 241.8 kJ
![Page 48: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/48.jpg)
48
© 2009 Brooks/Cole - Cengage
Making liquid H2O from H2 + O2 involves two exothermic steps.
USING ENTHALPYUSING ENTHALPY
H2 + O2 gas
Liquid H2OH2O vapor
![Page 49: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/49.jpg)
49
© 2009 Brooks/Cole - Cengage
Calorimetry
• Definition of calorimetry: measure heat flow in a chemical reaction.
• Two kinds of calorimeters (devices that measure heat flow):–Constant pressure (coffee cup calorimeter)–Constant volume (bomb calorimeter)
• Heat Capacity – amount of heat needed to raise an object’s temperature by 1°C or 1 K.
![Page 50: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/50.jpg)
50
© 2009 Brooks/Cole - Cengage
Constant Pressure Calorimetry
TmC
T
qH P
solution of grams
solution ofheat specificsolnrxn
m = mass of solutionC = heat capacity of the
calorimeter (J/g- C) (or K)⁰∆T = the change in temperature
in C or K⁰
![Page 51: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/51.jpg)
51
© 2009 Brooks/Cole - Cengage
Constant Pressure Calorimetry Practice 1
• When a 9.55 g sample of solid NaOH dissolves in 100.0g of water in a coffee-cup calorimeter, the temperature rises from 23.6˚C to 47.4˚C. Calculate the ΔH (in kJ/mol NaOH) for the solution process
NaOH(s) Na+(aq) + OH-(aq)• Assume the specific heat of the solution is
the same as that for water (4.184 J/g-˚C)• Hint: what is system, what are surroundings?
![Page 52: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/52.jpg)
52
© 2009 Brooks/Cole - Cengage
Constant Pressure Calorimetry Practice 2
• A 150.0 g sample of a metal at 75.0°C is added to 150.0 g H2O at 15.0°C. The temperature of the water rises to 18.3°C. Calculate the specific heat capacity of the metal.
![Page 53: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/53.jpg)
53
© 2009 Brooks/Cole - Cengage
Measuring Heats of ReactionConstant Volume CALORIMETRYConstant Volume CALORIMETRY
![Page 54: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/54.jpg)
54
© 2009 Brooks/Cole - Cengage
Measuring Heats of ReactionCALORIMETRYCALORIMETRY
Constant Volume “Bomb” Calorimeter
• Burn combustible sample.
• Measure heat evolved in a reaction.
• Derive ∆E for reaction.
![Page 55: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/55.jpg)
55
© 2009 Brooks/Cole - Cengage
CalorimetrySome heat from reaction warms waterqwater = (sp. ht.)(water mass)(∆T)
Some heat from reaction warms “bomb”qbomb = (heat capacity, J/K)(∆T)
Total heat evolved = qtotal = qwater + qbomb
![Page 56: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/56.jpg)
56
© 2009 Brooks/Cole - Cengage
Calculate energy of combustion (∆E) of octane. C8H18 + 25/2 O2 8 CO2 + 9 H2O
• Burn 1.00 g of octane
• Temp rises from 25.00 to 33.20 oC
• Calorimeter contains 1200. g water
• Heat capacity of bomb = 837 J/K
Measuring Heats of ReactionCALORIMETRY - Example
Measuring Heats of ReactionCALORIMETRY - Example
![Page 57: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/57.jpg)
57
© 2009 Brooks/Cole - Cengage
Step 1 Calc. energy transferred from reaction to water.
q = (4.184 J/g•K)(1200 g)(8.20 K) = 41,170 J
Step 2 Calc. energy transferred from reaction to bomb.
q = (bomb heat capacity)(∆T) = (837 J/K)(8.20 K) = 6860 JStep 3 Total energy evolved 41,200 J + 6860 J = 48,060 J
Energy of combustion (∆E) of 1.00 g of octane
= - 48.1 kJ
Measuring Heats of ReactionCALORIMETRY - Example
Measuring Heats of ReactionCALORIMETRY - Example
![Page 58: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/58.jpg)
58
© 2009 Brooks/Cole - Cengage
A 1.00 g sample of sucrose (C12H22O11) is burned in a bomb calorimeter. The temperature of 1500. g of water in the calorimeter rises from 25.00˚C to 27.32˚C. The heat capacity of the bomb is 837 J/K and the specific heat capacity of water is 4.18 J/g-K. Calculate the heat evolved a)Per gram of sucroseb)Per mole of sucrose (M = 343 g/mol)
‘BOMB’ CALORIMETRY PRACTICE ‘BOMB’ CALORIMETRY PRACTICE
![Page 59: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/59.jpg)
59
© 2009 Brooks/Cole - Cengage
Making H2O from H2 involves two steps.
