© 2006, koch membrane systems, inc. all rights reserved. mbr technology for water reuse in...

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© 2006, Koch Membrane Systems, Inc. All rights reserved. © 2006, Koch Membrane Systems, Inc. All rights reserved. in Municipal & Industrial Applications Christoph Kullmann Business Development Manager Submerged PURON ® Membranes Koch Membrane Systems

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© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

MBR Technology for Water Reuse inMunicipal & Industrial ApplicationsMBR Technology for Water Reuse inMunicipal & Industrial Applications

Christoph KullmannBusiness Development Manager

Submerged PURON® MembranesKoch Membrane Systems

Christoph KullmannBusiness Development Manager

Submerged PURON® MembranesKoch Membrane Systems

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Koch Membrane SystemsKoch Membrane Systems

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

MF – UF – NF – ROMF – UF – NF – RO

Hollow fiberHollow fiber SpiralSpiral TubularTubular

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Conventional biological wastewater treatmentConventional biological wastewater treatment

SGFPCBS

= Step screen= Grid and fat removal= Primary clarifier= Biological step

STTC

= Sedimentation tank= Third cleaning step (e.g. filtration + desinfection ozon or UV)

Conventional Process

Raw wastewater

S

Effluent

TCGF PC BS ST

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

First use of membranes in biological WWTFirst use of membranes in biological WWT

SGFPCBS

= Step screen= Grid and fat removal= Primary clarifier= Biological step

STTCMT

= Sedimentation tank= Third cleaning step (e.g. filtration)= Membrane technology

Effluent treatment with membrane technology – tertiary treatment

Raw wastewater

Effluent

S GF PC ST TCBS MT

Permeate

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Raw wastewater

S

Effluent

TCPC BS STGF

What changes if you come to an MBR?What changes if you come to an MBR?

SGFPCBS

= Step screen= Grid and fat removal= Primary clarifier= Biological step

STTC

MT

= Sedimentation tank= Third cleaning step (e.g. filtration + desinfection ozon or UV)= Membrane technology

Membrane bioreactor (MBR)

BSFS MT

Permeate

Combination of biological step and solid liquid separation

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

membrane bioreactor Membrane bioreactorMembrane bioreactor

Advantages of MBR over Conventional WWTP

Advantages of MBR over Conventional WWTP

Considerably improved water quality

Possibility for water reuse

Reduced footprint (approx. 50 %)

Avoids the problem of bulking and floating sludge

conventional plants

primary treatment

biological step clarifier

Conventional plantsConventional plants

Advantages:AdvantagesAdvantages

Lower life-cycle cost than conventional + UF for reuseLower life-cycle cost than conventional + UF for reuseLower life-cycle cost than conventional + UF for reuse

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

MBR with submerged modules - different configurations

MBR with submerged modules - different configurations

RC

RCRLMFNDN

recirculationreturn linemembrane filterNitrificationdenitrification

MFDN N

Internal submerged MBRInternal submerged MBR

RCRL

DN N MF

External submerged MBRExternal submerged MBR

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

The PURON® hollow membraneThe PURON® hollow membrane

SEM photo of pores (~10000x)

Membrane bundleMembrane bundle

SEM photo of pores (~10000x)SEM photo of pores (~10000x)

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Modular design of PURON moduleModular design of PURON module

Fibersupport

air

Permeate

air

Permeate manifolds

air

Membrane bundleMembrane bundle Module rowModule row ModuleModule

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

The PURON® ModuleThe PURON® Module

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Classification of membrane processesClassification of membrane processes

0,050,05

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Comparison microorganisms – membrane poresize

Comparison microorganisms – membrane poresize

poresize ~ 0,01 µm

ultrafiltration

poresize ~ 0,2 µm

microfiltration

E. Coli ~ 0,5 - 1,5 µm

MS2-Virus (Coliphage)~ 0,025 µm

B. Subtilis~ 0,3 µm

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

MBR provides better effluent qualityMBR provides better effluent quality

MLSS content in aeration tank

Ptotal with precipitation

COD

Solids

Parameter

< 5< 20g/l

0,8 – 1,0< 0,3mg/l

40 – 50< 30mg/l

10 –150mg/l

convent. plant

MBR

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Reduced footprintReduced footprint

Space requirements

source: D. Lawrence 2004

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Municipal MBR Kaarst – Germany (80.000 p.e.)

Municipal MBR Kaarst – Germany (80.000 p.e.)

source: N. Engelhardt Erftverband 2004

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Reduction of footprint by MBR technology in Kaarst (Germany, 80,000 p.e.)

Reduction of footprint by MBR technology in Kaarst (Germany, 80,000 p.e.)

Conventional plant Membrane bioreactor plant

source: N. Engelhardt Erftverband 2004

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Market areas for MBR technologyMarket areas for MBR technology

Membranebioreactors

leachate

municipal wastewater textile

industry

industriallaundries

pulp &paper

tank cleaning

beverageindustry

dairyindustry

vegetableindustry

fruitindustry slaughter-

house /rendering

petrochem.industry

chemical industry

pharmac.industry

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Industrial InstallationsIndustrial Installations

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Joe White Maltings (Australia)Joe White Maltings (Australia)

• Malting industry

• PURON® MBR + MegaMagnum® RO

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Joe White Maltings (Australia)Joe White Maltings (Australia)

ProblemProblem

• Expanding production

• Increased demand on fresh water

• Water shortage (Australia)

GoalGoal

• Water savings through partial water recycling by means of RO

• Looking for ideal pretreatment to feed the RO

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

RO Pretreatment OptionsRO Pretreatment Options

PretreatmentBacteria

& SS removal

BOD removal

Small footprint

EconomicsPrevention of

organic fouling & scaling in RO

Conventional – – – – – – –

Convent. + Tertiary 0 0 – – – –

Conv. + Tert. + UF + + + – – – + +

MBR + + + + + + + + +

+ ++ + excellentexcellent ++ goodgood 00 averageaverage – –– – poorpoor –– very poorvery poor

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Joe White Maltings (Australia)Joe White Maltings (Australia)

Fresh water

Steeping

Pre-screening

Wastewater

buffertank

Excess sludge

ROCIP tank

Barley

DischargeProcess

BiologyUF

MBR

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Joe White Maltings (Australia)Joe White Maltings (Australia)

Biological process tankBiological process tank

MegaMagnum RO® elementsMegaMagnum RO® elements

Submerged PURON® modulesSubmerged PURON® modules

© 2006, Koch Membrane Systems, Inc. All rights reserved.

© 2006, Koch Membrane Systems, Inc. All rights reserved.

Joe White Maltings (Australia)Joe White Maltings (Australia)

Commissioning of PURON® modulesCommissioning of PURON® modules