H2(g) + 1/2 O2(g) H2O(g) ΔrH˚ =-242 kJ
H2O(g) H2O(liq) ΔrH˚ =-44 kJ
-----------------------------------------------------------------------
H2(g) + 1/2 O2(g) H2O(liq) ΔrH˚ =-286 kJ
Example of HESS’S LAW—If a rxn. is the sum of 2 or more others, the net ∆H is the sum of the ∆H’s of the other rxns.
Ch. 6.3 – Hess’s Law
![Page 60: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/60.jpg)
60
© 2009 Brooks/Cole - CengageCopyright © Cengage Learning. All rights reserved 60
To play movie you must be in Slide Show ModePC Users: Please wait for content to load, then click to play
Hess’s Law
![Page 61: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/61.jpg)
61
© 2009 Brooks/Cole - Cengage
Hess’s Law & Energy Level Diagrams
Forming H2O can occur in a single step or in a two steps. ∆rHtotal is the same no matter which path is followed.
Active Figure 5.16
NOTE: ∆rH stands for the enthalpy change for a
reaction, r
NOTE: ∆rH stands for the enthalpy change for a
reaction, r
![Page 62: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/62.jpg)
62
© 2009 Brooks/Cole - Cengage
Hess’s Law & Energy Level Diagrams
Forming CO2 can occur in a single step or in a two steps. ∆rHtotal is the same no matter which path is followed.
Active Figure 5.16
![Page 63: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/63.jpg)
63
© 2009 Brooks/Cole - Cengage
Enthalpy and Hess’s Law• If a reaction is reversed, the sign of ∆H is also
reversed.
Xe(g) + 2F2(g) XeF4(s) ∆H=-251 kJ
XeF4(s) Xe(g) + 2F2(g) ∆H = +251 kJ• ∆H is also proportional to the quantities of the
reactants and product (mol-rxn). If you multiply the coefficients by an integer, the ∆H value is multiplied by the same integer.
2Xe(g) + 4F2(g) 2XeF4(s) ∆H =-502 kJ
![Page 64: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/64.jpg)
64
© 2009 Brooks/Cole - Cengage
Simple Hess’s Law problem
• C(graphite) + O2(g) → CO2(g)
ΔH° = –393.51 kJ mol–1
• C(diamond) + O2(g) → CO2(g)
ΔH° = –395.40 kJ mol–1
Calculate the ∆H for the conversion of graphite to diamond.
![Page 65: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/65.jpg)
65
© 2009 Brooks/Cole - Cengage
Simple Hess’s Law problem
• C(graphite) + O2(g) → CO2(g)
ΔH° = –393.51 kJ mol–1
• CO2(g) → C(diamond) + O2(g)
ΔH° = +395.40 kJ mol–1
Add rxns together, cancel out substances that appear on both sides and get:
C(graphite) C(diamond) ΔH = 1.9 kJ
![Page 66: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/66.jpg)
66
© 2009 Brooks/Cole - Cengage
Problem-Solving Strategy• Work backward from the required
reaction, using the reactants and products to decide how to manipulate the other given reactions at your disposal.
• Reverse any reactions as needed to give the required reactants and products.
• Multiply reactions to give the correct numbers of reactants and products.
Copyright © Cengage Learning. All rights reserved 66
![Page 67: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/67.jpg)
67
© 2009 Brooks/Cole - Cengage
Given:
C(s) + O2(g) CO2(g) ΔH= -393.5kJ/mol
S(s) + O2(g) SO2(g) ΔH= -296.8 kJ/mol
CS2(l) + 3O2(g) CO2(g) + 2SO2(g)
ΔH = -1103.9 kJ/molUse Hess’s Law to calculate enthalpy change for
the formation of CS2(l) from C(s) and S(s)
C(s) + 2S(s) CS2(l)
Harder Example of Hess’s Law
![Page 68: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/68.jpg)
68
© 2009 Brooks/Cole - Cengage
Multiply equations as needed:
C(s) + O2(g) CO2(g) ΔH= -393.5kJ/mol
2S(s) + 2O2(g) 2SO2(g) ΔH=2*(-296.8 kJ/mol)
=-593.6 kJ
CO2(g) + 2SO2(g) CS2(l) + 3O2(g)
ΔH = 1103.9 kJ/mol
C(s) + 2S(s) CS2(l) ΔH = 116.8 kJ
Reaction 1 was used as is
Reaction 2 was multiplied by 2 (SO2 cancels)
Reaction 3 was multiplied by -1 (Get CS2 on
product side)
![Page 69: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/69.jpg)
69
© 2009 Brooks/Cole - Cengage
• This equation is valid because ∆H is a STATE FUNCTION
• These depend only on the state of the system and not how it got there.
• V, T, P, energy — and your bank account!
• Unlike V, T, and P, one cannot measure absolute H. Can only measure ∆H.
∆H along one path = ∆H along another path
∆H along one path = ∆H along another path
![Page 70: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/70.jpg)
70
© 2009 Brooks/Cole - Cengage
Standard Enthalpy ValuesStandard Enthalpy ValuesMost ∆H values are labeled ∆Ho Measured under standard conditions:
• For a Compound– For a gas, pressure is exactly 1 atm.– For a solution, concentration is exactly 1 M.– Pure substance (liquid or solid)
• For an Element– The form [N2(g), K(s)] in which it exists at 1
atm and 25⁰C.
![Page 71: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/71.jpg)
71
© 2009 Brooks/Cole - Cengage
Ch. 6.4 – Standard Enthalpies of Formation
NIST (Nat’l Institute for Standards and Technology) gives values of
∆Hfo = standard molar enthalpy of
formation— the enthalpy change when 1 mol of compound is formed from elements under standard conditions.
See Appendix 4 (A19 – A22)
![Page 72: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/72.jpg)
72
© 2009 Brooks/Cole - Cengage
∆Hfo, standard molar
enthalpy of formation
H2(g) + 1/2 O2(g) H2O(g)
∆Hfo (H2O, g) = -241.8 kJ/mol
By definition,
∆Hfo
= 0 for elements in their
standard states.
![Page 73: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/73.jpg)
73
© 2009 Brooks/Cole - Cengage
Enthalpy of Formation Practice• Show the ΔHf˚ reaction for the
following compounds:
a) C2H2(g)
b) KCl(s)
• Why is the following not a ΔHf˚?
4Na(s) + O2(g) 2Na2O(s)
![Page 74: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/74.jpg)
74
© 2009 Brooks/Cole - Cengage
Hess’s Law and ΔHf° Practice
Given:
C2H2(g) + 5/2 O2(g) 2CO2(g) + H2O(l)
ΔHr° = -1300. kJ/mol-rxn
C(s) + O2(g) CO2(g) ΔHr° = -394. kJ/mol-rxn
H2(g) + ½O2(g) H2O(l) ΔHr° = -286. kJ/mol-rxn
Determine the ΔHf° for C2H2 (acetylene).
First, determine the overall reaction. Manipulate above reactions to obtain overall reaction.
![Page 75: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/75.jpg)
75
© 2009 Brooks/Cole - Cengage
Hess’s Law and ΔHf° Practice
Answer:-1( ) C2H2(g) + 5/2 O2(g) 2CO2(g) + H2O(l)
![Page 76: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/76.jpg)
76
© 2009 Brooks/Cole - Cengage
Using Standard Enthalpy Values
Using Standard Enthalpy Values
Use ∆H˚’s to calculate enthalpy change for
H2O(g) + C(graphite) H2(g) + CO(g)
(product is called “water gas”)
![Page 77: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/77.jpg)
77
© 2009 Brooks/Cole - Cengage
Using Standard Enthalpy Values
Using Standard Enthalpy Values
H2O(g) + C(graphite) H2(g) + CO(g)
From reference books we find
• H2(g) + 1/2 O2(g) H2O(g)
∆fH˚ of H2O vapor = - 242
kJ/mol
• C(s) + 1/2 O2(g) CO(g)
∆fH˚ of CO = - 111 kJ/mol
![Page 78: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/78.jpg)
78
© 2009 Brooks/Cole - Cengage
Using Standard Enthalpy Values
Using Standard Enthalpy Values
H2O(g) H2(g) + 1/2 O2(g) ∆Hro (= –∆Hr˚) =
+242 kJ
C(s) + 1/2 O2(g) CO(g) ∆Hro = -111 kJ
------------------------------------------------------------------------------------------------------
To convert 1 mol of water to 1 mol each of H2 and CO requires 131 kJ of
energy. The “water gas” reaction is ENDOthermic.
H2O(g) + C(graphite) H2(g) + CO(g)
∆Hronet = +131 kJ
H2O(g) + C(graphite) H2(g) + CO(g)
∆Hronet = +131 kJ
![Page 79: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/79.jpg)
79
© 2009 Brooks/Cole - Cengage
Using Standard Enthalpy Values
Using Standard Enthalpy Values
In general, when ALL
enthalpies of formation are known,
Calculate ∆H of reaction?
∆Hro = ∆fHf
o (products)
- ∆Hfo (reactants)
∆Hro = ∆fHf
o (products)
- ∆Hfo (reactants)
Remember that ∆ always = final – initial
![Page 80: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/80.jpg)
80
© 2009 Brooks/Cole - Cengage
Heats of Reactions(∆H⁰(r or rxn) = generic reaction)
• ∆H⁰combustion or ∆H⁰comb is amount of heat release when 1 mol of a substance is combusted (burned).
Ex: CH4 + 2O2 CO2 + 2H2O(g) ∆H = -890 kJ/mol
• ∆H⁰neutralization is the amount of heat released or absorbed when an acid is neutralized by a base
Ex: HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l)
∆Hneut =-57 kJ/mol-rxn
![Page 81: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/81.jpg)
81
© 2009 Brooks/Cole - Cengage
Heats of (Physical) Process (∆H⁰process = generic process)
• ∆H⁰solution is the amount of heat released or absorbed when a solid compound dissolves and becomes aqueous.
Ex: NaOH(s) Na+(aq) + OH-(aq) ∆H⁰sol = -43 kJ/mol• ∆H⁰fusion is the amount of heat needed to change 1
mole of a solid substance to a liquid, i.e. melting.
Ex: H2O(s) H2O(l) ∆H ⁰fus= 6.0 kJ/mol• ∆H⁰vaporization is the amount of heat needed to change 1
mole of a liquid to a vapor. Can use opposite too.
Ex: H2O(l) H2O(g) ∆H ⁰vap= 40.7 kJ/mol
![Page 82: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/82.jpg)
82
© 2009 Brooks/Cole - Cengage
Using Standard Enthalpy Values
Using Standard Enthalpy Values
Calculate the heat of combustion of
methanol, i.e., ∆Hocomb for
CH3OH(g) + 3/2 O2(g) CO2(g) + 2 H2O(g)
∆Hocomb = ∆Hf
o (prod) - ∆Hf
o (react)
![Page 83: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/83.jpg)
83
© 2009 Brooks/Cole - Cengage
Using Standard Enthalpy Values
Using Standard Enthalpy Values
∆Hocomb = ∆Hf
o (CO2) + 2 ∆Hf
o (H2O)
- {3/2 ∆Hfo
(O2) + ∆Hfo
(CH3OH)}
= (-393.5 kJ) + 2 (-241.8 kJ) - {0 + (-201.5 kJ)}
∆Hocomb = -675.6 kJ per mol of methanol
CH3OH(g) + 3/2 O2(g) CO2(g) + 2 H2O(g)
∆Hocomb = ∆Hf
o (prod) - ∆Hf
o (react)
![Page 84: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/84.jpg)
84
© 2009 Brooks/Cole - Cengage
Using Enthalpies of Formation calculate the Enthalpy of Combustion for the reaction below.
C3H8(g) + 5O2(g)→ 3CO2(g) + 4H2O(l)
ΔH° = 3ΔH°(CO2) + 4 ΔH°(H2O(l))–[ΔH°(C3H8) + 5ΔH°f(O2)]
DHocomb = 3 (-393.5) + 4 (-285.8) – [-103.8 + 5(0)]
• DH˚comb= -2220 kJ
Standard Enthalpy Values Example
products reactantsr f fH n H m H
![Page 85: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/85.jpg)
85
© 2009 Brooks/Cole - Cengage
ΔHrxn = ΔH1 + ΔH2 + ΔH3
![Page 86: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/86.jpg)
86
© 2009 Brooks/Cole - Cengage
Using Enthalpy of Reaction
Think of reaction like this:
3C(s) + 4H2(g) 5O2 3C + 3O2 4H2+2O2
C3H8 + 5O2 3CO2 + 4H2O
ΔrH = -ΔHf1 – ΔHf2 + 3ΔHf3 + 4ΔHf4
= +3ΔHf3 + 4ΔHf4 – (ΔHf1 + ΔHf2)
-ΔHf1° -ΔHf2° 3ΔHf3° 4ΔHf4°
Formation of elements Regroup and form new substances
![Page 87: © 2009 Brooks/Cole - Cengage Thermochemistry CHAPTER 6 1](https://reader033.vdocuments.us/reader033/viewer/2022061516/56649e9e5503460f94b9f644/html5/thumbnails/87.jpg)
87
© 2009 Brooks/Cole - Cengage
Enthalpy Practice Problem
Calculate the standard enthalpy change for the reaction below using the standard enthalpies of formation.
2Al(s) + Fe2O3(s) Al2O3(s) + 2Fe(s)
ΔH°f’s: 0 -825.5 -1675.7 0(kJ/mol)